Journal of Photochemistry and Photobiology C: Photochemistry Reviews最新文献

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How does the skin sense sun light? An integrative view of light sensing molecules 皮肤是如何感知阳光的?光传感分子的综合观点
IF 13.6 1区 化学
Journal of Photochemistry and Photobiology C: Photochemistry Reviews Pub Date : 2021-06-01 DOI: 10.1016/j.jphotochemrev.2021.100403
Leonardo Vinicius Monteiro de Assis , Paulo Newton Tonolli , Maria Nathalia Moraes , Maurício S. Baptista , Ana Maria de Lauro Castrucci
{"title":"How does the skin sense sun light? An integrative view of light sensing molecules","authors":"Leonardo Vinicius Monteiro de Assis ,&nbsp;Paulo Newton Tonolli ,&nbsp;Maria Nathalia Moraes ,&nbsp;Maurício S. Baptista ,&nbsp;Ana Maria de Lauro Castrucci","doi":"10.1016/j.jphotochemrev.2021.100403","DOIUrl":"https://doi.org/10.1016/j.jphotochemrev.2021.100403","url":null,"abstract":"<div><p>The consensus on the effects of excessive sun exposure on human health has long emphasized the negative effects of solar UV radiation. Nevertheless, although UV radiation has been demonized, less is known about the consequences of sun exposure while using sunscreen, which can lead to high visible light exposure. UV and visible light play key roles in vitamin D synthesis, reduction of blood pressure, among other beneficial effects. In this review, we aim to provide a comprehensive view of the wide range of responses of the human skin to sunlight by revisiting data on the beneficial and harmful effects of UV and visible light. We start by exploring the interaction of photons in the skin at several levels including physical (depth of photon penetration), chemical (light absorption and subsequent photochemical events), and biological (how cells and tissues respond). Skin responses to sun exposure can only be comprehensively understood through a consideration of the light-absorbing molecules present in the skin, especially the light-sensing proteins called opsins. Indeed, many of the cellular responses to sun exposure are modulated by opsins, which act as the “eyes of the skin”.</p></div>","PeriodicalId":376,"journal":{"name":"Journal of Photochemistry and Photobiology C: Photochemistry Reviews","volume":"47 ","pages":"Article 100403"},"PeriodicalIF":13.6,"publicationDate":"2021-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.jphotochemrev.2021.100403","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"2606851","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 33
Recent advances in wireless photofixation of dinitrogen to ammonia under the ambient condition: A review 环境条件下二氮无线固氨研究进展综述
IF 13.6 1区 化学
Journal of Photochemistry and Photobiology C: Photochemistry Reviews Pub Date : 2021-06-01 DOI: 10.1016/j.jphotochemrev.2021.100402
Sriram Mansingh, Kundan Kumar Das, Sabiha Sultana, Kulamani Parida
{"title":"Recent advances in wireless photofixation of dinitrogen to ammonia under the ambient condition: A review","authors":"Sriram Mansingh,&nbsp;Kundan Kumar Das,&nbsp;Sabiha Sultana,&nbsp;Kulamani Parida","doi":"10.1016/j.jphotochemrev.2021.100402","DOIUrl":"https://doi.org/10.1016/j.jphotochemrev.2021.100402","url":null,"abstract":"<div><p>Ammonia is the most necessitate and second largely produces chemical reagent worldwide to address the need of the fertilizer industry, as a precursor for many value-added chemicals and a competing source (17.6 wt% H<sub>2</sub>) for the blooming hydrogen economy. Although N<sub>2</sub> constitutes 78.09 % of the earth's atmosphere, however, its conversion to ammonia is strenuous because of its non-polar and triple bond character. To address the burgeoning demand, ammonia is typically synthesized via the conventional energy and capital intensive Haber-Bosch technique utilizing natural gas and releasing tons of (CO<sub>2</sub>) to the environment. On this basis, cost-effective photon-driven dinitrogen reduction reaction (NRR) is aroused thriving attention as a sustainable and eco-friendly process for ammonia production under ambient conditions. Yet, the photocatalytic ammonia production is not up to the mark for industrial application due to low conversion rate, less catalytic selectivity, ambiguous mechanism, and limited faradic or solar-to-chemical efficiency. Further, the NRR activity of a catalyst essentially depends upon its electronic and surface texture; hence the fabrication of advanced materials is of paramount interest to enhance the performance. The present review covers the underlying mechanism of N<sub>2</sub> photoreduction, prevailing theories, different catalytic engineering techniques, various detection methods, and critical challenges encountered in the theme of photofixation of dinitrogen to ammonia. Additionally, the overarching goal of this review is to bestow an outline of recent research articles in earmarking high-caliber photocatalytic systems and hence planting a strong foundation to ensure the succeeding improvement in this promising and hastily stretching field of dinitrogen photofixation research.