{"title":"Antioxidant Effect of Humic Substances from Hungarian Leonardite","authors":"A. Csicsor, E. Tombácz","doi":"10.33927/hjic-2022-01","DOIUrl":"https://doi.org/10.33927/hjic-2022-01","url":null,"abstract":"Humic substances are natural substances that are continuously formed from the decay of plant residues. These materials have a very diverse range of properties, making them versatile. According to many new studies, these humic substances also exhibit antioxidant propensities. The aim of this paper was to shed light on whether humic substances really have antioxidant properties.","PeriodicalId":43118,"journal":{"name":"Hungarian Journal of Industry and Chemistry","volume":" ","pages":""},"PeriodicalIF":0.2,"publicationDate":"2022-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44135405","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Membrane Unit for Integrated Gas Separation – Membrane Bioreactor (GS-MBR) System","authors":"Z. Pientka, J. Peter, R. Valek","doi":"10.33927/hjic-2022-04","DOIUrl":"https://doi.org/10.33927/hjic-2022-04","url":null,"abstract":"One of the research directions of renewable energy sources is the production of biohydrogen from the dark fermentation of organic matter. During this fermentation process, since hydrogen is produced along with a complex mixture of other gases and vapors, hydrogen gas requires further purification. One relatively easy solution to this problem might be the utilization of gas separation membrane modules given their low energy consumption, simple operation and ease of upscaling. In this work, hollow fiber (HF) membranes based on polyetherimide (PEI) were developed and tested. HF membranes were spun from a polymer solution of PEI using the wet phase inversion process into a water bath using a pilot-scale spinning device. Gas transport measurements showed that membranes exhibited permeances of between 9.3 and 19.2 GPU with CO2/H2 selectivities within the range of 3.3 - 5.6. Morphology studies showed regular shapes resembling hollow fibers with outer diameters within the range of 250-320 microns, depending on various parameters of the spinning process. The best performing membranes were selected and a morphological analysis carried out. Selected fibers were incorporated into two types of membrane modules. One type was a laboratory-scale membrane mini-module used for preliminary tests, while the other membrane module was designed for the treatment of larger amounts of biohydrogen. Two types of laboratory-scale membrane separation units were constructed. For laboratory use, the low-pressure unit proved more accurate regulation to match the fermenters performance with the separation unit in comparison with the high-pressure one.","PeriodicalId":43118,"journal":{"name":"Hungarian Journal of Industry and Chemistry","volume":" ","pages":""},"PeriodicalIF":0.2,"publicationDate":"2022-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42801438","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nevena Miličić, Ivana Ćevid, M. M. Çakar, M. Sudar, Z. Blažević
{"title":"Enzyme Reaction Engineering as a Tool to Investigate the Potential Application of Enzyme Reaction Systems","authors":"Nevena Miličić, Ivana Ćevid, M. M. Çakar, M. Sudar, Z. Blažević","doi":"10.33927/hjic-2022-08","DOIUrl":"https://doi.org/10.33927/hjic-2022-08","url":null,"abstract":"It is widely recognized and accepted that although biocatalysis is an exquisite tool to synthesize natural and unnatural compounds under mild process conditions, much can be done to better understand these processes as well as detect resulting bottlenecks and help to resolve them. This is the precise purpose of enzyme reaction engineering, a scientific discipline that focuses on investigating enzyme reactions with the goal of facilitating their implementation on an industrial scale. Even though reaction schemes of enzyme reactions often seem simple, in practice, the interdependence of differentvariables is unknown, very complex and may prevent further applications. Therefore, in this work, important aspects of the implementation of enzyme reactions are discussed using simple and complex examples, along with principles of mathematical modelling that provide explanations for why some reactions do not proceed as planned.","PeriodicalId":43118,"journal":{"name":"Hungarian Journal of Industry and Chemistry","volume":" ","pages":""},"PeriodicalIF":0.2,"publicationDate":"2022-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49183311","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. Jock, Messiah Luke Akpan, Francis Asokogene Oluwadayo
