Journal of Natural Gas Science and Engineering最新文献

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A quantitative analysis of flow properties and heterogeneity in shale rocks using computed tomography imaging and finite-element based simulation 基于计算机断层成像和有限元模拟的页岩流动特性和非均质性定量分析
IF 4.965 2区 工程技术
Journal of Natural Gas Science and Engineering Pub Date : 2022-10-01 DOI: 10.1016/j.jngse.2022.104742
James O. Adeleye, Lateef T. Akanji
{"title":"A quantitative analysis of flow properties and heterogeneity in shale rocks using computed tomography imaging and finite-element based simulation","authors":"James O. Adeleye,&nbsp;Lateef T. Akanji","doi":"10.1016/j.jngse.2022.104742","DOIUrl":"https://doi.org/10.1016/j.jngse.2022.104742","url":null,"abstract":"<div><p>A quantitative evaluation of flow property influenced by micro-scale heterogeneities in shale rocks is presented. Micro- and nano-Computed Tomography images of shale rock samples obtained from Mancos, Marcellus and Eagle Ford formations are digitised into entities such as shale grains, organic matter (kerogen), shale minerals, pores and micro-cracks. Numerical computation on selected layers and sub-micron divisions of the geometries is then carried out using a computationally efficient finite-element based simulation algorithms. Parameters such as pore-volume distribution, porosity, permeability and heterogeneity factor within and across layers are computed as part of pre- and post-process operations. The results of these flow properties characterisation indicated that some shale samples have micro cracks while some do not have. Meanwhile, the presence of micro-cracks in the shale samples contributed to the observed wide variation in permeability and porosity. The static characterisation revealed that different shale rock samples will have different morphological properties. The highest variance in permeability within a layer is of magnitude 5 in Eagle Ford while a magnitude of 2 was computed for Mancos perpendicular. However, magnitudes of 1 and 4 are recorded across layers for Mancos perpendicular and Eagle Ford perpendicular respectively. Contrary to existing assumption that heterogeneity at pore-scale is negligible, it is established from the aforementioned analysis that micro-scale heterogeneity can be quantified. Furthermore, through the analysis of variance and root-mean-square values, it was concluded that tortuosity is inversely related to porosity, permeability and their degree of heterogeneity.</p></div>","PeriodicalId":372,"journal":{"name":"Journal of Natural Gas Science and Engineering","volume":"106 ","pages":"Article 104742"},"PeriodicalIF":4.965,"publicationDate":"2022-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"1529726","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Investigating the micro-turbulent corrosion mechanism of pipeline defects based on a combined experimental and simulation approach 基于实验与仿真相结合的方法研究管道缺陷微湍流腐蚀机理
IF 4.965 2区 工程技术
Journal of Natural Gas Science and Engineering Pub Date : 2022-10-01 DOI: 10.1016/j.jngse.2022.104745
Liuyang Yang , Dalei Zhang , Haiming Fan , Zhuowei Tan , Shaohua Xing , Xiaorui Guan , Xiu Jiang
{"title":"Investigating the micro-turbulent corrosion mechanism of pipeline defects based on a combined experimental and simulation approach","authors":"Liuyang Yang ,&nbsp;Dalei Zhang ,&nbsp;Haiming Fan ,&nbsp;Zhuowei Tan ,&nbsp;Shaohua Xing ,&nbsp;Xiaorui Guan ,&nbsp;Xiu Jiang","doi":"10.1016/j.jngse.2022.104745","DOIUrl":"https://doi.org/10.1016/j.jngse.2022.104745","url":null,"abstract":"<div><p><span>The existence of pipeline defects in oil and gas gathering pipelines predisposed the pipeline to rupture under the synergistic effects<span> of local micro–turbulence and electrochemical corrosion. Here, a combination of experimental and simulation methods was proposed to facilitate the investigation of CO</span></span><sub>2</sub><span> corrosion and the mass transfer process in pipeline defects. The corrosion kinetic characteristics of the defect region were clarified by coupling wire beam microelectrode (WBE) and electrochemical impedance spectroscopy (EIS). Additionally, the effect of flow mass transfer on the corrosion of pipeline defects was investigated by using the existing mass transfer models and COMSOL Multiphysics simulations. The results showed that different locations of the pipeline defects exhibited different mass transfer behavior and corrosion variations. The mass transfer process at the bottom of the defect was lower than that in the upper and lower edge of the defect. Furthermore, the bottom of the defect behaved as an anode and corrodes more severely at low flow velocities. The enhanced mass transfer process led to more severe corrosion at the upper and lower edges of the defect at high flow velocities.