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Glass Physics and Chemistry最新文献

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Dual Effect of B3+ and Pb2+ Ions on the Elasticity and Semiconducting Nature of Sodium Zinc Borate Glass B3+ 和 Pb2+ 离子对硼酸锌钠玻璃的弹性和半导体性质的双重影响
IF 0.8 4区 材料科学
Glass Physics and Chemistry Pub Date : 2023-12-27 DOI: 10.1134/S1087659623600400
Mona Abo Zeed, R. M. El Shazly, E. Elesh, H. M. El-Mallah, Aly Saeed
{"title":"Dual Effect of B3+ and Pb2+ Ions on the Elasticity and Semiconducting Nature of Sodium Zinc Borate Glass","authors":"Mona Abo Zeed,&nbsp;R. M. El Shazly,&nbsp;E. Elesh,&nbsp;H. M. El-Mallah,&nbsp;Aly Saeed","doi":"10.1134/S1087659623600400","DOIUrl":"10.1134/S1087659623600400","url":null,"abstract":"<p>The influence of B<sup>3+</sup> and Pb<sup>2+</sup> ions on the electrical and mechanical properties of a borate network was extensively studied. A 30B<sub>2</sub>O<sub>3</sub>–10ZnO–60Na<sub>2</sub>O core network was prepared using the commercial melt/quenching technique and inlaid by different concentrations of B<sub>2</sub>O<sub>3</sub> + Pb<sub>3</sub>O<sub>4</sub> at the expense of Na<sub>2</sub>O. The impact of Pb<sup>2+</sup> and B<sup>3+</sup> ions on the mechanical properties were studied through ultrasonic wave velocities, elastic moduli, and microhardness. The more bridging oxygens BO<sub>4</sub> that brought to the considered borate network due to the more addition of B<sub>2</sub>O<sub>3</sub> and conversion of BO<sub>3</sub> to BO<sub>4</sub> via Pb<sup>2+</sup> ions penetration, formation of PbO<sub>6</sub>, and formation of the strong bonds B–O–Pb reinforced elastic moduli and microhardness of the studied borate network. Electrical properties through dielectric constant, electric modulus, impedance, and ac conductivity were extensively studied. The dielectric constant and electric modulus showed a behavior up to 20 mol % of Pb<sup>2+</sup> and 35 mol % of B<sup>3+</sup> differs from after that concentration, while ac conductivity differs at 40 mol % of Pb<sup>2+</sup> and 50 mol % of B<sup>3+</sup> from before that concentration. The results of the dependence of conductivity on frequency and temperature showed that the considered glass have a semiconducting nature.</p>","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":"49 6","pages":"593 - 603"},"PeriodicalIF":0.8,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139056253","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Molecular Dynamics Modeling of the Grade E Borosilicate Glass Structure Using a Crystal Structural Template 利用晶体结构模板建立 E 级硼硅玻璃结构的分子动力学模型
IF 0.8 4区 材料科学
Glass Physics and Chemistry Pub Date : 2023-12-27 DOI: 10.1134/S1087659623600631
G. I. Makarov, T. M. Makarova
{"title":"Molecular Dynamics Modeling of the Grade E Borosilicate Glass Structure Using a Crystal Structural Template","authors":"G. I. Makarov,&nbsp;T. M. Makarova","doi":"10.1134/S1087659623600631","DOIUrl":"10.1134/S1087659623600631","url":null,"abstract":"<p>A new method for molecular dynamics (MD) modeling of the glass structure using a crystal structural template is proposed. The template is based on the unit cell of the crystalline phase, whose composition is qualitatively similar to the modeled glass. Using this approach and multistage MD simulation, the model of the spatial structure of grade E borosilicate glass, reproducing its physicochemical characteristics, is obtained. The proposed method enables to model the glass structure using classical MD methods with greater productivity and stability.</p>","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":"49 6","pages":"635 - 641"},"PeriodicalIF":0.8,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139056316","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study of the Thermophysical Properties of Aluminophosphate and Borosilicate Glasses by DSC 利用 DSC 研究磷酸铝和硼硅玻璃的热物理性质
IF 0.8 4区 材料科学
Glass Physics and Chemistry Pub Date : 2023-12-27 DOI: 10.1134/S1087659623600552
