Sawyer Halingstad, , , Noemi Leick, , , Zhe Huang, , , James M. Crawford, , , Gerard Michael Carroll, , , Gabrielle A. Kliegle, , , James L. Young, , , Alexander J. Hill, , , Randy Cortright, , , Matthew M. Yung, , and , Wade A. Braunecker*,
{"title":"Photoreactive Capture and Conversion of Dilute Carbon Dioxide into Synthetic Natural Gas","authors":"Sawyer Halingstad, , , Noemi Leick, , , Zhe Huang, , , James M. Crawford, , , Gerard Michael Carroll, , , Gabrielle A. Kliegle, , , James L. Young, , , Alexander J. Hill, , , Randy Cortright, , , Matthew M. Yung, , and , Wade A. Braunecker*, ","doi":"10.1021/acsaem.5c01559","DOIUrl":"https://doi.org/10.1021/acsaem.5c01559","url":null,"abstract":"<p >This study introduces a photoreactive system that integrates the capture of dilute CO<sub>2</sub> streams with their catalytic conversion to synthetic natural gas (CH<sub>4</sub>), utilizing a Ru nanoparticle (NP)-doped TiO<sub>2</sub> composite loaded with linear polyethylenimine (L-PEI) and enhanced with plasmonic titanium nitride (TiN). This light-driven approach mitigates challenges that have plagued traditional thermal reactive carbon capture (RCC) methods, such as CO<sub>2</sub> slip and amine degradation. We demonstrate that L-PEI enables stable CO<sub>2</sub> capture and conversion, achieving ∼70% conversion of captured CO<sub>2</sub> to CH<sub>4</sub> across multiple reaction cycles using nonflammable forming gas (∼5% H<sub>2</sub>) as the reductant. In contrast, branched PEI (B-PEI)-loaded composites exhibited significant catalyst deactivation after several RCC cycles. Scanning transmission electron microscopy (STEM) imaging confirms that significant sintering of the Ru NPs occur in the B-PEI sample under RCC conditions, whereas their size remains stable in more rigid L-PEI composites. Technoeconomic analysis (TEA) estimates that CH<sub>4</sub> production using this system could cost less than $5/kg based on current electrocatalytic H<sub>2</sub> prices. These results represent one of the most promising demonstrations of amine-based RCC employing dilute CO<sub>2</sub> sources to date.</p>","PeriodicalId":4,"journal":{"name":"ACS Applied Energy Materials","volume":"8 18","pages":"13179–13184"},"PeriodicalIF":5.5,"publicationDate":"2025-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acsaem.5c01559","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145104002","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Amol S. Vedpathak*, , , Shubham S. Kalyane, , , Tanuja N. Shinde, , , Damini Bansod, , , Sambhaji S. Warule, , , Ravindra N. Bulakhe, , , Chandrakant Sonawane, , , Prasad Lokhande, , , Ji Man Kim, , and , Shrikrishna Dattatraya Sartale*,
{"title":"Interface-Engineered Nickel Preinserted Vanadium Oxide (Ni0.22V2O5) Nanobelts via Ultrasonic-Assisted Synthesis for High-Performance Solid-State Supercapacitors","authors":"Amol S. Vedpathak*, , , Shubham S. Kalyane, , , Tanuja N. Shinde, , , Damini Bansod, , , Sambhaji S. Warule, , , Ravindra N. Bulakhe, , , Chandrakant Sonawane, , , Prasad Lokhande, , , Ji Man Kim, , and , Shrikrishna Dattatraya Sartale*, ","doi":"10.1021/acsaem.5c01915","DOIUrl":"https://doi.org/10.1021/acsaem.5c01915","url":null,"abstract":"<p >Engineering nanostructured hybrid metal oxides via controlled ion preinsertion offers a promising strategy for enhancing interface properties, ion diffusion pathways, and structural integrity in energy storage materials. In this study, we report the synthesis of interface-engineered nickel-ion preinserted vanadium oxide (Ni<sub>0.22</sub>V<sub>2</sub>O<sub>5</sub>) nanobelts using a facile and cost-effective ultrasonic-assisted chemical route. This approach facilitates nickel incorporation within the V<sub>2</sub>O<sub>5</sub> matrix, resulting in expanded interlayer spacing and a layered monoclinic structure that promotes synergistic redox activity from both V and Ni elements. The nanobelt morphology further enhances electroactive surface area and ion diffusion pathways. The prepared nanobelts demonstrate exceptional electrochemical performance, achieving a specific capacitance of 913 F g<sup>–1</sup> at 0.5 A g<sup>–1</sup>, along with impressive cycling durability, retaining 90% capacitance after 10,000 cycles. Additionally, the fabricated asymmetric supercapacitor device delivers a optimal energy density of 45 Wh kg<sup>–1</sup> and power density of 4876 W kg<sup>–1</sup>, as validated through light-emitting diode (LED) lighting demonstrations. This work introduces a scalable synthesis platform for next-generation supercapacitors through transition metal ion preinsertion and interface modulation.