D.I. Snorrason , S.M. Adalsteinsson , T.K. Tryggvason , D. Dagbjartsson , A.S. Ingason , F. Magnus
{"title":"Structural stability and oxidation resistance of amorphous TaSi-based ternary alloy coatings","authors":"D.I. Snorrason , S.M. Adalsteinsson , T.K. Tryggvason , D. Dagbjartsson , A.S. Ingason , F. Magnus","doi":"10.1016/j.nocx.2023.100183","DOIUrl":"10.1016/j.nocx.2023.100183","url":null,"abstract":"<div><p>Amorphous metal coatings have great potential for corrosion protection but finding alloy compositions which form a stable amorphous structure can be an overwhelming task. We use combinatorial magnetron sputtering and X-ray analysis to map out the phase space of TaSiM (M = Al, Cr, Fe, Ti) alloys in order to identify amorphous compositions. Atomic percentages of above 10–15 at.% of each constituent yield amorphous coatings in all four systems. TaSiAl coatings are stable when annealed in air up to and including 550 °C whereas TaSiFe, TaSiCr and TaSiTi remain amorphous up to and including 750 °C. In particular, Ta<sub>35</sub>Si<sub>15</sub>Cr<sub>50</sub> is almost unchanged at that temperature, and has a stable surface oxide shell less than 20 nm in thickness at 650 °C. The stability of these materials at high temperatures means that they could be suitable as anti-corrosion coatings in high temperature applications.</p></div>","PeriodicalId":37132,"journal":{"name":"Journal of Non-Crystalline Solids: X","volume":"18 ","pages":"Article 100183"},"PeriodicalIF":0.0,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44290629","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
C. Ugwumadu , K.N. Subedi , R. Thapa , P. Apsangi , S. Swain , M.N. Kozicki , D.A. Drabold
{"title":"Structure, vibrations and electronic transport in silicon suboxides: Application to physical unclonable functions","authors":"C. Ugwumadu , K.N. Subedi , R. Thapa , P. Apsangi , S. Swain , M.N. Kozicki , D.A. Drabold","doi":"10.1016/j.nocx.2023.100179","DOIUrl":"10.1016/j.nocx.2023.100179","url":null,"abstract":"<div><p>This work focuses on the structure and electronic transport in atomistic models of silicon suboxides (a-SiO<sub><em>x</em></sub>; <em>x</em> = 1.3,1.5 and 1.7) used in the fabrication of a Physical Unclonable Function (PUF) devices. Molecular dynamics and density functional theory simulations were used to obtain the structural, electronic, and vibrational properties that contribute to electronic transport in a-SiO<sub><em>x</em></sub>. The percentage of Si-[Si<sub>1</sub>, O<sub>3</sub>] and Si-[Si<sub>3</sub>, O<sub>1</sub>], observed in a-SiO<sub>1.3</sub>, decrease with increasing O ratio. Vibrations in a-SiO<sub><em>x</em></sub> showed peaks that result from topological defects. The electronic conduction path in a-SiO<sub><em>x</em></sub> favored Si-rich regions and Si atoms with dangling bonds formed charge-trapping sites. For doped a-SiO<sub><em>x</em></sub>, the type of doping results in new conduction paths, hence qualifying a-SiOx as a viable candidate for PUF fabrication as reported by Kozicki [Patent-Publication-No.: US2021/0175185A1, 2021].</p></div>","PeriodicalId":37132,"journal":{"name":"Journal of Non-Crystalline Solids: X","volume":"18 ","pages":"Article 100179"},"PeriodicalIF":0.0,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46895491","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
U. Hoppe , R.K. Brow , A.C. Hannon , M.V. Zimmermann
{"title":"Erratum to “Structure of tin phosphate glasses by neutron and X-ray diffraction” [Journal of Non crystalline solids:X 2C (2019) 100017]","authors":"U. Hoppe , R.K. Brow , A.C. Hannon , M.V. Zimmermann","doi":"10.1016/j.nocx.2023.100152","DOIUrl":"10.1016/j.nocx.2023.100152","url":null,"abstract":"","PeriodicalId":37132,"journal":{"name":"Journal of Non-Crystalline Solids: X","volume":"18 ","pages":"Article 100152"},"PeriodicalIF":0.0,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47692072","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Parker T. Freudenberger, Rebekah L. Blatt, Richard K. Brow
{"title":"Dissolution rates of borophosphate glasses in deionized water and in simulated body fluid","authors":"Parker T. Freudenberger, Rebekah L. Blatt, Richard K. Brow","doi":"10.1016/j.nocx.2023.100181","DOIUrl":"10.1016/j.nocx.2023.100181","url":null,"abstract":"<div><p>Particles of borophosphate glasses with the nominal molar compositions 16Na<sub>2</sub>O-(24-y)CaO-ySrO-xB<sub>2</sub>O<sub>3</sub>-(60-x)P<sub>2</sub>O<sub>5</sub> (mol%), where 0 ≤ x ≤ 60 and y = 0, 12, and 24, were reacted in deionized water and in simulated body fluid (SBF) at 37 °C. For the dissolution experiments in water, the pH of the solution at the conclusion of the experiments increased systematically, from 2.1 to 9.5, for y = 0 glasses when ‘x’ increased from 0 to 60. The reaction rates over the first 8–24 h of dissolution in both SBF and deionized water followed linear kinetics, with reaction rates dependent on glass composition. For glass particles in SBF, replacing P<sub>2</sub>O<sub>5</sub> with up to 20 mol% B<sub>2</sub>O<sub>3</sub> decreased the dissolution rate (fraction dissolved) by two orders of magnitude, from 7.0 × 10<sup>−3</sup> h<sup>−1</sup> for x = 0 to 2.0 × 10<sup>−5</sup> h<sup>−1</sup> for x = 20. Further replacement of P<sub>2</sub>O<sub>5</sub> by B<sub>2</sub>O<sub>3</sub> increased dissolution rates by three orders of magnitude, to 2.3 × 10<sup>−2</sup> h<sup>−1</sup> at x = 60. The compositional dependence of the dissolution rates is explained by changes in the glass structure, with the most durable glasses possessing the greatest fraction of tetrahedral borophosphate sites in the glass network. Crystalline brushite was detected on Ca-glasses with 35 and 40 mol% B<sub>2</sub>O<sub>3</sub>, but the dominant precipitation phase on both the Ca- and Sr-glasses is an x-ray amorphous material constituted from orthophosphate and pyrophosphate anions.