Inorganic Materials最新文献_第9页

Synthesis of Semiorganic Crystals of Aluminum Guanidine Sulfate and Zinc Guanidine Sulfate, Raman Spectroscopy and Measurement of the Second Harmonic Generation Efficiency 硫酸胍嘧啶铝和硫酸胍锌半有机晶体的合成、拉曼光谱及二次谐波产生效率的测定

IF 0.7 4区材料科学

Inorganic Materials Pub Date : 2026-05-19 DOI: 10.1134/S002016852670007X

D. V. Belov, S. N. Belyaev, N. A. Sorokoletova, E. I. Serebrov, S. S. Arsentiev, D. B. Radishchev, M. O. Marychev

引用次数: 0

Thermolysis of Substitutional Solid Solutions and Composites Based on Polyantimonic Acid Containing Nb5+ Ions 含Nb5+离子的聚锑酸取代固溶体及其复合材料的热裂解

IF 0.7 4区材料科学

Inorganic Materials Pub Date : 2026-05-19 DOI: 10.1134/S0020168526700263

L. Yu. Kovalenko, L. M. Loginovskikh, D. A. Zakhar’evich, V. A. Burmistrov, K. G. Belova

{"title":"Thermolysis of Substitutional Solid Solutions and Composites Based on Polyantimonic Acid Containing Nb5+ Ions","authors":"L. Yu. Kovalenko, L. M. Loginovskikh, D. A. Zakhar’evich, V. A. Burmistrov, K. G. Belova","doi":"10.1134/S0020168526700263","DOIUrl":"10.1134/S0020168526700263","url":null,"abstract":"Thermolysis stages of Nb forms of polyantimonic acid that crystallize in the pyrochlore structure and composites based on polyantimonic acid containing Nb5+ ions have been identified in the temperature range 24–700°C. In the INTRODUCTION section, we depict distinctive structural features of polyantimonic acid: the presence of water molecules on particular crystallographic sites and adsorbed water molecules. In connection with this, the objectives of this work were to determine the amount of water of hydration in H2Sb2–хNbxO6∙nH2O samples and model the thermolysis process. Using a number of experimental techniques—X-ray diffraction, thermogravimetry, and IR spectroscopy—we have identified thermolysis stages, determined the phase composition of the thermolysis products, and proposed structural formulas of the synthesized compounds with allowance for the thermolysis model. The amount of water of hydration in the sample with the highest dopant concentration, x = 0.4, has been shown to be n = 5.34; the undoped sample, with x = 0, has n = 3.10. The content of water of hydration in the x = 0.6 composite, having the best proton-conducting properties, is n = 4.85. It seems likely that the proton conduction mechanism is influenced by the nonequivalence of the proton-containing groups, as evidenced by thermal analysis and IR spectroscopy data.","PeriodicalId":585,"journal":{"name":"Inorganic Materials","volume":"61 7-15","pages":"542 - 549"},"PeriodicalIF":0.7,"publicationDate":"2026-05-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147967976","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Structural and Spectroscopic Studies of (NH4Cl)[Ni2(H2O)6(Se2O5)Cl2] and (RbBr)[Ni(HSeO3)2(H2SeO3)0.5(H2O)0.5]—New Members of the Transition Metal (Hydro)Selenite-Halide Family （NH4Cl）[Ni2(H2O)6(Se2O5)Cl2]和（RbBr）[Ni(HSeO3)2(H2SeO3)0.5(H2O)0.5] -过渡金属（氢）亚硒酸盐族新成员的结构和光谱研究