</p></div>","PeriodicalId":376,"journal":{"name":"Journal of Photochemistry and Photobiology C: Photochemistry Reviews","volume":"47 ","pages":"Article 100402"},"PeriodicalIF":13.6,"publicationDate":"2021-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.jphotochemrev.2021.100402","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"2802547","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 15
Light-conversion phosphor nanoarchitectonics for improved light harvesting in sensitized solar cells 光转换荧光粉纳米结构改善敏化太阳能电池的光收集
IF 13.6 1区 化学
Journal of Photochemistry and Photobiology C: Photochemistry Reviews Pub Date : 2021-06-01 DOI: 10.1016/j.jphotochemrev.2021.100404
Xinjuan Liu , Taiqiang Chen , Yinyan Gong , Can Li , Lengyuan Niu , Shiqing Xu , Xingtao Xu , Likun Pan , Joseph G. Shapter , Yusuke Yamauchi , Jongbeom Na , Miharu Eguchi
{"title":"Light-conversion phosphor nanoarchitectonics for improved light harvesting in sensitized solar cells","authors":"Xinjuan Liu ,&nbsp;Taiqiang Chen ,&nbsp;Yinyan Gong ,&nbsp;Can Li ,&nbsp;Lengyuan Niu ,&nbsp;Shiqing Xu ,&nbsp;Xingtao Xu ,&nbsp;Likun Pan ,&nbsp;Joseph G. Shapter ,&nbsp;Yusuke Yamauchi ,&nbsp;Jongbeom Na ,&nbsp;Miharu Eguchi","doi":"10.1016/j.jphotochemrev.2021.100404","DOIUrl":"https://doi.org/10.1016/j.jphotochemrev.2021.100404","url":null,"abstract":"<div><p>Photovoltaic technology provides a promising approach for solar energy conversion. One significant factor limiting the efficiency is the poor light harvesting of solar energy, which is related to the mismatch between the energy distribution of photons and the absorption of semiconductor materials or dye. Light-conversion phosphors have been explored as spectral converters to improve the light-harvesting ability in sensitized solar cells. Many progressive studies have been conducted to expand the family of light-conversion phosphors and exploit their application in sensitized solar cells, bringing emerging opportunities to develop commercial sensitized solar cells. In this review, we survey the development of light-conversion phosphors in sensitized solar cells. First, the application and conversion mechanism of light-conversion phosphors, including up-conversion phosphors, down-conversion phosphors, up/down conversion phosphors, and long-lasting phosphors, are summarized in detail. After that, the challenging problems and possible solutions of applying light-conversion phosphors to sensitized solar cells are discussed. The review also highlights some new ideas in the development of sensitized solar cells and the application of light-conversion phosphors in other solar technology.</p></div>","PeriodicalId":376,"journal":{"name":"Journal of Photochemistry and Photobiology C: Photochemistry Reviews","volume":"47 ","pages":"Article 100404"},"PeriodicalIF":13.6,"publicationDate":"2021-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.jphotochemrev.2021.100404","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"2801382","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 24
HOFs under light: Relevance to photon-based science and applications 光下的hof:与光子科学及其应用的相关性
IF 13.6 1区 化学
Journal of Photochemistry and Photobiology C: Photochemistry Reviews Pub Date : 2021-06-01 DOI: 10.1016/j.jphotochemrev.2021.100418
Maria Rosaria di Nunzio , Ichiro Hisaki , Abderrazzak Douhal
