Bulletin of Materials Science最新文献

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A novel and highly effective iron-functionalized gel polymer for enhanced arsenic adsorption: A high-performance material for groundwater remediation 一种新型高效铁功能化凝胶聚合物增强砷吸附:一种用于地下水修复的高性能材料
IF 2.1 4区 材料科学
Bulletin of Materials Science Pub Date : 2026-10-05 DOI: 10.1007/s12034-026-03761-x
Bitan Ghosh, A K Ghosh
{"title":"A novel and highly effective iron-functionalized gel polymer for enhanced arsenic adsorption: A high-performance material for groundwater remediation","authors":"Bitan Ghosh,&nbsp;A K Ghosh","doi":"10.1007/s12034-026-03761-x","DOIUrl":"10.1007/s12034-026-03761-x","url":null,"abstract":"<div><p>The objective of this study was to develop a functionalized gel polymer having properties of specific adsorption for arsenic with the intention of arsenic decontamination from groundwater. A poly(glycidyl methacrylate) (PGMA) based polymer was synthesized and subsequently functionalized through amination and iron coordination for the development of an arsenic adsorption polymer gel. The functionalized polymers were characterized by identifying the functional group present and determining their tap density, swelling index, and amine content. Characterization of polymers functionalized with different amines confirmed the polymer’s improved swelling behavior and enabled effective iron loading. As the ethylenediamine-modified PGMA has shown the highest loading of amine, it was chosen for in-depth studies towards arsenic adsorption under different conditions. The resulting iron-functionalized polymer exhibited rapid adsorption kinetics and conformed to Langmuir isotherm behavior, suggesting a chemisorption mechanism. The material demonstrated saturation capacity as high as 31.0 and 39.0 mg/g for As (III) and As (V), respectively. It has shown strong selectivity toward arsenic species, maintained good efficiency under saline conditions, and performed optimally at near-neutral pH. These results highlight the potential of the PGMA-EN-Fe polymer as a selective, and scalable adsorbent for arsenic remediation from contaminated water sources.</p></div>","PeriodicalId":502,"journal":{"name":"Bulletin of Materials Science","volume":"49 4","pages":""},"PeriodicalIF":2.1,"publicationDate":"2026-10-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149132046","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Light-absorptive epoxy polymer composites highly loaded by Fe3O4/γ-Al2O3 filler for optical application 高负载Fe3O4/γ-Al2O3填充光吸收环氧聚合物复合材料的光学应用
IF 2.1 4区 材料科学
Bulletin of Materials Science Pub Date : 2026-10-05 DOI: 10.1007/s12034-026-03772-8
S K EVSTROPIEV, D V BULYGA, L L KHOMUTINNIKOVA, A I KASHURIN
{"title":"Light-absorptive epoxy polymer composites highly loaded by Fe3O4/γ-Al2O3 filler for optical application","authors":"S K EVSTROPIEV,&nbsp;D V BULYGA,&nbsp;L L KHOMUTINNIKOVA,&nbsp;A I KASHURIN","doi":"10.1007/s12034-026-03772-8","DOIUrl":"10.1007/s12034-026-03772-8","url":null,"abstract":"<div><p>Light absorptive polymer composites for the near IR spectral range were synthesized by the addition of large amounts (up to 69 wt.%) of nanocrystalline Fe<sub>3</sub>O<sub>4</sub> and γ-Al<sub>2</sub>O<sub>3</sub> fillers into the epoxy resin. The characterization of composites was carried out by differential scanning calorimetry and thermogravimetric technique, IR absorption and reflection spectroscopy, SEM analysis and microhardness measurements. It was found that the used combination of oxide fillers (Fe<sub>3</sub>O<sub>4 </sub>+ γ-Al<sub>2</sub>O<sub>3</sub>) increases the glass transition temperature of the epoxy polymer matrix and improves its cross-linkage. The data of IR spectroscopy shows that the addition of even large amounts of (Fe<sub>3</sub>O<sub>4 </sub>+ γ-Al<sub>2</sub>O<sub>3</sub>) fillers does not change the behavior of structural evolution in epoxy polymer during its curing process. The experimental light reflection values in the near-IR spectral range on the interface between the composites and air are 4.0–5.9%. Theoretical calculations showed that the light reflection values on the interface between the obtained composites and yttrium aluminum garnet crystals, widely used in laser systems, are less than 0.2%. The addition of large amount of (Fe<sub>3</sub>O<sub>4 </sub>+ γ-Al<sub>2</sub>O<sub>3</sub>) filler increased the Vickers microhardness of epoxy polymer from 120 MPa up to more than 200 MPa. Obtained composites are promising as light-absorbing cladding materials for lasers operating in the near-IR spectral range.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":502,"journal":{"name":"Bulletin of Materials Science","volume":"49 4","pages":""},"PeriodicalIF":2.1,"publicationDate":"2026-10-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149132479","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and growth mechanism of flake alumina via micro-zone composite molten salt method 微区复合熔盐法制备片状氧化铝及其生长机理
IF 2.1 4区 材料科学
Bulletin of Materials Science Pub Date : 2026-10-01 DOI: 10.1007/s12034-026-03757-7
Yunlong Zhao, Yanrong Zhao, Bolin Wu
{"title":"Synthesis and growth mechanism of flake alumina via micro-zone composite molten salt method","authors":"Yunlong Zhao,&nbsp;Yanrong Zhao,&nbsp;Bolin Wu","doi":"10.1007/s12034-026-03757-7","DOIUrl":"10.1007/s12034-026-03757-7","url":null,"abstract":"<div><p>As a high-performance functional powder, flake alumina is restricted from large-scale popularization and application due to the high preparation cost and difficulties in the precise control of product morphology and particle size. In this study, flake α-Al<sub>2</sub>O<sub>3</sub> was prepared via a micro-zone composite molten salt method using γ-Al<sub>2</sub>O<sub>3</sub> as the precursor. The effects of molten salt type, molten salt ratio, additive dosage and calcination regime on the regulation of the formation process and micro-morphology of flake alumina were systematically investigated, and its oriented growth mechanism was deeply elucidated. The results show that the sodium borate-sodium sulfate binary molten salt system can construct an excellent mass transfer environment for the dissolution-precipitation and crystal plane-oriented growth of alumina. The optimal formation of flake alumina is achieved when the mass ratio of Na<sub>2</sub>O/B<sub>2</sub>O<sub>3</sub> in the system is 0.85, the molten salt dosage is 40%, and the additive sodium phosphate dosage is 4%. Under the optimal conditions of calcination temperature at 1250°C and holding time for 3 h, the as-prepared flake α-Al<sub>2</sub>O<sub>3</sub> presents an average particle size of 6.03 μm with a uniform and concentrated particle size distribution. This study develops a novel preparation method for high-performance flake alumina, provides a brand-new strategy for realizing its low-cost and controllable preparation, and is expected to promote the large-scale and high-value-added application of flake alumina in the field of high-end materials.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":502,"journal":{"name":"Bulletin of Materials Science","volume":"49 4","pages":""},"PeriodicalIF":2.1,"publicationDate":"2026-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149132209","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
First-principles investigation of the electronic and optical behavior with emphasis on charge density distribution in Cs2AgAuCl6 double halide perovskite Cs2AgAuCl6双卤化物钙钛矿电子和光学行为的第一性原理研究,重点是电荷密度分布
IF 2.1 4区 材料科学
Bulletin of Materials Science Pub Date : 2026-10-01 DOI: 10.1007/s12034-026-03778-2