</span></p></div>","PeriodicalId":372,"journal":{"name":"Journal of Natural Gas Science and Engineering","volume":"106 ","pages":"Article 104745"},"PeriodicalIF":4.965,"publicationDate":"2022-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"1830217","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
The theoretical basis of model building for coal reservoir permeability: A review and improvement 煤储层渗透率模型建立的理论基础综述与改进
IF 4.965 2区 工程技术
Journal of Natural Gas Science and Engineering Pub Date : 2022-10-01 DOI: 10.1016/j.jngse.2022.104744
Tiantian Zhao , Hao Xu , Dazhen Tang , Peng Zong
{"title":"The theoretical basis of model building for coal reservoir permeability: A review and improvement","authors":"Tiantian Zhao ,&nbsp;Hao Xu ,&nbsp;Dazhen Tang ,&nbsp;Peng Zong","doi":"10.1016/j.jngse.2022.104744","DOIUrl":"https://doi.org/10.1016/j.jngse.2022.104744","url":null,"abstract":"<div><p>The dynamic permeability of coal reservoirs<span> is more complicated than that of conventional reservoirs because of the natural cleat system<span> and matrix shrinkage induced by methane desorption. Many permeability models have been built, but each model has its focus, and the theoretical basis used by them vary, which makes it difficult to compare different models. In this paper, the theoretical basis (basic equations and key relations) of widely cited models was summarized and strictly analyzed. Three limitations were found: the double effect of matrix shrinkage on permeability was not been realized, the concept of effective stress was not clear, and a reliable fracture closure equation was lacking to describe the mechanical response of cleats. Corresponding improvements have been made. Firstly, a new porosity-effective stress relation is obtained without introducing new parameters, which can describe the double effect of matrix shrinkage. Secondly, expressions of three effective stresses considering matrix shrinkage are obtained: Biot effective stress controls the bulk volume strain, pore effective stress controls the pore volume strain, and porosity effective stress controls porosity change. Thirdly, an explicit fracture closure equation is introduced to obtain the analytical permeability models considering the mechanical properties of cleats. Finally, based on the above improvements, a new permeability model system is obtained. Compared with previous models by theoretical analysis, the new models are more comprehensive in considering matrix shrinkage, more accurate in using the effective stresses, and include analytical models based on the mechanical property of cleats.</span></span></p></div>","PeriodicalId":372,"journal":{"name":"Journal of Natural Gas Science and Engineering","volume":"106 ","pages":"Article 104744"},"PeriodicalIF":4.965,"publicationDate":"2022-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"1830221","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Scaling analysis for a 3-D CO2 plume in a sloping aquifer at a late stage of injection 倾斜含水层注入后期三维CO2柱结垢分析
IF 4.965 2区 工程技术
Journal of Natural Gas Science and Engineering Pub Date : 2022-10-01 DOI: 10.1016/j.jngse.2022.104740
Andrey Afanasyev, Elena Vedeneeva, Sergey Grechko
{"title":"Scaling analysis for a 3-D CO2 plume in a sloping aquifer at a late stage of injection","authors":"Andrey Afanasyev,&nbsp;Elena Vedeneeva,&nbsp;Sergey Grechko","doi":"10.1016/j.jngse.2022.104740","DOIUrl":"https://doi.org/10.1016/j.jngse.2022.104740","url":null,"abstract":"<div><p><span>We investigate supercritical CO</span><span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span> injection into a sloping saline aquifer and propose a simple relationship to estimate the maximum gas migration distance in the updip direction. The estimate is derived from the system of governing equations for immiscible flow of gas and formation brine. By writing the equations in non-dimensional form, we guess the scaling law for the migration distance at a late stage of