Likun Long, Chaoyi Chen, Junqi Li, Linzhu Wang, Xiang Li
{"title":"New Insights Into the Formation Mechanism of TiN–Al2O3 Composite Inclusions in Nickel-Based Superalloys Based on Density Functional Theory","authors":"Likun Long, Chaoyi Chen, Junqi Li, Linzhu Wang, Xiang Li","doi":"10.1007/s11663-023-02890-6","DOIUrl":"https://doi.org/10.1007/s11663-023-02890-6","url":null,"abstract":"","PeriodicalId":51126,"journal":{"name":"Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science","volume":"110 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135938864","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effect of Thermal Aging on the Microstructure and Mechanical Properties of Inconel 625 Superalloy Fabricated by High-Speed Laser Metal Deposition","authors":"Cheng Zhong, Xuechong Ren, Kai Fu, Benli Luan","doi":"10.1007/s11663-023-02869-3","DOIUrl":"https://doi.org/10.1007/s11663-023-02869-3","url":null,"abstract":"","PeriodicalId":51126,"journal":{"name":"Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science","volume":"57 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135553077","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xingbang Wan, Dmitry Sukhomlinov, Pekka Taskinen, Mari Lindgren, Radoslaw Michallik, Ari Jokilaakso
{"title":"Arsenic Condensation and Reaction Mechanisms in Flash Smelting Off-Gas Line Conditions","authors":"Xingbang Wan, Dmitry Sukhomlinov, Pekka Taskinen, Mari Lindgren, Radoslaw Michallik, Ari Jokilaakso","doi":"10.1007/s11663-023-02871-9","DOIUrl":"https://doi.org/10.1007/s11663-023-02871-9","url":null,"abstract":"Abstract Arsenic is a common impurity element in sulfide concentrates. It tends to accumulate in the flue dust of smelting furnace due to the volatility and internal circulation of the flue dust practiced in the smelting-converting process chain. The only outlets for arsenic are anodes and discard slag. Arsenic condensation in dust-free conditions was studied below 800 °C where the gas atmosphere was controlled by SO 2 -air-N 2 gas mixtures. Based on these experimental results, we confirm the kinetically constrained formation mechanism of the arsenic-containing dust, and its speciation into metallic, oxidic (III, V), and sulfidic species. The influences of temperature and atmosphere on the speciation of arsenic were compared with industrial data and discussed. Graphical Abstract Condensed arsenic‐bearing particles collected by electrophoretic forces on the surface of fused SiO 2 in SO 2 ‐O 2 atmospheres: the crystal morphology shows euhedrally facetted As 2 O 3 crystals and initially molten As‐OS alloy droplets together with poorly crystallized AsS x particles.","PeriodicalId":51126,"journal":{"name":"Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science","volume":"239 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-07-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135657051","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sindre Engzelius Gylver, Kristian Etienne Einarsrud
{"title":"Modeling Alumina Feeding With the µ(I)-Rheology","authors":"Sindre Engzelius Gylver, Kristian Etienne Einarsrud","doi":"10.1007/s11663-023-02812-6","DOIUrl":"https://doi.org/10.1007/s11663-023-02812-6","url":null,"abstract":"Abstract Efficient feeding and dissolution of alumina are necessary in order to maintain a stable Hall–Héroult process. One dose of alumina contains several thousand grains, and simulating the motion of individual particles is in practice impossible. The current work proposes to model the alumina dose through a continuous formulation, using the µ (I)-rheology. The rheology is implemented as a viscosity model in OpenFOAM and initial verification cases showed an average deviation below 0.1 pct, and a benchmark case had an average deviation of 7.4 pct. A parametric study, where grains were simulated to collapse on a flat surface identified the two rheology parameters $$mu _2$$ <mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\"> <mml:msub> <mml:mi>μ</mml:mi> <mml:mn>2</mml:mn> </mml:msub> </mml:math> and $$I_{text{0}}$$ <mml:math xmlns:mml=\"http://www.w3.org/1998/Math/MathML\"> <mml:msub> <mml:mi>I</mml:mi> <mml:mtext>0</mml:mtext> </mml:msub> </mml:math> to be of particular importance, accounting for more than 70 pct of the variation seen. Finally, three-phase cases simulating the feeding of a dose in cryolite were conducted, and the µ (I)-rheology was able to let the parts of the dose disperse into the melt and detach, which is in accordance with what has been seen in experiments. The current work was also able to couple the model with an earlier developed solidification model, hence, creating a framework for developing a full model for alumina feeding.","PeriodicalId":51126,"journal":{"name":"Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science","volume":"73 