Ali Amor, Salim Djaili, Kouider Souleh, Tahar Smain, Brahim Lagoun, Brahim Beladel, Mohamed Halit
{"title":"First-principles investigation of the electronic and optical behavior with emphasis on charge density distribution in Cs2AgAuCl6 double halide perovskite","authors":"Ali Amor,&nbsp;Salim Djaili,&nbsp;Kouider Souleh,&nbsp;Tahar Smain,&nbsp;Brahim Lagoun,&nbsp;Brahim Beladel,&nbsp;Mohamed Halit","doi":"10.1007/s12034-026-03778-2","DOIUrl":"10.1007/s12034-026-03778-2","url":null,"abstract":"<div><p>The objective of this work is to explore the potential of the Cs<sub>2</sub>AgAuCl<sub>6</sub> double halide perovskite for solar cell applications by systematically investigating its electronic structure, charge density, and optical properties. First-principles calculations were performed using the full-potential linearized augmented plane wave (FP-LAPW) method within density functional theory, with the Tran–Blaha modified Becke–Johnson potential employed for accurate band gap estimation. The Brillouin zone was sampled with a 12 × 12 × 12 k-point mesh for ground-state properties and a denser 20 × 20 × 20 mesh for optical calculations, while the band structure was analyzed along an extended high-symmetry path (Γ–Δ–H–N–Σ–Γ–Δ–P) to capture the true conduction and valence band extrema. The results reveal that Cs<sub>2</sub>AgAuCl<sub>6</sub> is an indirect band gap semiconductor (~0.40 eV) corresponding to the infrared spectral region, and exhibits strong optical absorption in the visible range. While Cs<sub>2</sub>AgAuCl<sub>6</sub> has not yet been synthesized experimentally, similar double halide perovskites demonstrate the feasibility of such systems, and the present results may serve as a guide for future experimental realization. This work highlights the potential of Cs<sub>2</sub>AgAuCl<sub>6</sub> as a sustainable and non-toxic material for next-generation optoelectronic and energy conversion applications.</p></div>","PeriodicalId":502,"journal":{"name":"Bulletin of Materials Science","volume":"49 4","pages":""},"PeriodicalIF":2.1,"publicationDate":"2026-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149132245","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
First-principles insights into the thermodynamic and mechanical behavior of the β-phase in Mg–Zn alloys: Unveiling the underlying mechanisms Mg-Zn合金中β相热力学和力学行为的第一性原理研究:揭示其潜在机制
IF 2.1 4区 材料科学
Bulletin of Materials Science Pub Date : 2026-09-30 DOI: 10.1007/s12034-026-03737-x
Chunle Sun, Zhiyong You, Peide Han, Aoxue Jiang, Shuaishuai Jin
{"title":"First-principles insights into the thermodynamic and mechanical behavior of the β-phase in Mg–Zn alloys: Unveiling the underlying mechanisms","authors":"Chunle Sun,&nbsp;Zhiyong You,&nbsp;Peide Han,&nbsp;Aoxue Jiang,&nbsp;Shuaishuai Jin","doi":"10.1007/s12034-026-03737-x","DOIUrl":"10.1007/s12034-026-03737-x","url":null,"abstract":"<div><p>This study investigates the structural stability, mechanical properties, and thermodynamic behavior of the β-phase in the Mg–Zn system. The β-phase exhibits a trigonal crystal structure (space group R–3c) with a chemical composition of Mg<sub>126</sub>Zn<sub>150</sub>, featuring lattice parameters of a = b = 25.391 Å and c = 8.628 Å. Electronic structure analysis showed that the Mg-<i>s</i> and Zn-<i>p</i> orbitals hybridized in the low-energy region (−8 ~ −6 eV) to form covalent bonds, while the Zn-<i>d</i> orbitals dominated the metallic bonding, and the electron localization function (ELF) confirmed that the phase has mixed metallic, covalent, and ionic bonding. The ratio of bulk modulus to shear modulus (B/G = 2.150) and the positive Cauchy pressure (37.151 GPa) of the β-phase indicated its ductile nature. The elastic anisotropy parameters (A = 0.824, A<sup>U</sup> = 0.052) revealed significant directional