CO<span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span><span> injection. Then, we verify the scaling law by means of 3-D reservoir simulations of miscible CO</span><span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span><span><span><span> injection with account for the residual and solubility trapping. We derive an estimate that relates the maximum migration distance with the dip angle, the porosity, the anisotropic permeability, and the end-points of saturation functions. We show that the estimate is rather accurate for different </span>reservoir temperatures<span> and brine salinity and in the case of a </span></span>flue gas injection. The proposed scaling is useful for a quick assessment of the risk of CO</span><span><math><msub><mrow></mrow><mrow><mn>2</mn></mrow></msub></math></span><span> reaching a potential leakage site in a large regional aquifer. It can also be applied to estimate the propagation of the uncertainties of reservoir parameters to the uncertainty of the migration distance.</span></p></div>","PeriodicalId":372,"journal":{"name":"Journal of Natural Gas Science and Engineering","volume":"106 ","pages":"Article 104740"},"PeriodicalIF":4.965,"publicationDate":"2022-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"1830225","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Equilibrium conditions of CO2+C3H8 hydrates in pure and saline water solutions of NaCl CO2+C3H8水合物在NaCl纯盐水溶液中的平衡条件
IF 4.965 2区 工程技术
Journal of Natural Gas Science and Engineering Pub Date : 2022-10-01 DOI: 10.1016/j.jngse.2022.104734
Moeinoddin Naseh , Cavus Falamaki , Vahid Mohebbi
{"title":"Equilibrium conditions of CO2+C3H8 hydrates in pure and saline water solutions of NaCl","authors":"Moeinoddin Naseh ,&nbsp;Cavus Falamaki ,&nbsp;Vahid Mohebbi","doi":"10.1016/j.jngse.2022.104734","DOIUrl":"https://doi.org/10.1016/j.jngse.2022.104734","url":null,"abstract":"<div><p><span><span>Gas hydrate formation<span><span> and dissociation have been extensively studied in past decades after introducing hydrate-based technology in the energy and environmental fields. Among all, hydrate-based water </span>desalination (HBWD) has been receiving significant attention because of the shortage in water resources. The present study investigates the </span></span>equilibrium conditions for gas hydrate formation from propane and carbon dioxide gas mixtures in the presence of pure water and low saline aqueous solutions for the first time. According to the carried out sensitivity analysis on thermodynamic equilibrium conditions of the CO</span><sub>2</sub>+C<sub>3</sub>H<sub>8</sub><span> mixture with different mole fractions of propane (5–50% C</span><sub>3</sub>H<sub>8</sub> + balanced CO<sub>2</sub><span>) it was concluded that the addition of propane above 20% did not significantly affect the hydrate equilibrium condition. Experiments have been carried out with an initial gas molar composition of 20% C</span><sub>3</sub>H<sub>8</sub> and 80% CO<sub>2</sub><span> in a temperature range of 275.15–280.15 K, at isochoric conditions for the first time. The inhibition effect on the equilibrium conditions is reported in the case of NaCl addition (1, 1.5, 2, and 3 wt%). A reasonable agreement between the experimental data and those calculated from the thermodynamic model applied in this study has been obtained. According to the tests results, the coefficient of determination (R squared) of the final results of the conducted tests and the model predictions are 0.9987 and 0.9950 for pure and saline water, respectively.</span></p></div>","PeriodicalId":372,"journal":{"name":"Journal of Natural Gas Science and Engineering","volume":"106 ","pages":"Article 104734"},"PeriodicalIF":4.965,"publicationDate":"2022-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"1830227","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Dynamic response model and equivalent solution method of large-diameter buried energy transportation pipeline under moving load 移动荷载作用下大直径埋地输能管道动力响应模型及等效求解方法
IF 4.965 2区 工程技术
Journal of Natural Gas Science and Engineering Pub Date : 2022-10-01 DOI: 10.1016/j.jngse.2022.104724
Qian Xu , Gang Yang , Zhuorui Li , Zhenwei Zou , Qiang Zheng , Liqiong Zhong , Xingli Chen , Nevzat Akkurt , Yanping Du , Yaxuan Xiong , Yujie Qiang
