Journal of Materials Research and Technology-Jmr&t最新文献

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Achieving high work-hardening and high plasticity of metastable β-Ti-xV-5Zr–3Al–2Cr alloy through α" martensite
IF 6.2 2区 材料科学
Journal of Materials Research and Technology-Jmr&t Pub Date : 2025-03-18 DOI: 10.1016/j.jmrt.2025.03.158
Ruidong Yang , Zhefeng Xu , Mengying Zhu , Jiankai Bai , Yue Dong , Satoshi Motozuka , Yan Wang , Kazuhiro Matsugi , Mingzhen Ma
{"title":"Achieving high work-hardening and high plasticity of metastable β-Ti-xV-5Zr–3Al–2Cr alloy through α\" martensite","authors":"Ruidong Yang ,&nbsp;Zhefeng Xu ,&nbsp;Mengying Zhu ,&nbsp;Jiankai Bai ,&nbsp;Yue Dong ,&nbsp;Satoshi Motozuka ,&nbsp;Yan Wang ,&nbsp;Kazuhiro Matsugi ,&nbsp;Mingzhen Ma","doi":"10.1016/j.jmrt.2025.03.158","DOIUrl":"10.1016/j.jmrt.2025.03.158","url":null,"abstract":"<div><div>Metastable β titanium alloys have garnered significant attention owing to their excellent work-hardening ability and plasticity. In this work, four titanium alloys with varying initial structures were obtained by adjusting the V content: Ti-xV-5Zr–3Al–2Cr (x = 9,12,13,15 wt.%) (TxV). The influence of stress-induced α\" martensite transformation (SIMα\") on the mechanical properties of alloys was systematically investigated. The T9V alloy, despite its high content of α′ martensite, showed a total elongation of 27.7 %, attributed to SIMα\" alleviating stress concentration. In the T12V and T13V alloys, SIMα\" initially occurred, followed by the formation of {332} &lt;113&gt; twins within α\" martensite, which enhanced the uniform deformation ability, resulting in total elongation reached 44.7 % and 50.1 %, respectively. Concurrently, the reduction in the mean free path of dislocations and the reorientation of α\" martensite improved work-hardening ability. Notably, the existence of kind bands endowed the T12V alloy with a superior work-hardening rate (14.1 GPa). In contrast, the T15V alloy, which lacked SIMα\" during deformation, resulting in a lower total elongation of 19.0 %.</div></div>","PeriodicalId":54332,"journal":{"name":"Journal of Materials Research and Technology-Jmr&t","volume":"36 ","pages":"Pages 736-750"},"PeriodicalIF":6.2,"publicationDate":"2025-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143680396","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluation of 3D printed polycaprolactone/tetracalcium phosphate nanocomposite as potential scaffold for bone tissue engineering
IF 6.2 2区 材料科学
Journal of Materials Research and Technology-Jmr&t Pub Date : 2025-03-18 DOI: 10.1016/j.jmrt.2025.03.098
Shokoufeh Borhan , Saeed Hesaraki , Mostafa Shahrezaee
{"title":"Evaluation of 3D printed polycaprolactone/tetracalcium phosphate nanocomposite as potential scaffold for bone tissue engineering","authors":"Shokoufeh Borhan ,&nbsp;Saeed Hesaraki ,&nbsp;Mostafa Shahrezaee","doi":"10.1016/j.jmrt.2025.03.098","DOIUrl":"10.1016/j.jmrt.2025.03.098","url":null,"abstract":"<div><div>Three-dimensional (3D) printing is a novel technique for fabrication of bone tissue engineering scaffolds. Several inks and fillers have been used as the main components of scaffolds. This study develops scaffolds based on polycaprolactone (PCL), as printing ink, and different contents of tetracalcium phosphate nanoparticles (N-TTCP) (10–40 wt%), as a calcium-releasing source and antibacterial agent. Scanning electron microscopy and mercury porosimetry were used to investigate morphology and porosity of the scaffolds. The results showed the PCL/N-TTCP scaffolds possessed controllable porosity, in the range of 35–62 %, in which adding N-TTCP decreased the pore volume and size, in a concentration-dependent manner. Moreover, incorporating N-TTCP increased biodegradation of the PCL scaffold and improved its hydrophilicity. The compressive strength of pure PCL scaffold with the strand thickness of 355 μm was about 19 MPa. It reached to about 40 MPa by adding 40 wt% N-TTCP, with the strand thickness of 470 μm. The antibacterial activity of the pure PCL scaffold against staphylococcus aureus was 6.6 %, which increased to 58.6 % for the nanocomposite scaffold containing 40 wt % tetracalcium phosphate nanoparticles. The results of cell studies demonstrated that tetracalcium phosphate nanoparticles acted as a calcium releasing source and promoted adhesion, proliferation and ALP activity of MC3T3-E1 cells on the scaffold surfaces. Additionally, the PCL/N-TTCP scaffolds induced a higher level of bone metastasis-related proteins than the pure PCL scaffolds. Overall, the findings suggest that 3D-printed PCL/N-TTCP nanocomposite scaffold is an appropriate candidate for bone tissue engineering; however, complementary in-vivo and human clinical studies are expected.