dependence. The Debye temperature (θ<sub>d</sub> = 302.086 K) and Grüneisen parameter (γ = 0.782) suggested lattice vibrational properties and the influence of volume changes on phonon frequencies. This study revealed a unique structure–property correlation mechanism for the β-phase of Mg–Zn alloys. Magnesium alloy precipitation phases with combination of high strength, toughness and thermal stability were designed. The fundamental properties of the complex β-phase remain underexplored. This study is motivated by the potential of Mg–Zn alloys for lightweight engineering and biomedical applications, where understanding the characteristics of precipitate phases is crucial. The mechanical, anisotropic, and thermodynamic properties of the β-phase were investigated for the first time, addressing a critical gap in the literature and providing foundational insights for future alloy design.</p></div>","PeriodicalId":502,"journal":{"name":"Bulletin of Materials Science","volume":"49 4","pages":""},"PeriodicalIF":2.1,"publicationDate":"2026-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149133330","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Granule size-dependent sinterability of aurivillius-based ceramics 金相陶瓷的粒度依赖性烧结性能
IF 2.1 4区 材料科学
Bulletin of Materials Science Pub Date : 2026-09-30 DOI: 10.1007/s12034-026-03718-0
A Abourrig, M Afqir, M Elaatmani, D Fasquelle, A Tachafine
{"title":"Granule size-dependent sinterability of aurivillius-based ceramics","authors":"A Abourrig,&nbsp;M Afqir,&nbsp;M Elaatmani,&nbsp;D Fasquelle,&nbsp;A Tachafine","doi":"10.1007/s12034-026-03718-0","DOIUrl":"10.1007/s12034-026-03718-0","url":null,"abstract":"<div><p><span>({text{B}text{i}}_{4}{text{T}text{i}}_{3}{text{O}}_{12})</span>, Sr<span>({text{B}text{i}}_{4}{text{T}text{i}}_{4}{text{O}}_{15})</span> and Sr<span>({text{B}text{i}}_{2}{text{N}text{b}}_{2}{text{O}}_{9})</span> compounds were synthesized by the solid-state reaction method. Phase purity was assessed using high-resolution and conventional X-ray techniques. The calcined powder was sieved through different mesh sizes before being compacted into pellets and then sintered. Ceramics arising from powder retained within the 50–75 μm range, when exposed to 1100 °C (<span>({text{B}text{i}}_{4}{text{T}text{i}}_{3}{text{O}}_{12})</span>) and 1200 °C (Sr<span>({text{B}text{i}}_{4}{text{T}text{i}}_{4}{text{O}}_{15})</span> and Sr<span>({text{B}text{i}}_{2}{text{N}text{b}}_{2}{text{O}}_{9})</span>) for 3 h, achieved a high densification leading to improved sintering process. Based on the dielectric constant and dielectric loss, granulometric separation might be an effective vector for enhancing dielectric properties.</p></div>","PeriodicalId":502,"journal":{"name":"Bulletin of Materials Science","volume":"49 4","pages":""},"PeriodicalIF":2.1,"publicationDate":"2026-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149133341","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Magnetically recoverable and reusable BiOCl/YIG nanocomposite for high-efficiency Rhodamine B photodegradation 磁可回收和可重复使用的BiOCl/YIG纳米复合材料用于罗丹明B的高效光降解
IF 2.1 4区 材料科学
Bulletin of Materials Science Pub Date : 2026-09-30 DOI: 10.1007/s12034-026-03768-4
NAVEED RAHMAN, R YATHISH, S ABSARA FDO, P N ANANTHARAMAIAH, N MANIKANDA PRABU
