Journal of Electroceramics最新文献

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Effect of Dy3+ ions substitution on structural, electrical, and dielectric properties of SrDyxFe12-xO19 hexaferrite prepared by sol-gel combustion method Dy3+离子取代对溶胶-凝胶燃烧法制备SrDyxFe12-xO19六铁氧体结构、电学和介电性能的影响
IF 1.7 4区 材料科学
Journal of Electroceramics Pub Date : 2023-07-03 DOI: 10.1007/s10832-023-00320-2
Jayashri Mahapatro, Sher Singh Meena, Sadhana Agrawal
{"title":"Effect of Dy3+ ions substitution on structural, electrical, and dielectric properties of SrDyxFe12-xO19 hexaferrite prepared by sol-gel combustion method","authors":"Jayashri Mahapatro,&nbsp;Sher Singh Meena,&nbsp;Sadhana Agrawal","doi":"10.1007/s10832-023-00320-2","DOIUrl":"10.1007/s10832-023-00320-2","url":null,"abstract":"<div><p>The substitution of Dy<sup>3+</sup> ions in the M-type hexaferrite structure has been successfully synthesized by sol-gel combustion method according to the formula SrDy<sub>x</sub>Fe<sub>12-x</sub>O<sub>19</sub> (<i>x</i> = 0.0, 0.08, 0.16, 0.24, 0.32, and 0.40). The XRD analysis confirmed the formation of single-phase M-type hexagonal structures up to <i>x</i> = 0.24 compositions. The average crystallite size for the SrDy<sub>x</sub>Fe<sub>12-x</sub>O<sub>19</sub> samples ranges from 90.64 to 290.04 nm, whereas the value of the lattice parameters 'a' and 'c' vary from 5.8590 - 5.8879 Å and 22.9675 - 23.0761 Å, respectively. Scanning electron microscopy (SEM) was used for morphological analysis. Due to ceasing effect of polarization, the dielectric constant decreases in the higher frequencies. The SrDy<sub>x</sub>Fe<sub>12-x</sub>O<sub>19</sub> hexaferrites exhibit non-Debye type dielectric relaxation behavior confirmed by complex impedance spectroscopy (CIS) investigation. The SrDy<sub>x</sub>Fe<sub>12-x</sub>O<sub>19</sub> samples can be utilized as a promising material for various device applications due to a decrease in dielectric loss and an increase in dielectric constant with increasing Dy<sup>3+</sup> ions concentration.</p></div>","PeriodicalId":625,"journal":{"name":"Journal of Electroceramics","volume":"51 2","pages":"104 - 121"},"PeriodicalIF":1.7,"publicationDate":"2023-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47406848","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structural and electrical aspects of microwave sintered (Ba1-xCaxSn0.09 Ti0.91) O3 ceramics 微波烧结(Ba1-xCaxSn0.09 Ti0.91) O3陶瓷的结构和电学特性
IF 1.7 4区 材料科学
Journal of Electroceramics Pub Date : 2023-06-19 DOI: 10.1007/s10832-023-00319-9
Vaishnavi Khade, Madhuri Wuppulluri
{"title":"Structural and electrical aspects of microwave sintered (Ba1-xCaxSn0.09 Ti0.91) O3 ceramics","authors":"Vaishnavi Khade,&nbsp;Madhuri Wuppulluri","doi":"10.1007/s10832-023-00319-9","DOIUrl":"10.1007/s10832-023-00319-9","url":null,"abstract":"<div><p>Barium titanate ceramics with A- site and B-site substitutions are intriguing alternative to lead-based Pb (Zr, Ti) O<sub>3</sub> (PZT) because of its comparable properties to soft-PZTs. In this paper, (Ba<sub><i>x</i></sub>Ca<sub>1-<i>x</i></sub>Sn<sub>0.09</sub> Ti<sub>0.91</sub>) O<sub>3</sub> (<i>x</i> = 0.0525, 0.0575, 0.060) ceramics are prepared using a solid-state reaction technique followed by microwave sintering at 1350 °C for 30 minutes. Structural and electrical properties are investigated. X -ray diffraction shows that the compositions exhibit a tetragonal crystal