{"title":"Effect of Width of Gas/Liquid/Solid Three-Phase Boundary Zone of Discrete Water Film on Atmospheric Corrosion of Metals~!2009-10-12~!2010-05-01~!2010-08-09~!","authors":"Jia Wang, Jing Jiang","doi":"10.2174/1876503301003010064","DOIUrl":"https://doi.org/10.2174/1876503301003010064","url":null,"abstract":"The influence of potential on contact angle and the effect of TPB width on the cathodic corrosion processes of metals were studied by steady polarization and EIS technique combined with contact angle measurement. It is found that both cathodic limiting current density and corrosion current density linearly increases with increasing the TPB width, confirming the important role of TPB width in gas/liquid/solid multiphase corrosion systems. Based on above results, the effect of water film thickness on atmospheric corrosion rate was quantitatively evaluated by the TPB width.","PeriodicalId":420093,"journal":{"name":"The Open Corrosion Journal","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2010-08-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"121092180","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Electrochemical Determination of the Corrosion Resistance of NiCr Dental Casting Alloys~!2009-10-19~!2010-03-31~!2010-06-02~!","authors":"D. Mareci, A. Cailean, G. Ciurescu, D. Sutiman","doi":"10.2174/1876503301003010045","DOIUrl":"https://doi.org/10.2174/1876503301003010045","url":null,"abstract":"","PeriodicalId":420093,"journal":{"name":"The Open Corrosion Journal","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2010-07-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"130198820","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Surface Investigations of Aluminum in 2M Hydrochloric Acid Solution in the Presence of Potassium Iodate Inhibitor","authors":"A. E. Maghraby","doi":"10.2174/1876503301003010054","DOIUrl":"https://doi.org/10.2174/1876503301003010054","url":null,"abstract":"The results of investigations by using optical, scanning electron microscopy (SEM) and energy dispersive X- ray spectroscopy (EDS) to study the surface morphology, the composition of adsorbed film formed on the surface of aluminum samples in 2M hydrochloric acid solution containing 100 ppm optimum KIO3 dose. The data reveal that the additive improves the surface morphology of aluminum, due to the marked layer enrichment of Al- surface by inhibitor components. Detailed studies were carried out to investigate the effect of oxygen in the inhibition process. The nature and strength of the passive film and the mechanism of its formation are explained based on detailed studies conducted under experimental conditions.","PeriodicalId":420093,"journal":{"name":"The Open Corrosion Journal","volume":"11 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2010-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"127542564","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
R. Rathish, S. Rajendran, J. Christy, B. S. Devi, S. Johnmary, M. Manivannan, K. Rajam, P. Rengan
{"title":"Corrosion Behaviour of Metals in Artificial Sweat~!2010-01-04~!2010-02-25~!2010-05-06~!","authors":"R. Rathish, S. Rajendran, J. Christy, B. S. Devi, S. Johnmary, M. Manivannan, K. Rajam, P. Rengan","doi":"10.2174/1876503301003010038","DOIUrl":"https://doi.org/10.2174/1876503301003010038","url":null,"abstract":"","PeriodicalId":420093,"journal":{"name":"The Open Corrosion Journal","volume":"11 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2010-05-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126646568","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Corrosion Resistance of Rubber Concretes~!2009-10-22~!2009-12-16~!2010-04-09~!","authors":"O. Figovsky, V. Chmyhov, D. Beilin","doi":"10.2174/1876503301003010028","DOIUrl":"https://doi.org/10.2174/1876503301003010028","url":null,"abstract":"","PeriodicalId":420093,"journal":{"name":"The Open Corrosion Journal","volume":"10 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2010-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"131158625","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Corrosion Mechanism in the Obsidian and its Comparison with the Nuclear Waste Glass for Long-Term Performance Assessment in the Geological Repository","authors":"N. Rani, J. Shrivastava, R. Bajpai","doi":"10.2174/1876503301003010016","DOIUrl":"https://doi.org/10.2174/1876503301003010016","url":null,"abstract":"Present paper discusses experimental work on obsidian glass to understand corrosion mechanism at variable pressure temperature conditions. For comparison, Advanced Vitrification System, a nuclear waste glass was studied simultaneously under similar conditions. Owing to massive weight loss the glass samples were unable to sustain beyond 4 hour during the experiments. Corrosion experiments on both these glasses were performed under hydrothermal like conditions and observed that the changes in the experimental conditions have major control over the release of sodium and other ions from obsidian and nuclear waste glass, hence effecting corrosion mechanism. X-ray diffraction patterns of the residue obtained after the experiments on obsidian glass revealed appearance of neo-formed minerals, such as quartz, celadonite, halloysite, sodalite, heulandites and wairakite. High degree of corrosion and formation of amorphous residue observed in case of the experiments performed at 300 0 C over the granules of the nuclear waste glass. The back scattered electron images of the scanning electron microscope indicate distinctive microstructures, associated with the neo-formed minerals, and their formation is linked with the release of sodium, potassium and other ions, causing changes in the pH and conductivity of the leachate. In case of nuclear waste glass back scattered images of the scanning electron microscope indicates formation of multiple alteration layers and secondary alteration products. The surface of the