Geologica ActaPub Date : 2018-06-21DOI: 10.1344/GEOLOGICAACTA2018.16.2.2
P. N. Tehrani, A. A. Calagari, F. V. Roldan, V. Simmonds, Kamal Siahcheshm
{"title":"C and O stable isotopes and rare earth elements in the Devonian carbonate host rock of the Pivehzhan iron deposit, NE Iran","authors":"P. N. Tehrani, A. A. Calagari, F. V. Roldan, V. Simmonds, Kamal Siahcheshm","doi":"10.1344/GEOLOGICAACTA2018.16.2.2","DOIUrl":"https://doi.org/10.1344/GEOLOGICAACTA2018.16.2.2","url":null,"abstract":"The Pivehzhan iron deposit is located at about 80km southwest of Mashhad, NE Iran. They occur within the Devonian carbonates as lenticular and massive bodies, as well as veinlets of magnetite and iron sulphides, transformed to goethite and haematite by weathering process. The hydrothermal calcite is the most important gangue mineral, which is observed in the form of veins/veinlets and open-space filling. The iron ores are accompanied by some minor elements such as Mn, Ti, Cr, and V and negligible amounts of Co and Ni. The distribution pattern of Rare Earth Elements (REEs) normalized to Post Archean Australian Shale (PAAS), which is characterized by the upward convex, as well as the positive Eu anomalies indicate the activity of reduced and acidic hydrothermal fluids. The negative Ce anomalies of host carbonates, although slight, point to the dominance of anoxic conditions during interaction with hydrothermal fluids. The hydrothermal calcite and quartz coexisting with the iron minerals contain principally fluid, which were homogenized into liquid phase. The homogenization temperature (TH (L-V) ) and the salinity of the analysed fluid inclusions range from 129°C to 270°C and from 0.4wt.% to 9.41wt.% NaCl eq., respectively. The δ 13 C PDB and δ 18 O SMOW values ranges from -2.15‰ to -5.77‰ (PeeDee Belemnite standard, PDB) and from +19.87‰ to +21.64‰ (Standard Mean Ocean Water standard, SMOW) in hydrothermal calcite veinlets occurring with iron minerals and -0.66‰ to -4.37‰ (PDB) and +15.55‰ to +20.14‰ (SMOW) within the host carbonates, respectively. The field relations and petrographic examination along with geochemical and isotopic considerations indicate that the Pivehzhan iron deposit was formed through replacement processes by reducing and acid fluids containing light carbon and oxygen isotopes. Variations in the physico-chemical conditions of hydrothermal fluids and their interaction with carbonates were the most effective mechanisms in the formation of this iron deposit. The potential source of iron was probably the basement magmatic rocks from which iron was leached by hydrothermal solutions.","PeriodicalId":55107,"journal":{"name":"Geologica Acta","volume":null,"pages":null},"PeriodicalIF":1.5,"publicationDate":"2018-06-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44156630","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Geologica ActaPub Date : 2018-06-08DOI: 10.1344/GEOLOGICAACTA2018.16.3.1
J. Errandonea-Martin, F. Sarrionandia, M. Carracedo-Sánchez, J. G. Ibarguchi, L. Eguiluz
{"title":"Petrography and geochemistry of late- to post-Variscan vaugnerite series rocks and calc-alkaline lamprophyres within a cordierite-bearing monzogranite (the Sierra Bermeja Pluton, southern Iberian Massif).","authors":"J. Errandonea-Martin, F. Sarrionandia, M. Carracedo-Sánchez, J. G. Ibarguchi, L. Eguiluz","doi":"10.1344/GEOLOGICAACTA2018.16.3.1","DOIUrl":"https://doi.org/10.1344/GEOLOGICAACTA2018.16.3.1","url":null,"abstract":"The Sierra Bermeja Pluton (southern Central Iberian Zone, Iberian Massif) is a late-Variscan intrusive constituted by cordierite-bearing peraluminous monzogranites. Detailed field mapping has allowed to disclose the presence of several NE–SW trending longitudinal composite bodies, formed by either aphanitic or phaneritic mesocratic rocks. According to their petrography and geochemistry these rocks are categorised as calc-alkaline lamprophyres and vaugnerite series rocks. Their primary mineralogy is characterised by variable amounts of plagioclase, amphibole, clinopyroxene, biotite, K-feldspar, quartz and apatite. Broadly, they show low SiO2 content (49–56wt.%), and high MgO+FeOt (10–17wt.%), K2O (3–5wt.%), Ba (963–2095ppm), Sr (401–1149ppm) and Cr (87–330ppm) contents. Field scale observations suggest that vaugneritic rocks and lamprophyres would constitute two independent magma pulses. Vaugneritic dioritoids intruded as syn-plutonic dykes, whereas lamprophyres were emplaced after the almost complete consolidation of the host monzogranites. In this way, vaugnerite series rocks would be an evidence for the contemporaneity of crustal- and mantle-melting processes during a late-Variscan stage, while lamprophyres would represent the ending of this stage.","PeriodicalId":55107,"journal":{"name":"Geologica Acta","volume":null,"pages":null},"PeriodicalIF":1.5,"publicationDate":"2018-06-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41481532","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Geologica ActaPub Date : 2018-03-26DOI: 10.1344/GEOLOGICAACTA2018.16.1.5