{"title":"HOFs under light: Relevance to photon-based science and applications","authors":"Maria Rosaria di Nunzio ,&nbsp;Ichiro Hisaki ,&nbsp;Abderrazzak Douhal","doi":"10.1016/j.jphotochemrev.2021.100418","DOIUrl":"https://doi.org/10.1016/j.jphotochemrev.2021.100418","url":null,"abstract":"<div><p>Hydrogen-bonded Organic Frameworks (HOFs) are an appealing, newly emerging classes of porous materials whose bright potential as multifunctional resources is reflected in important applications like gas storage and separation, molecular recognition, electric and optical materials, chemical sensing, catalysis, and biomedicine. HOFs are assembled from organic building blocks through H-bonding interactions. The resultant framework can be further reinforced <em>via</em> weak connections such as π-π, van der Waals, and/or C-H-π interactions. The highly flexible and reversible HOF structures are exceptionally suitable for the realization of smart HOF materials. To this end, it is crucial to unravel and control the photobehavior of these compounds at intimate levels by the use of advanced laser-based spectroscopy and microscopy techniques. The use of light to study the photophysical processes of HOF-based systems will help to trigger further research to expand their applicability in the related fields. This Review surveys the past-10-years contributions on the spectroscopy and photoinduced fast/ultrafast dynamics of HOFs, the interactions between their building units, the effect of light on their photostability, and most important photonic applications. The aim of this work is to give a rich up-to-date summary of photochemistry and related applications of HOFs and their composites. The reviewed HOFs have been divided into different families based on the nature of the linker, with the purpose of offering to the reader a concise understanding of the related photoinduced processes within each family. The relevant applications of HOFs are also briefly summarized to validate their potential use in modern science and technology.</p></div>","PeriodicalId":376,"journal":{"name":"Journal of Photochemistry and Photobiology C: Photochemistry Reviews","volume":"47 ","pages":"Article 100418"},"PeriodicalIF":13.6,"publicationDate":"2021-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.jphotochemrev.2021.100418","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"2606852","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 25
IFC(EDITORIAL BOARD) 国际金融公司(编辑部)
IF 13.6 1区 化学
Journal of Photochemistry and Photobiology C: Photochemistry Reviews Pub Date : 2021-06-01 DOI: 10.1016/S1389-5567(21)00024-1
{"title":"IFC(EDITORIAL BOARD)","authors":"","doi":"10.1016/S1389-5567(21)00024-1","DOIUrl":"https://doi.org/10.1016/S1389-5567(21)00024-1","url":null,"abstract":"","PeriodicalId":376,"journal":{"name":"Journal of Photochemistry and Photobiology C: Photochemistry Reviews","volume":"47 ","pages":"Article 100425"},"PeriodicalIF":13.6,"publicationDate":"2021-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S1389-5567(21)00024-1","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"2238950","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Concepts of photochemical damage of Photosystem II and the role of excessive excitation 光系统II光化学损伤的概念及过度兴奋的作用
IF 13.6 1区 化学
Journal of Photochemistry and Photobiology C: Photochemistry Reviews Pub Date : 2021-06-01 DOI: 10.1016/j.jphotochemrev.2021.100421
Alonso Zavafer , Cristian Mancilla
{"title":"Concepts of photochemical damage of Photosystem II and the role of excessive excitation","authors":"Alonso Zavafer ,&nbsp;Cristian Mancilla","doi":"10.1016/j.jphotochemrev.2021.100421","DOIUrl":"https://doi.org/10.1016/j.jphotochemrev.2021.100421","url":null,"abstract":"<div><p>Photoinhibition is one of the most controversial topics in photophysiology. Well into the 21 st century, scientists have not agreed on the mechanism of action, primary site, and roles of excess energy absorbed by photosynthetic pigments. It is recognized that Photosystem II is the most fragile component during photoinhibition and that excess excitation absorbed by the photosynthetic pigments has a strong impact on it. Consensus is yet to come on terminology, guidelines to study photoinhibition, or boundaries of what can be considered photodamage. Some of these controversies are the result of how we understand the phenomenon of photoinhibition, as this is what determines a given experimental design. Thus, how we understand photodamage depends on the philosophical approach of each group. While some efforts have been made in the parametrization of Photosystem II photoinhibition, an updated review about the concepts of photoinhibition of Photosystem II and how to study it is still pending. In this work, a review of the concepts used in the field of photoinhibition is presented, accompanied by a synopsis on the history and mechanisms of action.</p></div>","PeriodicalId":376,"journal":{"name":"Journal of Photochemistry and Photobiology C: Photochemistry Reviews","volume":"47 ","pages":"Article 100421"},"PeriodicalIF":13.6,"publicationDate":"2021-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.jphotochemrev.2021.100421","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"2801384","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 24
