Е. Lantsev, N. Malekhonova, V. Chuvil’deev, А. Nokhrin, Y. Tsvetkov, Yu. V. Blagoveshchenskiy, M. Boldin, N. Isaeva, P. Andreev, K. Smetanina
{"title":"Study of high-speed sintering of fine-grained hard alloys based on tungsten carbide with ultralow cobalt content. III. Effect of C content on sintering kinetics of the nanopowders","authors":"Е. Lantsev, N. Malekhonova, V. Chuvil’deev, А. Nokhrin, Y. Tsvetkov, Yu. V. Blagoveshchenskiy, M. Boldin, N. Isaeva, P. Andreev, K. Smetanina","doi":"10.30791/0015-3214-2022-2-35-54","DOIUrl":"https://doi.org/10.30791/0015-3214-2022-2-35-54","url":null,"abstract":"The features of high-speed spark plasma sintering (SPS) of plasma-chemical nanopowders WC – (0.3, 0.6, 1) wt. % Co with the addition of 0.3 and 0.5 wt. % graphite were studied. The structural features of the ultralow-cobalt hard alloys with graphite addition during SPS are due to the simultaneous influence of an increased concentration of oxygen adsorbed on the surface of plasma-chemical WC – Co nanoparticles during mixing with graphite, and the effect of graphite, which leads to a decrease in activation energy of sintering due to a decrease in the intensity of formation of η-phase particles in “oxidized” WC – Co nanopowders, as well as the formation of a fairly uniform fine-grained structure. Samples of fine-grained ultralow-cobalt hard alloys with increased hardness and fracture toughness were obtained (for a WC – 0.6 wt. % Co – 0.3 wt. % C hard alloy with an average grain size of ~ (1 – 1.5) mm, the hardness is Hv = 20.2 – 20.5 GPa with a minimum crack resistance coefficient KIC = 9.2 – 10.4 MPa·m1/2).","PeriodicalId":366423,"journal":{"name":"Physics and Chemistry of Materials Treatment","volume":"126 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128062369","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. A. Dorofeev, A. Samokhin, A. Fadeev, N. Alekseev, M. Sinayskiy, I. S. Litvinova, I. Zavertyaev
{"title":"Investigation of the granulation process of the W – Ni – Fe system nanopowder by spray drying","authors":"A. A. Dorofeev, A. Samokhin, A. Fadeev, N. Alekseev, M. Sinayskiy, I. S. Litvinova, I. Zavertyaev","doi":"10.30791/0015-3214-2022-6-54-69","DOIUrl":"https://doi.org/10.30791/0015-3214-2022-6-54-69","url":null,"abstract":"A method for obtaining nanopowder microgranules of the W – Ni – Fe system (composition of the VNJ-90) of a micron size range by spray drying of a suspension based on composite nanoparticles obtained by plasma chemical synthesis is considered. The parameters of operation of the Buchi Mini Spray Dryer B-290 spray drying laboratory unit with an ultrasonic nozzle have been experimentally determined, providing for the production of nanopowder microgranules of VNJ-90 with an output of the target fraction of 25 – 63 µm at the level of 65 %. The dependence of the size and morphology of the obtained granules on the choice of the dispersion medium, the concentration of the dispersed phase and the organic binder in the suspension is established. The effect of the suspension flow rate during spray drying on the yield of granules of a fraction of 25 – 63 µm was evaluated. The test of the manufactured experimental sample of nanopowder microgranules in the process of plasma spheroidization was carried out.","PeriodicalId":366423,"journal":{"name":"Physics and Chemistry of Materials Treatment","volume":"122 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"128148542","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
О. V. Bakina, Е. А. Glazkova, Е. А. Vornakova, V. Zhou, K. Suliz
{"title":"Preparation of ZnFe2O4/ZnO/PMMA composition with antibacterial properties and low toxicity","authors":"О. V. Bakina, Е. А. Glazkova, Е. А. Vornakova, V. Zhou, K. Suliz","doi":"10.30791/0015-3214-2022-2-55-64","DOIUrl":"https://doi.org/10.30791/0015-3214-2022-2-55-64","url":null,"abstract":"In present work, the possibility of obtaining ZnFe2O4/ZnO nanoparticles by electric explosion of zinc and iron wires in an oxygen-containing atmosphere is shown. Based on the obtained nanoparticles and polymethyl methacrylate, ZnFe2O4/ZnO/PMMA composite was obtained, containing from 0.5 to 10 wt. % of nanoparticles. The composite film suppressed the viability of E. coli bacteria with an efficiency of 99.99 %, which is due to the generation of reactive oxygen species. The synthesized composite material with high antibacterial activity is promising for the production of antimicrobial materials for medicine for a long time.","PeriodicalId":366423,"journal":{"name":"Physics and Chemistry of Materials Treatment","volume":"114 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"115450256","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Study of operational properties of steel friction pairs with antifriction coating from copper alloys produced by electric spark