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Si掺杂调控15-冠-5配位Li+机理的理论研究。 Theoretical Studies on Mechanism of 15-Crown-5 Coordinating with Li+ Regulated by Si Doping Si掺杂调控15-冠-5配位Li+机理的理论研究。 Theoretical Studies on Mechanism of 15-Crown-5 Coordinating with Li+ Regulated by Si Doping
无机化学学报 Pub Date : 2021-11-10 DOI: 10.11862/cjic.2021.236
梁苏卓成,姬国勋,孙新利,李国东,张仕通
{"title":"Si掺杂调控15-冠-5配位Li+机理的理论研究。 Theoretical Studies on Mechanism of 15-Crown-5 Coordinating with Li+ Regulated by Si Doping","authors":"梁苏卓成,姬国勋,孙新利,李国东,张仕通","doi":"10.11862/cjic.2021.236","DOIUrl":"https://doi.org/10.11862/cjic.2021.236","url":null,"abstract":"基于密度泛函理论研究了以—SiMe2—SiMe2—单元或—CH2—SiMe2—单元取代—CH2—CH2—的方式调控15-冠-5配位Li+性能的机理。结果表明掺杂Si能够增大冠醚的尺寸，并且通过不同的掺杂方式可以有效增强/减弱冠醚配位Li+的能力。分子中的原子(AIM)理论的电子密度拓扑分析和对称匹配微扰理论(SAPT)能量分解分析表明，冠醚与Li+的相互作用本质为伴随少量轨道极化和电子转移的离子-偶极相互作用。由于Si的电子比C更容易被O和Li+极化，因此Si掺杂能够增强冠醚-Li+之间的静电相互作用和诱导相互作用，但自然布居分析表明，若掺杂之后冠醚环内存在Si—O—Si单元，整体上将使O难以充分极化Si的电子，同时导致带正电的Si与Li+距离更近，因此不利于冠醚配位Li+。","PeriodicalId":501515,"journal":{"name":"无机化学学报","volume":"10 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138535546","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
锰基配位聚合物的简易合成、结构及其在葡萄糖电化学传感中的应用。 Mn-Based Coordination Polymer: Facile Synthesis, Structure and Application in Glucose Electrochemical Sensing 锰基配位聚合物的简易合成、结构及其在葡萄糖电化学传感中的应用。 Mn-Based Coordination Polymer: Facile Synthesis, Structure and Application in Glucose Electrochemical Sensing
无机化学学报 Pub Date : 2021-11-10 DOI: 10.11862/cjic.2021.237
赵璐,陈彤丹,王晗叶,李晨曦,李江
{"title":"锰基配位聚合物的简易合成、结构及其在葡萄糖电化学传感中的应用。 Mn-Based Coordination Polymer: Facile Synthesis, Structure and Application in Glucose Electrochemical Sensing","authors":"赵璐,陈彤丹,王晗叶,李晨曦,李江","doi":"10.11862/cjic.2021.237","DOIUrl":"https://doi.org/10.11862/cjic.2021.237","url":null,"abstract":"利用刚性配体6-（3-吡啶基）间苯二甲酸（H2PIAD），制备了一种基于Mn（Ⅱ）的配位聚合物{[Mn（PIAD）（DMF）]·H2O}n（1）。采用后合成Ag纳米颗粒的策略制备了复合材料（Ag@1）以提高葡萄糖传感的电催化活性。在优化的外加电位下，通过计时电流法评估了Ag@1修饰的玻碳电极（GCE）的电催化性能。配位聚合物1为在其表面的Ag纳米颗粒均匀分布提供了固定基质，而且Ag@1传感器可以最大限度地发挥Ag与1结合对葡萄糖氧化的电催化协同效应。结果表明，Ag@1修饰的GCE对葡萄糖的检测性能良好，检出限低（6.36 μmol·L-1），选择性和灵敏度好（166.71 μA·L·mmol-1·cm-2）。","PeriodicalId":501515,"journal":{"name":"无机化学学报","volume":"12 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138535547","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
同构MOFs复合氧化石墨烯电极材料构筑高性能超级电容器。 High Performance Supercapacitors Constructed with Isomorphic MOFs Doped Graphene Oxide Electrode Materials 同构MOFs复合氧化石墨烯电极材料构筑高性能超级电容器。 High Performance Supercapacitors Constructed with Isomorphic MOFs Doped Graphene Oxide Electrode Materials