{"title":"Dynamic response model and equivalent solution method of large-diameter buried energy transportation pipeline under moving load","authors":"Qian Xu ,&nbsp;Gang Yang ,&nbsp;Zhuorui Li ,&nbsp;Zhenwei Zou ,&nbsp;Qiang Zheng ,&nbsp;Liqiong Zhong ,&nbsp;Xingli Chen ,&nbsp;Nevzat Akkurt ,&nbsp;Yanping Du ,&nbsp;Yaxuan Xiong ,&nbsp;Yujie Qiang","doi":"10.1016/j.jngse.2022.104724","DOIUrl":"https://doi.org/10.1016/j.jngse.2022.104724","url":null,"abstract":"<div><p>Long-distance energy pipeline pass under roads, subjecting them to repeated stress and posing pipeline safety problems. To simulate the effects of vehicles driving over energy transmission pipeline, this paper examines large-caliber buried pipelines in the suburbs. In this study, a mechanical action model of vehicle-soil-pipeline (VSP) interactions to transform the process of a vehicle driving into the dynamic process of a load changing with time in the specified area was created. The VSP model was used to analyze the influence of moving load and position on the structural characteristics of the pipeline section. An equivalent solution method with high precision and high calculation efficiency was proposed. The results showed that as the loading position approaches the pipeline or the load increases, the stress value at the top of the pipeline gradually exceeded the stress value at the bottom of the pipeline and became the area with the maximum stress value. The minimum stress location also changed from the lower half near the pipeline bottom (Point D-135°) to the upper half near the pipeline top (Point B-45°or Point H-315°). Using the polynomial fitting method, the stress values of the maximum points were equivalently converted. Under the premise of considering pipeline safety, the most suitable functional relationship for the moving load equivalent model was obtained.</p></div>","PeriodicalId":372,"journal":{"name":"Journal of Natural Gas Science and Engineering","volume":"106 ","pages":"Article 104724"},"PeriodicalIF":4.965,"publicationDate":"2022-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"3270825","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 7
Prediction of maximum slug length considering impact of well trajectories in British Columbia shale gas fields using machine learning 考虑井眼轨迹影响的英属哥伦比亚页岩气田段塞最长长度的机器学习预测
IF 4.965 2区 工程技术
Journal of Natural Gas Science and Engineering Pub Date : 2022-10-01 DOI: 10.1016/j.jngse.2022.104725
Sungil Kim , Youngwoo Yun , Jiyoung Choi , Majid Bizhani , Tea-woo Kim , Hoonyoung Jeong
{"title":"Prediction of maximum slug length considering impact of well trajectories in British Columbia shale gas fields using machine learning","authors":"Sungil Kim ,&nbsp;Youngwoo Yun ,&nbsp;Jiyoung Choi ,&nbsp;Majid Bizhani ,&nbsp;Tea-woo Kim ,&nbsp;Hoonyoung Jeong","doi":"10.1016/j.jngse.2022.104725","DOIUrl":"https://doi.org/10.1016/j.jngse.2022.104725","url":null,"abstract":"<div><p>In this study, the severity of slugging is assessed by predicting maximum slug lengths (MSL) quickly using the random forest (RF) algorithm based on the geometric features of well trajectories for a shale gas field. Severe slugging is one of the critical issues production engineering-wise because it causes operation shut-down. Thus it should be predicted for proactive measurements. A total of 5033 well trajectories were acquired from the northeastern area of British Columbia, Canada. The well trajectories are described using ten geometric features such as X, Y, and Z lengths in the Cartesian coordinate system, inclination, azimuth, and the other five. The 5033 well trajectories are grouped using the k-medoids clustering algorithm. The well trajectories in each group and the groups are compared visually to see if the ten features are representative enough to describe the geometric features of the well trajectories. The ten geometric features of the well trajectories are used as the input for RF, and MSL, which represents the severity of slugging, is used as the output for RF. The output data is simulation results by a pipe flow simulator, OLGA. The trained RF model provides the satisfactory prediction performance of MSL (R values, 0.866 and 0.857 for training and test data, respectively). In the trained RF model, X, Y, and Z lengths have the most significant importance among the ten geometric features. Because it is impractical to simulate all well trajectory scenarios by OLGA, the MSL values are projected onto a 3-dimensional map of which axes are X, Y, and Z lengths to visualize the trend of MSL. The 3-dimensional map showing the relation between MSL and the geometric features of well trajectories can be utilized as a quick reference to avoid severe slugging in designing well trajectories.