{"title":"Au Extraction from Mineral Rocks with Aeration-Cyanidation Hydrometallurgy and Comparative Study of Its Effectiveness in Various Methods and Solvents","authors":"D. Ariyanti, M. Syaifuddin","doi":"10.20961/JKPK.V4I2.29020","DOIUrl":"https://doi.org/10.20961/JKPK.V4I2.29020","url":null,"abstract":"Indonesia is a country with abundant mining potential, one of it is gold (Au) which has a high economic value. Separation of gold metal from mineral rock consists of several methods, such as extraction, hydrometallurgy, and membrane emulsifier technology. These three methods produce different effectiveness of percentage recovery (%recovery), depend on the optimum conditions of each method and type of solvent. This study aims to separate the gold metal from mineral rocks through the hydrometallurgical method with an aeration-cyanidation solvent combination. Hidrometallurgy method is liquid extraction from ores. The test used is a qualitative test of SnCl2 solution and characterization test with XRF. The results showed that the percentage of recovery (%recovery) of Au with aeration and cyanidation process for 24 hours was 92.8%. Aeration and cyanidation better than emulsifier membrane method and hydrometallurgy with sodium bisulphite, hydrogen peroxide, Cyanex 272 and NH4Cl 0.9 M.","PeriodicalId":394335,"journal":{"name":"JKPK (Jurnal Kimia dan Pendidikan Kimia)","volume":"2 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122158447","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Gina Mondrida, Triningsih Triningsih, K. D. Purwanti, Sutari Sutari, S. Setyowati, W. Lestari, A. Ariyanto, Puji Widayati
{"title":"Comparison Study Between Local TSH IRMA Kit (CRRT) and Imported TSH IRMA Kit (Riakey, Korea)","authors":"Gina Mondrida, Triningsih Triningsih, K. D. Purwanti, Sutari Sutari, S. Setyowati, W. Lestari, A. Ariyanto, Puji Widayati","doi":"10.20961/JKPK.V4I2.29756","DOIUrl":"https://doi.org/10.20961/JKPK.V4I2.29756","url":null,"abstract":"Thyroid Stimulating Hormone (TSH) is one of hormones that our body need for growth of brains, bones and other tissues and regulate the metabolism in the body. Normal range of TSH for adult is from 0.3 to 5.5 µIU/ml, whereas for baby ranged from 3 to 18 µIU/ml. An Immunoradiometricassay (IRMA) is one of immunoassay technique using radionuclide as the tracer to detect low quantity of analyte. This technique is suitable for determine TSH levels in human blood serum which has complex matrix and various concentration. The Center for Radioisotope and Radiopharmaceutical Technology (CRRT)-BATAN has developed a reagent of TSH IRMA kit. The aim of this research is to compare between local TSH IRMA kit (CRRT-BATAN) and imported TSH IRMA kit (Riakey, Korea) toward 110 adult samples obtained from PTKMR - BATAN. The results showed 97 samples as true negative, 5 samples as true positive, 1 sample as false negative and 7 samples false positive. The comparison study gave diagnostic sensitivity as much as 83.33 %, diagnostic spesificity as much as 93.27 % and accuracy as much as 92.72 %.","PeriodicalId":394335,"journal":{"name":"JKPK (Jurnal Kimia dan Pendidikan Kimia)","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128834791","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Morphology and Physical Properties, Colored Cotton Fabric, from the Biowashing Process Using Cellulase Enzymes Derived from Straw and Rice Husk Fermentation by Aspergillus niger Bacteria","authors":"E. Oktariani, I. N. Mauliza, Ikhwan Muslim","doi":"10.20961/JKPK.V4I2.29858","DOIUrl":"https://doi.org/10.20961/JKPK.V4I2.29858","url":null,"abstract":"Cellulose enzymes are widely use for biowashing process. It was derived from Aspergillus niger fermentation using rice straw and husk as inoculum medium. In this research, cellulose enzyme was applicated on denim fabric with various enzyme concentration 1%, 2%, 3% owf at 60oC and pH 7, liquor ratio 1: 20 for 30 minutes. Characterization of fabric are analized using Scanning Electrone Microscope shows morphological transformation indicate the decrease fabric tensile strenght and stiffness. Denim fabric treatment by 3% cellulose enzyme using rice straw substrate