无机化学学报 Pub Date : 2021-11-10 DOI: 10.11862/cjic.2021.241
籍文娟,王丹,王国娇,孙秀玲,付云龙
{"title":"同构MOFs复合氧化石墨烯电极材料构筑高性能超级电容器。 High Performance Supercapacitors Constructed with Isomorphic MOFs Doped Graphene Oxide Electrode Materials","authors":"籍文娟,王丹,王国娇,孙秀玲,付云龙","doi":"10.11862/cjic.2021.241","DOIUrl":"https://doi.org/10.11862/cjic.2021.241","url":null,"abstract":"在水热条件下一步自组装合成系列同构X-MOF（X6O（TATB）4（H+）2·（H2O）8·（DMF）2，X=Zn、Co、Ni；H3TATB=4，4'，4″-s-triazine-2，4，6-triyl-tribenzoic acid；DMF=N，N-二甲基甲酰胺）和氧化石墨烯（GO）的复合材料（X-MOF@GO），并探究其作为超级电容器电极材料的电化学性能。通过X射线粉末衍射、X射线光电子能谱和扫描电子显微镜测试证明GO和MOFs复合成功。其中，性能最优的Ni-MOFs@1.5GO（GO的添加量为1.5 mL）的比电容高达694.8 F·g-1（0.5 A·g-1），约是Ni-MOF的2倍。电化学测试结果表明：复合材料X-MOF@1.0GO较其原MOF表现出更大的比电容和更好的倍率性能。在3.5 A·g-1的电流密度下，1 000次循环充放电后，Ni-MOFs@1.0GO仍保持初始比电容量的81.2%。与活性炭（AC）组装的非对称超级电容器Ni-MOF@1.5GO//AC的性能最优，其功率密度为754.3 W·kg-1时，能量密度为15.4 Wh·kg-1，且循环3 000次后比电容保持率约为70.0%，显示出较长的循环寿命。","PeriodicalId":501515,"journal":{"name":"无机化学学报","volume":"62 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138541995","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
基于配位键和次级作用力协同效应构建的两个Co(Ⅱ) /Cd(Ⅱ) 配位超分子网络的结构及荧光性质。 Structures and Luminescence Property of Two Co(Ⅱ) and Cd(Ⅱ) Supramolecular Coordination Networks Created via Synergistic Effect of Coordination Bonds and Secondary Interactions 基于配位键和次级作用力协同效应构建的两个Co(Ⅱ) /Cd(Ⅱ) 配位超分子网络的结构及荧光性质。 Structures and Luminescence Property of Two Co(Ⅱ) and Cd(Ⅱ) Supramolecular Coordination Networks Created via Synergistic Effect of Coordination Bonds and Secondary Interactions
无机化学学报 Pub Date : 2021-11-10 DOI: 10.11862/cjic.2021.224
任永合,李鲁超,丁琦晖,黄永清,赵越
{"title":"基于配位键和次级作用力协同效应构建的两个Co(Ⅱ) /Cd(Ⅱ) 配位超分子网络的结构及荧光性质。 Structures and Luminescence Property of Two Co(Ⅱ) and Cd(Ⅱ) Supramolecular Coordination Networks Created via Synergistic Effect of Coordination Bonds and Secondary Interactions","authors":"任永合,李鲁超,丁琦晖,黄永清,赵越","doi":"10.11862/cjic.2021.224","DOIUrl":"https://doi.org/10.11862/cjic.2021.224","url":null,"abstract":"以3-羧基-1-(4-羧基苄基)吡啶溴酸盐((H2L) Br)分别与Co(Ⅱ) 和Cd(Ⅱ) 金属盐反应，制备了2个配合物[Co (L)2(H2O)4]·2H2O (1)和[Cd (L)2(H2O)]·3H2O (2)。晶体结构分析揭示配合物1是一个中性的单核配合物，其拥有丰富的并可作为超分子合成子的氢键和π-π作用力组分。对于1，单核的[Co (L)2(H2O)4]实体首先通过氢键形成具有孔道结构的二维层，该二维层进一步通过π-π堆积作用形成三维的多孔配位超分子。配合物2具有一维的“之”字形链状结构，该链通过悬挂的L配体之间的π-π作用力形成一维梯形结构。该一维梯形链进一步通过梯形边之间存在的2种π-π堆积作用形成波浪状的二维层。二维层进一步通过8种类型的O—H�O氢键连接形成三维的超分子结构。根据拓扑的观点，配合物2中的一维链采取胶合板排列。此外，配合物2显示了强的紫外荧光发射，平均寿命为2.54 ns。","PeriodicalId":501515,"journal":{"name":"无机化学学报","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138542026","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