structure having P4mm symmetry. Temperature dependent dielectric constant measurements in the temperature range of 25 °C to 120 °C shows high dielectric constant of 26250 at 40kHz for BCST ceramics with <i>x</i>=0.0525 and the Curie temperature T<sub>c</sub> increases with Ca concentration. The results of dielectric measurements as a function of frequency are also reported. The dielectric loss (tan δ) values in the temperature range 25 °C to 120 °C are observed to be less than 0.03, for all BCST ceramics. The AC conductivity, impedance spectroscopy studies and the conduction mechanism on the basis of Arrhenius plot are discussed in the above-mentioned temperature range.</p></div>","PeriodicalId":625,"journal":{"name":"Journal of Electroceramics","volume":"51 2","pages":"90 - 103"},"PeriodicalIF":1.7,"publicationDate":"2023-06-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47637426","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of K0.5Bi0.5TiO3 on energy storage properties and temperature stability of Bi0.5Na0.5TiO3-Bi0.2Sr0.7TiO3 ceramics K0.5Bi0.5TiO3对Bi0.5Na0.5TiO3-Bi0.2Sr0.7TiO3陶瓷储能性能和温度稳定性的影响
IF 1.7 4区 材料科学
Journal of Electroceramics Pub Date : 2023-06-10 DOI: 10.1007/s10832-023-00318-w
Xiaofang Zhang, Weimin Xia, Yuanqing Chen, Yannan Liang
{"title":"Effect of K0.5Bi0.5TiO3 on energy storage properties and temperature stability of Bi0.5Na0.5TiO3-Bi0.2Sr0.7TiO3 ceramics","authors":"Xiaofang Zhang,&nbsp;Weimin Xia,&nbsp;Yuanqing Chen,&nbsp;Yannan Liang","doi":"10.1007/s10832-023-00318-w","DOIUrl":"10.1007/s10832-023-00318-w","url":null,"abstract":"<div><p>In order to improve the energy storage performance of Bi-based lead-free ceramics in dielectric capacitors, K<sub>0.5</sub>Bi<sub>0.5</sub>TiO<sub>3</sub> is doped into Bi<sub>0.5</sub>Na<sub>0.5</sub>TiO<sub>3</sub>-Bi<sub>0.2</sub>Sr<sub>0.7</sub>TiO<sub>3</sub> (NBT-SBT) ceramics. We find that NBT-SBT-xK<sub>0.5</sub>Bi<sub>0.5</sub>TiO<sub>3</sub> (NBT-SBT-xBKT, x=0, 0.02, 0.03, 0.05 and 0.08) ceramic sheets maintain the perfect pure perovskite structures and show the character of relaxor ferroelectrics, indicating that the doped K<sup>+</sup> ions smoothly infiltrate into the host lattice of binary system NBT-SBT ceramics and then disturb the long-range order of ferroelectric material and cause the lattice deformation in NBT-SBT. As such, the NBT-SBT-0.03BKT ceramic sample obtains dielectric constant (<i>ε</i><sub>r</sub>) of 1736, dielectric loss (tanδ) of 0.05, and energy storage efficiency (η) of 70.7%, respectively. More strikingly, NBT-SBT-xBKT ceramics exhibit excellent temperature stability, which helps to store energy at high temperatures. This paper can provide an effective method for manufacturing ceramic based capacitors with high energy storage property.</p></div>","PeriodicalId":625,"journal":{"name":"Journal of Electroceramics","volume":"51 2","pages":"80 - 89"},"PeriodicalIF":1.7,"publicationDate":"2023-06-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46759291","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Shielding effectiveness of 0.96 MxMg1−xTiO3 - 0.04 SrTiO3 solid solutions in Ku and K frequency band (12.40 GHz-18.00 GHz) 0.96 MxMg1−xTiO3 - 0.04 SrTiO3固溶体在Ku和K频段(12.40 GHz-18.00 GHz)的屏蔽效能
IF 1.7 4区 材料科学
Journal of Electroceramics Pub Date : 2023-06-09 DOI: 10.1007/s10832-023-00316-y
Komal Sharma, Hardeep Kaur, Shalini Bahel