pellet after the experiment shows phyllosilicate with numerous tiny spherules embedded within the structure. These experimental results when extrapolated suggest formation of amorphous silica, quartz and chalcedony as end members in case of obsidian glass whereas, formation of iron rich fayalite and greenalite can be observed in case of nuclear waste glass. The mechanism, conditions of formation of neo-formed minerals and their stability have been discussed in the paper.","PeriodicalId":420093,"journal":{"name":"The Open Corrosion Journal","volume":"702 ","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2010-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"133817325","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Corrosion Behaviour of High-Mn TWIP Steels with Electroless Ni-P Coating","authors":"A. Hamada, L. P. Karjalainen","doi":"10.2174/1876503301003010001","DOIUrl":"https://doi.org/10.2174/1876503301003010001","url":null,"abstract":"An attempt has been taken to improve the corrosion resistance of twinning-induced plasticity (TWIP) steels (Fe-25Mn and Fe-25Mn-3Al) by electroless Ni-P coating. Corrosion resistance in 3.5% NaCl and 0.1M H2SO4 solutions was characterized by the potentiodynamic polarization curves and Tafel method calculations. It was found that Ni-P coating improved the corrosion resistance by the factor of 4 and 40 in 3.5%NaCl and 0.1M H2SO4, respectively. Post-heat treatments, commonly used to increase hardness and wear resistance of Ni-P deposits, were found to reduce the corrosion resistance, even though the 1 h annealing at 700°C less than at 350°C. Also, the adhesion of the coating on the steels was impaired in annealing. The lowered corrosion resistance in annealing can be suggested to result from the crystallization of the amorphous coating and the formation of Ni3P particles, but at 700°C, the formation MnO layer on the top of the coating promoted the resistance by enhancing the passivation in the 3.5% NaCl solution.","PeriodicalId":420093,"journal":{"name":"The Open Corrosion Journal","volume":"70 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2010-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126182857","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"The Isothermal Oxidation Behavior of a Ti3Al-Nb-V-Mo Alloy","authors":"Ying Wu, G. Song","doi":"10.2174/1876503301003010007","DOIUrl":"https://doi.org/10.2174/1876503301003010007","url":null,"abstract":"The isothermal oxidation behavior of Ti-24Al-14Nb-3V-0.5Mo alloy in synthetic air from 700°C to 1000°C was studied. The main emphasis was focused on the effect of microstructure obtained by different processes of melting and hot rolling, i.e. large and duplex of 2+B2, on the oxidation resistance. Regardless of the microstructure, the overall oxidation process of the specimens exposed at 700°C was dominantly controlled by the beneficial effect of Nb-addition due to the formation of a continuous -Al2O3 layer in the scale. However, both specimens showed poor oxidation resistance above 900°C, especially for the as-rolled specimen, because of higher volume fraction of the 2-phase. The spallation occurred in both specimens at 1000°C, which was probably relative to the formation of Ti2AlN between the thick scale and the substrate except for the TiO2 and -Al2O3.","PeriodicalId":420093,"journal":{"name":"The Open Corrosion Journal","volume":"222 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2010-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"131690300","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"The Influence of Liquid Surface Segregation on the Pitting Corrosion Behavior of Semi-Solid Metal High Pressure Die Cast Alloy F357","authors":"H. Möller, E. Masuku","doi":"10.2174/1876503300902010216","DOIUrl":"https://doi.org/10.2174/1876503300902010216","url":null,"abstract":"Semi-solid metal processing results in liquid segregation at the surface of the components. The pitting behavior of this surface layer of semi-solid metal processed alloy F357 was compared with the centre (or bulk) of cast plates in 3.5% NaCl aqueous solution. It is shown that pitting attack occurs preferentially in the eutectic regions at the interface between silicon particles and the alpha phase in the eutectic. Since the surface liquid segregation layer consists of mainly eutectic, this makes semi-solid metal processed components specially susceptible to pitting corrosion attack.","PeriodicalId":420093,"journal":{"name":"The Open Corrosion Journal","volume":"26 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2009-08-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"131699589","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Electroless Nickel-Phosphorus-Polymer Composite Coatings","authors":"O. Khalifa, E. Sakr","doi":"10.2174/1876503300902010211","DOIUrl":"https://doi.org/10.2174/1876503300902010211","url":null,"abstract":"This study examines the use of polyvinyl-pyrrolidone (nitrogen containing compound) (PVP) coating on electroless Ni-P deposit on low steel. Three different average molecular weights of PVP were used, molecular weight 10.000 (PVP-10), molecular weight of, 24.500 (PVP-24.5) and molecular weight 40.000 (PVP-40). Coatings were characterized using X- ray diffraction (XRD). Scanning electron microscope (SEM) was used to determine the surface morphology. The microhardness and corrosion resistance of the composite were studied. It was found that i- the micro hardness decreases in presence of the polymer PVP, ii- the corrosion resistance greatly increases in the presence of PVP and iii- the adhesion of the coatings with the substrate increase in the presence of polymer.","PeriodicalId":420093,"journal":{"name":"The Open Corrosion Journal","volume":"18 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2009-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128375400","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}