gives morphological and fabric properties characterization similiar with denim fabric treatment by commecial cellulose enzyme.","PeriodicalId":394335,"journal":{"name":"JKPK (Jurnal Kimia dan Pendidikan Kimia)","volume":"64 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"114322468","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effectiveness of Rice Husk and Bagasse Fly Ash as Adsorbent of Cr Metal on Batch System","authors":"Kharisma Resti Kurnia Diah Sangandita, Budi Utami","doi":"10.20961/JKPK.V4I2.29724","DOIUrl":"https://doi.org/10.20961/JKPK.V4I2.29724","url":null,"abstract":"This study aimed to utilize rice husk and bagasse fly ash as Cr metal adsorbent. In this study, the adsorption used batch system. The steps of research were preparation of materials, activation of materials with HCl and NaOH solutions, characterization test using SEM, FTIR and AAS. Determination of optimum condition of Cr metal adsorption on variation of adsorbent composition, adsorbent mass, adsorbate concentration and isotherm adsorption study. The result showed that the adsorbent of rice husk and bagasse fly ash can be used as adsorbent because there were pores that is based on SEM analysis, based on FTIR results that there were a –OH (hydroxyl) functional group at wavenumber 3424.76 cm-1 and Si-O from Si-O-Si (siloxane) functional group at wavenumber 1048.36 cm-1 in the combination of rice husk and bagasse fly ash adsorbent, based on AAS results it was found that the optimum composition ratio of rice husk and bagasse fly ash adsorbent was 1:2 with the percentage of Cr adsorbed 98.90%, the optimum adsorbent mass at 0.2 g with the percentage of Cr adsorbed 99.77% and the optimum adsorbate concentration at 20.645 mg/L with the percentage of Cr adsorbed 99.63%. The pattern of adsorption isotherm tends followed the Langmuir isotherm which means the adsorption process chemically.","PeriodicalId":394335,"journal":{"name":"JKPK (Jurnal Kimia dan Pendidikan Kimia)","volume":"135 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"132045908","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Theoretical Modification of Cyanidin as Sensitizers in Dye Sensitized Solar Cell (DSSC) Using Rhodanine Acetic Acid as Electron Withdrawing Group","authors":"Sudarlin Sudarlin","doi":"10.20961/JKPK.V4I1.28978","DOIUrl":"https://doi.org/10.20961/JKPK.V4I1.28978","url":null,"abstract":"Modification of cyanidin as sensitiser on Dye Sensitized Solar Cell (DSSC) has been carried out theoretically in this study using rhodanine acetic acid. The rhodanine acetic acid as electron withdrawing group can increase the electron density of the LUMO state, so injection of the excited electron to the semiconductor can also be increase. The theoretical method used is DFT/B3LYP theory by NWChem software. The calculation shows that the LUMO energy of cyanidin rhodanine acetic is higher than cyanidin, so electron injection to the conduction band of the semiconductor is easier. This condition is supported by reduced of HOMO-LUMO energy gap, so the range of the sunlight that can be involved in the electron excitation process is wider. In addition, the LUMO electron density of the cyanidin rhodanine acetic is localized at rhodanine acetic which makes the distance of the excited electron is closer to the semiconductor, thereby facilitating electron injection.","PeriodicalId":394335,"journal":{"name":"JKPK (Jurnal Kimia dan Pendidikan Kimia)","volume":"126 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"126152047","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Social Emotional Learning in Chemistry Learning : Group Investigation dan Contextual Learning Integration to Develop Student’s Social Emotional Competencies","authors":"Maulidya Virginanti, Y. Rahmawati, F. Kurniadewi","doi":"10.20961/JKPK.V4I1.13142","DOIUrl":"https://doi.org/10.20961/JKPK.V4I1.13142","url":null,"abstract":"This article presents the results from integrating Social Emotional Learning (SEL) through cooperative learning and contextual approach in chemistry learning. This study was conducted on 10th-grade students in the academic year of 2016/2017. Collaborative learning, as