S. S. Belevskii, A. V. Gotelyak, S. Kh. Ivashku, K. V. Kovalenko, A. I. Dikusar
{"title":"Anodic Dissolution of Surface Layers as a Means of Increasing the Microhardness of Alloy Coatings of Iron Group Metals with Tungsten Prepared by Induced Codeposition","authors":"S. S. Belevskii, A. V. Gotelyak, S. Kh. Ivashku, K. V. Kovalenko, A. I. Dikusar","doi":"10.3103/S1068375523050034","DOIUrl":"10.3103/S1068375523050034","url":null,"abstract":"<p>This work demonstrates that the macroscopic size effect, which consists in the influence of electrodeposition surface area on the composition and properties (microhardness and corrosion resistance) of alloy coatings prepared by induced codeposition of iron group metals with tungsten, is a particular case of this type of effects and this requires maintaining the volume current density (VCD) constant during electrodeposition. The effect is associated with the formation of surface oxy-hydroxide and hydrogenated layers. For electrodeposition of Fe–W and Co–W alloys from a citrate bath, it is established that a change in VCD at a definite value for current density of electrodeposition results in changes in the electrode potential, current efficiency, and alloy composition. Anodic dissolution of the modified surface layer allows increasing the microhardness but does not cancel the dependence of coating composition and properties on the electrode surface area.</p>","PeriodicalId":49315,"journal":{"name":"Surface Engineering and Applied Electrochemistry","volume":"59 5","pages":"549 - 555"},"PeriodicalIF":0.9,"publicationDate":"2023-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49671086","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Calculation of the Maximal Number of Zones of Longitudinal Periodic Localization of Drifting Electrons in the Metal Conductor with Electric Conduction Current","authors":"M. I. Baranov","doi":"10.3103/S1068375523050022","DOIUrl":"10.3103/S1068375523050022","url":null,"abstract":"<p>The results of an approximate calculation of the maximal value of the quantum number of <i>n = n</i><sub><i>m</i></sub> for the quantized standing longitudinal electron de Broglie half-waves λ<sub><i>ezn</i></sub><i>/</i>2 <i>= l</i><sub>0</sub><i>/n</i> long and, accordingly, of the maximal number of <i>n</i><sub><i>m</i></sub> of the quantized zones of the longitudinal periodic localization with the length Δ<i>z</i><sub><i>nh</i></sub> of the drifting free electrons in the cylindrical conductors of finite size (<i>l</i><sub>0</sub> in length and <i>r</i><sub>0</sub> in radius) with the axial conduction current <i>i</i><sub>0</sub>(<i>t</i>) of the indicated kinds and the amplitude and time parameters (ATPs) are presented, taking into account the quantum-wave nature of the electric conduction current <i>i</i><sub>0</sub>(<i>t</i>) of different kinds (direct, alternating, and pulse) and ATPs in the metal conductors. The results of a verification of the calculated quantum-mechanical relationship to determine the quantum number <i>n</i><sub><i>m</i></sub> confirm its validity in such areas of engineering as high-voltage high-current pulse equipment and the electrophysical processing of metals by a strong electromagnetic field and by the pressure of a large pulse current.</p>","PeriodicalId":49315,"journal":{"name":"Surface Engineering and Applied Electrochemistry","volume":"59 5","pages":"613 - 617"},"PeriodicalIF":0.9,"publicationDate":"2023-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49671098","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. I. Vovchenko, L. Yu. Demidenko, S. S. Kozyrev, L. E. Ovchinnikova
{"title":"Synthesis of Combined Power Sources Based on High-Voltage Electrochemical Explosion","authors":"A. I. Vovchenko, L. Yu. Demidenko, S. S. Kozyrev, L. E. Ovchinnikova","doi":"10.3103/S1068375523050174","DOIUrl":"10.3103/S1068375523050174","url":null,"abstract":"<div><div><h3>\u0000 <b>Abstract</b>—</h3><p>A stepwise algorithm was developed for the synthesis of combined power sources based on high-voltage electrochemical explosion (HVECE). These sources ensure the necessary spatial-temporal force and energy effects on objects of treatment to perform specific technological operations. Initially, a power source is synthesized based on high-voltage electrical discharge in condensed media through solving inverse synthesis problems. This determines the required total energy, which is then optimally divided into electrical and chemical components. The dependences of the force impact on the object of treatment on the energy characteristics of HVECE were experimentally studied. Based on the experimental results, criteria for the optimal division of the required total energy into the electrical and chemical components were established. A specific application example of the developed algorithm for the synthesis of a combined power source based on HVECE is provided, which confirmed that it can be used for engineering calculations.</p></div></div>","PeriodicalId":49315,"journal":{"name":"Surface Engineering and Applied Electrochemistry","volume":"59 5","pages":"690 - 697"},"PeriodicalIF":0.9,"publicationDate":"2023-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49671059","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
S. A. Kusmanov, I. V. Tambovskii, T. L. Mukhacheva, S. A. Silkin, S. S. Korableva, R. D. Belov, E. V. Sokova
