Dr. Lakshmana Reddy N, Kiyoung Lee, Yeon-Tae Yu, J. Theerthagiri, M. V. Shankar
{"title":"CHAPTER 4. Nanomaterials and Their Modification for Environmental Remediation","authors":"Dr. Lakshmana Reddy N, Kiyoung Lee, Yeon-Tae Yu, J. Theerthagiri, M. V. Shankar","doi":"10.1039/9781839165283-00079","DOIUrl":"https://doi.org/10.1039/9781839165283-00079","url":null,"abstract":"This chapter elucidates the environmental application of a wide range of nanomaterials. Environmental pollution and global warming are severe problems facing the world due to increased usage of fossil fuels and the size of the world's population. Thus, there is a need for smart materials with technological developments to overcome these problems. Therefore, we discuss the unique properties of various nanomaterials specially used for environmental remediation. The different types of nanomaterials discussed includes 0D nanoparticles, 1D nanorods, nanotubes, nanowires, and 2D nanosheet-based composite nanomaterials and nanostructures. It starts with a brief introduction followed by the various combinations of these nanomaterials viz., metal and non-metal doping, and composites of nanomaterials. Also discussed are the special properties of carbon-based nanomaterials like g-C3N4, carbon nanotubes, graphene, graphene oxide, and reduced graphene oxide. We explain how the special properties of these types of nanomaterials successfully address various critical environmental problems, such as organic dye degradation, air purification, and industrial waste water purification. Thus, this chapter gives an overview of various types of nanomaterials and their modifications and the unique properties that are actively involved in environmental remediation, and how nanoscience and technology help mankind to create new materials to tackle the day-to-day challenges in the world.","PeriodicalId":443511,"journal":{"name":"Chemistry in the Environment","volume":"12 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"121508130","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
N. Ahmad, P. Goh, A. K. Zulhairun, T. Wong, A. Ismail
{"title":"CHAPTER 1. The Role of Functional Nanomaterials for Wastewater Remediation","authors":"N. Ahmad, P. Goh, A. K. Zulhairun, T. Wong, A. Ismail","doi":"10.1039/9781839165283-00001","DOIUrl":"https://doi.org/10.1039/9781839165283-00001","url":null,"abstract":"Nanotechnology has gained prominence as an advanced field of science, particularly its propensity to solve various environmental challenges. The use of nanomaterials is advantageous due to the unprecedented properties of nanomaterials including high surface area, high reactivity and strong mechanical properties that have been shown to be highly efficient and effective characteristics for wastewater treatment. The development of various nanomaterials provide the most exciting and encouraging advances based on their size effects to the targeted particulates. Various forms of nanomaterials, single or hybrid, have been widely used for the removal of heavy metals, microorganisms and organic pollutants from wastewater. Thus, in this chapter, we review the roles of nanomaterials in their application to wastewater treatment, underlining their advantages. Particularly, nanomaterials possess unique characteristics, depending on their classification and dimensions, which are beneficial for wastewater treatment. Nanomaterials including carbon-based nanomaterials, metal and metal oxides, metal–organic frameworks as well as hybrid nanomaterials are covered in this chapter. Lastly, future directions in the use of hybrid nanomaterials for water remediation are highlighted.","PeriodicalId":443511,"journal":{"name":"Chemistry in the Environment","volume":"6 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"130923257","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"CHAPTER 2. Synthesis of Functional Hybrid Nanomaterials Using Green Chemistry Approaches","authors":"E. Salimi","doi":"10.1039/9781839165283-00029","DOIUrl":"https://doi.org/10.1039/9781839165283-00029","url":null,"abstract":"Fabrication of nano-scale hybrid materials having well-organized architectures is necessary for the next generation of miniaturized systems. The combination of molecular engineering and sophisticated processing techniques has enabled chemists to regulate the shape, composition and functionality of complicated organic–inorganic hybrid structures. The present chapter discusses a variety of concepts in the fabrication of nano-meter functional hybrid materials with different architectures. Strategies of employing functional precursors or using post-synthesis functionalization techniques have been investigated to cover broad aspects of functional hybrid architectures.","PeriodicalId":443511,"journal":{"name":"Chemistry in the Environment","volume":"10 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"123929231","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
S. Nagappan, J. Peter, A. Thomas, A. Mohan, Shamim Ahmed Hira, K. Park, C. Ha