{"title":"Production and Characterization of Sand-Plastic Composite Floor Tiles","authors":"A. Jock, Messiah Luke Akpan, Francis Asokogene Oluwadayo","doi":"10.33927/hjic-2022-06","DOIUrl":"https://doi.org/10.33927/hjic-2022-06","url":null,"abstract":"The amount of plastic waste generated in developing nations like Nigeria is increasing day by day, which is nonbiodegradable and causes environmental pollution. Among the plastics used, low-density polyethylene is abundant. These plastics can be removed from the environment and recycled into useful products. In this study, low-density polyethylene plastic waste was utilized in the manufacture of floor tiles to curb its generation. The tiles were produced by mixing fine sand with molten plastic waste in different proportions. The physical and mechanical properties of the floor tiles such as water absorption, density, tensile and compressive tests, modulus of elasticity as well as impact strength and friction tests were investigated. The water absorption ranged from 0.02 - 0.38 %(m/m), while the density varied between 998.5 and 1289 kg/m3. The tensile strength and modulus of elasticity fell within the range of 0.050 to 0.232 MPa and 0.924 to 2.806 MPa, respectively. This result proved the applicability of recycled plastic waste in the formulation of floor tiles.","PeriodicalId":43118,"journal":{"name":"Hungarian Journal of Industry and Chemistry","volume":" ","pages":""},"PeriodicalIF":0.2,"publicationDate":"2022-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42977586","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Influence of Mineral Composition in Natural Granite Rocks on Microhardness","authors":"Eszter Kelemen-Cserta, I. Gyurika","doi":"10.33927/hjic-2021-11","DOIUrl":"https://doi.org/10.33927/hjic-2021-11","url":null,"abstract":"Granites are becoming increasingly popular and, as a result, their areas of use are expanding. In addition to their colour and particle size, the surface roughness of the machined material is becoming an important aspect of their application. In order to create a suitable surface roughness, the type of rocks located on the surface, elemental composition and microhardness of the minerals are important, because knowledge of these characteristics can be used to determine the machining parameters. Microhardness is affected by the atomic percentage values of Si, Al and Na. In addition, for some minerals, a correlation can also be established between the Si, Al and Na components.","PeriodicalId":43118,"journal":{"name":"Hungarian Journal of Industry and Chemistry","volume":"1 1","pages":""},"PeriodicalIF":0.2,"publicationDate":"2021-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41375185","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Development of Compartment Models for Diagnostic Purposes","authors":"B. Tarcsay, Ágnes Bárkányi, T. Chován, S. Németh","doi":"10.33927/hjic-2021-07","DOIUrl":"https://doi.org/10.33927/hjic-2021-07","url":null,"abstract":"The importance of recognizing the presence of process faults and resolving these faults is continuously increasing parallel to the development of industrial processes. Fault detection methods which are both robust and sensitive help to recognize the presence of faults in time to avoid malfunctions, financial loss, environmental damage or loss of human life. In the literature, the use of various model-based fault detection methods has gained a considerable degree of popularity. Methods usually based on black-box models, data-based techniques or models using symbolic logic, e.g. expert systems, have become widespread. White-box models, on the other hand, have been applied less despite their considerable robustness because of multiple reasons. Firstly, their complexity and the relatively vast amount of technological and modelling knowledge needed to construct them for industrial systems. Secondly, their large computational demand which makes them less suitable for online fault detection. In this study, the aim was to resolve these problems by developing a method to simplify the complex Computational Fluid Dynamics models employed to describe the equipment used in the chemical industry into less complex model structures. These simpler structures are Compartment Models, a type of white-box model which breaks down a complex system into smaller units with idealized behaviour. In the case of a small number of compartments, the computational load of such models is not significant, therefore, they can be employed for the purposes of online fault detection while providing an accurate representation of the system. For the purpose of identifying the compartmental structure, fuzzy logic was employed to create a model which approximates the real behaviour of the system as accurately as possible. Our future objective is to explore the possibility of combining this model with various diagnostic methods (expert systems, Bayesian networks, parity relations, etc.) and derive robust tools for the purpose of fault detection.","PeriodicalId":43118,"journal":{"name":"Hungarian Journal of Industry and Chemistry","volume":" ","pages":""},"PeriodicalIF":0.2,"publicationDate":"2021-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42535186","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Asotah Wisdom, U. Mark, Elakhame Zeberu, A. Adeleke
{"title":"Optimisation of the Physical Properties of Rice Husk Ash in Ceramic Materials Using the Response Surface Methodology","authors":"Asotah Wisdom, U. Mark, Elakhame Zeberu, A. Adeleke","doi":"10.33927/hjic-2021-04","DOIUrl":"https://doi.org/10.33927/hjic-2021-04","url":null,"abstract":"Optimisation of the physical properties of rice husk ash (RHA) in ceramic materials was carried out using Response Surface Methodology. The independent variables, namely the firing temperature and residue content, were statistically combined in a Central Composite Design with the effects on water absorption, linear shrinkage, bulk density, apparent porosity and apparent specific gravity determined. Physical and microstructural analyses were carried out to obtain information on the processes that occurred within the ceramic materials. The results obtained were