NIR light-responsive nanocarriers for controlled release 可控释放的近红外光响应纳米载体
IF 13.6 1区 化学
Journal of Photochemistry and Photobiology C: Photochemistry Reviews Pub Date : 2021-06-01 DOI: 10.1016/j.jphotochemrev.2021.100420
Yiyuan Tang, Guojie Wang
{"title":"NIR light-responsive nanocarriers for controlled release","authors":"Yiyuan Tang,&nbsp;Guojie Wang","doi":"10.1016/j.jphotochemrev.2021.100420","DOIUrl":"https://doi.org/10.1016/j.jphotochemrev.2021.100420","url":null,"abstract":"<div><p>The near-infrared (NIR) light in the wavelength range of 780−1700 nm is regarded as transparency therapeutic window for light-activated delivery system in vivo due to the deep tissue penetration and minimum cellular damage of it. Numerous reports about NIR light-sensitive nanocarriers have emerged in the past few years. Here, strategies for the design and fabrication of nanocarriers for NIR light-controlled release are reviewed, which are based on three triggering mechanisms: (1) photoreactions of chromophores, including NIR light-induced photoreactions and upconversion nanoparticles (UCNPs)-mediated photochemical reactions; (2) photothermal effect, triggered by inorganic or organic photothermal conversion agents (PCAs) with the excitation of NIR light; (3) photo-oxidation, induced by reactive oxygen species (ROS) generated by photosensitizers under NIR light radiation. Finally, the challenges and perspectives of NIR light-sensitive nanocarriers for future development are given.</p></div>","PeriodicalId":376,"journal":{"name":"Journal of Photochemistry and Photobiology C: Photochemistry Reviews","volume":"47 ","pages":"Article 100420"},"PeriodicalIF":13.6,"publicationDate":"2021-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.jphotochemrev.2021.100420","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"2801383","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 28
Photogenerated electrophilic radicals for the umpolung of enolate chemistry 烯酸酯化学中光生亲电自由基的研究
IF 13.6 1区 化学
Journal of Photochemistry and Photobiology C: Photochemistry Reviews Pub Date : 2021-03-01 DOI: 10.1016/j.jphotochemrev.2020.100387
Giovanni V.A. Lenardon , Luca Nicchio , Maurizio Fagnoni
{"title":"Photogenerated electrophilic radicals for the umpolung of enolate chemistry","authors":"Giovanni V.A. Lenardon ,&nbsp;Luca Nicchio ,&nbsp;Maurizio Fagnoni","doi":"10.1016/j.jphotochemrev.2020.100387","DOIUrl":"https://doi.org/10.1016/j.jphotochemrev.2020.100387","url":null,"abstract":"<div><p><span><span>The use of enolate </span>chemistry is the election choice when a C</span><img><span>C bond formation is required exploiting the acidity of carbonyl derivatives in the α position. However, a reversed-polarity equivalent of enolate chemistry is emerging making use of electrophilic radicals having a radical site in place of a negative charge in the same α position. Visible light photoredox catalysis is becoming the ideal tool for the generation of these radicals thus allowing their wide application in several synthetic routes. Aim of this review is to collect recent examples of the chemistry of photogenerated electrophilic radicals for the forging of new C</span><img>C or other C<img>Y bonds.</p></div>","PeriodicalId":376,"journal":{"name":"Journal of Photochemistry and Photobiology C: Photochemistry Reviews","volume":"46 ","pages":"Article 100387"},"PeriodicalIF":13.6,"publicationDate":"2021-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.jphotochemrev.2020.100387","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"3125109","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Comprehensive review of photophysical parameters (ε, Φf, τs) of tetraphenylporphyrin (H2TPP) and zinc tetraphenylporphyrin (ZnTPP) – Critical benchmark molecules in photochemistry and photosynthesis 四苯基卟啉(H2TPP)和四苯基卟啉锌(ZnTPP)的光物理参数ε, Φf, τs的综合研究
IF 13.6 1区 化学
Journal of Photochemistry and Photobiology C: Photochemistry Reviews Pub Date : 2021-03-01 DOI: 10.1016/j.jphotochemrev.2020.100401
Masahiko Taniguchi , Jonathan S. Lindsey , David F. Bocian , Dewey Holten
