Journal of Electroceramics最新文献

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Quantum insights into physical characteristics for optoelectronic performance of TbSc1 − xMxO3 (Mx = Cr, V; x = 0.25): a DFT approach TbSc1−xMxO3 (Mx = Cr, V; x = 0.25)光电性能物理特性的量子洞察:DFT方法
IF 2.6 4区 材料科学
Journal of Electroceramics Pub Date : 2025-05-24 DOI: 10.1007/s10832-025-00414-z
Ejaz Ahmad Khera, Refka Ghodhbani, Abrar Nazir, Hafiz Muhammad Talha, Iqra Mukhtar, Mumtaz Manzoor, Youssef Bakkour, Ramesh Sharma
{"title":"Quantum insights into physical characteristics for optoelectronic performance of TbSc1 − xMxO3 (Mx = Cr, V; x = 0.25): a DFT approach","authors":"Ejaz Ahmad Khera,&nbsp;Refka Ghodhbani,&nbsp;Abrar Nazir,&nbsp;Hafiz Muhammad Talha,&nbsp;Iqra Mukhtar,&nbsp;Mumtaz Manzoor,&nbsp;Youssef Bakkour,&nbsp;Ramesh Sharma","doi":"10.1007/s10832-025-00414-z","DOIUrl":"10.1007/s10832-025-00414-z","url":null,"abstract":"<div><p>The structural, electronic, and optical characteristics of pure TbScO<sub>3</sub> and TbSc<sub>1-x</sub>M<sub>x</sub>O<sub>3</sub> (M<sub>x</sub> = Cr, V; x = 0.25), in order to enhance the efficiency of Resistive Random Access Memory (RRAM) devices have been examined in this work. Considering the parameters of the WEIN2k software for simulation, all computations have been carried out using the PBE-GGA and TB-mBJ potential. Here, the impact of different M<sub>x</sub> dopants (M<sub>x</sub> = Cr and V) has been noticed, particularly in terms of band gap tuning. Structural and mechanical parameters show structural and thermodynamic stability and a notable decrease in bulk modulus as dopant changes from Cr to V, which improves electrical conductivity. Furthermore, the Pugh and Poisson ratio values depicts that all the examined composites are ductile in nature. The calculated TDOS and band structure outcomes reveal that the band-gap of 3.20, 1.21, and 1.06 eV has been found for pristine TbScO<sub>3</sub>, TbSc<sub>1-x</sub>Cr<sub>x</sub>O<sub>3</sub>, and TbSc<sub>1-x</sub>V<sub>x</sub>O<sub>3</sub>, employing TB-mBJ potential respectively. The reduction in band-gap is because of conducting filaments (CF) that develop in the RRAM gadget’s functional layer. The PDOS results reflect the formation of V.B. and C.B. is due to hybridization of Sc-<i>3d</i>, O-<i>2p</i>, Cr-<i>3d</i>, and V-<i>3d</i> states, oblique with minimum partaking of Tb-<i>6s</i> orbitals. The calculated optical parameters reveal that TbSc<sub>1-x</sub>V<sub>x</sub>O<sub>3</sub> shows 365 nm–12.4 μm (UV-IR) broad range absorption, which makes it a better option for photo influencing going forward, particularly in infrared (IR) RRAM gadgets.</p></div>","PeriodicalId":625,"journal":{"name":"Journal of Electroceramics","volume":"53 4","pages":"496 - 506"},"PeriodicalIF":2.6,"publicationDate":"2025-05-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148061013","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tailoring dielectric and electrical conductivity in dy-doped K0.5Na0.5NbO3 ceramics: insights into rare Earth ion modified lead-free perovskites 镝掺杂K0.5Na0.5NbO3陶瓷的介电和导电性:稀土离子修饰无铅钙钛矿的见解
IF 2.6 4区 材料科学
Journal of Electroceramics Pub Date : 2025-05-24 DOI: 10.1007/s10832-025-00408-x
Pooja Dahiya, Riya Malik, Parveen Yadav, Ashima Hooda, Satish Khasa