</p></div>","PeriodicalId":37132,"journal":{"name":"Journal of Non-Crystalline Solids: X","volume":"18 ","pages":"Article 100181"},"PeriodicalIF":0.0,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41321287","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Erratum to indentation deformation in oxide glasses: Quantification, structural changes, and relation to cracking [Journal of Non crystalline solids:X 1C (2019) 100007]","authors":"Kacper Januchta, Morten M. Smedskjaer","doi":"10.1016/j.nocx.2022.100144","DOIUrl":"10.1016/j.nocx.2022.100144","url":null,"abstract":"","PeriodicalId":37132,"journal":{"name":"Journal of Non-Crystalline Solids: X","volume":"18 ","pages":"Article 100144"},"PeriodicalIF":0.0,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44955614","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Adjustment of refractive index of Ge-Ga-Se glass via Te addition for infrared-imaging applications","authors":"Hyun Kim, Il Jung Yoon, Yong Gyu Choi","doi":"10.1016/j.nocx.2023.100190","DOIUrl":"10.1016/j.nocx.2023.100190","url":null,"abstract":"<div><p>After assessing compositional dependence of thermal and optical properties of Ge-Ga-Se glasses, we introduce Te, via replacing Se, into Ge<sub>25</sub>Ga<sub>5</sub>Se<sub>70</sub> and Ge<sub>35</sub>Ga<sub>5</sub>Se<sub>60</sub> (mol%) glasses in an attempt to enhance their refractive index. In the case of Se-deficient Ge<sub>35</sub>Ga<sub>5</sub>Se<sub>60</sub> composition, vitrification is achieved for Te content up to 20 mol%. In the case of Se-sufficient Ge<sub>25</sub>Ga<sub>5</sub>Se<sub>70</sub> composition, however, formation of bulk glass is realized only when Te content ranges from 25 to 45 mol%. Being proportional to Te content, refractive index of Ge<sub>25</sub>Ga<sub>5</sub>Se<sub>30</sub>Te<sub>40</sub> glass is measured to approach 2.855 at 10 μm, which is far superior to that of any commercialized selenide glasses for infrared-imaging applications. This compositionally tailored Ge<sub>25</sub>Ga<sub>5</sub>Se<sub>30</sub>Te<sub>40</sub> glass is further verified to be compatible with the conventional precision glass molding process, and infrared-imaging performance of the resulting molded lens is as excellent as the existing selenide-glass-based lenses.</p></div>","PeriodicalId":37132,"journal":{"name":"Journal of Non-Crystalline Solids: X","volume":"18 ","pages":"Article 100190"},"PeriodicalIF":0.0,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44247989","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Erratum to “Review on the structural analysis of fluoride-phosphate and fluoro-phosphate glasses” [Journal of Non Crystalline Solids:X 3C (2019) 100026]","authors":"Doris Möncke , Hellmut Eckert","doi":"10.1016/j.nocx.2023.100158","DOIUrl":"10.1016/j.nocx.2023.100158","url":null,"abstract":"","PeriodicalId":37132,"journal":{"name":"Journal of Non-Crystalline Solids: X","volume":"18 ","pages":"Article 100158"},"PeriodicalIF":0.0,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43100075","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Erratum to “The irrelevance of phantom nuclei in crystallization kinetics: An integral equation approach” [Journal of Non Crystalline Solids:X 1C (2019) 100002]","authors":"Jonathan F. Stebbins","doi":"10.1016/j.nocx.2022.100141","DOIUrl":"10.1016/j.nocx.2022.100141","url":null,"abstract":"","PeriodicalId":37132,"journal":{"name":"Journal of Non-Crystalline Solids: X","volume":"18 ","pages":"Article 100141"},"PeriodicalIF":0.0,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41427262","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Philip S. Salmon , Gregory S. Moody , YoshikiIshii , Keiron J. Pizzey , Annalisa Polidori , Mathieu Salanne , Anita Zeidler , Michela Buscemi , Henry E. Fischer , Craig L. Bull , Stefan Klotz , Richard Weber , Chris J. Benmore , Simon G. MacLeod
{"title":"Erratum to “Pressure induced structural transformations in amorphous MgSiO3 and CaSiO3” [Journal of Non crystalline solids:X 3C (2019) 100024]","authors":"Philip S. Salmon , Gregory S. Moody , YoshikiIshii , Keiron J. Pizzey , Annalisa Polidori , Mathieu Salanne , Anita Zeidler , Michela Buscemi , Henry E. Fischer , Craig L. Bull , Stefan Klotz , Richard Weber , Chris J. Benmore , Simon G. MacLeod","doi":"10.1016/j.nocx.2023.100154","DOIUrl":"10.1016/j.nocx.2023.100154","url":null,"abstract":"","PeriodicalId":37132,"journal":{"name":"Journal of Non-Crystalline Solids: X","volume":"18 ","pages":"Article 100154"},"PeriodicalIF":0.0,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43869659","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}