{"title":"Comprehensive review of photophysical parameters (ε, Φf, τs) of tetraphenylporphyrin (H2TPP) and zinc tetraphenylporphyrin (ZnTPP) – Critical benchmark molecules in photochemistry and photosynthesis","authors":"Masahiko Taniguchi ,&nbsp;Jonathan S. Lindsey ,&nbsp;David F. Bocian ,&nbsp;Dewey Holten","doi":"10.1016/j.jphotochemrev.2020.100401","DOIUrl":"https://doi.org/10.1016/j.jphotochemrev.2020.100401","url":null,"abstract":"<div><p><span>Tetraphenylporphyrin (</span><strong>H<sub>2</sub>TPP</strong><span>) and zinc tetraphenylporphyrin (</span><strong>ZnTPP</strong><span>) are widely used benchmark molecules in diverse photochemical studies given facile synthetic access, rich visible-region spectra, and broad structural analogy to chlorophylls. Yet the literature values for each key photophysical parameter – the molar absorption coefficient (ε), fluorescence quantum yield (Φ</span><sub>f</sub>), and also singlet excited-state lifetime (τ<sub>S</sub>) – vary over an astonishing range. Here, a comprehensive literature review (∼1940–September 2020) encompassing 871 publications is reported for these essential parameters. Each parameter is determined by measurement with distinct instrumentation and suffers idiosyncratic sources of error. The best values for <strong>H<sub>2</sub>TPP</strong> are ε = 460,000 cm<sup>−1</sup>·M<sup>−1</sup>, Φ<sub>f</sub> = 0.090, and τ<sub>S</sub> = 12.8 ns in Ar- purged toluene (Φ<sub>f</sub> = 0.070, τ<sub>S</sub> = 9.9 ns in toluene in air); the best values for <strong>ZnTPP</strong> are ε = 560,000 cm<sup>−1</sup>·M<sup>−1</sup>, Φ<sub>f</sub> = 0.030, and τ<sub>S</sub> = 2.1 ns in Ar-purged toluene (Φ<sub>f</sub> = 0.029, τ<sub>S</sub><span><span> = 2.0 ns in toluene in air). The choice of values for such parameters has far-reaching consequences in photochemistry ranging from fluorescence (or Förster) </span>resonance energy transfer (FRET) processes to assessments of molecular brightness.</span></p></div>","PeriodicalId":376,"journal":{"name":"Journal of Photochemistry and Photobiology C: Photochemistry Reviews","volume":"46 ","pages":"Article 100401"},"PeriodicalIF":13.6,"publicationDate":"2021-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.jphotochemrev.2020.100401","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"1532948","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 70
Photocatalytic non-oxidative coupling of methane: Recent progress and future 甲烷光催化非氧化偶联研究进展及展望
IF 13.6 1区 化学
Journal of Photochemistry and Photobiology C: Photochemistry Reviews Pub Date : 2021-03-01 DOI: 10.1016/j.jphotochemrev.2020.100400
Shiqun Wu , Lingzhi Wang , Jinlong Zhang
{"title":"Photocatalytic non-oxidative coupling of methane: Recent progress and future","authors":"Shiqun Wu ,&nbsp;Lingzhi Wang ,&nbsp;Jinlong Zhang","doi":"10.1016/j.jphotochemrev.2020.100400","DOIUrl":"https://doi.org/10.1016/j.jphotochemrev.2020.100400","url":null,"abstract":"<div><p>The importance of effectively converting methane to hydrogen and high value-added hydrocarbons chemicals is becoming more significant due to the huge resources of methane and increasing demands for chemicals. However, it is hard to convert methane into more useful hydrocarbons and hydrogen due to the enormous thermodynamic barrier, which often needs high energy and often results in catalyst deactivation and unsatisfactory product selectivity. Recently, a growing number of researches focusing on photocatalytic methane conversion under mild conditions have attracted much attention, demonstrating that photocatalytic non-oxidative coupling of methane (PNOCM) is a prospective and green method for methane conversion under mild conditions. Herein, we provide a review of the recent advance, remaining challenges, and prospects in PNOCM. Moreover, this review provides considerable guidance for rational design of efficient and stable photocatalysts towards PNOCM by theory predictions and experiment results. We hope this review can attract more attention to the important research field of energy conversion.</p></div>","PeriodicalId":376,"journal":{"name":"Journal of Photochemistry and Photobiology C: Photochemistry Reviews","volume":"46 ","pages":"Article 100400"},"PeriodicalIF":13.6,"publicationDate":"2021-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.jphotochemrev.2020.100400","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"2606853","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 15
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