</p></div>","PeriodicalId":372,"journal":{"name":"Journal of Natural Gas Science and Engineering","volume":"106 ","pages":"Article 104725"},"PeriodicalIF":4.965,"publicationDate":"2022-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"1813514","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Chemical and physical systems for sour gas removal: An overview from reaction mechanisms to industrial implications 去除酸性气体的化学和物理系统:从反应机制到工业意义的概述
IF 4.965 2区 工程技术
Journal of Natural Gas Science and Engineering Pub Date : 2022-10-01 DOI: 10.1016/j.jngse.2022.104755
Ahmed Abotaleb , Ivan Gladich , Alaa Alkhateeb , Nour Mardini , Yusuf Bicer , Alessandro Sinopoli
{"title":"Chemical and physical systems for sour gas removal: An overview from reaction mechanisms to industrial implications","authors":"Ahmed Abotaleb ,&nbsp;Ivan Gladich ,&nbsp;Alaa Alkhateeb ,&nbsp;Nour Mardini ,&nbsp;Yusuf Bicer ,&nbsp;Alessandro Sinopoli","doi":"10.1016/j.jngse.2022.104755","DOIUrl":"https://doi.org/10.1016/j.jngse.2022.104755","url":null,"abstract":"<div><p>As global energy demand keeps rising, natural gas is meant to be the main protagonist of the clean energy transition, with increasingly importance in power generation and production of chemicals. However, the presence of contaminants in the raw gas, such as H<sub>2</sub>S and CO<sub>2</sub>, is the cause of several operational and technical issues ranging from equipment corrosion, fouling, catalyst deactivation, and environmental pollution. Therefore, it is necessary to remove contaminants from these gaseous mixtures for their efficient and safe use in multiple applications. The objective of this review is to explore different aspects of the acid gas removal (AGR) processes and technologies. The design of AGR unit and the main parameters affecting the process have been discussed. In the first part, the chemical absorption processes are summarised, including the chemical mechanisms involved and a screening of the main amine-based solvents currently used in such processes. In the second part, the physical absorption processes are presented, with properties, advantages and disadvantages of the typical absorbents. The comparison of various solvents, towards H<sub>2</sub>S and CO<sub>2</sub> removal techniques, has been discussed and supported by simulation and experimental studies. Industrial applications of AGR processes have been included in the discussion. Finally, the future directions of research to improve the removal processes and materials have been indicated.</p></div>","PeriodicalId":372,"journal":{"name":"Journal of Natural Gas Science and Engineering","volume":"106 ","pages":"Article 104755"},"PeriodicalIF":4.965,"publicationDate":"2022-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"3454230","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Construction of selective gas permeation channels in polymeric membranes using nanocage tuned ionic liquid/MIL-53 (Al) filler nanoparticles for effective CO2 separation 利用纳米笼调谐离子液体/MIL-53 (Al)填充纳米颗粒在聚合物膜中构建选择性气体渗透通道以实现有效的CO2分离
IF 4.965 2区 工程技术
Journal of Natural Gas Science and Engineering Pub Date : 2022-10-01 DOI: 10.1016/j.jngse.2022.104728
B. Sasikumar, G. Arthanareeswaran
{"title":"Construction of selective gas permeation channels in polymeric membranes using nanocage tuned ionic liquid/MIL-53 (Al) filler nanoparticles for effective CO2 separation","authors":"B. Sasikumar,&nbsp;G. Arthanareeswaran","doi":"10.1016/j.jngse.2022.104728","DOIUrl":"https://doi.org/10.1016/j.jngse.2022.104728","url":null,"abstract":"<div><p><span><span>Polymeric membranes with metal-organic frameworks (MOFs) holds great potential for gas separation. However, finely tailoring the adhesion between MOFs and polymer matrices<span><span> is crucial in reducing the membranes defective structure. The partial inorganic structure of MOFs limits the interaction with the polymer matrix, which tends to agglomerate on the membranes. Herein, an interfacial strategy is reported by post-synthetic functionalization of MIL-53 (Al) with ionic liquids (ILs) to construct IL@MIL-53 (Al) composite to improve </span>interfacial interaction<span> among