{"title":"CHAPTER 8. Antimicrobial Nanocomposites for Environmental Remediation","authors":"S. Nagappan, J. Peter, A. Thomas, A. Mohan, Shamim Ahmed Hira, K. Park, C. Ha","doi":"10.1039/9781839165283-00187","DOIUrl":"https://doi.org/10.1039/9781839165283-00187","url":null,"abstract":"In recent times, antimicrobial nanocomposites have attracted significant attention in various applications and products due to the safety and hygiene concerns of the modern life style as well as during the recent pandemic (COVID-19) situation. Antimicrobial nanocomposites are prepared generally by mixing antibacterial organic compounds with various metal ions or metal nanoparticles, such as silver, gold, zinc, copper, aluminium, etc., with a polymer and other nanomaterials as support. The use of high-cost metal nanoparticles limits practical applications. Hence, significant attention has been focussed on the development of low-cost antimicrobial nanocomposites for multiple applications. In this chapter, we briefly focus on various pathways of developing antimicrobial nanocomposites for a wide variety of applications and highlight the importance of antimicrobial nanocomposites and the future demand for environmentally friendly nanocomposites.","PeriodicalId":443511,"journal":{"name":"Chemistry in the Environment","volume":"47 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126349119","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. Nouri, Siew Fen Chua, E. Mahmoudi, S. Sakti, W. Ang
{"title":"CHAPTER 5. Polymer-based Nanocomposites for Environmental Remediation","authors":"A. Nouri, Siew Fen Chua, E. Mahmoudi, S. Sakti, W. Ang","doi":"10.1039/9781839165283-00101","DOIUrl":"https://doi.org/10.1039/9781839165283-00101","url":null,"abstract":"Environmental pollution has threatened the life of all living organisms on earth. The removal of pollutants from wastewater and contaminated water is desired to prevent the pollution issues from becoming worse. In this context, polymer-based nanocomposites have been developed and emerged as one of the advanced materials that can be used to solve the environmental pollution challenges. This composite material is produced by combining nanomaterials with polymers and usually appears in the form of membranes, adsorbents, hydrogels, and aerogels. These polymer-based nanocomposites possess improved characteristics and properties compared to the original individual material. Subsequently, the pollutants removal capability of the polymer-based nanocomposites has been enhanced significantly, with some even attaining new functionalities such as antibacterial and photocatalytic. This chapter features the development and application of four major classes of polymer-based nanocomposites (membrane, adsorbent, hydrogel, and aerogel) for environmental remediation. Various examples and latest findings are discussed, which provides up-to-date information for readers interested in this topic.","PeriodicalId":443511,"journal":{"name":"Chemistry in the Environment","volume":"5 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"121309771","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
S. A. Hashemifard, E. Babaei, A. Khosravi, S. Ghasemi, Z. Alihemati
{"title":"CHAPTER 9. Functional Nanocomposites for Heavy Metal Removal","authors":"S. A. Hashemifard, E. Babaei, A. Khosravi, S. Ghasemi, Z. Alihemati","doi":"10.1039/9781839165283-00216","DOIUrl":"https://doi.org/10.1039/9781839165283-00216","url":null,"abstract":"Heavy metals are widely found in effluents of various industrial wastewaters as well as in surface and groundwater. Heavy metals are located between groups 3 and 16 of the Periodic Table. Heavy metals are usually divided into three general groups, which are toxic to human and living organisms. A wide range of physical, chemical, and biological methods such as electrochemical processes, membrane technology, chemical deposition, coagulation, ion exchange, biodegradation, and adsorption techniques are available to remove heavy metals from contaminated water. To remove heavy metals from contaminated water, adsorption is one of the techniques that, due to its significant efficiency, low cost, simplicity, variety, selectivity for specific metals, less need to use chemical additives also A wide range of physical, chemical, and biological methods such as electrochemical processes, membrane technology, chemical deposition, coagulation, ion exchange, biodegradation, and adsorption techniques are available to remove heavy metals from contaminated water. To remove heavy metals from contaminated water, adsorption is one of the techniques that, due to its significant efficiency, low cost, simplicity, variety, selectivity for specific metals, less need to use chemical additives, and the possibility of regenerating and reusing the adsorbent, has been widely used. Although nano-adsorbents have considerable adsorption capacity, due to the nano scale of the particles their direct use in a discontinuous bed requires the integration of the adsorption process with an additional post-treatment process to completely remove the nanoparticles from the water before use. One of the suitable substrates to trap the nano-adsorbents are membrane structures called adsorbent membranes. This chapter deals with the synthesis, characterization, performance evaluation and challenges of adsorptive mixed matrix membranes for heavy metal removal.","PeriodicalId":443511,"journal":{"name":"Chemistry in the Environment","volume":"15 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"115341631","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"CHAPTER 11. Functional Nanocomposites for Removal of Contaminants of Emerging Concern","authors":"S. Samsami, M. Sarrafzadeh, Abbas Ahmadi","doi":"10.1039/9781839165283-00275","DOIUrl":"https://doi.org/10.1039/9781839165283-00275","url":null,"abstract":"Contaminants of emerging concern are micropollutants, which require legislation to set their threshold concentration levels in treated water or revise their current maximum allowable levels. Since conventional techniques have been known as