ACS Applied Engineering Materials最新文献_第2页

A Facile and Low-Energy Consumption Preparation Method for Biochar via the Hofmeister Effect for Dye Adsorption and the Electrode of Supercapacitor 利用霍夫迈斯特吸附染料效应和超级电容器电极制备生物炭的简易低耗能方法

ACS Applied Engineering Materials Pub Date : 2025-10-01 DOI: 10.1021/acsaenm.5c00652

Siqi Wei, Jiaxin Duan, Dezhan Ye, Yanhu Zhan, Xiancai Jiang

{"title":"A Facile and Low-Energy Consumption Preparation Method for Biochar via the Hofmeister Effect for Dye Adsorption and the Electrode of Supercapacitor","authors":"Siqi Wei, Jiaxin Duan, Dezhan Ye, Yanhu Zhan, Xiancai Jiang","doi":"10.1021/acsaenm.5c00652","DOIUrl":"https://doi.org/10.1021/acsaenm.5c00652","url":null,"abstract":"Activated biochar has exhibited huge potential in high performance adsorbent and supercapacitor. However, the single pyrolysis process usually could provide poor pore structure, limited surface area and insufficient surface oxygen-containing groups. Herein, we innovatively propose a facile and low-energy consumption preparation method to provide biochar with high surface area and sufficient oxygen-containing groups via gelling at room temperature, conventional drying method and one-step carbonization at 350 °C. Specially, bamboo powder, a byproduct of bamboo processing, and poly(vinyl alcohol) (PVA) were selected as the raw materials. Potassium nitrate with the strong salting-out effect was introduced into the bamboo/PVA solution at the presence of CaCl2 to lead to the sol–gel transition to form the bamboo/PVA blocks at room temperature. The bamboo/PVA blocks could be dried by the conventional drying method without the collapse of pore structure. Bamboo/PVA blocks were carbonized at 300–450 °C and the characterization indicated that the BCM-350 had significant structural advantages: the specific surface area of 907.18 ± 28.31 m2/g, the rich N/O codoped surface functional groups, and the unique micromesoporous hierarchical structure. The biochar showed excellent performance in both environmental and energy applications. For pollutant removal, it exhibited a high adsorption capacity of 569.69 ± 60.92 mg/g for methyl orange dye. As a supercapacitor electrode, it showed a high specific capacitance of 120.82 ± 0.064 mF/cm2 and excellent rate performance. The whole process is free of freezing-drying and supercritical drying process and the carbonization process is just at 350 °C. This work provided a facile and low-energy consumption preparation method for biochar.","PeriodicalId":504002,"journal":{"name":"ACS Applied Engineering Materials","volume":"3 10","pages":"3544-3556"},"PeriodicalIF":0.0,"publicationDate":"2025-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147888797","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Intrinsic Flame-Retardant Phosphorylated Solid–Solid Organic Phase Change Materials for Safe Thermal Energy Storage 安全储热用特性阻燃磷酸化固-固有机相变材料

ACS Applied Engineering Materials Pub Date : 2025-09-29 DOI: 10.1021/acsaenm.5c00548

Guangyuan Liang, Yitong Cao, Yuanzheng Liu, Guo Li, Long Geng, Jiateng Zhao, Changhui Liu

引用次数: 0

Tailorable Smart Attapulgite-Based Hybrid Material for Efficient Multifunctional Oil–Water Separation and Heavy Metal Removal 可定制的智能凹凸棒土基混合材料，用于高效多功能油水分离和重金属去除

ACS Applied Engineering Materials Pub Date : 2025-09-22 DOI: 10.1021/acsaenm.5c00592

Yuying Wang, Feifei Shao, Jianfen Jing, Han Miao, Shaoliang Lin, Xinxin Li

{"title":"Tailorable Smart Attapulgite-Based Hybrid Material for Efficient Multifunctional Oil–Water Separation and Heavy Metal Removal","authors":"Yuying Wang, Feifei Shao, Jianfen Jing, Han Miao, Shaoliang Lin, Xinxin Li","doi":"10.1021/acsaenm.5c00592","DOIUrl":"https://doi.org/10.1021/acsaenm.5c00592","url":null,"abstract":"We report a tailorable strategy of constructing pH-responsive multifunctional attapulgite (APT)-polymer hybrid material by precisely grafting polymer chains onto the surface of APT via surface-initiated activators regenerated by electron transfer atom transfer radical polymerization (SI-ARGET ATRP), enabling the fine-tuning of interfacial properties by molecular-level design and leading to a smart inorganic–organic system with integrated oil/water separation and heavy metal ion removal capabilities. The resulting attapulgite-poly(2-(dimethylamino)ethyl methacrylate) (APT-PDMAEMA) hybrid exhibits reversible pH-responsive wettability and strong environmental adaptability, achieving remarkable separation efficiencies (>99.9%) and flux (∼170 L·m–2·h–1) for various types of oil–water mixtures with excellent recyclability over 10 cycles, and allowing efficient demulsification of surfactant-stabilized emulsions (>99.5% separation efficiency), high-purity and stable water flux (∼150 L·m–2·h–1). Simultaneously, the material achieves high adsorption performance for a series of heavy metal ions with removal efficiencies up to 99% across a range of pH and concentration conditions. The strategy offers modularity, scalability, and compatibility for different environmental needs. The mechanisms underlying the pH-triggered wettability and adsorption behavior were systematically investigated, offering fundamental insights into the design of smart interfaces. Overall, this work presents a versatile and scalable strategy for the tailored design of hybrid materials, providing both theoretical significance and practical value for next-generation multifunctional wastewater treatment technologies.","PeriodicalId":504002,"journal":{"name":"ACS Applied Engineering Materials","volume":"3 10","pages":"3464-3477"},"PeriodicalIF":0.0,"publicationDate":"2025-09-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147888359","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Preparation of Superhydrophobic Nonwoven Fabrics via PDMS-Cross-Linked SiO ₂ and ZnO for Effective Oil–Water Separation and Antibacterial Properties pdms交联二氧化硅和氧化锌制备超疏水非织造布的研究

ACS Applied Engineering Materials Pub Date : 2025-09-20 DOI: 10.1021/acsaenm.5c00634

Rui He, Kangli Yang, Cancheng Li, Xuyu Long, Qian Su, Zhiqing Yuan, Shoutong Meng, Sau Chung Fu, Zixuan Dai

引用次数: 0

Phycocyanin/Liquid Metal Hydrogel-Based Wearable Electronics for Monitoring Physical Stimulus-Response Behavior 基于藻蓝蛋白/液态金属水凝胶的可穿戴电子设备用于监测物理刺激反应行为

ACS Applied Engineering Materials Pub Date : 2025-08-14 DOI: 10.1021/acsaenm.5c00286

Bei Jing, Xinghai Wang, Jinxue Zhao, Xuejing Zhai, Xia Wei, Peiyi Li, Hongtao Lei, Lidong Wu

引用次数: 1

Multicompartment Synthetic Vesicles for Artificial Cell Applications 用于人工细胞应用的多室合成囊泡

ACS Applied Engineering Materials Pub Date : 2024-03-21 DOI: 10.1021/acsaenm.3c00812

Jooyong Shin, Yeongseon Jang

引用次数: 0

Constitutionally Isomeric Peptides: Subtle Changes Leading to Dramatic Differences in Properties 同分异构肽：微妙变化导致性质的巨大差异

ACS Applied Engineering Materials Pub Date : 2024-01-31 DOI: 10.1021/acsaenm.3c00787

Yin Wang, Yuxuan Lyu, Zhao Li

引用次数: 0