{"title":"Magnetically recoverable and reusable BiOCl/YIG nanocomposite for high-efficiency Rhodamine B photodegradation","authors":"NAVEED RAHMAN,&nbsp;R YATHISH,&nbsp;S ABSARA FDO,&nbsp;P N ANANTHARAMAIAH,&nbsp;N MANIKANDA PRABU","doi":"10.1007/s12034-026-03768-4","DOIUrl":"10.1007/s12034-026-03768-4","url":null,"abstract":"<div><p>In the present study, synthesis and photocatalytic degradation of BiOCl/YIG nanocomposites prepared using 75:25 wt%, 50:50 wt% and 25:75 wt% of BiOCl and Yttrium iron garnet (YIG) are reported. BiOCl and YIG were prepared using coprecipitation and tartaric acid-gel methods, respectively. The composites were prepared by mixing respective wt% ratios by mechanical grinding and subsequently subjected to calcination at 350°C for 2 h. Phase formation of BiOCl, YIG and the composites was analyzed using powder XRD. Band gaps of as-synthesized BiOCl, YIG, B75–Y25, B50–Y50 and B25–Y75 were measured to be 3.52, 2.19, 3.34, 3.43 and 2.35 eV, respectively. Surface morphology and elemental analysis were studied using FESEM, TEM and EDS. Magnetic properties of YIG and the composites were investigated using VSM, which confirmed the possibility for magnetic separation of the nanocomposite photocatalysts. Photocatalytic studies were performed using Rhodamine B (RhB) as a model pollutant. The photocatalytic activities were found to be 96, 2, 100, 97 and 7% for BiOCl, YIG, B75–Y25, B50–Y50, and B25–Y75, respectively, in 180 min under sunlight exposure. The B75–Y25 composite was magnetically recovered, and reusability studies were carried out. The heat-treated and regenerated spent composite showed 97 and 94% efficiency for the second and third cycles. Radical scavenging studies showed the dominant role of holes in the photocatalytic degradation process. A direct Z-scheme mechanism is proposed for the B75–Y25 based on the band potential calculations and scavenging studies. This investigation demonstrated the potential of B75–Y25 as an effective, magnetically separable and reusable photocatalyst for environmental remediation.</p></div>","PeriodicalId":502,"journal":{"name":"Bulletin of Materials Science","volume":"49 4","pages":""},"PeriodicalIF":2.1,"publicationDate":"2026-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149133191","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Numerical investigation of blood micromixing under surface acoustic waves using Carreau–Yasuda rheology and ALE-based fluid–structure interaction 基于carau - yasuda流变学和基于ale的流固相互作用的表面声波下血液微混合数值研究
IF 2.1 4区 材料科学
Bulletin of Materials Science Pub Date : 2026-09-30 DOI: 10.1007/s12034-026-03767-5
VAHID RABIEI FARADONBEH, SOHEIL SALAHSHOUR, MAHMUT TANER, DAVOOD TOGHRAIE
{"title":"Numerical investigation of blood micromixing under surface acoustic waves using Carreau–Yasuda rheology and ALE-based fluid–structure interaction","authors":"VAHID RABIEI FARADONBEH,&nbsp;SOHEIL SALAHSHOUR,&nbsp;MAHMUT TANER,&nbsp;DAVOOD TOGHRAIE","doi":"10.1007/s12034-026-03767-5","DOIUrl":"10.1007/s12034-026-03767-5","url":null,"abstract":"<div><p>The primary objective of this study is to conduct a parametric analysis of the rheological behavior of blood flow in an acoustofluidic micromixing process. To account for viscosity effects, the Carreau–Yasuda fluid model is used to characterize blood flow. The micromixing performance of blood is examined across four Peclet numbers (90, 225, 360, and 450) and within a viscosity power index range of 0.3 to 0.7, corresponding to shear-thinning behavior. The numerical solution is obtained by decomposing the governing equations into three orders: zeroth-order, first-order, and second-order. The influence of channel material properties on micromixing efficiency is investigated by solving the fully coupled fluid–structure interaction (FSI) equations at the fluid–solid interface using the arbitrary Lagrangian–Eulerian (ALE) framework. The results indicate that an increase in viscosity generally weakens micromixing performance, except at a Peclet number of 90, where the trend is reversed. Additionally, as the Peclet number increases and viscosity decreases, the size of the generated vortices increases significantly. This study uniquely integrates the Carreau–Yasuda rheological model with ALE-based fluid–structure interaction, establishing a novel framework for blood micromixing. The findings highlight its potential to advance biomedical applications, particularly in lab-on-a-chip diagnostic devices and targeted drug-delivery systems.</p></div>","PeriodicalId":502,"journal":{"name":"Bulletin of Materials Science","volume":"49 4","pages":""},"PeriodicalIF":2.1,"publicationDate":"2026-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149133381","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Li-ion conduction study of scandium- and gallium-doped Li1.3Al0.3Ti1.7(PO4)3 NASICON compound 钪和镓掺杂Li1.3Al0.3Ti1.7(PO4)3 NASICON化合物的锂离子导电研究