alloying","authors":"L. Kuksenova, D. Kozlov, M. Alekseeva","doi":"10.30791/0015-3214-2021-4-31-41","DOIUrl":"https://doi.org/10.30791/0015-3214-2021-4-31-41","url":null,"abstract":"Improving the reliability, durability and safety of operation of heavily loaded friction units is an urgent problem in physics, chemistry and surface mechanics. The tribotechnical characteristics of coatings made of bronzes BrAZhMts10-3-1.5 and BrMtsF3-6, applied by electrospark alloying on bushings made of structural steel 30KhGSN2A for operation under conditions of high contact pressure under friction without lubrication, have been investigated. Modes of coating deposition from the standpoint of tribology (the value of the electric discharge current in a pulse, the value of the longitudinal electrode feed per one rotation of the part, the rotation speed of the workpiece, the number of passes during processing, finishing of the coating) have been developed. It was found that when applying bronze BrMtsF3-6 to obtain a high-quality coating, the process must be performed in a protective atmosphere of argon to prevent phosphorus burnout. The tribotechnical efficiency of coatings when working under dry friction conditions is shown. For the steady-state wear mode, the friction coefficient is 0.10 – 0.13 at a pressure of 200 – 250 MPa, the wear resistance of coated steel is doubled. Steel with a bronze coating BrAZhMts10-3-1.5 has a higher bearing capacity, with BrMtsF3-6 coating — a higher antifriction. The ways of increasing the service life of steel-coated steel friction pair are analyzed.","PeriodicalId":366423,"journal":{"name":"Physics and Chemistry of Materials Treatment","volume":"115 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"125031931","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
P. Maryin, N. Ivanova, E. Shesterikov, E. Bolbasov, S. Tverdokhlebov, Radioelectronics
{"title":"Effect of the target intermediate ion cleaning on the structure of bioresorbable PLLA scaffolds under the coating deposition by DC reactive magnetron sputtering method","authors":"P. Maryin, N. Ivanova, E. Shesterikov, E. Bolbasov, S. Tverdokhlebov, Radioelectronics","doi":"10.30791/0015-3214-2019-4-36-45","DOIUrl":"https://doi.org/10.30791/0015-3214-2019-4-36-45","url":null,"abstract":"","PeriodicalId":366423,"journal":{"name":"Physics and Chemistry of Materials Treatment","volume":"57 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122821557","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
S. Ovsepyan, Fsue “Viam”, Y. Kolobov, M. V. Akhmedzyanov, S. Manokhin, E. Filonova, I. Ras
{"title":"Investigation of the nitride phase in a heat-resistant alloy of the Ni – Co – W – Ti system, hardened by internal nitration","authors":"S. Ovsepyan, Fsue “Viam”, Y. Kolobov, M. V. Akhmedzyanov, S. Manokhin, E. Filonova, I. Ras","doi":"10.30791/0015-3214-2021-2-63-71","DOIUrl":"https://doi.org/10.30791/0015-3214-2021-2-63-71","url":null,"abstract":"In a high-temperature alloy of the Ni – Co – Cr – W – Ti system grade VZh171, using X-ray spectral analysis, scanning and transmission electron microscopy, the composition of the particles of the hardening phase — nitrides after internal nitriding and subsequent heat treatment was studied. It was found that the particles differ on it chemical composition: the main constituent element, titanium or chromium, is proportionally replaced by other alloy components. The nitride compositions near the surface and in the center of the sample differ in the titanium to chromium ratio. After annealing, this difference is smaller, and the chromium content also decreases. It was found that the nitrides formed during nitriding are compounds in which the main forming element, titanium or chromium, is proportionally replaced by other alloy components. The nitride compositions near the surface and in the center of the sample differ in the titanium to chromium ratio. After annealing, this difference is smaller, and the chromium content also decreases.","PeriodicalId":366423,"journal":{"name":"Physics and Chemistry of Materials Treatment","volume":"278 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122852287","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Interaction of B and Hf with oxygen in a nickel melt at РAr = 0.1 MPa and analysis of nonmetallic inclusions","authors":"V. Burtsev, E. Chabina","doi":"10.30791/0015-3214-2021-5-49-59","DOIUrl":"https://doi.org/10.30791/0015-3214-2021-5-49-59","url":null,"abstract":"The deoxidation of complex alloyed nickel-based alloys during melting in vacuum is carried out in the presence of aluminum with strong deoxidizers B and Hf, which requires additional knowledge about the activity of dissolved oxygen. For this, the activity was investigated in model melts Ni – O – (B/Hf, 0.001 – 0.1 wt. % of each) and Ni – O – Al (5 %) – (B/Hf, 0.001 – 0.1 wt. % of each) at 1560 °C and РAr = 0.1 MPa by the method of instantaneous EMF recording using certified sensors. It was shown that a[O] with the introduction of