Matthias Langhansl, Jörg Dörrstein, Peter Hornberger, Cordt Zollfrank
{"title":"Fabrication of 3D-printed hygromorphs based on different cellulosic fillers","authors":"Matthias Langhansl, Jörg Dörrstein, Peter Hornberger, Cordt Zollfrank","doi":"10.1186/s42252-020-00014-w","DOIUrl":"https://doi.org/10.1186/s42252-020-00014-w","url":null,"abstract":"<p>The aim of this work is to characterize the moisture-dependent actuation behavior of bioinspired and additively manufactured hygromorphs based by following deductive and inductive design approaches. Fused Filament Fabrication (FFF) is employed to print bilayered structures consisting of swellable active layers and rigid passive layers. The active layer is composed of a polylactic acid (PLA) matrix filled with different hygroscopic cellulosic materials (native and modified) up to a filler content of 50?m%. Acrylonitrile Butadiene Styrene (ABS) is used for the passive layer. The FFF process allows the generation of desired differential swelling properties in the composites upon moisture absorption. The moisture dependent actuation strain of the printed bilayers was determined by video analyses. Some influencing geometrical factors which contribute to the actuation were deduced from x-ray diffraction (XRD) and micro computed tomography (μCT). The investigation of the mean cellulose microfibril orientation on the surface of the active layer suggested a preferential orientation with respect to printing direction. Furthermore, a gradient of cellulosic material within a single printed layer was observed, which indicates fiber sedimentation. Comparison with the thermomechanical model derived from Timoshenko (1925) shows that the computational prediction of the moisture dependent actuation is considerably accurate for most selected cellulosic materials and filler contents.</p>","PeriodicalId":576,"journal":{"name":"Functional Composite Materials","volume":"2 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1186/s42252-020-00014-w","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"5112382","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Fausta Loffredo, Loredana Tammaro, Tiziana Di Luccio, Carmela Borriello, Fulvia Villani, Saverio De Vito, Karthik Ramachandran, Julia A. Kornfield
{"title":"Effect of tungsten disulfide nanotubes on crystallization of polylactide under uniaxial deformation and annealing","authors":"Fausta Loffredo, Loredana Tammaro, Tiziana Di Luccio, Carmela Borriello, Fulvia Villani, Saverio De Vito, Karthik Ramachandran, Julia A. Kornfield","doi":"10.1186/s42252-021-00016-2","DOIUrl":"https://doi.org/10.1186/s42252-021-00016-2","url":null,"abstract":"<p>Tungsten disulfide (WS<sub>2</sub>) nanotubes (NTs) are examined here as a filler for polylactide (PLA) for their ability to accelerate PLA crystallization and for their promising biocompatibility in relevant to biomedical applications of PLA-WS<sub>2</sub> nanocomposites. In this work, we have studied the structural and thermal properties of PLA-WS<sub>2</sub> nanocomposite films varying the concentration of WS<sub>2</sub> NTs from 0 (neat PLA) to 0.6?wt%. The films were uniaxially drawn at 90?°C and annealed at the same temperature for 3 and 10?min. Using wide angle x-ray scattering, Raman spectroscopy and differential scanning calorimetry, we probed the effects of WS<sub>2</sub> NT addition on the structure of the PLA films at various stages of processing (unstretched, stretching, annealing). We found that 0.6?wt% of WS<sub>2</sub> induces the same level of crystallinity in as stretched PLA-WS<sub>2</sub> as annealing in neat PLA for 10?min. These data provide useful insights into the role of WS<sub>2</sub> NTs on the structural evolution of PLA-WS<sub>2</sub> composites under uniaxial deformation, and extend their applicability to situations where fine tuning of PLA crystallinity is desirable.</p>","PeriodicalId":576,"journal":{"name":"Functional Composite Materials","volume":"2 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1186/s42252-021-00016-2","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"5004495","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Capacitance measurements on integrated conductors for detection of matrix cracks in GFRP","authors":"Christina Buggisch, Abedin Gagani, Bodo Fiedler","doi":"10.1186/s42252-020-00013-x","DOIUrl":"https://doi.org/10.1186/s42252-020-00013-x","url":null,"abstract":"<p>For the reliable and cost-efficient application of glass fibre polymer composites in structural applications, knowledge of the damage state of the material during operation is necessary. Within this work, a structural health monitoring method based on in-situ electrical capacitance measurements is presented, which enables damage monitoring in glass fibre reinforced polymers. For this purpose, individual glass fibre rovings in a non-crimp fabric were replaced by carbon fibre rovings at regular intervals. Additionally, specimens with solid or stranded copper conductors were manufactured to gain insights into the influences of conductor material