</div></div>","PeriodicalId":54332,"journal":{"name":"Journal of Materials Research and Technology-Jmr&t","volume":"36 ","pages":"Pages 1130-1145"},"PeriodicalIF":6.2,"publicationDate":"2025-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143680465","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study on the electrical conductivity, strength properties and failure modes of concrete incorporating carbon fibers and iron tailings
IF 6.2 2区 材料科学
Journal of Materials Research and Technology-Jmr&t Pub Date : 2025-03-18 DOI: 10.1016/j.jmrt.2025.03.155
Ping Jiang , Xingchen Hu , Na Li , Wei Wang , De Zhang , Haihua Zhan , Ru Song , Song Yang
{"title":"Study on the electrical conductivity, strength properties and failure modes of concrete incorporating carbon fibers and iron tailings","authors":"Ping Jiang ,&nbsp;Xingchen Hu ,&nbsp;Na Li ,&nbsp;Wei Wang ,&nbsp;De Zhang ,&nbsp;Haihua Zhan ,&nbsp;Ru Song ,&nbsp;Song Yang","doi":"10.1016/j.jmrt.2025.03.155","DOIUrl":"10.1016/j.jmrt.2025.03.155","url":null,"abstract":"<div><div>This study aims to explore the feasibility of preparing conductive concrete using carbon fibers and iron tailings and its application in snow and ice melting on roads, and to solve the problem of excessive stacking of iron tailings. In addition, the effects and action mechanisms of the water-binder ratio, the content of silica fume, the sand-binder ratio, and the content of carbon fibers on the electrical conductivity, mechanical properties, and failure modes of the concrete were studied. The results show that: (1) When the volume content of carbon fibers is 1 %, Carbon Fiber - Iron Tailing Conductive Concrete (CF-ITCC) has good electrical conductivity. Its resistivity ranges from 400 to 1800 Ω cm, which meets the requirements for conductive concrete used in snow and ice melting on roads. (2) When the water-binder ratio is 0.24, the content of silica fume is 18 %, and the sand-binder ratio is 0.8, the compressive strength and flexural strength of CF-ITCC are the highest. (3) The digital image correlation (DIC) technique was used to reveal that the main failure mode of CF-ITCC is shear failure. However, specimens G18 % and I1.6 exhibit some bulging failures, accompanied by corresponding \"X\" and \"H\" type cracks. The research shows that it is feasible to prepare conductive concrete for snow and ice melting on roads and building heating using carbon fibers and iron tailings, thereby reducing the potential environmental impacts associated with iron tailings and meeting the requirements of the green development of the construction industry.</div></div>","PeriodicalId":54332,"journal":{"name":"Journal of Materials Research and Technology-Jmr&t","volume":"36 ","pages":"Pages 522-538"},"PeriodicalIF":6.2,"publicationDate":"2025-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143645062","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mechanical properties, corrosion resistance and microstructural analysis of recycled aggregate concrete made with ceramic wall waste and ultrafine ceria
IF 6.2 2区 材料科学
Journal of Materials Research and Technology-Jmr&t Pub Date : 2025-03-18 DOI: 10.1016/j.jmrt.2025.03.154
Ansam Ali Hashim , Rana Anaee , Mohammed Salah Nasr , Ali Shubbar , Turki S. Alahmari