B into the melt without aluminum is 1.3 times less than with the introduction of Hf, and for melts with aluminum, a[O] decreased 1.6 times as compared with Hf. The study of the morphology and composition of non-metallic inclusions of the Ni – O – (B/Hf) systems showed that the inclusions are located along grain boundaries, have various complex configurations and sizes from 2 to 100 μm. These phases contain Ni, Fe, Zr, S, O, as well as Hf, Pb, Bi, Si, Mg after deoxidation of Hf and an increased content of Zr after deoxidation of B.","PeriodicalId":366423,"journal":{"name":"Physics and Chemistry of Materials Treatment","volume":"16 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"125741955","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
E. O. Nasakina, A. D. Popova, M. Kaplan, A. Mikhailova, M. Sudarchikova, D. A. Novikova, K. V. Sergienko, A. Kolmakov, M. A. Sevost’yanov
{"title":"Study of the influence of surface layer parameters on the level of their X-ray contrast","authors":"E. O. Nasakina, A. D. Popova, M. Kaplan, A. Mikhailova, M. Sudarchikova, D. A. Novikova, K. V. Sergienko, A. Kolmakov, M. A. Sevost’yanov","doi":"10.30791/0015-3214-2022-5-21-30","DOIUrl":"https://doi.org/10.30791/0015-3214-2022-5-21-30","url":null,"abstract":"Nano- and microdimensional tantalum surface layers were created on wire and flat NiTi substrates by magnetron sputtering. The samples structure and composition were determined using SEM and Auger spectroscopy. As the sputtering time increases, the thickness of the surface layer increases non-linearly, which leads to a change in the radiopacity of the material relative to the substrate. Based on the calculations of the coefficient of linear attenuation of X-ray radiation, it is shown that a layered composite in the form of a plate with a surface layer on only one side can be conditionally represented as a multicomponent monolith, but with a rounded sample section, a continuous surface layer surrounding it from all sides has a greater effect on radiopacity.","PeriodicalId":366423,"journal":{"name":"Physics and Chemistry of Materials Treatment","volume":"131 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"121609063","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
A. Grebennikov, A. I. Bocharov, S. B. Kushchev, D. Serikov, A. B. Kostyuchenko, E. Fedorova, I. V. Izvekova, I. Safonov, Military Educational
{"title":"Effect of pulsed photon treatment on electrophysical and thermal properties of n-type solid solution on the base of Bi2Te3-Bi2Se3. II. Thermal conductivity and thermoelectric figure of merit","authors":"A. Grebennikov, A. I. Bocharov, S. B. Kushchev, D. Serikov, A. B. Kostyuchenko, E. Fedorova, I. V. Izvekova, I. Safonov, Military Educational","doi":"10.30791/0015-3214-2019-6-22-27","DOIUrl":"https://doi.org/10.30791/0015-3214-2019-6-22-27","url":null,"abstract":"","PeriodicalId":366423,"journal":{"name":"Physics and Chemistry of Materials Treatment","volume":"29 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"122445903","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
S. V. Simakov, N. Vinogradova, A. Ashmarin, A. B. Mikhajlova, O. N. Nikitushkina, E. E. Starostin, V. I. Tovtin
{"title":"Effect of plastic deformation, heat treatment and electron irradiation on structural-phase state of Cu – 40 аt. % Pd alloy","authors":"S. V. Simakov, N. Vinogradova, A. Ashmarin, A. B. Mikhajlova, O. N. Nikitushkina, E. E. Starostin, V. I. Tovtin","doi":"10.30791/0015-3214-2022-6-11-16","DOIUrl":"https://doi.org/10.30791/0015-3214-2022-6-11-16","url":null,"abstract":"Effect of plastic deformation, heat treatment, and electron irradiation on the structural-phase state of Cu – 40 at. % Pd is studied. X-ray phase analysis of initial samples, samples obtained by rolling up to 0.2 mm, samples annealed after rolling in an argon atmosphere at 950 °C for 1 h, and samples irradiated by high-energy electron in air at temperature of 300 °C was carried out. A change in the phase composition of the samples after rolling was found: ~ 6 % of the ordered β-phase with bcc structure was formed, which disappears after annealing. As a result of irradiation, a layer of copper oxide CuO formed on the surface of the alloy, which under normal thermal conditions is formed at a temperatures of 400 – 500 °C, and the reflections of the ordered β-phase also disappeared in the near-surface layer. The elemental composition of the alloy changed in depth from the irradiated metal surface. Phases with a low degree of long-range order and an increased content of palladium were formed. The presence of these phases is due mainly to the selective oxidation of copper.","PeriodicalId":366423,"journal":{"name":"Physics and Chemistry of Materials Treatment","volume":"5 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"1900-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"121107947","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}