CHAPTER 6. Magnetic Nanocomposites for Environmental Remediation

S. Ghasemi, A. Khosravi, S. A. Hashemifard
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Abstract

Rapid population growth and industrial development have led to increasing environmental pollution caused by a variety pollutants such as radionuclides, heavy metals, and pesticides in surface and underground water resources. Magnetic nanoparticles (MNPs) and nanocomposites have received significant attention over recent decades in both fundamental research as well as environmental sciences. The unique characteristics of these materials, such as high physical and chemical stabilities, biocompatibility, low toxicity, easy synthesis, excellent recycling capability, and processability under a magnetic field, make them promising candidates as part of the next-generation technology for the treatment of pollutants. Iron-based nanoparticles (INPs), including magnetite (Fe3O4), maghemite (γ-Fe2O3), hematite (α-Fe2O3), and goethite (α‐FeOOH) have been exploited in environmental applications such as the removal of metalloids, heavy metals, dyes, and organic compounds because of their large surface area to volume ratio, various morphologies, and catalytic properties. In fact, the large iron surface area plays an essential role in the interaction with pollutant contaminants. Unlike the bulk, MNPs exhibit unique magnetism, easily tuned to the desired applications. In this chapter, various properties, different synthesis methods, and characterization of magnetic NPs have been summarized. Finally, the application of the different MNPs have been considered to eliminate and purify hazardous and harmful pollutants from water and wastewater.
第六章。磁性纳米复合材料用于环境修复
人口的快速增长和工业的发展,导致地表水和地下水资源中放射性核素、重金属、农药等多种污染物对环境的污染日益严重。近几十年来,磁性纳米粒子(MNPs)和纳米复合材料在基础研究和环境科学中都受到了极大的关注。这些材料的独特特性,如高物理和化学稳定性,生物相容性,低毒性,易于合成,出色的回收能力,以及在磁场下的可加工性,使它们成为下一代污染物处理技术的一部分。铁基纳米颗粒(INPs),包括磁铁矿(Fe3O4)、磁赤铁矿(γ-Fe2O3)、赤铁矿(α- fe2o3)和针铁矿(α‐FeOOH),由于它们具有较大的表面积体积比、多种形态和催化性能,已被广泛应用于去除类金属、重金属、染料和有机化合物等环境应用中。事实上,大的铁表面积在与污染物的相互作用中起着至关重要的作用。与块体不同,MNPs具有独特的磁性,易于调整到所需的应用。本章综述了磁性纳米粒子的各种性质、不同的合成方法和表征。最后,考虑了不同MNPs的应用,以消除和净化水和废水中的危险和有害污染物。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
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