Journal of Non-Crystalline Solids: X最新文献_第3页

Dissolution rates of borophosphate glasses in deionized water and in simulated body fluid 硼磷酸盐玻璃在去离子水和模拟体液中的溶解速率

Journal of Non-Crystalline Solids: X Pub Date : 2023-06-01 DOI: 10.1016/j.nocx.2023.100181

Parker T. Freudenberger, Rebekah L. Blatt, Richard K. Brow

{"title":"Dissolution rates of borophosphate glasses in deionized water and in simulated body fluid","authors":"Parker T. Freudenberger, Rebekah L. Blatt, Richard K. Brow","doi":"10.1016/j.nocx.2023.100181","DOIUrl":"10.1016/j.nocx.2023.100181","url":null,"abstract":"<div>Particles of borophosphate glasses with the nominal molar compositions 16Na2O-(24-y)CaO-ySrO-xB2O3-(60-x)P2O5 (mol%), where 0 ≤ x ≤ 60 and y = 0, 12, and 24, were reacted in deionized water and in simulated body fluid (SBF) at 37 °C. For the dissolution experiments in water, the pH of the solution at the conclusion of the experiments increased systematically, from 2.1 to 9.5, for y = 0 glasses when ‘x’ increased from 0 to 60. The reaction rates over the first 8–24 h of dissolution in both SBF and deionized water followed linear kinetics, with reaction rates dependent on glass composition. For glass particles in SBF, replacing P2O5 with up to 20 mol% B2O3 decreased the dissolution rate (fraction dissolved) by two orders of magnitude, from 7.0 × 10−3 h−1 for x = 0 to 2.0 × 10−5 h−1 for x = 20. Further replacement of P2O5 by B2O3 increased dissolution rates by three orders of magnitude, to 2.3 × 10−2 h−1 at x = 60. The compositional dependence of the dissolution rates is explained by changes in the glass structure, with the most durable glasses possessing the greatest fraction of tetrahedral borophosphate sites in the glass network. Crystalline brushite was detected on Ca-glasses with 35 and 40 mol% B2O3, but the dominant precipitation phase on both the Ca- and Sr-glasses is an x-ray amorphous material constituted from orthophosphate and pyrophosphate anions.</div>","PeriodicalId":37132,"journal":{"name":"Journal of Non-Crystalline Solids: X","volume":"18 ","pages":"Article 100181"},"PeriodicalIF":0.0,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41321287","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 2

Erratum to indentation deformation in oxide glasses: Quantification, structural changes, and relation to cracking [Journal of Non crystalline solids:X 1C (2019) 100007] 氧化物玻璃压痕变形勘误表：量化、结构变化和与开裂的关系[非晶态固体杂志：X 1C（2019）100007]

Journal of Non-Crystalline Solids: X Pub Date : 2023-06-01 DOI: 10.1016/j.nocx.2022.100144

Kacper Januchta, Morten M. Smedskjaer

引用次数: 0

Adjustment of refractive index of Ge-Ga-Se glass via Te addition for infrared-imaging applications 红外成像中Ge-Ga-Se玻璃折射率的Te调节

Journal of Non-Crystalline Solids: X Pub Date : 2023-06-01 DOI: 10.1016/j.nocx.2023.100190