V. A. Kazakov, N. P. Starovoitov, V. A. Dudkin, S. V. Korenev, P. V. Kozlov, M. B. Remizov
{"title":"Study of the Thermophysical Properties of Aluminophosphate and Borosilicate Glasses by DSC","authors":"V. A. Kazakov,&nbsp;N. P. Starovoitov,&nbsp;V. A. Dudkin,&nbsp;S. V. Korenev,&nbsp;P. V. Kozlov,&nbsp;M. B. Remizov","doi":"10.1134/S1087659623600552","DOIUrl":"10.1134/S1087659623600552","url":null,"abstract":"<p>A technique for the experimental determination of the thermophysical characteristics of inactive aluminophosphate and borosilicate glasses by differential scanning calorimetry (DSC) is proposed and tested. The advantages of this measurement technique are shown. For glassy matrices of various compositions, the specific heat capacity and thermal conductivity coefficient are determined. The obtained experimental values make it possible to calculate the thermal conductivity values. The applicability of this method is proved by working with real samples of vitrified high-level waste to study their properties and form a database based on them.</p>","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":"49 6","pages":"564 - 572"},"PeriodicalIF":0.8,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139056372","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effects of Different Quenching Rate on the Various Properties of Fe–Si–B Amorphous Alloy Prepared by Melt Spinning Method 不同淬火速率对熔融纺丝法制备的 Fe-Si-B 非晶合金各种性能的影响
IF 0.8 4区 材料科学
Glass Physics and Chemistry Pub Date : 2023-12-27 DOI: 10.1134/S1087659622600752
Narges Amini,  Safdar Habibi, Nahid Mohammadiparsa
{"title":"Effects of Different Quenching Rate on the Various Properties of Fe–Si–B Amorphous Alloy Prepared by Melt Spinning Method","authors":"Narges Amini,&nbsp; Safdar Habibi,&nbsp;Nahid Mohammadiparsa","doi":"10.1134/S1087659622600752","DOIUrl":"10.1134/S1087659622600752","url":null,"abstract":"<p>In this work an attempt is made to study the impact of the quenching rate upon structure, hyperfine interactions, magnetic and mechanical properties of Fe<sub>78</sub>Si<sub>9</sub>B<sub>13</sub> metallic glasses. Other involved parameters in melt spinning method were kept invariant. Analytical techniques comprising X-ray diffraction, transmission Mössbauer spectrometry, vibration sample magnetometer, Vickers microhardness and differential scanning calorimetry were employed. Minor effect of quenching rate upon the macroscopic magnetic properties was detected. It was shown that notable changes in the local atomic arrangement, structure, and mechanical properties were unveiled, dominantly by represent the crystallization at the lowest quenching rate.</p>","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":"49 6","pages":"617 - 624"},"PeriodicalIF":0.8,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139056579","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Silica Addition on Lead Ion Adsorption Ability of Alkali-Activated Blast Furnace Slag 添加二氧化硅对碱活化高炉渣铅离子吸附能力的影响
IF 0.8 4区 材料科学
Glass Physics and Chemistry Pub Date : 2023-12-27 DOI: 10.1134/S1087659623600035
Yosuke Uchida, Takumi Iwaki, Teruhisa Hongo
{"title":"Effect of Silica Addition on Lead Ion Adsorption Ability of Alkali-Activated Blast Furnace Slag","authors":"Yosuke Uchida,&nbsp;Takumi Iwaki,&nbsp;Teruhisa Hongo","doi":"10.1134/S1087659623600035","DOIUrl":"10.1134/S1087659623600035","url":null,"abstract":"<p>Blast furnace slag is produced in large quantities as a by-product in the steel manufacturing process. In this study, a method for synthesizing lead ion adsorbent with high adsorption ability was investigated by alkali activation of the blast furnace slag. A sodium hydroxide aqueous solution was used as an alkali activator, and silica was added to the aqueous solution to improve the adsorption capacity. Alkali activation of the blast furnace slag with the sodium hydroxide aqueous solution yielded lead ion adsorbent. Addition of silica to the sodium hydroxide aqueous solution further increased the lead ion adsorption capacity. Langmuir adsorption isotherms revealed that the highest maximum adsorption capacity of 1658.1 mg-Pb/g was obtained when 5 g of silica was added to 50 mL of the sodium hydroxide aqueous solution. The adsorption capacity for lead ion decreased when more than 10 g of silica was added to the sodium hydroxide aqueous solution.