{"title":"Tailoring dielectric and electrical conductivity in dy-doped K0.5Na0.5NbO3 ceramics: insights into rare Earth ion modified lead-free perovskites","authors":"Pooja Dahiya,&nbsp;Riya Malik,&nbsp;Parveen Yadav,&nbsp;Ashima Hooda,&nbsp;Satish Khasa","doi":"10.1007/s10832-025-00408-x","DOIUrl":"10.1007/s10832-025-00408-x","url":null,"abstract":"<div><p>Rare earth (RE) element Dy doped K<sub>0.<i>5</i></sub>Na<sub>0.5</sub>NbO<sub>3</sub> (Dy<sub><i>x</i></sub>(K<sub>0.5</sub>Na<sub>0.5</sub>)<sub>1-<i>x</i></sub>NbO<sub>3</sub>) perovskites were synthesized through solid-state reaction method. X-ray diffraction peak profile confirmed phase purity and the crystalline orthorhombic structure of the prepared samples, belonging to the Amm2 space group. The frequency dispersion was exhibited by dielectric constant (ε′) attributed to Maxwell Wagner Space charge polarization. The Dy-KNN1 sample demonstrated the highest dielectric constant (ε´⁓2250 at 100 Hz frequency, at 400 °C temperature) compared to all other prepared samples. Tangent loss (tan δ) also shows similar dispersion to that observed for dielectric constant. The ac conductivity exposed an upward trend with increasing frequency and temperature. The ac conductivity lies within the range of 10<sup>− 3</sup>(Sm<sup>-1</sup>) of prepared samples. The results of E<sub>a</sub> suggest that conductivity property can be attributed to presence of oxygen vacancies. The energy band gap of the samples ranged from 3.15 to 3.47 eV. highlighting their potential for applications in energy conversion and sensing.</p></div>","PeriodicalId":625,"journal":{"name":"Journal of Electroceramics","volume":"53 4","pages":"482 - 495"},"PeriodicalIF":2.6,"publicationDate":"2025-05-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148061012","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evidenced piezoelectricity in pulsed laser deposited perovskite tin titanate on silicon substrate 用脉冲激光在硅衬底上沉积钛酸钙钛锡,证明了其压电性
IF 2.6 4区 材料科学
Journal of Electroceramics Pub Date : 2025-05-23 DOI: 10.1007/s10832-025-00407-y
Priya Ranjan, Surajit Das, Swadesh Paul, Shubhankar Barman, Vishal dev Ashok, Anuja Datta
{"title":"Evidenced piezoelectricity in pulsed laser deposited perovskite tin titanate on silicon substrate","authors":"Priya Ranjan,&nbsp;Surajit Das,&nbsp;Swadesh Paul,&nbsp;Shubhankar Barman,&nbsp;Vishal dev Ashok,&nbsp;Anuja Datta","doi":"10.1007/s10832-025-00407-y","DOIUrl":"10.1007/s10832-025-00407-y","url":null,"abstract":"<div><p>Perovskite-SnTiO<sub>3</sub> (<i>p</i>-SNO), due to its predicted ferroelectricity and possessing low bandgap, remains under continual investigation for the interesting fundamental and functional properties. However, reports of tetragonal <i>p</i>-SNO have always been controversial. Although, phase and subsequently the properties can be associated and modulated by strain engineering; the area remains largely unexplored and hence ferroelectricity as well as piezoelectricity in <i>p</i>-SNO are hardly testified. In the present work, major phase perovskite phase SNO film is grown by the pulsed laser deposition on silicon (100) and the strain and oxygen vacancy induced piezopotential generation and emergence of weak ferroelectricity are reported. Piezoresponse force microscopy (PFM) shows nanoscale domain reversal with a d<sub>33</sub> ~ 15 pm/V, while a minor polarisation of ~ 13 nC/cm<sup>2</sup> is recorded with incipient switching current. The relationships between the structure and the emergent functional properties are verified using finite element analysis, whereas, strain-induced piezoelectricity in this system rests as a significant finding.</p></div>","PeriodicalId":625,"journal":{"name":"Journal of Electroceramics","volume":"53 4","pages":"458 - 470"},"PeriodicalIF":2.6,"publicationDate":"2025-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148060643","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
LiTaO3 doping-induced modifications in structure and electromechanical properties of lead-free BNT-6BT ceramics 掺杂LiTaO3对无铅BNT-6BT陶瓷结构和机电性能的影响
IF 2.6 4区 材料科学
Journal of Electroceramics Pub Date : 2025-05-23 DOI: 10.1007/s10832-025-00413-0
Vishal Rohilla, Mukesh Kumar, Narayan Singh Panwar