{"title":"Shielding effectiveness of 0.96 MxMg1−xTiO3 - 0.04 SrTiO3 solid solutions in Ku and K frequency band (12.40 GHz-18.00 GHz)","authors":"Komal Sharma,&nbsp;Hardeep Kaur,&nbsp;Shalini Bahel","doi":"10.1007/s10832-023-00316-y","DOIUrl":"10.1007/s10832-023-00316-y","url":null,"abstract":"<div><p>In this research work, the microwave dielectric and shielding properties of (0.96M<sub>x</sub>Mg<sub>1-x</sub>TiO<sub>3</sub> – 0.04SrTiO<sub>3</sub>) (M = 0, x = 0.0; M = Zn, x = 0.05; M = Zn, x = 0.075; M = Co, x = 0.05; and M = Co, x = 0.075) solid solutions were studied in a Ku and K frequency band using a vector network analyzer. The samples were prepared via the auto-ignition combustion method and sintered at a temperature of 1200°C for 4 hours. An investigation of the shielding properties revealed that these materials' shielding effectiveness (SE) varied as a function of composition and frequency. The shielding analysis exhibited that compositions (M = Zn, x = 0.05) and (M = Co, x = 0.05) showed maximum shielding effectiveness by providing SE &gt; 10 dB for a bandwidth of 2.72 GHz and 4.48 GHz, respectively. The highest SE was observed for composition (M = Co, x = 0.05) at a frequency of 17.21 GHz with SE~31.05 dB corresponding to a restriction of 99.81 % of incident power. These compositions are proposed as effective shielding materials for electromagnetic radiations in Ku-band and K-band.</p></div>","PeriodicalId":625,"journal":{"name":"Journal of Electroceramics","volume":"51 2","pages":"71 - 79"},"PeriodicalIF":1.7,"publicationDate":"2023-06-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42627900","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Phase compositions and dielectric properties of Li2Mg3Sn1 − xO6 ceramics attained by reaction sintering process Li2Mg3Sn1的相组成和介电性能 − 反应烧结法制备xO6陶瓷
IF 1.7 4区 材料科学
Journal of Electroceramics Pub Date : 2023-06-06 DOI: 10.1007/s10832-023-00317-x
Yu Zhang, Jianli Ma, Chang Li, Chen Chen, Yubin She
{"title":"Phase compositions and dielectric properties of Li2Mg3Sn1 − xO6 ceramics attained by reaction sintering process","authors":"Yu Zhang,&nbsp;Jianli Ma,&nbsp;Chang Li,&nbsp;Chen Chen,&nbsp;Yubin She","doi":"10.1007/s10832-023-00317-x","DOIUrl":"10.1007/s10832-023-00317-x","url":null,"abstract":"<div><p>The reaction sintering, without calcination and following re-grinding, has been paid increasing attention. Non - stoichiometric Li<sub>2</sub>Mg<sub>3</sub>Sn<sub>1 − <i>x</i></sub>O<sub>6</sub> (<i>x</i> = 0.00, 0.02, 0.04, 0.06, 0.08, 0.10) ceramics were successfully gained through reaction sintering process in the study, and its phase composition, morphology and dielectric characteristics were studied. This XRD patterns of Li<sub>2</sub>Mg<sub>3</sub>Sn<sub>1 − <i>x</i></sub>O<sub>6</sub> samples prepared after sintering at 1,305 ℃ for 6 h indicates that green bodies are mainly composed of Li<sub>2</sub>Mg<sub>3</sub>SnO<sub>6</sub> phase, accompanied by the second phase of Mg<sub>2</sub>SnO<sub>4</sub>. A host of pores, elliptic - like grains and wrinkle - like grains were visibly observed from the SEM images of Li<sub>2</sub>Mg<sub>3</sub>Sn<sub>1 − <i>x</i></sub>O<sub>6</sub> ceramics, which is because of the severe volatilization of Li elements at high temperature. The apparent density, relative permittivity, quality factor and temperature coefficient of resonant frequency of samples will be devastate owing to porous morphology and Mg<sub>2</sub>SnO<sub>4</sub> phase to a large extent. Finally, when <i>x</i> = 0.08, Li<sub>2</sub>Mg<sub>3</sub>Sn<sub>0.92</sub>O<sub>6</sub> ceramics have optimal dielectric performances: <i>ε</i><sub><i>r</i></sub> = 9.133, <i>Q×f</i> = 55,429 GHz, <i>τ</i><sub><i>f</i></sub> = -36.1 ppm/℃.