{"title":"Electrolyte-Plasma Nitriding of Austenitic Stainless Steel under Cathodic and Anodic Polarity","authors":"S. A. Kusmanov, I. V. Tambovskii, T. L. Mukhacheva, S. A. Silkin, S. S. Korableva, R. D. Belov, E. V. Sokova","doi":"10.3103/S1068375523050101","DOIUrl":"10.3103/S1068375523050101","url":null,"abstract":"<div><div><h3>\u0000 <b>Abstract</b>—</h3><p>The article presents the results of surface modification of austenitic stainless steel by electrolyte-plasma nitriding under anodic and cathodic polarity of the product being treated. The morphology and surface roughness, phase composition, and microhardness of diffusion layers, as well as tribological and corrosion properties, were studied. The effect of physicochemical processes during anodic and cathodic treatments on the features of the formation of a modified surface and its operational properties is demonstrated. The anodic treatment increased the hardness of the nitrided layers up to 1150 HV, halved the surface roughness, improved the wear resistance by a factor of 166, and decreased the coefficient of friction by a factor of 1.6. The cathodic treatment increased the hardness only to 580 HV and improved the wear resistance by a factor of 13.6. Both treatments were shown to decrease pitting corrosion in a sodium chloride medium.</p></div></div>","PeriodicalId":49315,"journal":{"name":"Surface Engineering and Applied Electrochemistry","volume":"59 5","pages":"582 - 589"},"PeriodicalIF":0.9,"publicationDate":"2023-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49671017","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effect of Uneven Microwave Heating of the Liquid–Liquid System on the Intensity of a Chemical Process in a Microreactor","authors":"A. V. Markov, V. A. Borovkov, Yu. P. Yulenets","doi":"10.3103/S1068375523050113","DOIUrl":"10.3103/S1068375523050113","url":null,"abstract":"<p>In this paper, we study the effect of microwave heating of liquid reagents in a closed-type beam chamber on the intensity of a chemical process in a microreactor. The heating of the reagents, which is uneven along the length of the microreactor, is shown to stimulate the development of thermocapillary convection and significantly intensifies the chemical process. The maximal velocities of thermocapillary motion developed at the interphase boundary of contacting liquids depending on the specific power of internal heat sources and the longitudinal temperature gradient is numerically estimated.</p>","PeriodicalId":49315,"journal":{"name":"Surface Engineering and Applied Electrochemistry","volume":"59 5","pages":"628 - 633"},"PeriodicalIF":0.9,"publicationDate":"2023-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49671051","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sijad Hussain, Asim Yaqub, Zulfiqar Ahmad Bhatti, Romana Khan, Huma Ajab, Mohamed Hasnain Isa
{"title":"Electrocoagulation of Reactive Orange 16 Textile Dye Solution Using Steel, Aluminum, and Copper Metal Plates as Electrodes","authors":"Sijad Hussain, Asim Yaqub, Zulfiqar Ahmad Bhatti, Romana Khan, Huma Ajab, Mohamed Hasnain Isa","doi":"10.3103/S1068375523050095","DOIUrl":"10.3103/S1068375523050095","url":null,"abstract":"<p>This study presented the comparison of the electrocoagulation efficiencies for steel, aluminum, and copper electrodes for the chemical oxygen demand (COD) removal and decolorization from solutions comprising the reactive orange 16. The electrodes were used in similar couples in this research, namely, Fe (anode) to Fe (cathode), Al (anode) to Al (cathode), and Cu (anode) to Cu (cathode). The samples were analyzed using spectrophotometric techniques UV/VIS and a colorimetric method. Higher removal efficiencies for color and COD were found at the current density of 0.025 A/cm<sup>2</sup>, i.e. Fe/Al/Cu electrodes gave 91, 62, and 51% in the COD removal and 93, 82, and 70% for color removal. Other parameters taken such as pH, electrolysis time, and the initial azo dye concentrations were also optimized at all of the electrodes. The decolorization and COD removal efficiencies were found decreased with increasing the initial dye concentration. Being simple and cost effective, this technique can be applicable for the treatment of real textile wastewater.</p>","PeriodicalId":49315,"journal":{"name":"Surface Engineering and Applied Electrochemistry","volume":"59 5","pages":"661 - 669"},"PeriodicalIF":0.9,"publicationDate":"2023-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49671096","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Features of Electrodeless Electrochemical Reactions","authors":"S. V. Rzayeva","doi":"10.3103/S1068375523050150","DOIUrl":"10.3103/S1068375523050150","url":null,"abstract":"<p>This article deals with reactions occurring under the action of active particles formed during the flash of a corona electric discharge between a solid electrode and the surface of a liquid—electrochemical reactions without an electrode. Reactions take place in a thin surface layer of water, where there are no electrodes, so the reactions are called electrodeless. The electrodes are used only to excite the reaction zone and do not directly participate in the reaction. The oxidation of organic compounds to carbon dioxide and water occurs in an electrodeless reaction.</p>","PeriodicalId":49315,"journal":{"name":"Surface Engineering and Applied Electrochemistry","volume":"59 5","pages":"590 - 594"},"PeriodicalIF":0.9,"publicationDate":"2023-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49671001","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