M. Bieńkowska-Wasiluk, M. Pałdyna
{"title":"Taxonomic revision of the Oligocene percoid fish Oligoserranoides budensis (Heckel, 1856), from the Paratethys and paleobiogeographic comments","authors":"M. Bieńkowska-Wasiluk, M. Pałdyna","doi":"10.1344/GEOLOGICAACTA2018.16.1.5","DOIUrl":"https://doi.org/10.1344/GEOLOGICAACTA2018.16.1.5","url":null,"abstract":"Small perch-like fishes from the Oligocene of the Paratethys were traditionally assigned to Serranus budensis (Heckel, 1856). A new morphological study of the holotype and specimens from the Outer Carpathians, Poland, is provided herein. Oligoserranoides budensis (Heckel, 1856), Percoidei incertae sedis, is revised and compared with other small perch-like fishes from the Oligocene Paratethys. Caucasoserranoides morozkiensis, Carpathoserranoides brnoensis, Carpathoserranoides polonicus and Oligoserranoides comparabilis are very similar to O. budensis and further studies are necessary to clarify the validity of those species. O. budensis is compared with the Oligocene-Lower Miocene Pirsagatia sytchevskayae, the Eocene Jimtylerius temnopterus, Ottaviania mariae,O. leptacanthus, Veranichthys ventralis and the Palaeocene Proserranus lundensis. O. budensis shares many characters with the Lutjanoidea, and differs in a toothless palatine. The palaeobiogeography of Oligocene small perch-like fishes in the Paratethys is presented.","PeriodicalId":55107,"journal":{"name":"Geologica Acta","volume":null,"pages":null},"PeriodicalIF":1.5,"publicationDate":"2018-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47894251","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Geologica ActaPub Date : 2018-03-26DOI: 10.1344/GEOLOGICAACTA2018.16.1.6
M. Peral, Manel Fernàndez, M. Torné
{"title":"Resolution test of GOCE satellite data applied to density anomalies at crustal and upper mantle levels.","authors":"M. Peral, Manel Fernàndez, M. Torné","doi":"10.1344/GEOLOGICAACTA2018.16.1.6","DOIUrl":"https://doi.org/10.1344/GEOLOGICAACTA2018.16.1.6","url":null,"abstract":"The Gravity field and steady-state Ocean Circulation Explorer (GOCE) satellite mission was devised by the European Space Agency to study the Earth’s gravity field with an unprecedented accuracy using gravity gradient data. The goal of this study is to analyze the resolution in terms of size, burial depth and density contrast of anomalous bodies related to geological structures that can be identified from GOCE data. A parametric study is performed by calculating the gravity gradients associated with rectangular prisms with fixed aspect ratio of 9:3:1 and varying the size, burial depth, and density contrast, selecting those structures showing amplitudes and wavelength variations comparable to the accuracy of GOCE data. Results show that the minimum size for crustal anomalies to be resolved for the vertical component of the gravity gradient is 22.5x7.5x2.5km for a Δρ=500kg/m 3 , burial depth of 0km, and at computation height of 255km. To generate a sufficient signal in amplitude and wavelength in all the components, the size of the anomalous body is 270x90x30km. For a body with Δρ=50kg/m 3 and 0km burial depth a minimum size of 41.4x13.8x4.6km is required for the vertical component at a computation height of 255km. In addition, the application to the 3D case of a passive continental margin which broadly resembles the crustal structure of the NW-Iberia shows that the signal of all gravity gradient components is dominated by the crustal thinning associated with the passive continental margins and the corresponding isostatic response.","PeriodicalId":55107,"journal":{"name":"Geologica Acta","volume":null,"pages":null},"PeriodicalIF":1.5,"publicationDate":"2018-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45512603","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Geologica ActaPub Date : 2018-03-26DOI: 10.1344/GEOLOGICAACTA2018.16.1.4