and composition. The modified fabrics were implemented as 90<sup>°</sup> layers of [0/90<sub>4</sub>]<sub><i>s</i></sub> glass fibre polymer cross-ply laminates. To monitor the progressive damage, conductive rovings were contacted, forming the capacitor walls of interleaved capacitors. Carbon fibre conductors show higher sensitivity of the capacitance to crack formation than solid or stranded copper conductors. Capacitance decrease measured in-situ during tensile tests on specimens with carbon fibre conductors shows a high correlation with crack initiation, further crack formation and speed of crack evolution. An analytical model can describe the correlation based on the assumptions of an ideal plate capacitor. Thus, the structural health monitoring method developed in this work can reveal in-situ knowledge of the material damage state.</p>","PeriodicalId":576,"journal":{"name":"Functional Composite Materials","volume":"2 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4492339","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Christopher Leow, Peter B. Kreider, Christian Notthoff, Patrick Kluth, Antonio Tricoli, Paul Compston
{"title":"A graphene film interlayer for enhanced electrical conductivity in a carbon-fibre/PEEK composite","authors":"Christopher Leow, Peter B. Kreider, Christian Notthoff, Patrick Kluth, Antonio Tricoli, Paul Compston","doi":"10.1186/s42252-020-00015-9","DOIUrl":"https://doi.org/10.1186/s42252-020-00015-9","url":null,"abstract":"<p>Carbon-fibre reinforced composites are seeing increased deployment, especially in the aerospace industry, and the next-generation of these materials will need to meet demanding performance requirements beyond just specific strength. The incorporation of nanomaterials such as graphene into composites has great potential for enhancing electrical, thermal, and mechanical properties, which could then enable new capabilities such as built-in lightning strike protection and electromagnetic shielding. One major challenge is successful integration of nanomaterials into the composite during the manufacturing process especially for thermoplastic based composites. This work explores the spray deposition of exfoliated graphene in liquid suspensions for the nano-enhancement of electrical properties in carbon-fibre reinforced polyether ether keytone (PEEK) composites. Developed thin films were smooth with RMS roughness of 1.06?μm on Si substrates and RMS roughness of 1.27?μm on CF-PEEK tapes. The addition of 1.3?wt% graphene into the interlayers of CF-PEEK composites resulted in bulk electrical conductivity enhancement both in plane and through thickness of ~?1100% and 67.5% respectively. This approach allows for pre-consolidation introduction of high-performance nanomaterials directly to thermoplastic prepregs which could open simple pathways for the in-situ manufacturing of carbon-fibre reinforced polymer nanocomposites.</p>","PeriodicalId":576,"journal":{"name":"Functional Composite Materials","volume":"2 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-01-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1186/s42252-020-00015-9","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4655921","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Griselda V. Nájera-Romero, Muhammad Yar, Ihtesham Ur Rehman
{"title":"Heparinized chitosan/hydroxyapatite scaffolds stimulate angiogenesis","authors":"Griselda V. Nájera-Romero, Muhammad Yar, Ihtesham Ur Rehman","doi":"10.1186/s42252-020-00012-y","DOIUrl":"https://doi.org/10.1186/s42252-020-00012-y","url":null,"abstract":"<p>Formation of blood vessels during bone regeneration represents a major challenge for tissue engineered constructs. Poor revascularization can lead to scaffold failure and consequently, leads to non-healing fracture. Heparin is known to bind with angiogenic growth factors influencing the process of new blood vessels formation. There are several problems associated with the use of growth factors in clinic such as low stability, uncontrolled delivery to the site, and high price. The aim of the present study was to explore the potential of heparin to produce pro-angiogenic bone regeneration materials. Chitosan/hydroxyapatite freeze-gelled scaffolds were prepared and loaded with heparin. Different concentrations of heparin were successfully loaded onto the scaffolds, its release from the scaffold was analysed by toluidine blue assay and their angiogenic effect was evaluated by chorioallantoic membrane (CAM) assay to determine the optimal concentration of heparin to induce a proangiogenic effect. It was noted that low heparin concentrations exhibited a positive effect, with approximately 28?μg per scaffold indicating a significant increment in blood vessels. The synthesized materials showed no cytotoxic effects when evaluated by using U2OS cell line.</p>","PeriodicalId":576,"journal":{"name":"Functional Composite Materials","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-10-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1186/s42252-020-00012-y","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"5185592","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Mpho Phillip Motloung, Simphiwe Zungu, Vincent Ojijo, Jayita Bandyopadhyay, Suprakas Sinha Ray