</p></div>","PeriodicalId":625,"journal":{"name":"Journal of Electroceramics","volume":"51 1","pages":"51 - 58"},"PeriodicalIF":1.7,"publicationDate":"2023-06-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41082686","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Electrically conductive PDMS/Clay nanocomposites assembled with graphene, copper and silver nanoparticles for flexible electronic applications 石墨烯、铜和银纳米颗粒组装的导电PDMS/粘土纳米复合材料,用于柔性电子应用
IF 1.7 4区 材料科学
Journal of Electroceramics Pub Date : 2023-05-30 DOI: 10.1007/s10832-023-00315-z
Ameen Abdelrahman, Fouad Erchiqui, Mourad Nedil, Brahim Aïssa, Mohemed Siaj
{"title":"Electrically conductive PDMS/Clay nanocomposites assembled with graphene, copper and silver nanoparticles for flexible electronic applications","authors":"Ameen Abdelrahman,&nbsp;Fouad Erchiqui,&nbsp;Mourad Nedil,&nbsp;Brahim Aïssa,&nbsp;Mohemed Siaj","doi":"10.1007/s10832-023-00315-z","DOIUrl":"10.1007/s10832-023-00315-z","url":null,"abstract":"<div><p>We describe the development and characterization of a stretchy and resilient micro-strip antenna made from a nanocomposite of polydimethylsiloxane (PDMS) and bentonite clay loaded with silver, copper, and graphene nanoparticles. The physical, mechanical, and thermal characteristics of the nanocomposite were extensively evaluated in relation to the different nanomaterial loading into the PDMS. This has included UV-Vis spectroscopy, X-ray diffraction, and other techniques in addition to tensile and flexural tests, rheological analysis, thermogravimetric analysis, scanning and transmission electron microscopy, dynamic viscosity study, and ion coupled plasma. The conductivity of the fabricated micro-strip antennas was assessed using electrochemical impedance spectroscopy, and the antenna pattern was suitable for usage in RF equipment for cutting-edge applications like military, sensing, and space.</p></div>","PeriodicalId":625,"journal":{"name":"Journal of Electroceramics","volume":"51 1","pages":"37 - 50"},"PeriodicalIF":1.7,"publicationDate":"2023-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41082685","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Measurement and control of oxygen non-stoichiometry in praseodymium-cerium oxide thin films by coulometric titration 库仑滴定法测定和控制氧化镨铈薄膜中氧的非化学计量
IF 1.7 4区 材料科学
Journal of Electroceramics Pub Date : 2023-05-17 DOI: 10.1007/s10832-023-00309-x
Yun Zhao, Hongyang Su, Jianbing Xu, Shengru Chen, Peng Liu, Er-Jia Guo, Yuanhua Lin, Harry L. Tuller, Di Chen
{"title":"Measurement and control of oxygen non-stoichiometry in praseodymium-cerium oxide thin films by coulometric titration","authors":"Yun Zhao,&nbsp;Hongyang Su,&nbsp;Jianbing Xu,&nbsp;Shengru Chen,&nbsp;Peng Liu,&nbsp;Er-Jia Guo,&nbsp;Yuanhua Lin,&nbsp;Harry L. Tuller,&nbsp;Di Chen","doi":"10.1007/s10832-023-00309-x","DOIUrl":"10.1007/s10832-023-00309-x","url":null,"abstract":"<div><p>Oxygen non-stoichiometry profoundly impacts the electrical, magnetic, and catalytic properties of metal oxide. Limited by the low mass and volume of thin oxide films, conventional quantification methods, such