</p>","PeriodicalId":4,"journal":{"name":"ACS Applied Energy Materials","volume":"8 18","pages":"13539–13548"},"PeriodicalIF":5.5,"publicationDate":"2025-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145104000","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Anastasia Grebenshchikova, , , Jacob Olchowka, , , Loïc Simonin, , , Mathieu Duttine, , , François Weill, , , Emmanuelle Suard, , , Christian Masquelier*, , and , Laurence Croguennec*,
{"title":"NaSICON NaFe2PO4(SO4)2 Revisited: Insights into the Crystal Structure and Electrochemical Performance","authors":"Anastasia Grebenshchikova, , , Jacob Olchowka, , , Loïc Simonin, , , Mathieu Duttine, , , François Weill, , , Emmanuelle Suard, , , Christian Masquelier*, , and , Laurence Croguennec*, ","doi":"10.1021/acsaem.5c01935","DOIUrl":"https://doi.org/10.1021/acsaem.5c01935","url":null,"abstract":"<p >With the aim to meet the needs for positive electrode materials for Na-ion batteries, based on abundant elements, synthesis routes using two different Fe<sup>3+</sup> precursors were explored for the preparation of a pure mixed phosphate-sulfate NaSICON-type compound, NaFe<sub>2</sub><sup>3+</sup>PO<sub>4</sub>(SO<sub>4</sub>)<sub>2</sub> (NFPS). Interestingly, a structural model described in the <i>R</i>-3 space group is found from careful analysis of X-ray, neutron, and electron diffraction. Atoms P and S (and thus, PO<sub>4</sub> and SO<sub>4</sub> anionic groups) are statistically distributed within the polyanionic framework, with a splitting of the conventional Na2 3<i>b</i> site into two positions 3<i>a</i> and 18<i>f</i>. Na-half cells with NFPS as a positive electrode material delivered 126 mAh/g, nearly the full theoretical capacity, at a cycling rate of D/30–C/30 (i.e., the exchange of 2 Na<sup>+</sup> in 30 h).</p>","PeriodicalId":4,"journal":{"name":"ACS Applied Energy Materials","volume":"8 18","pages":"13620–13630"},"PeriodicalIF":5.5,"publicationDate":"2025-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145104095","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Microplate-Based Multielectrochemical Cells as a Platform for High-Throughput Parallel Experiments for Accelerating the Discovery of Multicomponent Electrocatalysts","authors":"Shoichi Matsuda*, , , Ryo Tamura*, , , Misato Takahashi, , , Kazuha Nakamura, , and , Taiga Ozawa, ","doi":"10.1021/acsaem.5c02030","DOIUrl":"https://doi.org/10.1021/acsaem.5c02030","url":null,"abstract":"<p >The development of efficient electrocatalysts is a critical challenge in the advancement of energy conversion technologies. Among the diverse material candidates, multielement systems exhibit significant potential due to their compositional versatility. However, the vast number of possible combinations makes it infeasible to experimentally evaluate all candidates. High-throughput experimental approaches offer a promising solution. In this study, we developed a high-throughput platform combining parallel synthesis and evaluation based on a microplate-based electrochemical cell. The developed system enables the synthesis and electrochemical characterization of 96 samples in a parallel manner. To demonstrate its utility, we synthesized and evaluated 127 candidates for the oxygen evolution reaction (OER). Our results revealed that quaternary materials containing Fe, Ni, Cu, and Ag exhibit superior OER activity. Notably, removing any single element significantly decreased the activity, indicating the critical role of specific elements. Further analysis identified Ag and Ni as the key contributors to the enhanced OER performance. By further improvement of the synthesis throughput, this platform holds the potential to explore larger compositional spaces, accelerating the discovery of high-performance electrocatalyst materials.