O. Fatka, P. Budil
{"title":"Digestive structures in Middle Ordovician trilobite Prionocheilus Rouault 1847, from the Barrandian area of Czech Republic.","authors":"O. Fatka, P. Budil","doi":"10.1344/GEOLOGICAACTA2018.16.1.4","DOIUrl":"https://doi.org/10.1344/GEOLOGICAACTA2018.16.1.4","url":null,"abstract":"Remains of a digestive system from a slightly damaged articulated specimen of the comparatively rare bathycheilid trilobite Prionocheilus vokovicensis (Snajdr, 1956) are described for the first time. The specimen comes from the Middle Ordovician Sarka Formation of the Prague Basin and contains the midgut region of the digestive system preserved through the axial region of glabella and six anterior thoracic segments. The anterior-most part of the digestive system is unknown as the anterior glabellar lobes are not preserved in the studied specimen. In the cephalic shield, the remains of two pairs of gut diverticulae are seen in the posterior region of the glabella. Remains of five pairs of small cavities developed in the axis of the first six thoracic segments represent the remains of thoracic gut diverticulae. The discussed specimen possess the first undoubted remain of digestive structures established within the family Bathycheilidae (PŘibyl, 1953).","PeriodicalId":55107,"journal":{"name":"Geologica Acta","volume":null,"pages":null},"PeriodicalIF":1.5,"publicationDate":"2018-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41463205","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Geologica ActaPub Date : 2018-03-26DOI: 10.1344/GEOLOGICAACTA2018.16.1.3
L. Li, G. Yao, M. Cai, Y. Liu
{"title":"Organic petrology and geochemistry of mudstones from the lower Shahejie Formation, in the Tanggu area of eastern China: evidence for the presence of an ancient saline lake","authors":"L. Li, G. Yao, M. Cai, Y. Liu","doi":"10.1344/GEOLOGICAACTA2018.16.1.3","DOIUrl":"https://doi.org/10.1344/GEOLOGICAACTA2018.16.1.3","url":null,"abstract":"Mudstones in the lower Shahejie Formation, in the Tanggu area of the Huanghua Depression, have been found to contain analcime and ankerite. Hydrothermal sedimentation has been invoked to explain the origin of these two minerals, raising the question of whether hydrothermal activity occurred at a sufficient scale to significantly raise the salinity of the depositional environment. We applied a suite of organic petrological and geochemical methods to directly address this question. Maceral composition, kerogen type, and the distribution of n-alkanes, hopanes, and steranes indicate that the organic matter contained in these mudstones and dolomitic mudstones is mainly derived from algae and bacteria. The dominant acritarch genera, C31R/C30 hopane ratio, gammacerane index, Pr/Ph ratio, and the relationship between Pr/n-C17 and Ph/n-C18 suggest that the mudstones and dolomitic mudstones were deposited in an anoxic, saline lacustrine environment. Tmax, biomarker maturity indices, the thermal alteration index (TAI) and acritarch alteration index (AAI), and vitrinite reflectance all indicate that the organic matter is at an immature to early mature stage. The estimated maximum paleotemperature is close to the present-day burial temperature, and much lower than the homogenization temperature of the analcime veins. Combined with the absence of unresolved complex mixtures on the n-alkane pattern, this suggests that hydrothermal activity had a negligible impact on the salinity and alkalinity of the depositional lake.","PeriodicalId":55107,"journal":{"name":"Geologica Acta","volume":null,"pages":null},"PeriodicalIF":1.5,"publicationDate":"2018-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42646460","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Geologica ActaPub Date : 2018-03-26DOI: 10.1344/GEOLOGICAACTA2018.16.1.2
J. P. López, Laura Iudith Bellos, J. Díaz-Alvarado, A. Castro