</p>","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":"49 6","pages":"651 - 656"},"PeriodicalIF":0.8,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139056192","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Conditions of Mannitol-Nitrate Synthesis on Photocatalytic Properties of φ-Bi8Pb5O17 硝酸甘露醇合成条件对 φ-Bi8Pb5O17 光催化性能的影响
IF 0.8 4区 材料科学
Glass Physics and Chemistry Pub Date : 2023-12-27 DOI: 10.1134/S1087659623600679
D. S. Ershov, N. V. Besprozvannykh, O. Yu. Sinelshchikova
{"title":"Effect of Conditions of Mannitol-Nitrate Synthesis on Photocatalytic Properties of φ-Bi8Pb5O17","authors":"D. S. Ershov,&nbsp;N. V. Besprozvannykh,&nbsp;O. Yu. Sinelshchikova","doi":"10.1134/S1087659623600679","DOIUrl":"10.1134/S1087659623600679","url":null,"abstract":"<p>The article presents the results of a study of new ceramic materials φ-Bi<sub>8</sub>Pb<sub>5</sub>O<sub>17</sub> obtained by pyrolysis using mannitol C<sub>6</sub>H<sub>14</sub>O<sub>6</sub> as a reducing fuel. The values of the band gap of the obtained compositions are determined by analyzing the diffuse reflectance spectra using the Tauc construction. They are in the range from 2.57 to 2.67 eV, which corresponds to visible light photocatalysts. The degree of degradation of methylene orange when using synthesized samples ranged from 95 to 99% when irradiated for 3 h with a fluorescent mercury lamp.</p>","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":"49 6","pages":"680 - 686"},"PeriodicalIF":0.8,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139056315","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study of the Stability of Zeolites in Model Biological Environments 沸石在模拟生物环境中的稳定性研究
IF 0.8 4区 材料科学
Glass Physics and Chemistry Pub Date : 2023-12-27 DOI: 10.1134/S1087659623600734
N. Yu. Ul’yanova, E. Yu. Brazovskaya, O. Yu. Golubeva
{"title":"Study of the Stability of Zeolites in Model Biological Environments","authors":"N. Yu. Ul’yanova,&nbsp;E. Yu. Brazovskaya,&nbsp;O. Yu. Golubeva","doi":"10.1134/S1087659623600734","DOIUrl":"10.1134/S1087659623600734","url":null,"abstract":"<p>The stability of synthetic and natural zeolites in model biological media simulating the environment of the stomach (pH 1.8), blood plasma (pH 6.9), and intestines (pH 8) is studied. The effect of long-term exposure (up to 7 days) to biological media on the crystal structure of Beta, Rho, Y, and clinoptilolite zeolites is studied. The degree of degradation of the crystal structure of zeolites is controlled by X-ray phase analysis. Based on the results obtained, conclusions are drawn on the prospects for the use of synthetic and natural zeolites as drug carriers.</p>","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":"49 6","pages":"706 - 708"},"PeriodicalIF":0.8,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139056574","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study on the Influence of Low Temperatures on the Physicochemical Properties of Xerogels, Powders and Ceramics Based on ZrO2 低温对基于 ZrO_2 的 Xerogels、粉末和陶瓷的物理化学特性的影响研究
IF 0.8 4区 材料科学
Glass Physics and Chemistry Pub Date : 2023-12-27 DOI: 10.1134/S1087659623600655
O. L. Belousova, V. A. Kuznetsova, N. Yu. Fedorenko, V. L. Ugolkov, T. V. Khamova, O. A. Shilova