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135692846","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Decomposition Characteristics of CO2 in Molten Iron and a Novel Process for Carbon-Free Deoxidation of CO2 to Produce CO","authors":"Wenhe Wu, Guangsheng Wei","doi":"10.1007/s11663-023-02819-z","DOIUrl":"https://doi.org/10.1007/s11663-023-02819-z","url":null,"abstract":"","PeriodicalId":51126,"journal":{"name":"Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science","volume":"8 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135643294","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Characteristics of AlN Precipitation and Growth During Solidification of FeCrAl Stainless Steel","authors":"Zhenqiang Deng, Jianhua Liu, Yang He","doi":"10.1007/s11663-023-02800-w","DOIUrl":"https://doi.org/10.1007/s11663-023-02800-w","url":null,"abstract":"","PeriodicalId":51126,"journal":{"name":"Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science","volume":"41 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135642906","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Amanda Vickerfält, Joar Huss, Johan Martinsson, Du Sichen
{"title":"Reaction Mechanisms During Melting of H-DRI Focusing on Slag Formation and the Behavior of Vanadium","authors":"Amanda Vickerfält, Joar Huss, Johan Martinsson, Du Sichen","doi":"10.1007/s11663-023-02827-z","DOIUrl":"https://doi.org/10.1007/s11663-023-02827-z","url":null,"abstract":"Abstract The reaction mechanisms during melting of hydrogen direct reduced iron pellets (H-DRI) with different degrees of reduction were studied experimentally at 1773 K to 1873 K at different times (60 to 600 seconds), focusing on the autogenous slag formation. It was found that an autogenous slag is formed inside the pellets prior to the melting of the metal phase. The formation of the autogenous slag started with the melting of FeO, initially located in the center of the iron grains. The liquid FeO flowed into the pore network of the pellet. While flowing, the liquid FeO dissolved parts of the residual oxides, forming an autogenous slag. The slag stayed in the pore network until the iron was molten. Upon melting of the iron, the slag coalesced into spherical droplets. The final state is reached upon the separation of the metal and slag phases by flotation, as a bulk slag was formed on the surface of the liquid iron. In addition, since the iron ore used in this study contains vanadium, the behavior of V was discussed separately based on the experimental observations to build a basis for future studies on V extraction.","PeriodicalId":51126,"journal":{"name":"Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science","volume":"49 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135477915","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Phosphorus Partition Between Liquid Crude Steel and High-Basicity Basic Oxygen Furnace Slags Containing V2O5","authors":"Lukas Neubert, Oleksandr Kovtun, Thilo Kreschel, Olena Volkova","doi":"10.1007/s11663-023-02778-5","DOIUrl":"https://doi.org/10.1007/s11663-023-02778-5","url":null,"abstract":"Abstract The influence of V 2 O 5 on the phosphorus partition between liquid crude steel and heterogenous basic oxygen furnace (BOF) slag with CaO/SiO 2 = 4.2 was investigated at a temperature of 1600 °C in a middle frequency induction furnace. Thereby the phosphorus transfer from “steel to slag” as well as from “slag to steel” was studied over a holding time of 60 minutes. The measured results were shown as phosphorus partition and phosphorus capacity and compared with the experimental values from the literature. It was found that V 2 O 5 in highly basic BOF slags decreases phosphorus partition and phosphorus capacity. In addition, the resulting slags were investigated using a scanning electron microscope (SEM).","PeriodicalId":51126,"journal":{"name":"Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science","volume":"45 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-04-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135756936","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Analysis of the Kinetics of Devitrification and Crystallization of a Melilite Mold Powder Slag for Medium Carbon Steel Billet Casting","authors":"P. La, A. Rodríguez, C. Ortega","doi":"10.1007/S11663-019-01761-3","DOIUrl":"https://doi.org/10.1007/S11663-019-01761-3","url":null,"abstract":"","PeriodicalId":51126,"journal":{"name":"Metallurgical and Materials Transactions B-Process Metallurgy and Materials Processing Science","volume":"37 1","pages":"732-755"},"PeriodicalIF":3.0,"publicationDate":"2020-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76504960","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}