</p>","PeriodicalId":4,"journal":{"name":"ACS Applied Energy Materials","volume":"8 18","pages":"13714–13721"},"PeriodicalIF":5.5,"publicationDate":"2025-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/pdf/10.1021/acsaem.5c02030","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145104137","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Doping Element Effects on the Thermoelectric Output Performance of Metallized Mg2Si0.9Sn0.1 Synthesized by the Single-Step SPS Technique","authors":"Saravanan Muthiah*, , , Priyanka Sangwan, , , Sushantika Choudhary, , and , Titas Dasgupta, ","doi":"10.1021/acsaem.5c02523","DOIUrl":"https://doi.org/10.1021/acsaem.5c02523","url":null,"abstract":"<p >Stable, durable, and inexpensive thermoelectric power generators are desirable in waste heat recovery applications for effectively utilizing depleting fossil energy sources and protecting the environment by reducing greenhouse and toxic gas emissions. However, due to their low power conversion efficiency, usage of expensive materials, high production cost, complex contact selection, and fabrication strategy, the thermoelectric devices are not the best alternative in renewable energy sectors. The present study demonstrated the simultaneous fabrication of Mg<sub>2</sub>(Si<sub>0.9</sub>Sn<sub>0.1</sub>)<sub>0.95</sub>Bi<sub>0.05</sub> thermoelectric compound and contact electrode joint, eliminating the thermoelectric leg element’s manufacturing complexity. Further, the cross-section microstructural analysis of the synthesized thermoelectric element confirmed the thermoelectric materials’ phase purity and adequate interfacial joining materials’ diffusion chemistry. Also, the thermoelectric conversion efficiency evaluation system assessed the synthesized elements’ electrical properties by real-time temperature difference conditions (Δ<i>T</i> ≈ 30 to 480 K). The synthesized Mg<sub>2</sub>(Si<sub>0.9</sub>Sn<sub>0.1</sub>)<sub>0.95</sub>Bi<sub>0.05</sub> silicide material with contact electrode joining imparts low and stable contact resistance values from low to high temperatures in the measured temperature range.</p>","PeriodicalId":4,"journal":{"name":"ACS Applied Energy Materials","volume":"8 18","pages":"13970–13977"},"PeriodicalIF":5.5,"publicationDate":"2025-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145104097","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Negative Fading Phenomenon in Si/C Composite Anode with a Mixed Carbon Layer","authors":"Zi-Chen Lin, , , Yuanyuan Jiang, , , Wanwen Huang, , , Jie Gao*, , , Guodong Yang, , , Lei Miao*, , , Jianhua Zhou, , , Jun-Liang Chen, , , Haiqing Qin, , and , Feng Dang, ","doi":"10.1021/acsaem.5c01987","DOIUrl":"https://doi.org/10.1021/acsaem.5c01987","url":null,"abstract":"<p >The research into the causes of negative fading, an anomalous reversible cycling phenomenon where the cycling capacity increases with the number of cycles, is considered to potentially offer insights into achieving a leap in the cycling performance of anode materials. However, for the carbon-coated Si composite anode, which is regarded as the most promising alternative to a graphite-based anode, this phenomenon has received little attention. In this study, the Si nanoparticles coated with a mixed carbon layer derived from polydopamine and waterborne polyurethane were fabricated, and the negative fading behavior of the carbon-coated Si composite was systematically investigated. The discharging specific capacity of this anode gradually increased from 222.91 mAh g<sup>–1</sup> in the fourth cycle to 770.63 mAh g<sup>–1</sup> in the 210th cycle, and finally declined to 559.93 mAh g<sup>–1</sup> after 300 cycles. Morphological and electrochemical analyses indicate that the observed negative fading phenomenon can be attributed to the transition of flower-like carbon-coated Si aggregates from micrometer-scale to nanoscale during the cycling process, thereby enabling lithium ions to gradually intercalate into the internal Si nanoparticles. This work elucidates the correlation between morphological evolution and negative fading behavior in Si/C anodes, offering a valuable reference for the study of the abnormal cycling behavior in Si-based anodes.