IF 2.1 4区 材料科学
Bulletin of Materials Science Pub Date : 2026-09-30 DOI: 10.1007/s12034-026-03750-0
DHARMESH H KOTHARI, D K KANCHAN, KETAN CHAUDHARI
{"title":"Li-ion conduction study of scandium- and gallium-doped Li1.3Al0.3Ti1.7(PO4)3 NASICON compound","authors":"DHARMESH H KOTHARI,&nbsp;D K KANCHAN,&nbsp;KETAN CHAUDHARI","doi":"10.1007/s12034-026-03750-0","DOIUrl":"10.1007/s12034-026-03750-0","url":null,"abstract":"<div><p>The structural changes in polycationic material with an impact on Li–Li correlation and Li<sup>+</sup> conductivity in Li-conducting NASICON Li<sub>1.3</sub>Al<sub>0.3</sub>Ti<sub>1.7</sub>(PO<sub>4</sub>)<sub>3</sub> (LATP) and its doped versions Li<sub>1.3</sub>Al<sub>0.29</sub>Ga<sub>0.01</sub>Ti<sub>1.7</sub>(PO<sub>4</sub>)<sub>3</sub> (LAGTP) and Li<sub>1.3</sub>Al<sub>0.29</sub>Sc<sub>0.01</sub>Ti<sub>1.7</sub>(PO<sub>4</sub>)<sub>3</sub> (LASTP) and Li<sub>1.3</sub>Al<sub>0.29</sub>Ga<sub>0.005</sub>Sc<sub>0.005</sub>Ti<sub>1.7</sub>(PO<sub>4</sub>)<sub>3</sub> (LAGSTP) are discussed in the present study. The samples were prepared via the solid-state reaction method and characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, electrochemical impedance spectroscopy (EIS) and cyclic voltammetry techniques. Trivalent dopant cations M<sup>3+</sup> (M = Al<sup>3+</sup>, Ga<sup>3+</sup>, Sc<sup>3+</sup>) were found to substitute Ti<sup>4+</sup> in the LiTi<sub>2</sub>(PO<sub>4</sub>)<sub>3</sub> (LTP) framework which undermined the Ti<sub>2</sub><sup>IV</sup>(PO<sub>4</sub>)<sup>3–</sup> framework flexibility. The dopants preferentially occupied one of the two Ti sites, which resulted in sluggish Li<sup>+</sup> hopping and adversely affected the self and distinct correlation of Li<sup>+</sup>. A ‘collective’ correlation value for LATP was found to be more than 4 times that of the doped samples. LATP also showed Li<sup>+</sup> conductivity ~10<sup>–4</sup> S/cm, whereas that for the doped samples was ~10<sup>–4</sup>–10<sup>–6</sup> S/cm at room temperature. Mean square displacement analysis suggested a higher self-correlation for LATP, which was verified from the high hopping rate of Li<sup>+</sup>. Further, the effect of structural modifications on the Ti<sup>4+</sup>/Ti<sup>3+</sup> redox in the presence of Ga in LAGTP enhanced the anodic current by an order of magnitude (~10<sup>–5</sup> A). Similarly, LAGTP displayed a higher capacitive retention and energy density compared to LATP. The Ti<sup>4+</sup>/Ti<sup>3+</sup> redox was found to be suppressed in scandium containing samples.</p></div>","PeriodicalId":502,"journal":{"name":"Bulletin of Materials Science","volume":"49 4","pages":""},"PeriodicalIF":2.1,"publicationDate":"2026-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149133331","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A self-healing and injectable hydrogel for sustained delivery of BMSC-derived exosomes to promote osteogenesis and inhibit osteoclastogenesis in vitro 一种自我修复的可注射水凝胶,用于持续递送骨髓间充质干细胞衍生的外泌体,以促进体外成骨和抑制破骨细胞的发生
IF 2.1 4区 材料科学
Bulletin of Materials Science Pub Date : 2026-09-30 DOI: 10.1007/s12034-026-03774-6
Zhida Chen, Yangpeng Wu, Hanjie Zhuang, Yuanjie Jiang, Guofeng Huang, Taoyi Cai
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