异核Ln(Na)-MOFs(Ln=Tb、Dy、Ho)的晶体结构及对乙醛、Fe3+、Cr2O72-的荧光传感和邻苯二酚的电化学传感。 Heterometallic Ln(Na)-MOFs (Ln=Tb, Dy, Ho): Crystal Structures, Luminescent Sensing for Acetaldehyde, Fe3+, Cr2O72-, and Electrochemical Sensing for Catechol 异核Ln(Na)-MOFs(Ln=Tb、Dy、Ho)的晶体结构及对乙醛、Fe3+、Cr2O72-的荧光传感和邻苯二酚的电化学传感。 Heterometallic Ln(Na)-MOFs (Ln=Tb, Dy, Ho): Crystal Structures, Luminescent Sensing for Acetaldehyde, Fe3+, Cr2O72-, and Electrochemical Sensing for Catechol
无机化学学报 Pub Date : 2021-11-10 DOI: 10.11862/cjic.2021.232
柴红梅,闫佳伶,任宜霞 ,高楼军,张钢强,张琰,郝书苑
{"title":"异核Ln(Na)-MOFs(Ln=Tb、Dy、Ho)的晶体结构及对乙醛、Fe3+、Cr2O72-的荧光传感和邻苯二酚的电化学传感。 Heterometallic Ln(Na)-MOFs (Ln=Tb, Dy, Ho): Crystal Structures, Luminescent Sensing for Acetaldehyde, Fe3+, Cr2O72-, and Electrochemical Sensing for Catechol","authors":"柴红梅,闫佳伶,任宜霞 ,高楼军,张钢强,张琰,郝书苑","doi":"10.11862/cjic.2021.232","DOIUrl":"https://doi.org/10.11862/cjic.2021.232","url":null,"abstract":"在溶剂热条件下合成了3个新型三维微孔同构异核金属有机骨架Ln（Na）-MOFs：{[LnNa（BDT）（H2O）3]·2H2O}n（Ln=Tb（1）、Dy（2）、Ho（3），H4BDT=3，5-二（3'，5'-二羧基苯基）-1H-1，2，4-三唑），并通过单晶X射线衍射、元素分析、热重分析和粉末X射线衍射技术对其进行表征。结构分析表明，Ln（Na）-MOFs是具有相同的异核双金属单元的三维骨架结构。荧光研究表明，Tb（Na）-MOF（1）可以荧光传感检测水中Fe3+、Cr2O72-以及乙醛分子，具有较高的灵敏度和选择性，也可用于水中邻苯二酚的电化学检测。","PeriodicalId":501515,"journal":{"name":"无机化学学报","volume":"49 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138535539","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Au@ZIF-8核壳结构中金纳米粒子分布的调控及其在荧光分子光致发光传感中的应用。 Controlling Distribution of Gold Nanoparticles in Au@ZIF-8 Core-Shell Structures for Sensing Fluorescent Molecules with Photoluminescence Au@ZIF-8核壳结构中金纳米粒子分布的调控及其在荧光分子光致发光传感中的应用。 Controlling Distribution of Gold Nanoparticles in Au@ZIF-8 Core-Shell Structures for Sensing Fluorescent Molecules with Photoluminescence
无机化学学报 Pub Date : 2021-11-10 DOI: 10.11862/cjic.2021.229
张炜,张钰伊,卞亚杰,陈梦迪,张晓磊,金庆原,胡炳文
{"title":"Au@ZIF-8核壳结构中金纳米粒子分布的调控及其在荧光分子光致发光传感中的应用。 Controlling Distribution of Gold Nanoparticles in Au@ZIF-8 Core-Shell Structures for Sensing Fluorescent Molecules with Photoluminescence","authors":"张炜,张钰伊,卞亚杰,陈梦迪,张晓磊,金庆原,胡炳文","doi":"10.11862/cjic.2021.229","DOIUrl":"https://doi.org/10.11862/cjic.2021.229","url":null,"abstract":"控制金属@MOF核壳纳米结构中金属纳米粒子的分布不容易实现。我们应用了合成MOF胶体粒子所用到的配位调制方法来合成Au@ZIF-8核壳纳米结构。通过使用过量的2-甲基咪唑和不同用量的1-甲基咪唑可获得不同的Au@ZIF-8。该合成方法可在ZIF-8纳米晶体中灵活调整Au纳米粒子（Au NPs）的分布。此外，我们分别研究了2种不同尺寸的荧光分子与Au@ZIF-8结合后的光致发光光谱和寿命。ZIF-8的孔径可以决定这2种分子是否可通过多孔壳结构接近Au NPs。分子光学特性对Au NPs近场的发光增强和荧光猝灭的竞争非常敏感。","PeriodicalId":501515,"journal":{"name":"无机化学学报","volume":"82 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138535550","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