{"title":"Mechanical properties, corrosion resistance and microstructural analysis of recycled aggregate concrete made with ceramic wall waste and ultrafine ceria","authors":"Ansam Ali Hashim ,&nbsp;Rana Anaee ,&nbsp;Mohammed Salah Nasr ,&nbsp;Ali Shubbar ,&nbsp;Turki S. Alahmari","doi":"10.1016/j.jmrt.2025.03.154","DOIUrl":"10.1016/j.jmrt.2025.03.154","url":null,"abstract":"<div><div>This study examines how incorporating ultrafine cerium dioxide particles (UFCe) into recycled coarse aggregate concrete affects its physical, mechanical, and long-term properties. No analogous research exists about the impact of ultrafine cerium dioxide particles on various characteristics of concrete containing recycled aggregates (RCA). UFCe was employed, and its mean particle size was 350 nm in different doses (0.0, 0.5, 1.0, and 1.5 % by cement weight) to explore its effect on the properties of concrete containing 25 % coarse aggregates (RCA) prepared from ceramic wall waste. The setting time, slump flow, porosity, water absorption, compressive and tensile strengths, electrical resistance, chloride penetration resistance, corrosion resistance, and microstructure analysis were investigated. The findings indicated that UFCe significantly enhanced the compressive and tensile strength while decreasing water absorption and pore ratio comparison to the control mixture after 90 days of curing. Moreover, all mixtures displayed significantly lower chloride penetration depth and corrosion rate than the reference mixture. The inclusion of UFCe additionally improved the microstructure due to the enhancement of the ultrafine particle hydration process. On the other hand, the optimum improvement of mechanical strength, durability properties, and microstructure was recorded at a UFCe replacement rate of 0.5 %. For example, the compressive and tensile strengths increased by 33 % and 9 %, respectively, while the total water absorption and migration coefficient were reduced by 42 % and 67 % at 90 days, respectively, compared with the reference sample.</div></div>","PeriodicalId":54332,"journal":{"name":"Journal of Materials Research and Technology-Jmr&t","volume":"36 ","pages":"Pages 627-640"},"PeriodicalIF":6.2,"publicationDate":"2025-03-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143680690","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
In-situ DIC measurement to investigate initial generation mechanism of residual stress during the machining process
IF 6.2 2区 材料科学
Journal of Materials Research and Technology-Jmr&t Pub Date : 2025-03-17 DOI: 10.1016/j.jmrt.2025.03.141
Kai Ma , Zhanqiang Liu , Bing Wang
{"title":"In-situ DIC measurement to investigate initial generation mechanism of residual stress during the machining process","authors":"Kai Ma ,&nbsp;Zhanqiang Liu ,&nbsp;Bing Wang","doi":"10.1016/j.jmrt.2025.03.141","DOIUrl":"10.1016/j.jmrt.2025.03.141","url":null,"abstract":"<div><div>Residual stresses induced during the cutting process have either beneficial or detrimental effects on the corrosion resistance and fatigue performance of the manufactured parts. To effectively control or restrain residual stresses, it is crucial to gain a deep understanding of the mechanism behind their generation during the cutting process. However, the understanding of the mechanism of residual stress generation during the cutting process remains limited. This work aims to investigate the initial mechanism of residual stress generation through the subsurface deformation information within the machined and unmachined subsurface zones using the in-situ digital image correlation (DIC) technique. A high-speed in-situ measurement system was developed to obtain high-resolution microscopic images within the cutting zones. Meanwhile, a new Drop Hammer based Orthogonal Cutting (DHOC) testing machine was designed to achieve orthogonal cutting with continuous cutting speed change. Displacement and shear strain fields were obtained to identify the material flow characteristics within the subsurface zones. The effect of subsurface deformation caused by serrated chip formation on the generation of residual stress was revealed. The initiation of residual stress development was determined based on the subsurface deformation state during the cutting process. This work provides a new viewpoint to understand the generation mechanism of residual stress and develops a measurement methodology for investigating the generation process of residual stress during the cutting process.</div></div>","PeriodicalId":54332,"journal":{"name":"Journal of Materials Research and Technology-Jmr&t","volume":"36 ","pages":"Pages 939-948"},"PeriodicalIF":6.2,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143680392","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhancing phase characterization of AlCuCrFeNi high entropy alloys using hybrid machine learning models: A comprehensive XRD analysis