{"title":"LiTaO3 doping-induced modifications in structure and electromechanical properties of lead-free BNT-6BT ceramics","authors":"Vishal Rohilla,&nbsp;Mukesh Kumar,&nbsp;Narayan Singh Panwar","doi":"10.1007/s10832-025-00413-0","DOIUrl":"10.1007/s10832-025-00413-0","url":null,"abstract":"<div><p>0.94(Bi<sub>0.5</sub>Na<sub>0.5</sub>TiO<sub>3</sub>) − 0.06(BaTiO<sub>3</sub>), abbreviated as BNT − 6BT, is a ceramic of significant importance due to its promising ferroelectric properties. In this study, LiTaO<sub>3</sub> (LT) was doped in BNT − 6BT according to, (0.94-<i>x</i>)(Bi<sub>0.5</sub>Na<sub>0.5</sub>TiO<sub>3</sub>) − 0.06(BaTiO<sub>3</sub>) − (<i>x</i>)(LiTaO<sub>3</sub>) by changing ‘<i>x</i>’ from 0.00 to 0.05. Samples of each composition were systematically prepared and studied for their structural and electrical properties, including dielectric, ferroelectric, and electric field (E-field) induced strain. Structural characterization by the room temperature X-ray diffraction and <i>Rietveld</i> refinement confirmed the existence of rhombohedral and tetragonal phases. Combining the temperature-dependent dielectric measurements revealed that the ferroelectric to relaxor crossover temperature (<i>T</i><sub>F-R</sub>) decreased towards ambient temperature (~ 25° C) with increasing LT doping. For <i>x</i> ˃ 0.02, <i>T</i><sub>F-R</sub> was decreased below ambient temperature and became not observable. <i>x</i> = 0.03 was found to be a critical concentration for which the dielectric, ferroelectric, and strain properties were found promising. A large E-field-induced strain of 0.49% at 62 kV/cm and a corresponding normalized strain (<i>d</i><sub>33</sub><i>*</i>) of 787 pm/V were achieved, which are high and comparable to many lead-based ceramics at room temperature. Based on the results obtained, it seems that the ceramic BNT-6BT ceramic doped with 3 at. % of LiTaO<sub>3</sub> (BNT-6BT-3LT) is a good contender for piezoelectric applications. Further, the study indicated that the mixing of LT in the BNT − 6BT attributed to the transformation of long-range ferroelectric orders to polar nano-regions relaxor; therefore, it can enhance the physical properties of BNT − 6BT ceramic.</p></div>","PeriodicalId":625,"journal":{"name":"Journal of Electroceramics","volume":"53 4","pages":"471 - 481"},"PeriodicalIF":2.6,"publicationDate":"2025-05-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148060642","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Reduced graphene oxide and fullerene-coated Mn-Doped ZrO₂: A synergistic approach to advanced supercapacitors 还原氧化石墨烯和富勒烯包覆mn掺杂ZrO 2:先进超级电容器的协同方法
IF 2.6 4区 材料科学
Journal of Electroceramics Pub Date : 2025-05-20 DOI: 10.1007/s10832-025-00410-3
Maria Sadiq, Ahmad M. Saeedi, Raed H. Althomali, Gideon F. B. Solre, Sana Ullah Asif, Majed M. Alghamdi, Adel A. El-Zahhar
{"title":"Reduced graphene oxide and fullerene-coated Mn-Doped ZrO₂: A synergistic approach to advanced supercapacitors","authors":"Maria Sadiq,&nbsp;Ahmad M. Saeedi,&nbsp;Raed H. Althomali,&nbsp;Gideon F. B. Solre,&nbsp;Sana Ullah Asif,&nbsp;Majed M. Alghamdi,&nbsp;Adel A. El-Zahhar","doi":"10.1007/s10832-025-00410-3","DOIUrl":"10.1007/s10832-025-00410-3","url":null,"abstract":"<div><p>Electrolytes for the fuel cell and supercapacitors are very vital in searching for green energy solutions for the demands on the energy scale. This paper presents the synthesis of zirconium oxide (Zr) and manganese-doped zirconium oxide (MnZr), which was further improved in binary composites with reduced graphene oxide (MnZr/rGO), and fullerene (MnZr/C60), by employing a sol–gel technique. XRD revealed a crystalline structure, while FTIR confirmed the presence of functional groups. SEM images showed uniform aggregation and I-V measurements indicated that all synthesized composites had an ohmic behavior. The state of elements is analyzed by using XPS, and BET analysis evaluates the pore radius and surface area. Cyclic voltammetry, galvanostatic charge–discharge, and electrochemical impedance spectroscopy are used to evaluate the electrochemical performances. Among the composites, MnZr/C60 delivered an excellent specific capacitance of 1296 F/g at 5 mV/s. These results indicate that MnZr/C60 nanocomposite materials might be of great use in further developing the technology of supercapacitors and the enhancement of energy storage performance.