{"title":"Morphological, thermal, and thermomechanical properties of cellulose nanocrystals reinforced polylactide/poly [(butylene succinate)-co-adipate] blend composite foams","authors":"Mpho Phillip Motloung, Simphiwe Zungu, Vincent Ojijo, Jayita Bandyopadhyay, Suprakas Sinha Ray","doi":"10.1186/s42252-020-00011-z","DOIUrl":"https://doi.org/10.1186/s42252-020-00011-z","url":null,"abstract":"<p>This study examines the influence of cellulose nanocrystal (CN) particles on the morphological, thermal, and thermo-mechanical properties of polylactide (PLA)/poly [(butylene succinate)-co-adipate] (PBSA) blend foams prepared by casting and particulate leaching method using fructose as porogen particles. The morphological analysis showed an interconnected open-cell structure, with porosity above 80%. The crystallinity of the prepared foams was disrupted by the inclusion of CN particles as observed from XRD analyses, which showed a decrease in PLA crystal peak intensity. With regards to neat blend foam, the onset thermal degradation increased with the addition of CN particles, which also increased the thermal stability at 50% weight loss. Furthermore, CN acted as a reinforcing agent in improving the stiffness of the prepared blend foam. Overall, completely environmentally friendly foams were successfully prepared, as a potential material that can replace the current existing foam materials that pose many environmental concerns. However, there is a need to develop an environmentally friendly processing technique.</p>","PeriodicalId":576,"journal":{"name":"Functional Composite Materials","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1186/s42252-020-00011-z","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4322382","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Long-fibre reinforced polymer composites by 3D printing: influence of nature of reinforcement and processing parameters on mechanical performance","authors":"Francis Dantas, Kevin Couling, Gregory J. Gibbons","doi":"10.1186/s42252-020-00010-0","DOIUrl":"https://doi.org/10.1186/s42252-020-00010-0","url":null,"abstract":"<p>The aim of this study was to identify the effect of material type (matrix and reinforcement) and process parameters, on the mechanical properties of 3D Printed long-fibre reinforced polymer composites manufactured using a commercial 3D Printer (Mark Two). The effect of matrix material (Onyx or polyamide), reinforcement type (Carbon, Kevlar?, and HSHT glass), volume of reinforcement, and reinforcement lay-up orientation on both Ultimate Tensile Strength (UTS) and Flexural Modulus were investigated.</p><p>For Onyx, carbon fibre reinforcement offered the largest increase in both UTS and Flexural Modulus over unreinforced material (1228?±?19% and 1114?±?6% respectively). Kevlar? and HSHT also provided improvements but these were less significant. Similarly, for Nylon, the UTS and Flexural Modulus were increased by 1431?±?56% and 1924?±?5% by the addition of carbon fibre reinforcement. Statistical analysis indicated that changing the number of layers of reinforcement had the largest impact on both UTS and Flexural Strength, and all parameters were statistically significant.</p>","PeriodicalId":576,"journal":{"name":"Functional Composite Materials","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1186/s42252-020-00010-0","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4847358","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Olivia V. López, María E. Villanueva, Guillermo J. Copello, Marcelo A. Villar
{"title":"Flexible thermoplastic starch films functionalized with copper particles for packaging of food products","authors":"Olivia V. López, María E. Villanueva, Guillermo J. Copello, Marcelo A. Villar","doi":"10.1186/s42252-020-00009-7","DOIUrl":"https://doi.org/10.1186/s42252-020-00009-7","url":null,"abstract":"<p>Biodegradable films based on thermoplastic corn starch (TPS) and copper particles with antimicrobial capacity were developed. Copper nanoparticles (Cu) and silica coated copper microparticles (Si-Cu) in the range of 0.25 to 5% were used. Composite films were obtained by melt-mixing and subsequent thermo-compression. Particles distribution within TPS matrix and the presence of some pores and cracks, induced by Si-Cu particles, was evaluated by SEM. The presence of both fillers gave composite films a brown pigmentation and decreased their transparency; these effects were more pronounced at higher particles concentrations. Regarding mechanical properties, copper particles at 1 and 5% acted as reinforcing agents increasing the maximum tensile strength but their presence lead to a decrease in elongation at break, affecting films ductility. Composites inhibited the growth of Gram+ and Gram- bacteria, demonstrating their antimicrobial capacity. Copper effectively migrated to a simulant of aqueous foods and naked particles concentration in the simulant medium resulted higher than the minimum inhibitory concentration for bacteria. The characteristics and properties of developed composite films make them an interesting material for food primary packaging, mainly for meat fresh products.