IF 0.7 4区材料科学

Inorganic Materials Pub Date : 2026-05-19 DOI: 10.1134/S0020168526700433

D. O. Charkin, A. M. Gorianskii, V. Yu. Grishaev, A. A. Kompanchenko, A. N. Gosteva, S. M. Aksenov

{"title":"Structural and Spectroscopic Studies of (NH4Cl)[Ni2(H2O)6(Se2O5)Cl2] and (RbBr)[Ni(HSeO3)2(H2SeO3)0.5(H2O)0.5]—New Members of the Transition Metal (Hydro)Selenite-Halide Family","authors":"D. O. Charkin, A. M. Gorianskii, V. Yu. Grishaev, A. A. Kompanchenko, A. N. Gosteva, S. M. Aksenov","doi":"10.1134/S0020168526700433","DOIUrl":"10.1134/S0020168526700433","url":null,"abstract":"Single crystals of two new nickel diselenite/hydroselenite halides, (NH4Cl)[Ni2(H2O)6(Se2O5)Cl2] (1) and (RbBr)[Ni(HSeO3)2(H2SeO3)0.5(H2O)0.5] (2), were produced upon evaporation of aqueous solutions containing nickel and rubidium (ammonium) halide and selenious acid. Both structures correspond to new structure types. That of 1 is comprised of neutral [Ni2(H2O)6(Se2O5)Cl2] chains aligned into weakly bonded layers linked by hydrogen bonding. The ammonium cations and extra chloride anions reside in the interlayer space. The structure of 2 belong to the family of the so-called “layered hydroselenites” with neutral [Ni(HSeO3)2] layers decorated by Br– and linked by H2SeO3 molecules into a weak hydrogen-bonded framework with Rb+ cations filling the voids therein. Under the same conditions, no analogies have hitherto been found to the products formed in related systems containing copper, cobalt, or zinc halides.","PeriodicalId":585,"journal":{"name":"Inorganic Materials","volume":"61 7-15","pages":"664 - 674"},"PeriodicalIF":0.7,"publicationDate":"2026-05-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147968045","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Effect of Thermal Tests Modeling the VVER-1000 Fuel Rods Dry Storage Conditions on the Microstructure and Mechanical Properties of Claddings 模拟VVER-1000燃料棒干贮存条件的热试验对包壳组织和力学性能的影响

IF 0.7 4区材料科学

Inorganic Materials Pub Date : 2026-05-19 DOI: 10.1134/S0020168526700093

I. N. Volkova, G. P. Kobylyansky, E. A. Zvir, P. A. Ilyin, A. V. Obukhov, D. E. Markelov, E. V. Chertopyatov, G. V. Shishalova

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Electron Beam Powder Coating on Titanium Alloy in a Fore-Vacuum 钛合金的前真空电子束粉末涂层

IF 0.7 4区材料科学

Inorganic Materials Pub Date : 2026-05-19 DOI: 10.1134/S0020168526700378

A. A. Zenin, A. S. Klimov, A. V. Dolgova, V. A. Burdovitsin, E. M. Oks, L. J. Ngon A Kiki, F. A. Sukhovolsky

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Magnesium-Thermal SHS of Silicon Carbide Using Graphite Powders as a Carbon Source 以石墨粉为碳源的碳化硅镁热SHS

IF 0.7 4区材料科学

Inorganic Materials Pub Date : 2026-05-19 DOI: 10.1134/S0020168526700160

N. S. Shibakova, V. V. Zakorzhevsky, M. I. Alymov, I. A. Shibakov, I. D. Kovalev, N. I. Mukhina

引用次数: 0

Study of the Physical and Mechanical Properties of Welded Samples of Heat-Resistant Nickel Alloy Obtained by Rotary (Inertia) Friction Welding 旋转（惯性）摩擦焊接耐热镍合金试样的物理力学性能研究

IF 0.7 4区材料科学

Inorganic Materials Pub Date : 2026-05-19 DOI: 10.1134/S0020168526700135

A. V. Babaytsev, T. T. Fozilov

{"title":"Study of the Physical and Mechanical Properties of Welded Samples of Heat-Resistant Nickel Alloy Obtained by Rotary (Inertia) Friction Welding","authors":"A. V. Babaytsev, T. T. Fozilov","doi":"10.1134/S0020168526700135","DOIUrl":"10.1134/S0020168526700135","url":null,"abstract":"The article presents the results of a study on the influence of friction stir welding modes and subsequent heat treatment on the physical and mechanical properties of the deformable heat-resistant nickel alloy VZh175-ID. The study examines the processes of rotational (inertial) friction welding with and without preheating (grinding). Metallographic studies show a significant difference in the mechanisms of alloy hardening during heat treatment of samples obtained by rotational friction welding. The samples showed a deformation texture and elongation of particles in the direction of rotation. In the base material zone, hardening occurs through the mechanism of precipitation of strengthening intermetallic compounds ranging in size from 0.5 to 10 μm with a total grain size of 3 to 24 μm. In the zone of thermomechanical impact, grain coarsening was observed, and the separated γ'-phase particles were irregularly rounded in shape with the formation of carbides. Mechanical tests were performed. In a welded joint, hardening occurs through grain refinement, with grain size reduced by 2–3 times relative to the base material. The particles of the primary, secondary, and tertiary γ'-phase that are released retain their proportions relative to grain size, as in the base material. The hardening of two different mechanisms is equivalent, but due to grain growth in the modified zone, additional technological measures must be taken, since the mismatch in grain size leads to embrittlement and can serve as a source of crack initiation.","PeriodicalId":585,"journal":{"name":"Inorganic Materials","volume":"61 7-15","pages":"422 - 430"},"PeriodicalIF":0.7,"publicationDate":"2026-05-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147968073","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Impact of X-ray Radiation on the Microstructure and Properties of Composite Polytetrafluoroethylenes x射线辐射对复合聚四氟乙烯微观结构和性能的影响