analysed to determine the optimum physical properties of the ceramic materials within the range investigated. The residue content had a significant influence (at 95% confidence level) on the bulk density, water absorption, apparent porosity and apparent specific gravity but not on the linear shrinkage. The firing temperature had a more significant effect on the linear shrinkage than on the residue content, so that when elevated it contributed to an increase in linear shrinkage. The optimum residue content and firing temperature to enhance physical properties within the range investigated were 5.85% RHA and 1029.64°celsius, respectively. These optimal conditions are expected to produce a ceramic material with a bulk density, linear shrinkage, apparent porosity, water absorption and apparent specific gravity of 1.64 g/cm3, 0.29%, 0.29 g/cm3, 18.26% and 2.11, respectively with a composite desirability of 100%.","PeriodicalId":43118,"journal":{"name":"Hungarian Journal of Industry and Chemistry","volume":" ","pages":""},"PeriodicalIF":0.2,"publicationDate":"2021-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48046872","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
T. Rózsenberszki, L. Koók, P. Bakonyi, N. Nemestóthy, K. Bélafi-Bakó
{"title":"Comparative Study on Anaerobic Degradation Processes of Pressed Liquid Fraction of Organic Solid Waste","authors":"T. Rózsenberszki, L. Koók, P. Bakonyi, N. Nemestóthy, K. Bélafi-Bakó","doi":"10.33927/hjic-2021-05","DOIUrl":"https://doi.org/10.33927/hjic-2021-05","url":null,"abstract":"Anaerobic degradation processes: anaerobic digestion (biogasification), biohydrogen fermentation (dark) and microbial fuel cells were applied to treat the organic fraction of a municipal solid waste. The processes were compared based on their ability of energy recovery and Chemical Oxygen Demand reduction.","PeriodicalId":43118,"journal":{"name":"Hungarian Journal of Industry and Chemistry","volume":" ","pages":""},"PeriodicalIF":0.2,"publicationDate":"2021-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42398460","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"The Experimental Verification of a Generalized Model of Equivalent Circuits","authors":"Z. Lukács, Dávid Baccilieri, T. Kristóf","doi":"10.33927/hjic-2021-01","DOIUrl":"https://doi.org/10.33927/hjic-2021-01","url":null,"abstract":"The determination of typical parameters of electrochemical systems, e.g. the polarization or charge transfer resistances, can be critical with regard to the application of Electrochemical Impedance Spectroscopy (EIS) if the lower frequency range is biased as a result of transport and/or adsorption/desorption processes. In such cases, the charge transfer resistance should be assessed from the higher frequency range which is typically inadequate in itself as an input for nonlinear parameter fitting. In earlier publications, an alternative mathematical treatment of both the Equivalent Circuit (EC) and of the parameter dispersion was provided using a generalized model of ECs and also a dispersion-invariant model of the electrochemical interface. In the present work, the previously presented experimental EIS results were crosschecked to verify the performance of the generalized model against a series of redox and corrosion systems. The results proved that the applied method is consistent and provides a fairly good correlation between the principal resistance data assessed by different methods.","PeriodicalId":43118,"journal":{"name":"Hungarian Journal of Industry and Chemistry","volume":" ","pages":""},"PeriodicalIF":0.2,"publicationDate":"2021-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44905864","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Photocatalytic Degradation of Rhodamine B in Heterogeneous and Homogeneous Systems","authors":"Asfandyar Khan, Zsolt Valicsek, O. Horváth","doi":"10.33927/hjic-2021-02","DOIUrl":"https://doi.org/10.33927/hjic-2021-02","url":null,"abstract":"This study focuses on the photocatalytic degradation of Rhodamine B (RhB) in heterogeneous and homogeneous photo-Fenton reactions. In the heterogeneous system, iron(II) doped copper ferrite CuII(x)FeII(1-x)FeIII2O4 nanoparticles (NPs) prepared in our previous work were employed as potential catalysts. The photodegradation of RhB was carried out in a quartz cuvette located in a diode array spectrometer. The experimental conditions such as pH, NPs dosage and H2O2 dosage with regard to the photocatalytic degradation of RhB were optimized to be 7.5, 500 mg/L and 8.9x10-2 mol/L, respectively. In addition, visible light-induced photodegradation of RhB was also carried out by using ch{H2O2} over a wide pH range in the absence of heterogeneous photocatalysts. It was observed that the reaction rate significantly increased above pH 10, resulting in a faster rate of degradation of RhB, which may be attributed to the deprotonation of hydrogen peroxide. Furthermore, the potential antibacterial property of such catalysts against the Gram-negative bacterium Vibrio fischeri in a bioluminescence assay yielded inhibition activities of more than 60% in all cases.","PeriodicalId":43118,"journal":{"name":"Hungarian Journal of Industry and Chemistry","volume":" ","pages":""},"PeriodicalIF":0.2,"publicationDate":"2021-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48576879","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}