</p></div>","PeriodicalId":625,"journal":{"name":"Journal of Electroceramics","volume":"53 4","pages":"444 - 457"},"PeriodicalIF":2.6,"publicationDate":"2025-05-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148061092","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Diffuse phase transition and ferroelectric/piezoelectric properties of Pr-doped 28PIN-38PMN-34PT ceramics 掺pr 28PIN-38PMN-34PT陶瓷的扩散相变和铁电/压电性能
IF 2.6 4区 材料科学
Journal of Electroceramics Pub Date : 2025-05-13 DOI: 10.1007/s10832-025-00409-w
Hongle Fan, Bangxian Xie, Renjun Xu, Chunming Chen, Aihong Yang, Xueli Cao, Laijun Liu
{"title":"Diffuse phase transition and ferroelectric/piezoelectric properties of Pr-doped 28PIN-38PMN-34PT ceramics","authors":"Hongle Fan,&nbsp;Bangxian Xie,&nbsp;Renjun Xu,&nbsp;Chunming Chen,&nbsp;Aihong Yang,&nbsp;Xueli Cao,&nbsp;Laijun Liu","doi":"10.1007/s10832-025-00409-w","DOIUrl":"10.1007/s10832-025-00409-w","url":null,"abstract":"<div><p>Transparent piezoelectric ceramic Pb(In<sub>1/2</sub>Nb<sub>1/2</sub>)O<sub>3</sub>-Pb(Mg<sub>1/3</sub>Nb<sub>2/3</sub>)O<sub>3</sub>-PbTiO<sub>3</sub> (PIN-PMN-PT) can couple several physical effects such as acoustics, optics, mechanics and electricity, which can be used as mechanical-electro-optical multifunctional devices. The diffuse phase transition induced by composition has a significant impact on piezoelectric/ferroelectric properties. In this paper, we found a dramatic influence of Pr on the diffusion phase transition and electric properties of 28PIN-38PMN-34PT-<i>x</i>Pr. A phase coexistence of rhombohedral and tetragonal with trace of pyrochlore phase appears in the system, and the fraction of rhombohedral phase increases firstly and then decreases with the increase of Pr. Temperature dependence of dielectric permittivity exhibits a clear change from diffusion phase transition behavior (0%≦<i>x</i> ≦ 1.5%) to frequency dispersion behavior (2%≦<i>x</i> ≦ 3.5%). The size of polar nanoregions (PNRs) remains unchanged for <i>x</i> ≦ 1.5% characterized by the phenomenological statistical model, and it decreases first and then increases for <i>x</i> ≧ 1.5%, which is consistent with the trend of spontaneous polarization and piezoelectric coefficient having the same change with PNRs. This work gives an insight on the relationship between electrical properties and phase structure modified by composition in perovskite oxides.</p></div>","PeriodicalId":625,"journal":{"name":"Journal of Electroceramics","volume":"53 4","pages":"433 - 443"},"PeriodicalIF":2.6,"publicationDate":"2025-05-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148061032","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrodeposition of fabricated tin sulfide nanoparticles on graphene oxide and natural fibers based robust freestanding electrodes for flexible energy storage devices 制备的硫化锡纳米颗粒电沉积在氧化石墨烯和天然纤维上,用于柔性储能装置的坚固独立电极
IF 2.6 4区 材料科学
Journal of Electroceramics Pub Date : 2025-05-09 DOI: 10.1007/s10832-025-00404-1
Sameen Ilyas, Fatima Kainat, Sadaf Manzoor, I. Sultana, Imran Rafiq, Naushad Ahmad, Shahid M. Ramay, Aamir Razaq