{"title":"Hybridization between I-type and S-type granites in the Ordovician Famatinian magmatic arc, Tafí del Valle, Tucumán, NW Argentina.","authors":"J. P. López, Laura Iudith Bellos, J. Díaz-Alvarado, A. Castro","doi":"10.1344/GEOLOGICAACTA2018.16.1.2","DOIUrl":"https://doi.org/10.1344/GEOLOGICAACTA2018.16.1.2","url":null,"abstract":"In the Tafi del Valle region, in northwestern Argentina, several intrusive bodies of lower Paleozoic age were emplaced in the metasedimentary Puncoviscana Formation, belonging to the Sierras Pampeanas. Four intrusive bodies outcrop in the study area: La Ovejeria, El Infiernillo, Loma Pelada and Los Cuartos. La Ovejeria and El Infiernillo intrusive bodies represent the I-type magmatism according to their major element contents and show cotectic evolutions similar to those described by Famatinian I-type batholiths. These moderately peraluminous adakitic trondhjemites have characteristic high Sr/Y ratios and low Fe 2 O 3 +MgO+MnO+TiO 2 contents. They are related to high-pressure conditions at the source, where dehydration melting of basaltic rocks may be involved and garnet is retained in the residue leading to generation of HREE depleted melts. The Loma Pelada granites show characteristics of S-type magmatism (low CaO and MgO, and high SiO 2 and K 2 O contents) typical of granites segregated in the last stages of magmatic differentiation, or anatectic granites. They show an increasing peraluminosity due to garnet entrainment and they are related to the anatectic melts generated in the Puncoviscana Formation. Both the Loma Pelada and Los Cuartos granitoids include samples with intermediate geochemical characteristics that range between those of the El Infiernillo and La Ovejeria and the regional metasedimentary rocks. These characteristics could be explained by assimilation processes involving the I-type intrusive magmas and the metasedimentary host rocks or by hybridization processes between trondhjemitic I-type magmas as La Ovejeria and El Infiernillo and anatectic S-type melts.","PeriodicalId":55107,"journal":{"name":"Geologica Acta","volume":null,"pages":null},"PeriodicalIF":1.5,"publicationDate":"2018-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41702427","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Geologica ActaPub Date : 2018-01-01DOI: 10.1344/GEOLOGICAACTA2018.16.1.1
Jaakko Kara, M. Väisänen, Å. Johansson, Y. Lahaye, H. O’Brien, O. Eklund
{"title":"1.90-1.88Ga arc magmatism of central Fennoscandia: geochemistry, U-Pb geochronology, Sm-Nd and Lu-Hf isotope systematics of plutonic-volcanic rocks from southern Finland","authors":"Jaakko Kara, M. Väisänen, Å. Johansson, Y. Lahaye, H. O’Brien, O. Eklund","doi":"10.1344/GEOLOGICAACTA2018.16.1.1","DOIUrl":"https://doi.org/10.1344/GEOLOGICAACTA2018.16.1.1","url":null,"abstract":"The earliest Svecofennian magmatism in southern Finland has been dated at 1.90-1.88Ga. As an example of this, the Orijarvi (ca. 1.89Ga) and Enklinge (ca. 1.88Ga) volcanic centres comprise bimodal plutonic batholiths surrounded by volcanic rocks of comparable ages and chemical compositions. Here, we report geochemical and Sm-Nd isotope data from intrusive and extrusive samples, combined with zircon U-Pb and Lu-Hf isotopes for granodiorites from both study areas. The samples range from gabbros to granites and indicate a subduction-related continental margin setting. The zircons from the Orijarvi granodiorite define an age of 1892±4Ma whereas the Enklinge granodiorite yields an age of 1882±6Ma. Several inherited ages of 2.25-1.95Ga as well as younger ages of 1.86-1.80Ga were found in the Enklinge granodiorite. The initial e Nd values from the mafic rocks from both locations fall in the range +1.1 to +2.9 whereas the felsic rocks exhibit initial e Nd values of -0.4 to +1.2. The magmatic zircons from the Orijarvi and Enklinge granodiorites show average initial e Hf values of -1.1 (at 1892Ma) and zero (at 1882Ma), respectively, each with a spread of about 7 e-units. The initial e Hf values for the inherited zircons from Enklinge range from +3.5 to +7.6 with increasing age. The Sm-Nd data indicate that the mafic rocks were derived from a “mildly depleted” mantle source while the felsic rocks show larger crustal contribution. Also, the variation in e Hf values indicates minor mixing between mildly depleted mantle derived magmas and crustal sources. U-Pb ages and Hf isotopes for inherited zircons in the Enklinge granodiorite suggest the presence of juvenile Svecofennian “proto-crust” at depth.","PeriodicalId":55107,"journal":{"name":"Geologica Acta","volume":null,"pages":null},"PeriodicalIF":1.5,"publicationDate":"2018-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"66405049","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Geologica ActaPub Date : 2017-12-18DOI: 10.1344/GEOLOGICAACTA2017.15.4.2
J. Díaz-Alvarado