H. T. Doan, D. A. Golosov, J. Zhang, S. N. Melnikov, S. M. Zavadski
{"title":"Application of Optical Emission Spectroscopy for Predicting the Composition of Films in Reactive Magnetron Sputtering of Ti–Al Composite Targets","authors":"H. T. Doan, D. A. Golosov, J. Zhang, S. N. Melnikov, S. M. Zavadski","doi":"10.3103/S106837552305006X","DOIUrl":"10.3103/S106837552305006X","url":null,"abstract":"<div><div><h3>\u0000 <b>Abstract</b>—</h3><p>The processes of reactive magnetron sputtering of Ti–Al composite targets with varying Al/Ti ratios were studied. Dependences of deposition rate, discharge voltage, elemental composition, and intensity of reference plasma emission lines were determined as functions of the oxygen concentration in the Ar–O<sub>2</sub> gas mixture. It was demonstrated that, in reactive sputtering of Ti–Al composite targets, the discharge voltage is determined by the effective ion–electron emission coefficient (IEEC), which depends on the area occupied by the metals on the target, their oxidation states, and the IEEC of the metals and their oxides. The deposition rate of Ti<sub><i>x</i></sub>Al<sub>1 – <i>x</i></sub>O<sub><i>y</i></sub> films both in the metallic and transitional sputtering modes increases proportionally to the fraction of Al in the target, and the relative concentration of the metals in the deposited films depends on the oxygen concentration in the Ar–O<sub>2</sub> gas mixture and is determined by the reactivity of the constituent materials in the target. By optical emission spectroscopy (OES), it was shown that the ratio of the atomic concentrations of Al and Ti in the deposited Ti<sub><i>x</i></sub>Al<sub>1 – <i>x</i></sub>O<sub><i>y</i></sub> films uniquely depends on the ratio of the intensities of the aluminum emission line (AlI) and the titanium emission line (TiI) in the plasma. This allows using OES for predicting the metal contents in the films in reactive magnetron sputtering of Ti–Al targets.</p></div></div>","PeriodicalId":49315,"journal":{"name":"Surface Engineering and Applied Electrochemistry","volume":"59 5","pages":"682 - 689"},"PeriodicalIF":0.9,"publicationDate":"2023-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49671011","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Development and Creation of a New Class of Graded-Gap Structures Based on Silicon with the Participation of Zn and Se Atoms","authors":"N. F. Zikrillaev, O. B. Tursunov, G. A. Kushiev","doi":"10.3103/S1068375523050198","DOIUrl":"10.3103/S1068375523050198","url":null,"abstract":"<p>The possibility of the formation of structures such as compounds of elements between chalcogenides and the transition group of metals in the crystal lattice of silicon is studied. This is an urgent problem in electronics. It is shown that, under certain technological conditions, a sufficient concentration of unit cells is formed, which leads to a change in the band structure of silicon itself; i.e., a micro- and nanoscale inclusion in silicon with a direct-gap structure is obtained. The possibilities of creating a fundamentally new class of photocells with an extended spectral sensitivity region, as well as light-emitting devices, light-emitting diodes, and lasers based on them, are shown.</p>","PeriodicalId":49315,"journal":{"name":"Surface Engineering and Applied Electrochemistry","volume":"59 5","pages":"670 - 673"},"PeriodicalIF":0.9,"publicationDate":"2023-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49671027","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A Model of the Flow of a Nanomedium Removing Particles from the Electroerosion Zone","authors":"V. S. Deeva, S. M. Slobodyan, V. S. Teterin","doi":"10.3103/S1068375523050058","DOIUrl":"10.3103/S1068375523050058","url":null,"abstract":"<div><div><h3>\u0000 <b>Abstract</b>—</h3><p>A model was proposed and studied to explore the changes in the dynamics of the physical properties and structure of a homogeneous medium in the anode–cathode (SWCNT–surface) gap due to the influence of stochastic emission of erosion particles into the random interval during their carryover by the medium from the electroerosion zone during making micro- and nanoholes in the material. The model takes into account the influence exerted on the properties of the combined flow by the dynamics of the motion of a tool (SWCNT–electrode), the orientation of the erosion zone and particle removal, and the variable density of the homogeneous phase of the flow. Changes were identified in the properties and parameters of the combined flow during the carryover of its erosion particles at different angles of orientation of the erosion zone. Verification using the methods of similarity theory and practice showed satisfactory agreement between the modeling results, numerical experiments, and natural experiments conducted by other researchers.</p></div></div>","PeriodicalId":49315,"journal":{"name":"Surface Engineering and Applied Electrochemistry","volume":"59 5","pages":"556 - 568"},"PeriodicalIF":0.9,"publicationDate":"2023-10-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49671063","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}