{"title":"Electrodeposition of fabricated tin sulfide nanoparticles on graphene oxide and natural fibers based robust freestanding electrodes for flexible energy storage devices","authors":"Sameen Ilyas,&nbsp;Fatima Kainat,&nbsp;Sadaf Manzoor,&nbsp;I. Sultana,&nbsp;Imran Rafiq,&nbsp;Naushad Ahmad,&nbsp;Shahid M. Ramay,&nbsp;Aamir Razaq","doi":"10.1007/s10832-025-00404-1","DOIUrl":"10.1007/s10832-025-00404-1","url":null,"abstract":"<div><p>Graphene-oxide (GO) based composites exhibit promising energy storage properties like adaptable porosity, chemical stability, excellent conductivity, and exceptional ability to charge storage processes. However, the inherent rigid structure of GO limits its use for modern flexible and disposable energy storage devices. This study presents the fabrication of Graphene oxide/tin sulfide-based flexible composites by employing natural fibers (as a binder) extracted from wasted bioresources (banana peels). GO and tin sulfide (SnS) nanoparticles are synthesized by a facile and fast microwave-assisted approach. Furthermore, SnS nanoparticles are deposited electrochemically on fabricated GO-based paper electrodes to enhance their electronic conductivity and energy storage characteristics. Highly flexible paper-based electrodes are characterized by different characterization techniques, i.e., scanning electron microscopy (SEM), Fourier transform infrared (FTIR) spectroscopy, and RAMAN spectroscopy to observe their morphology and chemical bonding. Electrochemical measurements, including Cyclic voltammetry (CV), galvanostatic charge/discharge (GCD), and electrochemical impedance spectroscopy (EIS), are performed to observe the kinetics and capacitive behavior of the electrodes. LC/GO/SnS 2400 s exhibit specific capacitance of 68.78 F/g at which is greater than GO/LC (30.97 F/g). Prepared tertiary composite (GO/LC/SnS) depicts excellent charge-discharge behavior. LC/GO/SnS 2400 s reveals power density of 84.6 W/kg at 4.57 Wh/kg and also show specific capacitance of 55.4 F/g. Superior electrochemical characteristics are indicated by the GO/LC/SnS (2400 s) electrode and lower Rs (0.89Ω) and Rct(1.7Ω) values as compared to the binary composite (GO/LC). These composites provide a deep insight into the construction of electrodes with high ionic/electronic conductivity for fast-charging energy storage devices.</p></div>","PeriodicalId":625,"journal":{"name":"Journal of Electroceramics","volume":"53 3","pages":"393 - 403"},"PeriodicalIF":2.6,"publicationDate":"2025-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145100681","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of electrical and optoelectronic properties of NaCo₂O₄ ceramic based device for functional applications NaCo₂O₄功能性陶瓷器件的电学和光电子性能研究
IF 2.6 4区 材料科学
Journal of Electroceramics Pub Date : 2025-05-09 DOI: 10.1007/s10832-025-00405-0
Mehmet Okan Erdal, Ali Akbar Hussaini, Adem Koçyiğit, Kemal Doğan, Murat Yıldırım
{"title":"Investigation of electrical and optoelectronic properties of NaCo₂O₄ ceramic based device for functional applications","authors":"Mehmet Okan Erdal,&nbsp;Ali Akbar Hussaini,&nbsp;Adem Koçyiğit,&nbsp;Kemal Doğan,&nbsp;Murat Yıldırım","doi":"10.1007/s10832-025-00405-0","DOIUrl":"10.1007/s10832-025-00405-0","url":null,"abstract":"<div><p>This study investigates the electrical and optoelectronic properties of an Al/NaCo₂O₄/n-Si heterojunction device for photodetection applications. NaCo₂O₄ powder was synthesized via sol-gel electrospinning and characterized by XRD, UV-Vis, FESEM, and EDX, confirming phase purity and revealing a wide bandgap of 3.81 eV. The material was deposited on n-Si by ultrasonic spray pyrolysis to fabricate a Schottky diode, which exhibited exceptional photodiode and broadband photodetector performance. Under 2 V bias, the device achieved a high responsivity of 2.98 A/W and detectivity of 3.95 × 10¹¹ Jones. At zero bias, it demonstrated broadband sensitivity from UV to near-infrared (1100 nm), with responsivity of 1.25 mA/W and detectivity of 1.02 × 10⁹ Jones. Frequency-dependent transient measurements (100–1000 kHz) revealed ultrafast response, with rise/fall times improving from 133.9 ns/2.77 µs at 100 kHz to 36.7 ns/165 ns at 1 MHz. Impedance spectroscopy further elucidated the device’s capacitive behavior. These results position the NaCo₂O₄-interlayered heterojunction as a promising candidate for high-speed photodiodes, broadband photodetectors, and fast-switching devices.