IF 6.2 2区 材料科学
Journal of Materials Research and Technology-Jmr&t Pub Date : 2025-03-17 DOI: 10.1016/j.jmrt.2025.03.147
Mohamed Yasin Abdul Salam , Enoch Nifise Ogunmuyiwa , Victor Kitso Manisa , Abid Yahya , Irfan Anjum Badruddin
{"title":"Enhancing phase characterization of AlCuCrFeNi high entropy alloys using hybrid machine learning models: A comprehensive XRD analysis","authors":"Mohamed Yasin Abdul Salam ,&nbsp;Enoch Nifise Ogunmuyiwa ,&nbsp;Victor Kitso Manisa ,&nbsp;Abid Yahya ,&nbsp;Irfan Anjum Badruddin","doi":"10.1016/j.jmrt.2025.03.147","DOIUrl":"10.1016/j.jmrt.2025.03.147","url":null,"abstract":"<div><div>High-Entropy Alloys (HEAs) offer exceptional mechanical and thermal properties, driving advancements in aerospace, energy, and biomedical applications. However, their complex phase diagrams present challenges for accurate phase prediction. This study introduces the Tree-Neural Ensemble Classifier (TNEC), a hybrid model integrating tree-based models and neural networks within a boosting framework to enhance phase classification accuracy. Experimental data from X-ray Diffraction (XRD) analysis of AlCuCrFeNi HEAs, subjected to heat treatments at 800 °C, 950 °C, and 1100 °C, alongside untreated samples, were used for model training. Preprocessing techniques, including noise reduction and feature extraction, ensured high-quality datasets. TNEC achieved an accuracy of 92 %, significantly outperforming Random Forest (RF) at 85 %, Support Vector Machine (SVM) at 80 %, and state-of-the-art Gradient Boosting and XGBoost models 89 %. Principal Component Analysis (PCA) confirmed structural transformations induced by temperature variations. These results highlight TNEC's capability to accurately predict phase compositions and structural transitions, providing a significant step toward real-time phase optimization in HEAs, accelerating materials discovery, and enhancing manufacturing efficiency.</div></div>","PeriodicalId":54332,"journal":{"name":"Journal of Materials Research and Technology-Jmr&t","volume":"36 ","pages":"Pages 592-605"},"PeriodicalIF":6.2,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143680687","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluation of erosive-abrasive wear resistance of Fe-19 %Cr-1.9 %C high chromium cast iron using an impeller-tumbler test device
IF 6.2 2区 材料科学
Journal of Materials Research and Technology-Jmr&t Pub Date : 2025-03-17 DOI: 10.1016/j.jmrt.2025.03.152
Jaime Alberto Sanchez Caceres, Adonias Ribeiro Franco Júnior, Leandro Bastos Bergami, Izandro de Sena Vicente
{"title":"Evaluation of erosive-abrasive wear resistance of Fe-19 %Cr-1.9 %C high chromium cast iron using an impeller-tumbler test device","authors":"Jaime Alberto Sanchez Caceres,&nbsp;Adonias Ribeiro Franco Júnior,&nbsp;Leandro Bastos Bergami,&nbsp;Izandro de Sena Vicente","doi":"10.1016/j.jmrt.2025.03.152","DOIUrl":"10.1016/j.jmrt.2025.03.152","url":null,"abstract":"<div><div>High chromium cast irons (HCCIs) are commonly used by the mining industry which high wear resistance are required. One of its applications is in iron ore pellets chutes, where plates used to protect the equipment under go high wear rates. However, since chromium content used in HCCI has large influence on the parts costs, it is important to ensure that the heat treatments applied are appropriate for each alloy composition. The present study evaluated the influence of temperature and time of austenite destabilization on the hardness and wear resistance and identified the wear mechanisms found in the experiments. The samples were subjected to temperatures of 900, 1000, and 1100 °C for 30 min and then cooled at air. Wear tests were done using tumbler impeller tribometer, equipment capable of simulating a tribo system. The results showed that the destabilization heat treatmentat 900 °C and 30 min with air cooling has better results in terms of wear resistence and hardness due to the new microstructure formed mainly by martensite and small secondary carbides dispersed in the matrix.</div></div>","PeriodicalId":54332,"journal":{"name":"Journal of Materials Research and Technology-Jmr&t","volume":"36 ","pages":"Pages 606-612"},"PeriodicalIF":6.2,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143680688","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The combined effect of reflow soldering time and Bi doping on the interfacial behavior and shear properties of Sn-0.7Cu-0.8Zn/Cu solders joint