well as the use of real-life scenario, are some of the teaching practices for facilitating Social Emotional Learning (SEL) and promotes students' social-emotional competenciesthat aligned with affective competencies in Indonesia’s 2013 curricula. The proposed teaching practices also answer the challenges faced by the implementation of the 2013 curricula, finding proper teaching practices to integrate to develop student’s character through learning activity. The empirical work of the study is based on a qualitative approach. Six Group Investigation’s stage integrated with the use of real-life scenario was analyzed through various method such as observations, interviews, reflective journals, and student’s worksheets answer. The results found that students showed positive attitudes and perspective’s change towards chemistry learning, establish positive relationship with peers, cooperative skill, tolerance, and responsible decision making by considered himself, others, and community within the learning process.","PeriodicalId":394335,"journal":{"name":"JKPK (Jurnal Kimia dan Pendidikan Kimia)","volume":"40 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"127308309","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Anna Roseliana, W. Witarti, E. Lestari, M. E. Sriyani, W. Widjaksana
{"title":"Determination Stability of 99mTc-Etambutol Radiopharmaceuticals for Tuberculosis Detected","authors":"Anna Roseliana, W. Witarti, E. Lestari, M. E. Sriyani, W. Widjaksana","doi":"10.20961/JKPK.V4I1.22364","DOIUrl":"https://doi.org/10.20961/JKPK.V4I1.22364","url":null,"abstract":"99mTc-ethambutol radiopharmaceutical is a diagnostic kit based on the anti-tuberculosis drug, ethambutol, labeled with radioactive tracer 99mTc. This radiopharmaceutical is a result of research development in Centre for Radioisotope and Radiopharmaceutical Technology, BATAN. 99mTc-ethambutol radiopharmaceutical in the hospital used as a diagnostic agent for tuberculosis detected, particularly tuberculosis in extra pulmonary organs that is not easily detected by existing conventional methods. The aim of study to find out how stable ethambutol kit when stored at certain temperature and how stable ethambutol stability after labelled with 99mTc. These stability data are required by hospitals which used 99mTc-ethambutol . The stability test performed by measuring the radiochemical purity of ethambutol kits which were stored at certain time period and labelled with 99mTc using thin layer chromatography (TLC) method. Radiochemical purity tests were also performed on 99mTc-ethambutol at certain time period after its labeling process. Based on experiment results, it was obtained that ethambutol kit was still stable for up to 9 months when stored at refrigerator temperature 8 oC with percentage of radiochemical purity average > 85% and up to 11 months when stored in deep freezer temperature -80 oC with percentage of radiochemical purity average 90%. While 99mTc-ethambutol was still stable for up to 4 hours after labeling with percentage of radiochemical purity more than > 85%.","PeriodicalId":394335,"journal":{"name":"JKPK (Jurnal Kimia dan Pendidikan Kimia)","volume":"46 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"127294822","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
W. A. E. Setyowati, Elfi Susanti Vh, Iis Alviah, Melati Kusuma Wardani
{"title":"Cinnamon Oil as an Antibacterial Agent on Natural Paper from Banana Peel (Musa paradisiaca Linn.)","authors":"W. A. E. Setyowati, Elfi Susanti Vh, Iis Alviah, Melati Kusuma Wardani","doi":"10.20961/JKPK.V4I1.26120","DOIUrl":"https://doi.org/10.20961/JKPK.V4I1.26120","url":null,"abstract":"<p>The research about the use of cinnamon oil as an antibacterial agent on natural paper from Banana <em>(musa<strong> </strong>paradisiaca Linn.) </em>Peel has been conducted. The preparation of the paper using alkalization method, with the use of NaOH 4% at the temperature of 100<sup>o</sup>C for 1.5 hours. The paper is made in two variations, ie with additive cinnamon oil and without additive. The natural paper produced are tested for pH based on SNI ISO 6588-1.2010 and water content by dry-oven method based on SNI ISO 287:2010. The antibacterial activities were tested against <em>Staphylococcus aureus</em> and <em>Escherichia coli </em>using Kirby-Bauer disc diffusion method. The paper produced meet the standard of ISO 6519:2016 about Basic Paper for Laminated Plastic Wrapping Paper within the parameter of pH and water content. The results showed that the paper with additive cinnamon oil have antibacterial activity againts <em>S</em><em>.