IF 0.7 4区材料科学

Inorganic Materials Pub Date : 2026-05-19 DOI: 10.1134/S0020168526700287

E. V. Vinogradov, N. G. Valko, N. A. Bulychev, V. G. Lugin

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Computer Modeling of Lubricant Desizing from Fiber Fillers for Polymer Composites by Low-Energy Ion Bombardment 聚合物复合材料纤维填料低能离子轰击退浆的计算机模拟

IF 0.7 4区材料科学

Inorganic Materials Pub Date : 2026-05-19 DOI: 10.1134/S0020168526700470

F. R. Sagitova, V. S. Zheltukhin, M. Z. Garayev, I. K. Nekrasov, A. D. Kudryavyi

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Microstructure and Composition of Anodic Tin Oxide Grown in NaOH Electrolyte 在NaOH电解液中生长的阳极氧化锡的微观结构和组成

IF 0.7 4区材料科学

Inorganic Materials Pub Date : 2026-05-19 DOI: 10.1134/S0020168526700457

V. A. Stepanova, M. V. Berekchiian, I. V. Roslyakov, A. A. Poyarkov, T. B. Shatalova, I. V. Kolesnik, R. G. Valeev, A. V. Lukashin, A. A. Eliseev

{"title":"Microstructure and Composition of Anodic Tin Oxide Grown in NaOH Electrolyte","authors":"V. A. Stepanova, M. V. Berekchiian, I. V. Roslyakov, A. A. Poyarkov, T. B. Shatalova, I. V. Kolesnik, R. G. Valeev, A. V. Lukashin, A. A. Eliseev","doi":"10.1134/S0020168526700457","DOIUrl":"10.1134/S0020168526700457","url":null,"abstract":"The work reports on the structure of anodic tin oxide (ATO) films, synthesized in 0.5 M NaOH electrolyte at anodizing voltage of 4–12 V and temperature of 5 and 25°C. The microstructure and composition of the films were characterized with scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), Raman and infrared (IR) spectroscopy, and thermogravimetric analysis (TG). Pore diameter of ATO linearly increases with anodization voltage with a slope coefficient of 3.0 nm/V at either 5 or 25°C, providing average pore diameters in the range of 20–45 nm. Temperature does not affect significantly pores diameter, while determining anodization current and the growth rate. Film thickness is limited to ~150 µm due to dissolution of oxide layer at the oxide/electrolyte interface. ATO dissolution results in the diminishing of current efficiency from >95% for the film thickness of ~60 µm (spent charge 44.2 C/cm2) to ~25% for the film thickness of ~120 µm (spent charge 176.8 C/cm2). The films are amorphous, composed of non-stoichiometric SnOx·nH2O with x = 1.5–1.9. It is suggested, that the porous structure forms due to preferential dissolution of Sn4+ oxide, contacting with electrolyte, while Sn2+ at the pores interstitials reveals much higher stability towards basic environment. Most homogeneous films with minimal number of cracking defects, are formed at 8 V, 5°C, and spent charge of >176.8 C/cm2. The films reveal high conductivity as shown with impedance spectroscopy.","PeriodicalId":585,"journal":{"name":"Inorganic Materials","volume":"61 7-15","pages":"682 - 690"},"PeriodicalIF":0.7,"publicationDate":"2026-05-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147968068","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0