IF 6.2 2区 材料科学
Journal of Materials Research and Technology-Jmr&t Pub Date : 2025-03-17 DOI: 10.1016/j.jmrt.2025.03.134
Wenbin Tu , Shanlin Wang , Weihua Chen , Pengfei Wang , Jilin Xie , Si Chen , Min Zheng , Mingwei Wei , Yuhua Chen , Fan Wu
{"title":"The combined effect of reflow soldering time and Bi doping on the interfacial behavior and shear properties of Sn-0.7Cu-0.8Zn/Cu solders joint","authors":"Wenbin Tu ,&nbsp;Shanlin Wang ,&nbsp;Weihua Chen ,&nbsp;Pengfei Wang ,&nbsp;Jilin Xie ,&nbsp;Si Chen ,&nbsp;Min Zheng ,&nbsp;Mingwei Wei ,&nbsp;Yuhua Chen ,&nbsp;Fan Wu","doi":"10.1016/j.jmrt.2025.03.134","DOIUrl":"10.1016/j.jmrt.2025.03.134","url":null,"abstract":"<div><div>The interfacial intermetallic compounds (IMC) layers evolution and shear properties in Sn-0.7Cu-0.8Zn/Cu and Sn-0.7Cu-0.8Zn–5Bi/Cu solder joint at different reflow soldering time were investigated. The results demonstrated that the IMC layers of solder joint with/without Bi doping and the increase of reflow soldering time are Cu<sub>6</sub>Sn<sub>5</sub> phase. However, Bi addition will increase the γ-Cu<sub>5</sub>Zn<sub>8</sub> phase closed to the IMC layer in solder matrix. The doping Bi can decrease the growth rate and voids of IMC layer. The decrease in IMC layer thickness is associated with the decline in the availability of Cu atoms and hindering the diffusion path for Cu atoms. In the case of short-time reflow soldering time, the grain size of the IMC layer in Bi-free solder joint is smaller compared to Bi-added solder joint. However, the grain size of the IMC layer of Bi-free solder joint is larger than that of Bi-added solder joint after long reflow soldering time. Although the shear strength of Bi-free and Bi-added solder joints decreases as reflow soldering time are prolonged, the shear strength of Bi-added solder joints is higher compared to Bi-free solder joints, which is the combined effect of solution strengthening, thickness reduction and grain refinement of IMC layer.</div></div>","PeriodicalId":54332,"journal":{"name":"Journal of Materials Research and Technology-Jmr&t","volume":"36 ","pages":"Pages 435-447"},"PeriodicalIF":6.2,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143645072","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Unveiling the TiZrNbTaFeCx high entropy alloy carbide coatings fabricated by superimposed HiPIMS-MF technique- effect of carbon contents on the microstructure, mechanical properties, and corrosion resistance
IF 6.2 2区 材料科学
Journal of Materials Research and Technology-Jmr&t Pub Date : 2025-03-17 DOI: 10.1016/j.jmrt.2025.03.143
Ismail Rahmadtulloh , Chaur-Jeng Wang , Bih-Show Lou , Chia-Lin Li , Igamcha Moirangthem , Krishnakant Tiwari , Chen-Hao Wang , Jyh-Wei Lee
{"title":"Unveiling the TiZrNbTaFeCx high entropy alloy carbide coatings fabricated by superimposed HiPIMS-MF technique- effect of carbon contents on the microstructure, mechanical properties, and corrosion resistance","authors":"Ismail Rahmadtulloh ,&nbsp;Chaur-Jeng Wang ,&nbsp;Bih-Show Lou ,&nbsp;Chia-Lin Li ,&nbsp;Igamcha Moirangthem ,&nbsp;Krishnakant Tiwari ,&nbsp;Chen-Hao Wang ,&nbsp;Jyh-Wei Lee","doi":"10.1016/j.jmrt.2025.03.143","DOIUrl":"10.1016/j.jmrt.2025.03.143","url":null,"abstract":"<div><div>In this research, TiZrNbTaFe high entropy alloy (HEA) and five TiZrNbTaFeC<sub>x</sub> HEA carbide coatings with different carbon contents were fabricated by a superimposed HiPIMS-MF system under different C<sub>2</sub>H<sub>2</sub> gas flow rates. The phase structure of the coating changed from amorphous to FCC at 32.40 at.% carbon. Hardness increased from 7.7 to 22.1 GPa as the carbon content increased from 0 to 32.40 at.