</p>","PeriodicalId":4,"journal":{"name":"ACS Applied Energy Materials","volume":"8 18","pages":"13663–13670"},"PeriodicalIF":5.5,"publicationDate":"2025-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145104069","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jinyu Zhang, , , Guangxiang Lu*, , , Zien Cheng, , , Rihong Cong*, , and , Tao Yang*,
{"title":"d10 Metal s-Orbital-Derived Conduction Band Enables Efficient Charge Separation in LiIn2SbO6: A Combined Band Structure and Molecular Orbital Analysis","authors":"Jinyu Zhang, , , Guangxiang Lu*, , , Zien Cheng, , , Rihong Cong*, , and , Tao Yang*, ","doi":"10.1021/acsaem.5c02242","DOIUrl":"https://doi.org/10.1021/acsaem.5c02242","url":null,"abstract":"<p >Developing efficient photocatalysts for overall water splitting remains a key challenge in solar energy conversion, mainly due to limitations in charge separation and band alignment. Here, we propose a methodological framework that combines band theory with molecular orbital theory to move beyond conventional descriptors limited to band edge positions or crystal structure. This approach enables the rapid discovery and design of photocatalysts with efficient bulk charge transport and separation pathways through orbital composition, orientation, and bonding analysis. Using LiIn<sub>2</sub>SbO<sub>6</sub> as a case study, density functional theory calculations reveal its conduction band minimum (CBM) originates from antibonding interactions between In/Sb 5s and O 2s orbitals, while the valence band maximum (VBM) consists mainly of O 2p nonbonding orbitals. This unique frontier orbital composition and orientation lead to spatially separated electron and hole transport pathways, facilitating bulk charge carrier separation via a one-dimensional covalent network of [In<sub>2</sub>O<sub>10</sub>] and [SbO<sub>6</sub>] units. Then, LiIn<sub>2</sub>SbO<sub>6</sub> was synthesized via solid-state reaction and shows a UV absorption edge ∼3.99 eV. Although the pristine sample is photocatalytically inactive, loading with Pt cocatalyst effectively activates its performance, enabling overall water splitting under UV light with H<sub>2</sub> and O<sub>2</sub> generation rates of 13.7(2) and 6.8(1) μmol/h, respectively, and an apparent quantum yield of 1.84% at 254 nm. This confirms its superior bulk charge carrier separation efficiency. This work highlights the promise of d<sup>10</sup> metal s-orbital-derived CBM for enhancing charge transport and provides a framework for discovering efficient photocatalysts through electronic structure and bonding analyses.</p>","PeriodicalId":4,"journal":{"name":"ACS Applied Energy Materials","volume":"8 18","pages":"13884–13893"},"PeriodicalIF":5.5,"publicationDate":"2025-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145104099","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Efficient Production of Green Hydrogen by Ethanol Electrolysis at a PtRhRu Catalyst","authors":"Ahmed Hashem Ali, and , Peter G. Pickup*, ","doi":"10.1021/acsaem.5c01929","DOIUrl":"https://doi.org/10.1021/acsaem.5c01929","url":null,"abstract":"<p >Production of green hydrogen by electrolysis of ethanol is potentially a more efficient technology than water electrolysis because it requires much lower cell potentials. However, separation and valorization of the acetic acid and acetaldehyde byproducts are required, producing greater uncertainty in the cost of hydrogen. Fluctuations in commodity prices also make it difficult to select the most appropriate catalysts and operating conditions. These issues are addressed here by the analysis of electrochemical data and product distributions, over a range of potentials and ethanol concentrations, using a techno-economic framework to estimate the projected cost of hydrogen. For Jan 2025 prices, a minimum cost