1，4-二氮杂二环[2.2.2]辛烷-氰基合钴(Ⅲ)三维框架氢键型晶体的合成、相变及介电性质。 Synthesis, Phase Transition and Dielectric Properties of 1, 4-Diazabicyclo[2.2.2]octane-Cyanide Cobalt(Ⅲ) Three-Dimensional Framework Hydrogen-Bonding Crystal 1，4-二氮杂二环[2.2.2]辛烷-氰基合钴(Ⅲ)三维框架氢键型晶体的合成、相变及介电性质。 Synthesis, Phase Transition and Dielectric Properties of 1, 4-Diazabicyclo[2.2.2]octane-Cyanide Cobalt(Ⅲ) Three-Dimensional Framework Hydrogen-Bonding Crystal
无机化学学报 Pub Date : 2021-11-10 DOI: 10.11862/cjic.2021.21
徐慧婷,刘洋,秦刘磊,齐欢欢,刘尊奇
{"title":"1，4-二氮杂二环[2.2.2]辛烷-氰基合钴(Ⅲ)三维框架氢键型晶体的合成、相变及介电性质。 Synthesis, Phase Transition and Dielectric Properties of 1, 4-Diazabicyclo[2.2.2]octane-Cyanide Cobalt(Ⅲ) Three-Dimensional Framework Hydrogen-Bonding Crystal","authors":"徐慧婷,刘洋,秦刘磊,齐欢欢,刘尊奇","doi":"10.11862/cjic.2021.21","DOIUrl":"https://doi.org/10.11862/cjic.2021.21","url":null,"abstract":"室温下以1，4-二氮杂二环[2.2.2]辛烷（Dabco）和钴氰酸为原料、水和甲醇为混合溶剂，以缓慢蒸发的方式获得Dabco-氰基合钴氢键型框架晶体材料（H3O）（H2Dabco）[Co（CN）6]·H2O（1）。并通过单晶X射线衍射、红外光谱、元素分析、粉末X射线衍射、热重分析、差示扫描量热、变温-变频介电常数测试对其结构、热性能与电性能进行表征。在低温（100 K）与室温（296 K）下，化合物均为单斜晶系P21/c空间群。单晶结构显示氰基合钴阴离子、水分子与水合质子在晶体内部通过氢键的相互作用形成三维网状框架，质子化的（H2Dabco）2+阳离子镶嵌在其中构成分子马达型囊状结构。随着温度的升高（H2Dabco）2+阳离子发生弹簧式扭转，从而引发晶体在254 K附近相变，在相同温度下沿着晶体的3个轴向发生介电异常，呈现明显的介电各向异性。","PeriodicalId":501515,"journal":{"name":"无机化学学报","volume":"23 Suppl 6 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138535540","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
松针状NiCo2O4@碳布复合材料在锂硫电池中的应用。 Application of Needle-like NiCo2O4@Carbon Cloth Composites in Lithium-Sulfur Batteries 松针状NiCo2O4@碳布复合材料在锂硫电池中的应用。 Application of Needle-like NiCo2O4@Carbon Cloth Composites in Lithium-Sulfur Batteries
无机化学学报 Pub Date : 2021-11-10 DOI: 10.11862/cjic.2021.222
杨小兰,吴忠辉,张亚军,何欣健,贾金柱,杨雄智,周俊丽
{"title":"松针状NiCo2O4@碳布复合材料在锂硫电池中的应用。 Application of Needle-like NiCo2O4@Carbon Cloth Composites in Lithium-Sulfur Batteries","authors":"杨小兰,吴忠辉,张亚军,何欣健,贾金柱,杨雄智,周俊丽","doi":"10.11862/cjic.2021.222","DOIUrl":"https://doi.org/10.11862/cjic.2021.222","url":null,"abstract":"以碳布（CC）作为柔性基底，采用水热法在其表面原位生长松针状网络结构NiCo2O4，制得NiCo2O4@CC复合材料，并应用于锂硫电池。NiCo2O4在碳纤维表面竖直生长形成三维纳米针簇网络，为硫的存储提供更多的空间，有效缓解硫电极的体积膨胀。通过吸附实验，证明了NiCo2O4@CC能有效吸附多硫化物，从而抑制多硫化物的穿梭效应。与CC/S相比（933 mAh·g-1），NiCo2O4@CC/S复合材料用于锂硫电池具有更优异的电池性能，在0.1C下初始放电比容量高达1 467 mAh·g-1，在0.2C下初始放电比容量为1 098 mAh·g-1，经200次循环后，放电比容量仍然保持在879 mAh·g-1，平均每圈衰减率为0.09%，表现出良好的循环性能。","PeriodicalId":501515,"journal":{"name":"无机化学学报","volume":"12 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138535541","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