{"title":"Experimental early crystallization of K-feldspar in granitic systems : implications on the origin of magmatic fabrics in granitic rocks","authors":"J. Díaz-Alvarado","doi":"10.1344/GEOLOGICAACTA2017.15.4.2","DOIUrl":"https://doi.org/10.1344/GEOLOGICAACTA2017.15.4.2","url":null,"abstract":"One of the most outstanding characteristics of some granodioritic to granitic rocks is the presence of K-feldspar megacrysts. For instance, granodiorites and monzogranites of the Spanish Central System batholith present variable amounts of large (up to 10cm in length) euhedral K-feldspar crystals. The porphyritic textures, the euhedral shape, the alignment of plagioclase and biotite inclusions and the magmatic fabrics point to a magmatic origin for these megacrysts. This work presents a phase equilibria study in a high-K 2 O granodioritic system. A series of experiments were conducted with a granodioritic composition (GEMbiot) to study the crystallization sequence at the emplacement conditions in the Gredos massif, i.e. 4 H 2 O wt.% and 0.4GPa. Experimental results show that orthopiroxene is the liquidus phase at 1010oC, which reacts with the H 2 O-rich melt to stabilize biotite between 980 and 940oC. Plagioclase crystallizes at around 910oC, and K-feldspar crystallizes in the matrix between 750 and 700oC when the crystal fraction is around 0.5. However, at 850 oC, a pelite-doped experiment shows euhedral K-feldspar (≈5vol%) in both the reactive xenolith domain together with cordierite and the granodioritic domain, where the K 2 O wt.% rise from 4.5 in the normal experiment to 5.9 in the doped experiment. These results suggest that the bulk-assimilation process promotes the bulk and heterogeneous K 2 O enrichment in a huge granodioritic magma volume, which triggers an early crystallization of K-feldspar megacrysts. Because of this early crystallization of the megacrysts, the magmatic foliations defined by K-feldspar megacrysts are formed during and after the emplacement processes and are highly influenced by tectonic kinematics.","PeriodicalId":55107,"journal":{"name":"Geologica Acta","volume":null,"pages":null},"PeriodicalIF":1.5,"publicationDate":"2017-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44767363","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Geologica ActaPub Date : 2017-11-22DOI: 10.1344/GEOLOGICAACTA2017.15.4.5
G. Galán, P. Enrique, L. Butjosa, M. Fernández-Roig
{"title":"Spinels of Variscan olivine hornblendites related to the Montnegre granitoids revisited (NE Spain): petrogenetic evidence of mafic magma mixing","authors":"G. Galán, P. Enrique, L. Butjosa, M. Fernández-Roig","doi":"10.1344/GEOLOGICAACTA2017.15.4.5","DOIUrl":"https://doi.org/10.1344/GEOLOGICAACTA2017.15.4.5","url":null,"abstract":"Olivine hornblendites (cortlandtites) form part of the Montnegre mafic complex related to late-Variscan I-type granitoids in the Catalan Coastal Ranges. Two generations of spinel are present in these hornblendites: Spl1 forms euhedral crystals included in both olivine and Spl2. Spl2 forms euhedral to anhedral crystals associated with phlogopite and fibrous colourless amphibole forming pseudomorphs after olivine. Compositions of Spl1 are picotite-Al chromite (Fe#: 77.78-66.60; Cr#: 30.12-52.22; Fe3+/R3+: 6.99-21.89; 0.10< TiO2%<0.62). Compositions of Spl2 are pleonaste (Fe#: 37.86-52.12; Cr#: 1.00-15.45; Fe3+/R3+: 0.31-5.21; TiO2%<0.10). The two types of spinel follow a CrAl trend, mainly due to the substitution (Fe2+)-1Cr-1= MgAl, which is interpreted as the result of mixing between two different mantle-derived melts. The compositions of early Spl1 crystals included in olivine are characteristic of Al-rich basalts. More aluminous Spl2 would result from reaction of olivine with a less evolved, Al and K-rich mantle-derived melt after new refilling of the magma chamber or channel. As a whole, spinels from similar examples of Variscan olivine hronblendites also follow a CrAl trend with high Fe# and starting at higher Cr# than other trends of this type. Cr# heterogeneity in the early spinels from these Variscan hornblendites would be inherited from the variable Al content of the mafic melts involved in their genesis.","PeriodicalId":55107,"journal":{"name":"Geologica Acta","volume":null,"pages":null},"PeriodicalIF":1.5,"publicationDate":"2017-11-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43649302","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}