of 4.5 USD kg<sup>–1</sup> was obtained for the production of hydrogen using a PtRhRu catalyst, which is at the high end of a range estimated for water electrolysis. However, a sensitivity analysis shows that a doubling of the price of acetic acid to 1 USD kg<sup>–1</sup> would decrease the hydrogen cost to 1.1 USD kg<sup>–1</sup>. The stoichiometry for ethanol oxidation has a strong influence on the cost, since it determines the selectivity for hydrogen production (hydrogen:ethanol ratio). Consequently, the PtRhRu catalyst is more efficient than the PtRu catalysts that are generally employed for ethanol electrolysis due to the high yields of acetic acid and CO<sub>2</sub> that it can produce. Overall, the results of the cost of hydrogen estimates and their dependence on the ethanol concentration and cell potential provide a comprehensive view of the economic potential of ethanol electrolysis and framework for optimizing catalysts and operating parameters in response to changing market conditions.</p>","PeriodicalId":4,"journal":{"name":"ACS Applied Energy Materials","volume":"8 18","pages":"13598–13606"},"PeriodicalIF":5.5,"publicationDate":"2025-09-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145104075","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Welcoming a New Associate Editors to ACS Applied Energy Materials: Professor Yoon Seok Jung","authors":"By Yiying Wu, and , Chengmei Zhong, ","doi":"10.1021/acsaem.5c02558","DOIUrl":"https://doi.org/10.1021/acsaem.5c02558","url":null,"abstract":"","PeriodicalId":4,"journal":{"name":"ACS Applied Energy Materials","volume":"8 17","pages":"12438–12439"},"PeriodicalIF":5.5,"publicationDate":"2025-09-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145007441","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Muneeb Tariq, , , Amrutha M, , , Mala N. Rao, , and , Brahmananda Chakraborty*,
{"title":"Zr-Decorated Synthesized 2D Aza-Triphenylene for High-Capacity Hydrogen Storage: Insights from DFT Simulations","authors":"Muneeb Tariq, , , Amrutha M, , , Mala N. Rao, , and , Brahmananda Chakraborty*, ","doi":"10.1021/acsaem.5c02664","DOIUrl":"https://doi.org/10.1021/acsaem.5c02664","url":null,"abstract":"<p >In our study, we explored the practical hydrogen storage properties of transition-metal (Zr)-doped two-dimensional conjugated covalent organic frameworks (COFs), i.e., Aza-triphenylene + Zr (AzaCOF + Zr). We computed the subsequent H<sub>2</sub> adsorption energies and obtained an average adsorption energy of −0.38 eV/H<sub>2</sub>. The average desorption temperature at 5 bar pressure is 310.46 K. The AzaCOF + Zr system can store a maximum of seven H<sub>2</sub> molecules per unit cell, resulting in a weight percentage of 7.26 wt %, which is higher than the gravimetric density requirement (6.5%) set by the US Department of Energy (US-DOE) for H<sub>2</sub> storage. Using charge transfer and orbital density of states (DOS) analyses, we elucidated the mechanism of TM and H<sub>2</sub> binding in Zr-decorated AzaCOF. A charge-transfer mechanism mediates the interaction between H<sub>2</sub> and the AzaCOF + Zr system, wherein each Zr atom loses a net charge of 1.58e to the AzaCOF system, computed by the aid of Bader and charge density analysis. The structural stability of Zr-decorated AzaCOF is checked using ab initio molecular dynamics simulations at a temperature of 300 K. A high diffusion energy barrier (6.4 eV) encountered by the metal adatom nullifies the possibility of metal cluster formation. Thus, by the assistance of density functional theory simulations, we predict high-storage performance of hydrogen in Zr-doped AzaCOF. Such promising theoretical predictions may inspire the experimentalists to design Zr-doped AzaCOF as a high-capacity H<sub>2</sub> storage material.</p>","PeriodicalId":4,"journal":{"name":"ACS Applied Energy Materials","volume":"8 18","pages":"13986–13998"},"PeriodicalIF":5.5,"publicationDate":"2025-09-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145104033","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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