</p></div>","PeriodicalId":625,"journal":{"name":"Journal of Electroceramics","volume":"53 4","pages":"417 - 432"},"PeriodicalIF":2.6,"publicationDate":"2025-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10832-025-00405-0.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148060851","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Exploring thermally stable dielectric and energy storage response of Bi-based ceramics for renewable energy storage applications 探索可再生能源存储应用中铋基陶瓷的热稳定介电和储能响应
IF 2.6 4区 材料科学
Journal of Electroceramics Pub Date : 2025-05-07 DOI: 10.1007/s10832-025-00402-3
Ali Ahmad Khan, Muhammad Salman Habib, Muhammad Asif Rafiq, Adnan Maqbool, Muhammad Asif Hussain, Rizwan Ahmed Malik, Mohsin Saleem, Imran Hussain Khan, Mahnoor Nawaz
{"title":"Exploring thermally stable dielectric and energy storage response of Bi-based ceramics for renewable energy storage applications","authors":"Ali Ahmad Khan,&nbsp;Muhammad Salman Habib,&nbsp;Muhammad Asif Rafiq,&nbsp;Adnan Maqbool,&nbsp;Muhammad Asif Hussain,&nbsp;Rizwan Ahmed Malik,&nbsp;Mohsin Saleem,&nbsp;Imran Hussain Khan,&nbsp;Mahnoor Nawaz","doi":"10.1007/s10832-025-00402-3","DOIUrl":"10.1007/s10832-025-00402-3","url":null,"abstract":"<div><p>Renewable energy is accelerating rapidly, driven by the urgent need to mitigate environmental depletion, which has intensified the demand to produce environment-friendly perovskite materials. Among the promising candidates, undoped bismuth sodium titanate-strontium titanate 0.74Bi<sub>0.5</sub>Na<sub>0.5</sub>TiO<sub>3</sub>–0.26SrTiO<sub>3</sub> (BNST) ceramics and niobium-doped BNST (BNST–Nb) ceramics have emerged as innovative materials that were prepared using mixed oxide solid-state synthesis. The X-ray diffraction (XRD) confirmed the phase structure of BNST–Nb, while the dense microstructure with equiaxed grain size was confirmed by scanning electron microscopy (SEM). The electrochemical impedance spectroscopy (EIS) confirmed that electrical microstructure explained the grain and grain boundary contribution. Increasing temperature, with increased Nb content in BNST, predicts a dielectric constant (<i>ε</i><sub><i>r</i></sub> ̴ 3000), and curie temperature (<i>T</i><sub>c</sub> ̴ 250 ℃) for 0.5% Nb. It has an energy density (<i>W</i>) of 0.6 J/cm<sup>3</sup> and an efficiency (<i>η</i>) of 93% was observed. Niobium-doped BNST ceramics have specific benefits over other materials, especially for high-temperature applications at 500 ℃. Unlike many typical ceramics, which deteriorate at high temperatures, BNST-Nb retains and even improves its dielectric characteristics. The investigation of charge conduction and polarization at high temperatures yields novel insights, making BNST–Nb a viable material for advanced thermal and electrical applications.</p></div>","PeriodicalId":625,"journal":{"name":"Journal of Electroceramics","volume":"53 3","pages":"377 - 392"},"PeriodicalIF":2.6,"publicationDate":"2025-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145100733","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Exploring the first order reversal curves of Mn, Nd doped CoFe2O4–Yb doped PbZrTiO3 based composites 探索Mn, Nd掺杂CoFe2O4-Yb掺杂PbZrTiO3基复合材料的一阶反转曲线
IF 2.6 4区 材料科学
Journal of Electroceramics Pub Date : 2025-04-30 DOI: 10.1007/s10832-025-00403-2
Nahida Hassan, Rubiya Samad, Basharat Want
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