as thermogravimetry, are not directly applicable. While chemical capacitance has been successfully applied to monitor oxygen non-stoichiometry in thin oxide films, detailed a-priori understanding of the defect chemistry is often very helpful in its interpretation. In this study, changes in non-stoichiometry in Pr doped CeO<sub>2</sub> (PCO) thin films are measured by coulometric titration. <i>I</i>-<i>V</i> titration measurements are performed on electrochemical cells, over the temperature range from 550 to 700 ℃, oxygen partial pressure range from 10<sup>-4</sup> to 0.21 atm, and bias range of -50 mV to 50 mV, to extract changes in stoichiometry. The results agree well with values obtained by chemical capacitance, demonstrating the utility in applying coulometric titration to investigate oxygen non-stoichiometry in oxide thin films.</p></div>","PeriodicalId":625,"journal":{"name":"Journal of Electroceramics","volume":"51 1","pages":"28 - 36"},"PeriodicalIF":1.7,"publicationDate":"2023-05-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10832-023-00309-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41082670","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Visible light-embedded CuO/ZnO twofold execution for photocatalysis and photoluminescence 可见光嵌入CuO/ZnO的光催化和光致发光双重执行
IF 1.7 4区 材料科学
Journal of Electroceramics Pub Date : 2023-05-16 DOI: 10.1007/s10832-023-00311-3
Abdallah M. Elgorban, D. Sivaganesh, Muthuraj Arunpandian, Ali H. Bahkali, Rajalakshmanan Eswaramoorthy, Nouf S. S. Zaghloul, Meenakshi Verma, Asad Syed
{"title":"Visible light-embedded CuO/ZnO twofold execution for photocatalysis and photoluminescence","authors":"Abdallah M. Elgorban,&nbsp;D. Sivaganesh,&nbsp;Muthuraj Arunpandian,&nbsp;Ali H. Bahkali,&nbsp;Rajalakshmanan Eswaramoorthy,&nbsp;Nouf S. S. Zaghloul,&nbsp;Meenakshi Verma,&nbsp;Asad Syed","doi":"10.1007/s10832-023-00311-3","DOIUrl":"10.1007/s10832-023-00311-3","url":null,"abstract":"<div><p>In the present work, tackle the two issues with one single activity resource that strategy has followed. The organic dye methyl orange (MO) and drug ciprofloxacin (CIP) have been effectively degraded by the synthesized ZnO@CuO under visible light irradiation. The hexagonal structured zinc oxide (ZnO), monoclinic structured copper oxide (CuO) and the mixed phase of ZnO@CuO has been prepared by the hydrothermal method. The structural characterization of prepared materials has been analyzed by powder X-ray diffraction (P-XRD) and the Rietveld refinement technique. The surface morphology of synthesized materials has been measured by scanning electron microscope characterization. The luminescence performance of prepared materials has studied by photoluminescence (PL) characterization. The photocatalytic results suggest that the ZnO@CuO composite is the effective candidate of degradation of ciprofloxacin antibiotic drug and methyl orange dye. From the results, ZnO@CuO revealed excellent photocatalytic behavior for CIP and MO degradation under stimulated sun light irradiation with the efficiency of above 95%. In addition, the optimum parameters were analyzed to the degradation process. This type of affordable photocatalyst gives a new beginning for further research studies. In addition, the electron density distribution analysis of synthesized materials has been studied.