</p>","PeriodicalId":576,"journal":{"name":"Functional Composite Materials","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-07-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1186/s42252-020-00009-7","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4056781","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Carbonized lignosulfonate-based porous nanocomposites for adsorption of environmental contaminants","authors":"Jenevieve Yao, Karin Odelius, Minna Hakkarainen","doi":"10.1186/s42252-020-00008-8","DOIUrl":"https://doi.org/10.1186/s42252-020-00008-8","url":null,"abstract":"<p>Carbon-based adsorbents possess exceptional adsorption capability, making them an ideal platform for the remediation of environmental contaminants. Here, we demonstrate carbonized lignosulfonate (LS)-based porous nanocomposites with excellent adsorption performance towards heavy metal ions and cationic dye pollutants. Through microwave-assisted hydrothermal carbonization, a green approach was employed to carbonize lignosulfonate to carbon spheres. The LS-derived carbon spheres were then oxidized into nanographene oxide (nGO) carbon dots. A facile two-step procedure that involved the self-assembly of nGO and gelatin into a hydrogel precursor coupled with freeze-drying enabled the construction of three-dimensional (3D) free-standing porous composites without the use of organic solvents or chemical crosslinking agents. The favorable pore structure and abundance of surface functional groups on the nGO/gelatin porous composite proved to substantially facilitate the adsorption of Cu(II) in comparison to conventionally-used activated carbon. Further enhancement of adsorption performance was achieved by introducing additional surface functional groups through a non-covalent functionalization of the porous composite with lignosulfonate. The presence of negatively-charged sulfonate groups increased the Cu(II) equilibrium adsorption capacity (66?mg/g) by 24% in comparison to the non-functionalized nGO/gelatin counterpart. Both functionalized and non-functionalized composites exhibited significantly faster adsorption rates (40?min) compared to many graphene- or GO-based adsorbents reported in literature. In addition to the adsorption of heavy metal ions, the composites also demonstrated good adsorption capacity towards cationic dyes such as methylene blue. This paves the way for a high value-added application of lignin in environmental remediation and opens up new possibilities for the development of sustainable materials for adsorption and water purification.</p>","PeriodicalId":576,"journal":{"name":"Functional Composite Materials","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-06-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1186/s42252-020-00008-8","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4091279","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Fused deposition modelling (FDM) of composites of graphene nanoplatelets and polymers for high thermal conductivity: a mini-review","authors":"Valentina Guerra, Chaoying Wan, Tony McNally","doi":"10.1186/s42252-020-00005-x","DOIUrl":"https://doi.org/10.1186/s42252-020-00005-x","url":null,"abstract":"<p>Composites of polymers and the graphene family of 2D materials continue to attract great interest due their potential to dissipate heat, thus extending the in-service life of electronic and other devices. Such composites can be 3D printed using Fused Deposition Modelling into complex bespoke structures having enhanced properties, including thermal conductivity in different directions. While there are controversial opinions on the limitations of FDM for large-scale and high volume production (e.g. long production times, and expensive printers required), FDM is an innovative solution to the manufacture of small objects where effective thermal management is required and it is a valid alternative for the manufacture of (micro)-electronic components. There are few papers published on the FDM of functional composite materials based on graphene(s). In this mini-review, we describe the many technical challenges that remain to successful printing of these composites by FDM, including orientation effects, void formation, printing and feeding rates, nozzle and printing bed temperatures and the role each has in determining the thermal conductivity of any composite product made by FDM. We also compare these initial reports with those on FDM of other and related carbonaceous fillers, such as multi-walled carbon nanotubes and carbon fibre.</p>","PeriodicalId":576,"journal":{"name":"Functional Composite Materials","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-05-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4758323","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}