%, then decreased to 19.5 GPa at 35.78 at.% C due to too much soft amorphous carbon phase. The HEA coating with the highest carbon content of 35.78 at.% exhibited the best wear resistance, with a lower coefficient of friction of 0.21 and the lowest wear rate of 3.80 × 10<sup>−6</sup> mm<sup>3</sup>N<sup>−1</sup>m<sup>−1</sup>. According to the potentiodynamic polarization and electrochemical impedance spectroscopy tests, the TiZrNbTaFe coating exhibited excellent corrosion resistance in 0.5 M H<sub>2</sub>SO<sub>4</sub>, which is 802.7 times better than that of bare AISI 52100. We can conclude that the 35.78 at.% C contained TiZrNbTaFeC HEA carbide coating exhibited a hardness of 19.5 GPa, excellent tribological performance, and the second-best corrosion resistance, which can be used in severely corrosive and stress bearing environments.</div></div>","PeriodicalId":54332,"journal":{"name":"Journal of Materials Research and Technology-Jmr&t","volume":"36 ","pages":"Pages 661-679"},"PeriodicalIF":6.2,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143680453","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Basic research on the effect of nitrogen content on nitride formation and grain size in titanium microalloyed low carbon steel
IF 6.2 2区 材料科学
Journal of Materials Research and Technology-Jmr&t Pub Date : 2025-03-17 DOI: 10.1016/j.jmrt.2025.03.090
Rui Yang, Yang Li, Meng Sun, Shuai Ma, Yunqie Mao, Yanshuo Ma, Tianci Li, Yucheng Wang, Dengyunfei Nie, Zhouhua Jiang
{"title":"Basic research on the effect of nitrogen content on nitride formation and grain size in titanium microalloyed low carbon steel","authors":"Rui Yang,&nbsp;Yang Li,&nbsp;Meng Sun,&nbsp;Shuai Ma,&nbsp;Yunqie Mao,&nbsp;Yanshuo Ma,&nbsp;Tianci Li,&nbsp;Yucheng Wang,&nbsp;Dengyunfei Nie,&nbsp;Zhouhua Jiang","doi":"10.1016/j.jmrt.2025.03.090","DOIUrl":"10.1016/j.jmrt.2025.03.090","url":null,"abstract":"<div><div>This study targeted titanium microalloyed low-carbon steel, focusing on the effects of nitrogen content on nitride formation and austenite grain size. A continuous nitrogen-increase experiment was conducted in molten steel, supported by thermodynamic calculations and scanning electron microscopy-energy dispersive spectroscopy (SEM-EDS), optical microscopy (OM), high-temperature confocal laser scanning microscopy (HT- CLSM) and electron probe microanalysis (EPMA). The results show that the nitrogen content in the steel rises with prolonged nitrogen blowing, reaching saturation after approximately 35 min. SEM-EDS revealed the mechanism of complex nitride inclusions in steel gradually complicated with the increase of nitrogen content. These progress from almost no nitrides (0.0064 % N) to combinations such as TiN, BN, and TiN-BN (0.0128 % N), and further to complex inclusions including TiN–Al<sub>2</sub>O<sub>3</sub> and BN-Al<sub>2</sub>O<sub>3</sub> (0.0232 % N), eventually reaching Al<sub>2</sub>O<sub>3</sub>-TiN-BN (0.0386 % N). Thermodynamic calculations reveal a sequential formation of nitrides: TiN→BN→AlN. The maximum quantity of nitrides increases with nitrogen content, and the revelation of the mechanism by which BN inhibits formation of AlN through thermodynamic calculations combined with in situ observations. BN and AlN formation involve nitrogen extraction from TiN, reducing the quantity of TiN. Additionally, the lattice mismatch calculation and EPMA show that the three nitrides can significantly promote austenite grain refinement during heat preservation. This behavior pins austenite grains, refining their size. Nitrogen solubility in this system ranges from 0.0400 % to 0.0451 %, with the optimal nitrogen addition recommended to stay below 0.02 %. These findings provide guidance for controlling nitrogen levels to enhance steel properties through microstructural refinement.</div></div>","PeriodicalId":54332,"journal":{"name":"Journal of Materials Research and Technology-Jmr&t","volume":"36 ","pages":"Pages 337-349"},"PeriodicalIF":6.2,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143645065","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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