</p><h3>Graphical Abstract</h3>\u0000 <figure><div><div><div><picture><source><img></source></picture></div></div></div></figure>\u0000 </div>","PeriodicalId":625,"journal":{"name":"Journal of Electroceramics","volume":"51 1","pages":"12 - 27"},"PeriodicalIF":1.7,"publicationDate":"2023-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10832-023-00311-3.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41082671","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The enhanced electrical properties of TiO2-Nb2O5-ZnO varistor by sintering with the pre-synthesized B-Bi-O frit 用预合成的B-Bi-O玻璃料烧结TiO2-Nb2O5-ZnO压敏电阻提高其电学性能
IF 1.7 4区 材料科学
Journal of Electroceramics Pub Date : 2023-05-03 DOI: 10.1007/s10832-023-00312-2
Xiaolong Huang, Xin Liao, Yong Pu, Dachuan Zhu, Qun Yan
{"title":"The enhanced electrical properties of TiO2-Nb2O5-ZnO varistor by sintering with the pre-synthesized B-Bi-O frit","authors":"Xiaolong Huang,&nbsp;Xin Liao,&nbsp;Yong Pu,&nbsp;Dachuan Zhu,&nbsp;Qun Yan","doi":"10.1007/s10832-023-00312-2","DOIUrl":"10.1007/s10832-023-00312-2","url":null,"abstract":"<div><p>In this work, H<sub>3</sub>BO<sub>3</sub> and Bi<sub>2</sub>O<sub>3</sub> with the ratio 3:2 were melted at 750 °C and then quenched in water to produce B-Bi-O frit, which was sintered and co-doped with TiO<sub>2</sub>-0.60Nb<sub>2</sub>O<sub>5</sub>-0.50ZnO varistor ceramics. It is found that B-Bi-O frit can reduce the sintering temperature and improve the electrical properties of TiO<sub>2</sub> ceramics. The best comprehensive electrical properties with the nonlinear coefficient up to 8.9, the breakdown voltage down to 4.92 V/mm, the relative dielectric constant of 4.47*10<sup>5</sup> and the leakage current of 0.102 mA are achieved by sintering the ceramics doped with 3 wt% B-Bi-O frit at 1400 °C. XRD analysis shows that B-Bi-O frit is an amorphous phase, and no second phase can be found in ceramics after the frit is doped. SEM morphologies display that B-Bi-O frit is beneficial to decrease the porosity while increase the grain size, and EDS mapping further presents no elements segregate on the grain boundary. XPS spectra demonstrate the coexistence of Ti<sup>3+</sup> ions, Ti<sup>4+</sup> ions and oxygen vacancies in TiO<sub>2</sub> ceramics. As a result, it can be concluded that the enhancement of the electrical properties of TiO<sub>2</sub> ceramics is mainly attributed to the following aspects: on the one hand, B-Bi-O frit helps to produce liquid phase sintering, which would reduce the porosity while increase grain size and promote solid solution of Nb<sub>2</sub>O<sub>5</sub> and ZnO in TiO<sub>2</sub> ceramic. On the other hand, B and Bi elements can also act as acceptor dopants in TiO<sub>2</sub> ceramic to further promote grain semi-conductivity and increase grain boundary barrier height.</p></div>","PeriodicalId":625,"journal":{"name":"Journal of Electroceramics","volume":"51 1","pages":"1 - 11"},"PeriodicalIF":1.7,"publicationDate":"2023-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10832-023-00312-2.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41082672","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Conduction mechanisms and complex impedance analysis in La0.6Sr0.4FeO3 ceramic La0.6Sr0.4FeO3陶瓷的传导机理及复杂阻抗分析
IF 1.7 4区 材料科学
Journal of Electroceramics Pub Date : 2023-04-28 DOI: 10.1007/s10832-023-00310-4
R. Lataoui, A. Triki, S. Hcini, A. Oueslati, S. Zemni, O. Kanoun
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