Dongsheng Wang, Haina Qi, Anran Yu, Limin Tan, Tingyu He
{"title":"A MOF-derived carbon-coated Co/CoO nanomaterial for highly efficient activation of PMS to degrade tetracycline","authors":"Dongsheng Wang, Haina Qi, Anran Yu, Limin Tan, Tingyu He","doi":"10.1088/1742-6596/3013/1/012003","DOIUrl":"https://doi.org/10.1088/1742-6596/3013/1/012003","url":null,"abstract":"Abstract This study successfully fabricated a carbon-based material Co/CoO@NC catalyst derived from Co-MOF and applied it to activate PMS for the degradation of tetracycline. In the TC degradation experiments, Co/CoO@NC demonstrated remarkable catalytic performance. Under specific circumstances, only a small quantity of Co/CoO@NC was sufficient to activate PMS effectively, accomplishing the degradation of TC in a short time, with a degradation rate reaching up to 93.3%. The study on reaction kinetics revealed that the degradation process conformed to a first-order reaction kinetics model, and the reaction rate constant was 0.0360 min −1 . Additionally, the impacts of different reaction parameters such as PMS concentration, Co/CoO@NC dosage, solution pH value, and catalyst recycling times on the degradation effect were systematically examined. Meanwhile, the possible catalytic mechanism was explored through free radical capture experiments, which elucidated the essential roles of active species like SO 4 ·− , ·OH, and ·O 2 − in the TC degradation process. This study has provided more possibilities for the application of carbon-based catalysts derived from MOF precursors in the field of environmental remediation and demonstrated their great potential in treating wastewater containing tetracycline antibiotics.","PeriodicalId":506941,"journal":{"name":"Journal of Physics: Conference Series","volume":"3013 1","pages":"012003-012003"},"PeriodicalIF":0.0,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147333022","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Vertically aligned flower-like phosphorus-doped MoSe<sub>2</sub> for hydrogen evolution reaction","authors":"Qili Wang, Jing Chen","doi":"10.1088/1742-6596/3008/1/012032","DOIUrl":"https://doi.org/10.1088/1742-6596/3008/1/012032","url":null,"abstract":"Abstract In the context of escalating environmental pollution and the persistent energy crisis, there is an increasing demand for new and clean energy sources. The subject of hydrogen energy has attracted extensive attention from the public because of its remarkably high energy density and zero-emission environmental characteristics. It is regarded as a potentially significant energy source, with the potential to displace fossil fuels in the future, thereby marking a new era in energy transformation and sustainable development. However, the lack of inexpensive, abundant, and high-performance electrocatalysts hinders the advancement of hydrogen energy. In this paper, we have synthesized MoSe 2 by hydrothermal method and subsequently prepared phosphorusdoped MoSe 2 (P-MoSe 2 ) by phosphorization treatment. The P-MoSe 2 catalyst prepared in this study demonstrated excellent hydrogen evolution performance in an alkaline environment. At the prevailing current density of 10 mA·cm -2 , the catalyst demonstrated superior performance, exhibiting an overpotential of 173 mV and the Tafel slope was determined to be 88.91 mV/dec -1 . This finding provides novel insights and avenues for the exploration of new types of hydrogen evolution catalysts, thereby facilitating technical progress and practical applications in this field.","PeriodicalId":506941,"journal":{"name":"Journal of Physics: Conference Series","volume":"3008 1","pages":"012032-012032"},"PeriodicalIF":0.0,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147333484","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Enhanced Methane Production Of Food Waste Via Conductive Materials In Two-phase Anaerobic Digestion: Substance Conversion And Microbial Communities","authors":"Rufei Liu, Weijie Fan, Jie Liu","doi":"10.1088/1742-6596/3015/1/012024","DOIUrl":"https://doi.org/10.1088/1742-6596/3015/1/012024","url":null,"abstract":"Abstract The treatment and resource utilization of solid waste were the important problems that should be solved instantly. Food waste was an organic solid waste available for the production of sustainable energy. This study investigated the effects of activated carbon (AC), zero-valent iron (ZVI), and magnetite (Mt) on two-phase anaerobic digestion performance of food waste. The results suggested that adding ZVI in the acidification phase improved the concentration of volatile fatty acid by 46.4%-47.9% than that of the control group, which provided a better initial condition for the methanation phase and decreased the delay time of methane production. In the methanation phase, adding AC and Mt increased the methane production by 28.1%-68.4% compared with the control group. The analysis of microbial community structure indicated that adding ZVI improved the relative abundance of hydrolytic acidifying bacteria, including Corvnebacteriun , Fastidiosipila , Gallicola , and Syntrophaceticus in the acidification phase. Moreover, the addition of conductive materials promoted the dominant relative abundance of Methanobacterium , Methanoculleus , and Methanosarcina to stimulate the multiple methanogenic pathways of hydrogen and acetic acid.","PeriodicalId":506941,"journal":{"name":"Journal of Physics: Conference Series","volume":"3015 1","pages":"012024-012024"},"PeriodicalIF":0.0,"publicationDate":"2025-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147332866","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Encapsulation of Urea Fertilizer