</em><em> aureus</em> and <em>E. coli </em>with inhibition diameter zone 15 mm and 13 mm respectively, whereas paper without cinnamon oil additives has no antibacterial activity against either <em>S</em><em>.</em><em> aureus</em> or <em>E. coli. </em> These result indicate that cinnamon oil can be used as an antibacterial agent on the natural paper from Banana peel <em>(musa paradisiaca </em>Linn.<em>)</em>.</p>","PeriodicalId":394335,"journal":{"name":"JKPK (Jurnal Kimia dan Pendidikan Kimia)","volume":"5 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"129310377","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Optimation of NaOH Catalyst Consentration on 1,3-Diphenyl-2-propen-1-on Synthesis Using Microwave-Assisted Organic Synthesis (MAOS) Method","authors":"Iin Narwanti, Narendra Bagus Kusumajati","doi":"10.20961/JKPK.V4I1.25790","DOIUrl":"https://doi.org/10.20961/JKPK.V4I1.25790","url":null,"abstract":"with a variation of NaOH catalyst concentration has been done. The purpose of this study was to determine the concentration of NaOH catalyst in the synthesis of 1,3-diphenyl-2-propen-1-on using MAOS method which produced optimal yield. The synthesis of 1,3-diphenyl-2-propen-1-on using benzaldehyde and acetophenone was carried out using the MAOS method with NaOH catalyst. The variation of NaOH catalyst concentration was 10%, 20%, 30%, and 40%. Microwave radiation was carried out at 140 watts for 20 seconds. The purity of the synthesized 1,3-diphenyl-2-propen-1-on was tested by melting point, TLC, and gas chromatography. The structure of the synthesized 1,3-diphenyl-2-propen-1-on was characterized by FTIR, GC-MS and NMR. The results showed that the compound 1,3-diphenyl-2-propen-1-on can be synthesized from benzaldehyde and acetophenone using MAOS method. The obtained yield at varying catalyst concentrations of 10, 20, 30 and 40% were (50.58±1.84%, (69.20±1.58)%, (84.55±1.50)% and (90.60±0.96)%, respectively. The concentration of 40% NaOH catalyst produces the most optimal yield of synthesis products. ","PeriodicalId":394335,"journal":{"name":"JKPK (Jurnal Kimia dan Pendidikan Kimia)","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"121313880","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Analysis of Chloride Levels in Well and PDAM Water in Ngelom Village, Sidoarjo","authors":"Khoirul Ngibad, Dheasy Herawati","doi":"10.20961/JKPK.V4I1.24526","DOIUrl":"https://doi.org/10.20961/JKPK.V4I1.24526","url":null,"abstract":"Chloride is an anion that dissolves easily in water samples and it is the main inorganic anion founded in water samples. Excess of chloride ions in drinking water can damage the kidneys. The aims of this study is to determine chloride levels in well and PDAM water samples in Ngelom Village. Determination of chloride levels in water samples using the Mohr argentometric titration method. The samples used was well water and PDAM water, each was taken from 20 locations in Ngelom Village. The samples were mixed with K2CrO4 indicator and then were titrated using the silver nitrate standard solution until the end point of the titration was marked with a brick red color. The results of the analysis of chloride levels in well water of 92 to 491 mg/L and in PDAM of 57 to 230 mg/L. Based on these results, it can be concluded that chloride levels in both well water and PDAM water samples were below maximum threshold which appointed in Permenkes RI No. 416/Menkes/Per/IX/1990 (≤600 mg/L).","PeriodicalId":394335,"journal":{"name":"JKPK (Jurnal Kimia dan Pendidikan Kimia)","volume":"1 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2019-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"127469656","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}