自支撑多孔碳/硒复合柔性电极的制备及其电化学性能。 Preparation and Electrochemical Performance of Porous Carbon/Selenium Composite Free-Standing Electrode 自支撑多孔碳/硒复合柔性电极的制备及其电化学性能。 Preparation and Electrochemical Performance of Porous Carbon/Selenium Composite Free-Standing Electrode
无机化学学报 Pub Date : 2021-11-10 DOI: 10.11862/cjic.2021.242
杨淳,赵欣悦,张灵志
{"title":"自支撑多孔碳/硒复合柔性电极的制备及其电化学性能。 Preparation and Electrochemical Performance of Porous Carbon/Selenium Composite Free-Standing Electrode","authors":"杨淳,赵欣悦,张灵志","doi":"10.11862/cjic.2021.242","DOIUrl":"https://doi.org/10.11862/cjic.2021.242","url":null,"abstract":"以二氧化硅（SiO2）为模板，结合静电纺丝与溶胶-凝胶法制备了多孔碳纳米纤维膜（PCNFS），再通过熔融扩散法负载硒，制备了一种柔性的碳/硒复合电极（Se@PCNFS）。结合X射线衍射（XRD）、扫描电子显微镜（SEM）和透射电子显微镜（TEM）对材料的微观结构和形貌进行表征，结果显示多孔碳纤维直径约300 nm，硒均匀地嵌入碳纤维膜的孔洞中。电化学测试结果表明，1Se@PCNFS电极在锂硒电池中表现出优异的循环性能和倍率性能。在0.5C倍率下，初始放电比容量达到569 mAh·g-1，循环500次后比容量为340 mAh·g-1；在2C倍率时，比容量为403 mAh·g-1。","PeriodicalId":501515,"journal":{"name":"无机化学学报","volume":"45 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138535542","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
基于咪唑羧酸配体镉(Ⅱ)配合物的合成、结构调控及其性质表征。 Synthesis, Structure Regulation and Characterization of Cadmium(Ⅱ) Complexes Based on Imidazole Carboxylic Acid Ligands 基于咪唑羧酸配体镉(Ⅱ)配合物的合成、结构调控及其性质表征。 Synthesis, Structure Regulation and Characterization of Cadmium(Ⅱ) Complexes Based on Imidazole Carboxylic Acid Ligands
无机化学学报 Pub Date : 2021-11-10 DOI: 10.11862/cjic.2021.231
熊鼎奇,傅鹏鲲,李雨燕,张小雨,杨青林,贾梅梅,朱艳艳,董秀延
{"title":"基于咪唑羧酸配体镉(Ⅱ)配合物的合成、结构调控及其性质表征。 Synthesis, Structure Regulation and Characterization of Cadmium(Ⅱ) Complexes Based on Imidazole Carboxylic Acid Ligands","authors":"熊鼎奇,傅鹏鲲,李雨燕,张小雨,杨青林,贾梅梅,朱艳艳,董秀延","doi":"10.11862/cjic.2021.231","DOIUrl":"https://doi.org/10.11862/cjic.2021.231","url":null,"abstract":"利用水热法，以2-（4-羧基-苯基）咪唑-4，5-二羧酸（H3L）为主配体，在辅配体1，10-菲咯啉（1，10-phen）和1，4-二（1-咪唑基）苯（dib）的调控作用下得到2个新的镉（Ⅱ）配合物：[Cd2（HL）2（1，10-phen）2（H2O）2]（1），{[Cd（HL）（dib）0.5（H2O）2]·2H2O}n（2）。并通过单晶X射线衍射、元素分析、热重分析、粉末X射线衍射、红外光谱、Hirshfeld表面分析和密度泛函理论量化计算对1和2进行了分析和表征。配合物1和2均属于三斜晶系和P1空间群，且1为零维结构，2为一维链状结构。","PeriodicalId":501515,"journal":{"name":"无机化学学报","volume":"17 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138535545","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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