Hyun Kim, Il Jung Yoon, Yong Gyu Choi

{"title":"Adjustment of refractive index of Ge-Ga-Se glass via Te addition for infrared-imaging applications","authors":"Hyun Kim, Il Jung Yoon, Yong Gyu Choi","doi":"10.1016/j.nocx.2023.100190","DOIUrl":"10.1016/j.nocx.2023.100190","url":null,"abstract":"<div>After assessing compositional dependence of thermal and optical properties of Ge-Ga-Se glasses, we introduce Te, via replacing Se, into Ge25Ga5Se70 and Ge35Ga5Se60 (mol%) glasses in an attempt to enhance their refractive index. In the case of Se-deficient Ge35Ga5Se60 composition, vitrification is achieved for Te content up to 20 mol%. In the case of Se-sufficient Ge25Ga5Se70 composition, however, formation of bulk glass is realized only when Te content ranges from 25 to 45 mol%. Being proportional to Te content, refractive index of Ge25Ga5Se30Te40 glass is measured to approach 2.855 at 10 μm, which is far superior to that of any commercialized selenide glasses for infrared-imaging applications. This compositionally tailored Ge25Ga5Se30Te40 glass is further verified to be compatible with the conventional precision glass molding process, and infrared-imaging performance of the resulting molded lens is as excellent as the existing selenide-glass-based lenses.</div>","PeriodicalId":37132,"journal":{"name":"Journal of Non-Crystalline Solids: X","volume":"18 ","pages":"Article 100190"},"PeriodicalIF":0.0,"publicationDate":"2023-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44247989","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Erratum to “Review on the structural analysis of fluoride-phosphate and fluoro-phosphate glasses” [Journal of Non Crystalline Solids:X 3C (2019) 100026] “氟-磷酸盐和氟-磷酸盐玻璃结构分析综述”的勘误[非结晶固体学报:X 3C (2019) 100026]

Journal of Non-Crystalline Solids: X Pub Date : 2023-06-01 DOI: 10.1016/j.nocx.2023.100158

Doris Möncke , Hellmut Eckert

引用次数: 0

Erratum to “TiO2(B) nanocrystals in Ti-doped lithium aluminosilicate glasses” [Journal of Non Crystalline Solids:X 2C (2019) 100025] “Ti掺杂锂铝硅酸盐玻璃中的TiO2（B）纳米晶体”勘误表[非结晶固体杂志：X 2C（2019）100025]

Journal of Non-Crystalline Solids: X Pub Date : 2023-06-01 DOI: 10.1016/j.nocx.2022.100146

A. Zandona , C. Patzig , B. Rüdinger , O. Hochrein , J. Deubener

引用次数: 0

Erratum to “The irrelevance of phantom nuclei in crystallization kinetics: An integral equation approach” [Journal of Non Crystalline Solids:X 1C (2019) 100002] “结晶动力学中幻影核的不相关性：积分方程方法”勘误表[非结晶固体杂志：X 1C（2019）100002]

Journal of Non-Crystalline Solids: X Pub Date : 2023-06-01 DOI: 10.1016/j.nocx.2022.100141

Jonathan F. Stebbins

引用次数: 0

Erratum to “Pressure induced structural transformations in amorphous MgSiO3 and CaSiO3” [Journal of Non crystalline solids:X 3C (2019) 100024] “非晶态MgSiO3和CaSiO3的压力诱导结构转变”勘误表[非晶态固体杂志：X 3C（2019）100024]

Journal of Non-Crystalline Solids: X Pub Date : 2023-06-01 DOI: 10.1016/j.nocx.2023.100154

Philip S. Salmon , Gregory S. Moody , YoshikiIshii , Keiron J. Pizzey , Annalisa Polidori , Mathieu Salanne , Anita Zeidler , Michela Buscemi , Henry E. Fischer , Craig L. Bull , Stefan Klotz , Richard Weber , Chris J. Benmore , Simon G. MacLeod

引用次数: 0

Characterising the glass transition temperature-structure relationship through a recurrent neural network 通过递归神经网络表征玻璃化转变温度-结构关系

Journal of Non-Crystalline Solids: X Pub Date : 2023-06-01 DOI: 10.1016/j.nocx.2023.100185

Claudia Borredon , Luis A. Miccio , Silvina Cerveny , Gustavo A. Schwartz

引用次数: 0

Glass-water interaction of a potassium phospho-aluminosilicate glass: Influence on mechanical behavior 磷酸钾铝硅酸盐玻璃的玻璃-水相互作用:对力学行为的影响

Journal of Non-Crystalline Solids: X Pub Date : 2023-06-01 DOI: 10.1016/j.nocx.2023.100184

Emily M. Aaldenberg, Jared S. Aaldenberg, Timothy M. Gross

引用次数: 0

Femtosecond laser direct-writing of perovskite nanocrystals in glasses 玻璃中钙钛矿纳米晶的飞秒激光直写

Journal of Non-Crystalline Solids: X Pub Date : 2023-06-01 DOI: 10.1016/j.nocx.2023.100182

Zihuai Su , Shengzhi Sun , Ye Dai , Xiaofeng Liu , Jianrong Qiu

引用次数: 0