filler and polysulfone (PSf) matrices. At 2 wt% of IL@MIL-53 (Al), the composite membranes </span></span></span>tensile strength<span> and % elongation were enhanced by about 66.13 and 97.40% compared to the neat PSf membrane. The intimate contact between IL@MIL-53 (Al) and PSf matrices renders uniform dispersion evident from morphological studies. The gas permeation properties were evaluated for carbondioxide (CO</span></span><sub>2</sub>), nitrogen (N<sub>2</sub>), methane (CH<sub>4</sub><span>) gases. At 2 wt% of MIIL-53 (Al) nanofiller, the CO</span><sub>2</sub><span> permeance<span> was found to be 37.56 ± 0.63 GPU which was significantly higher than the neat PSf membrane. Besides, the CO</span></span><sub>2</sub> permeance of the PSf/2% IL@MIL-53 (Al) membrane was noted to be 34.23 ± 0.68 GPU, whereas the CO<sub>2</sub>/CH<sub>4</sub> and CO<sub>2</sub>/N<sub>2</sub><span> selectivities were 48.64 and 49.19% higher than the neat membrane. As the pressure increased from 2 to 10 bar, the CO</span><sub>2</sub>, N<sub>2,</sub> and CH<sub>4</sub> gas permeances in composite PSf membranes were decreased, whereas the CO<sub>2</sub>/N<sub>2</sub> and CO<sub>2</sub>/CH<sub>4</sub> selectivities were observed to be increased. The introduction of ILs into the MOFs pores will tune pore size with the enhanced adsorption selectivity due to its high CO<sub>2</sub><span> solubility and affinity of ILs. ILs functionalization on the cores of the MIL-53 (Al) structure is an effective strategy, which opens up the selection to a broad range of fillers in the aspect of commercialization.</span></p></div>","PeriodicalId":372,"journal":{"name":"Journal of Natural Gas Science and Engineering","volume":"106 ","pages":"Article 104728"},"PeriodicalIF":4.965,"publicationDate":"2022-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"2554428","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 4
Permeability changes in mining-damaged coal: A review of mathematical models 采动损伤煤的渗透率变化:数学模型综述
IF 4.965 2区 工程技术
Journal of Natural Gas Science and Engineering Pub Date : 2022-10-01 DOI: 10.1016/j.jngse.2022.104739
Shouqing Lu , Mingjie Li , Yankun Ma , Shengcheng Wang , Wei Zhao
{"title":"Permeability changes in mining-damaged coal: A review of mathematical models","authors":"Shouqing Lu ,&nbsp;Mingjie Li ,&nbsp;Yankun Ma ,&nbsp;Shengcheng Wang ,&nbsp;Wei Zhao","doi":"10.1016/j.jngse.2022.104739","DOIUrl":"https://doi.org/10.1016/j.jngse.2022.104739","url":null,"abstract":"<div><p>Coal seam<span> gas drainage is not only the effective measure for gas outbursts control, but also has the great significance for the use of gas energy and reduction of greenhouse-gas emissions. Coal permeability is the key parameter of gas drainage, and the permeability model of mining-damaged coal has the important theoretical guidance value for gas drainage in low permeability coal seams. In order to better understand the permeability model of damaged coal, the key points during the establishment of permeability model, which are the selection of coal structure, selection of boundary conditions and influencing factors, were first analyzed. Then, the expression and application of permeability models of mining-damaged coal in recent 20 years were reviewed. According to the contribution of new fractures, the permeability models of mining-damaged coal were divided into the empirical permeability models (EPM), volumetric strain permeability models (VSPM), plastic strain permeability models (PSPM) and damage variable permeability models (DVPM). After that, the quantitative characterization of key parameters, scientific issues of permeability models of mining-damaged coal were reviewed and discussed. Finally, the prioritization of 18 indexes affecting the permeability were determined, and the potential research directions of permeability models of mining-damaged coal were pointed out. The results of this paper can provide the theoretical guidance for the improvement of permeability model of mining-damage coal in the future.</span></p></div>","PeriodicalId":372,"journal":{"name":"Journal of Natural Gas Science and Engineering","volume":"106 ","pages":"Article 104739"},"PeriodicalIF":4.965,"publicationDate":"2022-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"1826674","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 12
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