in Natural Polymer Chitosan using the Ionic Gelation Emulsion Method","authors":"Mahir A. Jalal, Christina Winarti, Mersi Kurniati","doi":"10.1088/1742-6596/2973/1/012018","DOIUrl":"https://doi.org/10.1088/1742-6596/2973/1/012018","url":null,"abstract":"Abstract Using urea fertilizer directly over a long period will damage soil quality. Encapsulating urea fertilizer in a material can initiate a slow release of fertilizer to reduce fertilizer residue in the soil. In this research, encapsulation of urea fertilizer using the ionic gelation emulsion method, put on chitosan as a polymer component, sodium tripolyphosphate as an ionic cross-linking agent, and polysorbates as a surfactant or emulsifying agent. Chitosan-urea nanoemulsions were made by varying the chitosan concentration to obtain nanoemulsion droplet size and porous particles. The nanoemulsion diameter size of particle was characterized using a particle size analyzer (PSA), functional groups were investigated using a Fourier-transmission infrared spectrometer, and surface morphology was using a scanning electron microscope. The result showed the average diameter of the chitosan-urea particles at the nano droplet range 140.53 nm – 787.55 nm. Spectrum band analysis obtained vibrations from the amino (-NH 2 ) and hydroxyl (-OH) functional groups, aromatic nitro compounds which indicate a combination of chitosan and the ionic cross-linking agent sodium tripolyphosphate, secondary amine (N-H) related to chitosan and amide and C-N compounds related to urea fertilizer. The morphological structure of chitosan-urea nanoemulsion for all concentrations shows a porous surface with particles that have aggregation due to the freeze-drying process. The addition of chitosan concentration can reduce the porosity of chitosan-urea. These results show the potential of gelation ionic emulsion as a method for encapsulating urea into polymers to support the slow-release fertilizer.","PeriodicalId":506941,"journal":{"name":"Journal of Physics: Conference Series","volume":"2973 1","pages":"012018-012018"},"PeriodicalIF":0.0,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://iopscience.iop.org/article/10.1088/1742-6596/2973/1/012018/pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147331757","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Self-assembled micelles prepared from amphiphilic Dextran-Jeffamine diblock copolymers","authors":"Shuxin Wang, Mengxiao Sun, Zhaoning Zeng, Dandan Wang, Xin Shen, Suming Li, Feng Su","doi":"10.1088/1742-6596/2961/1/012012","DOIUrl":"https://doi.org/10.1088/1742-6596/2961/1/012012","url":null,"abstract":"Abstract The creation of Dextran-Jeffamine (DEX-JEF) amphiphilic block polymers was achieved through the process of reductive amination. This synthesis involved reacting the semi-acetal terminal of the hydrophilic dextran (DEX) with the amine termini of Jeffamine (JEF), which could be in monoamine, diamine, or triamine forms. The result was a collection of block copolymers that included diblock, triblock, and triarm structures, each with distinct hydrophilic ratios and varying block lengths. These polymers were thoroughly analyzed by using nuclear magnetic resonance (NMR) spectroscopy and Fourier-transform infrared (FT-IR) spectroscopy to determine their structural characteristics. After the DEX-JEF polymer was self-assembled into micelles in a water medium, the micellar structure, dimensions, and zeta potential were analyzed by using Transmission Electron Microscopy (TEM) and Dynamic Light Scattering (DLS) techniques. Furthermore, the stability of the micelles was assessed by determining the Critical Micelle Concentration (CMC) through fluorescence spectroscopy measurements. Finally, the drug-carrying properties of the polymer micelles were also evaluated. The results showed that the micelle sizes ranged from 104.6-202.1 nm, CMC ranging from 0.04-0.28 mg/mL, and drug loading ranging from 4.71-7.16%. It is expected to be a potential drug carrier.","PeriodicalId":506941,"journal":{"name":"Journal of Physics: Conference Series","volume":"2961 1","pages":"012012-012012"},"PeriodicalIF":0.0,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147333314","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"In-situ polarized scaffold activated by ultrasound cycle","authors":"Xing Zhang","doi":"10.1088/1742-6596/2954/1/012046","DOIUrl":"https://doi.org/10.1088/1742-6596/2954/1/012046","url":null,"abstract":"Abstract Intervention measures are essential in clinically treating significant bone defects or poor osteogenic conditions. Although autologous transplantation is the preferred method, it has the risk of secondary injury and infection. Bone tissue engineering technology uses biomaterial scaffolds and biochemical and biophysical signals to regulate cell behaviour and promote tissue repair. The Endogenous electric field is vital in tissue regeneration, especially in bone. The piezoelectric effect of collagen matrix is closely related to bone growth and remodelling. This study prepared PCL/PTFE composite scaffolds by melting near-field direct writing technology, and an in-situ polarized was realized during the printing process. Then, periodic ultrasonic excitation was introduced to improve the polarized scaffold’s potential attenuation and realize the scaffold’s piezoelectric excitation. The results showed that the in-situ polarized scaffold could significantly promote cell proliferation and osteogenic differentiation under cyclic ultrasound stimulation. The scheme of in situ polarized scaffold combined with ultrasonic stimulation proposed in this study is expected to be applied to repair bone tissue defects and