{"title":"Study on the Influence of Low Temperatures on the Physicochemical Properties of Xerogels, Powders and Ceramics Based on ZrO2","authors":"O. L. Belousova,&nbsp;V. A. Kuznetsova,&nbsp;N. Yu. Fedorenko,&nbsp;V. L. Ugolkov,&nbsp;T. V. Khamova,&nbsp;O. A. Shilova","doi":"10.1134/S1087659623600655","DOIUrl":"10.1134/S1087659623600655","url":null,"abstract":"<p>By using the method of coprecipitation of hydroxides in the ZrO<sub>2</sub>–CaO–MgO system, xerogels, powders, and ceramics based on them are obtained. The effect of low temperatures during the preparation of precursors on the phase composition and physicochemical properties of the materials is studied. It is shown that the use of precipitate’s cryotreatment makes it possible to reduce the open porosity and water absorption of the ceramics.</p>","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":"49 6","pages":"687 - 692"},"PeriodicalIF":0.8,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139189908","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Xerogel and Powder Synthesis Conditions on the Properties of Ceramics Based on t-ZrO2 in the ZrO2–СeO2–Al2O3 System Xerogel 和粉末合成条件对 ZrO_2-СeO_2-Al_2O_3 体系中基于 t-ZrO_2 的陶瓷特性的影响
IF 0.8 4区 材料科学
Glass Physics and Chemistry Pub Date : 2023-12-27 DOI: 10.1134/S1087659623600667
O. L. Belousova, A. N. Parunova, N. Yu. Fedorenko, V. L. Ugolkov, T. V. Khamova, O. A. Shilova
{"title":"Effect of Xerogel and Powder Synthesis Conditions on the Properties of Ceramics Based on t-ZrO2 in the ZrO2–СeO2–Al2O3 System","authors":"O. L. Belousova,&nbsp;A. N. Parunova,&nbsp;N. Yu. Fedorenko,&nbsp;V. L. Ugolkov,&nbsp;T. V. Khamova,&nbsp;O. A. Shilova","doi":"10.1134/S1087659623600667","DOIUrl":"10.1134/S1087659623600667","url":null,"abstract":"<p>Xerogels and powders of a solid solution based on zirconium dioxide are synthesized by the method of coprecipitation of hydroxides from aqueous solutions of salts of zirconium nitrate ZrO(NO<sub>3</sub>)<sub>2</sub>⋅2H<sub>2</sub>O, aluminum Al(NO<sub>3</sub>)<sub>3</sub>⋅9H<sub>2</sub>O, and cerium Ce(NO<sub>3</sub>)<sub>3</sub>⋅9H<sub>2</sub>O with an aqueous 1 M solution of ammonia NH<sub>4</sub>OH. A dense ceramic with low porosity and water absorption is obtained. The effect of the ultrasonic treatment of the precipitate and mechanical treatment of the xerogel on the physicochemical properties of the obtained materials is evaluated.</p>","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":"49 6","pages":"664 - 671"},"PeriodicalIF":0.8,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139191487","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of Rare Earth Ion Doping on ac Conductivity and Dielectric Properties of Lithium Cadmium Borate Glasses 稀土离子掺杂对硼酸镉锂玻璃电导率和介电性质的影响
IF 0.8 4区 材料科学
Glass Physics and Chemistry Pub Date : 2023-12-27 DOI: 10.1134/S1087659622600636
J. Anjaiah
{"title":"Effect of Rare Earth Ion Doping on ac Conductivity and Dielectric Properties of Lithium Cadmium Borate Glasses","authors":"J. Anjaiah","doi":"10.1134/S1087659622600636","DOIUrl":"10.1134/S1087659622600636","url":null,"abstract":"<p>The dielectric constant (ε'), loss factor (tanδ), and ac conductivity (σ<sub>ac</sub>) of 30 Li<sub>2</sub>O–10CdO–(60 – <i>x</i>)-B<sub>2</sub>O<sub>3</sub>:<i>x</i>Ln<sub>2</sub>O<sub>3</sub>, where (<i>x</i> = 0 and 1) and (Ln = Pr, Nd, Sm, and Eu) were investigated using a frequency range of 10<sup>2</sup>–10<sup>5</sup> Hz and temperature ranging from 30 to 250°C in this work. The differential scanning calorimetry (DSC) technique was employed to confirm the glassy nature of the materials under study. The dielectric parameters ε', tan δ, and σ<sub>ac</sub> rise when rare-earth ions are added to the glass matrix at any frequency or temperature. Dielectric breakdown and activation energies are lower in doped than in undoped glasses while ac current flows through them at room temperature. Rare-earth ion doping’s dielectric parameter values decrease with temperature as atomic number (<i>Z</i>) rises. The dielectric parameter values for the Pr<sup>3+</sup> doped glass matrix is the highest. QM tunnelling model was used to describe the ac conduction behaviour of these glasses.</p>","PeriodicalId":580,"journal":{"name":"Glass Physics and Chemistry","volume":"49 6","pages":"584 - 592"},"PeriodicalIF":0.8,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139056194","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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