unsatisfactory methods to remove these contaminants, recent studies have centered on nanotechnology. Functional nanocomposites with encouraging outcomes are considered as one of the most promising applications of nanotechnology. Ever-increasing attention to applying a wide range of nanomaterials in functionalizing nanocomposites has led to incessant attempts to develop different functional nanocomposites with favorable properties. The present chapter addresses the prominent role of functional nanocomposites and their recent development for the remove of these pollutants. Emphasis has been placed on metal–organic frameworks, which have gained great attention as burgeoning materials in this field. Herein, the most recent findings of using metal–organic frameworks for preparing functional nanocomposites for removing emerging pollutants by adsorption and photocatalysis, their removal capacity, mechanism, and influencing factors are overviewed in detail.","PeriodicalId":443511,"journal":{"name":"Chemistry in the Environment","volume":"22 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126497468","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"CHAPTER 6. Magnetic Nanocomposites for Environmental Remediation","authors":"S. Ghasemi, A. Khosravi, S. A. Hashemifard","doi":"10.1039/9781839165283-00133","DOIUrl":"https://doi.org/10.1039/9781839165283-00133","url":null,"abstract":"Rapid population growth and industrial development have led to increasing environmental pollution caused by a variety pollutants such as radionuclides, heavy metals, and pesticides in surface and underground water resources. Magnetic nanoparticles (MNPs) and nanocomposites have received significant attention over recent decades in both fundamental research as well as environmental sciences. The unique characteristics of these materials, such as high physical and chemical stabilities, biocompatibility, low toxicity, easy synthesis, excellent recycling capability, and processability under a magnetic field, make them promising candidates as part of the next-generation technology for the treatment of pollutants. Iron-based nanoparticles (INPs), including magnetite (Fe3O4), maghemite (γ-Fe2O3), hematite (α-Fe2O3), and goethite (α‐FeOOH) have been exploited in environmental applications such as the removal of metalloids, heavy metals, dyes, and organic compounds because of their large surface area to volume ratio, various morphologies, and catalytic properties. In fact, the large iron surface area plays an essential role in the interaction with pollutant contaminants. Unlike the bulk, MNPs exhibit unique magnetism, easily tuned to the desired applications. In this chapter, various properties, different synthesis methods, and characterization of magnetic NPs have been summarized. Finally, the application of the different MNPs have been considered to eliminate and purify hazardous and harmful pollutants from water and wastewater.","PeriodicalId":443511,"journal":{"name":"Chemistry in the Environment","volume":"15 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"127510344","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
N. Ismail, H. S. Zakria, S. Noor, M. Othman, M. A. Rahman, J. Jaafar, A. Ismail
{"title":"CHAPTER 7. Photocatalytic Nanocomposites for Environmental Remediation","authors":"N. Ismail, H. S. Zakria, S. Noor, M. Othman, M. A. Rahman, J. Jaafar, A. Ismail","doi":"10.1039/9781839165283-00161","DOIUrl":"https://doi.org/10.1039/9781839165283-00161","url":null,"abstract":"The wastewater problem is a worldwide problem that is experienced by every single country. In total, 80% of wastewater enters our environment without being treated, filtered or reused. Wastewater, which contains organic pollutants, inorganic pollutants, textile dyes, pharmaceuticals, faeces, heavy metals and microorganisms, spoils our drinking water and affects our health. Efficient wastewater treatment is a critical requirement for the removal of contaminants in order to maintain a better and safe environment. In this chapter, the use of photocatalysis in previous studies, using various photocatalyst nanocomposites and UV-light and visible light for the removal of numerous pollutants, is reviewed. It is hoped that the use of photocatalytic nanocomposites for environmental remediation will provide the potential to minimize these environmental issue in the future.","PeriodicalId":443511,"journal":{"name":"Chemistry in the Environment","volume":"46 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126844470","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"CHAPTER 3. Characterization of Functional Hybrid Nanomaterials","authors":"E. Salimi, M. N. Z. Abidin","doi":"10.1039/9781839165283-00056","DOIUrl":"https://doi.org/10.1039/9781839165283-00056","url":null,"abstract":"Arrangement, spatial configuration and chemical interactions of organic and inorganic elements in hybrid structures have led to the generation of various materials that range in size from nanometers to macrometers. In order to analyze the physical, chemical and also mechanical properties of these newly emerged compounds, a combination of different analytical techniques is necessary. This chapter provides a broad overview on the characterization strategies used to study the features of functional hybrid nanomaterials.","PeriodicalId":443511,"journal":{"name":"Chemistry in the Environment","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2021-09-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"121872637","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}