has a broad application potential.","PeriodicalId":506941,"journal":{"name":"Journal of Physics: Conference Series","volume":"2954 1","pages":"012046-012046"},"PeriodicalIF":0.0,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147331516","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"The Effect of Calibration with Different Matrix Reference Materials on the Accuracy of Oxygen Determination by Inert Gas Fusion-Infrared Absorptiometry","authors":"Ying Li, Ziheng Sang, Zhihe Zhao, Li Zhu, Xiaolu Shi, Huanming Lu, Yingli Sun, Peiling Ke, Gongjun Zhang","doi":"10.1088/1742-6596/2959/1/012004","DOIUrl":"https://doi.org/10.1088/1742-6596/2959/1/012004","url":null,"abstract":"Abstract The inert gas fusion-infrared absorptiometry is an effective means of determination of oxygen. The results need to be calibrated with reference materials (RMs), which is required to have the similar composition as the samples. However, due to the limited types of RMs on the market, currently, calibration with different matrix is widely used in the determination of oxygen of various materials. In this study, oxygen content was measured in 17 types of materials, including steels, metal oxides, non-metallic compounds, organic compounds, and oxygen-containing salts. The accuracy of oxygen determination was analyzed, and it was concluded that steel and iron oxide are effective RMs for low and high oxygen determination, respectively. It provides the experimental basis for the application of calibration with different matrix RMs to the determination of oxygen by inert gas fusion-infrared absorptiometry.","PeriodicalId":506941,"journal":{"name":"Journal of Physics: Conference Series","volume":"2959 1","pages":"012004-012004"},"PeriodicalIF":0.0,"publicationDate":"2025-02-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147331915","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Shengli Zhang, Zhichun Zeng, Yupei Sun, Long He, Changhao Wang
{"title":"Research on predicting air resistance in complex pipelines with fans","authors":"Shengli Zhang, Zhichun Zeng, Yupei Sun, Long He, Changhao Wang","doi":"10.1088/1742-6596/2791/1/012033","DOIUrl":"https://doi.org/10.1088/1742-6596/2791/1/012033","url":null,"abstract":"\u0000 This article proposes a prediction method for air resistance in aircraft brake chambers by analyzing the theoretical resistance along the pipeline and local resistance. It develops an air resistance calculation software based on this method. Finally, the air resistance of aircraft brake chamber pipes with three different specifications of fans was predicted using the methods and software presented in this article. The comparison between the predicted results and the simulation results shows that the method is accurate and reliable, and can be used to predict the air resistance inside the aircraft brake chamber.","PeriodicalId":506941,"journal":{"name":"Journal of Physics: Conference Series","volume":"12 5","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141698670","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Stellar models with like-Wyman IIa complexity factor","authors":"J. Andrade, D. Andrade","doi":"10.1088/1742-6596/2796/1/012007","DOIUrl":"https://doi.org/10.1088/1742-6596/2796/1/012007","url":null,"abstract":"\u0000 The goal of this work is to build a new family of stellar interior solutions in the anisotropic regime of pressure using the framework of gravitational decoupling via minimal geometric deformation. For such purpose, we use a generalization of the complexity factor of the well-known Wyman IIa (n = 1) interior solution in order to close the Einstein’s Field Equations, as well we use the Wyman IIa, Tolman IV, and Heintzmann IIa and Durgapal IV models as seeds solutions. These models fulfill the fundamental physical acceptability conditions for the compactness factor of the system 4U 1820-30. Stability against convection and against collapse are also studied.","PeriodicalId":506941,"journal":{"name":"Journal of Physics: Conference Series","volume":"10 6","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141702754","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Geometry-based multi-beam survey line layout problem","authors":"Chuangqi Li, Yuhang Wang, Fan Hu","doi":"10.1088/1742-6596/2791/1/012022","DOIUrl":"https://doi.org/10.1088/1742-6596/2791/1/012022","url":null,"abstract":"\u0000 The multi-beam measurement system plays a crucial role in ocean mapping and underwater terrain detection. By simultaneously transmitting multiple beams, the system can accurately receive sound waves reflected from the seabed, providing more precise and comprehensive water depth information while effectively revealing the complexity and characteristics of underwater terrain. Under the background and application provided by Question B of the 2023 National Mathematical Contest in Modeling for College Students, this paper investigates the relationship between ocean floor width measurement and factors such as beam position, angle, and slope. Utilizing geometric relations, trigonometric similarity, and sine theorem, a mathematical model is established to determine adjacent strip coverage width and overlap ratio. Furthermore, an optimal strategy is determined by using a greedy algorithm, while binary search backtracking is employed to derive the interval of the next adjacent survey line with the required overlap ratio to obtain an optimal terrain detection strategy.","PeriodicalId":506941,"journal":{"name":"Journal of Physics: Conference Series","volume":"15 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141706538","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}