Sofia Buritica , Julian Gutteriez , Véronique Lapeyre , Patrick Garrigue , Alain Brisson , Sisareuth Tran , Eric Laurichesse , Isabelle Ly , Véronique Schmitt , Olivier Diat , Pierre Bauduin , Valérie Ravaine
{"title":"Inter cross-linking microgels by superchaotropic nano-ions at interface: Controlled stabilization of emulsions","authors":"Sofia Buritica , Julian Gutteriez , Véronique Lapeyre , Patrick Garrigue , Alain Brisson , Sisareuth Tran , Eric Laurichesse , Isabelle Ly , Véronique Schmitt , Olivier Diat , Pierre Bauduin , Valérie Ravaine","doi":"10.1016/j.jcis.2025.138257","DOIUrl":"10.1016/j.jcis.2025.138257","url":null,"abstract":"<div><h3>Hypothesis</h3><div>Poly(<em>N</em>-isopropylacrylamide) (pNIPAM) microgels are soft particles that adsorb at liquid interfaces and confer emulsion stability against coalescence. Their conformation and interactions at the interface greatly impact the mechanical properties of the interface. In particular, the interfacial elastic modulus increases as the microgel cross-linking density decreases, as a consequence of microgel ability to deform and entangle with neighbors. The purpose of this work is to investigate how these features can be tuned by physical interactions between superchaotropic Keggin nano-ions (POMs) and pNIPAM microgels.</div></div><div><h3>Experiments</h3><div>Interactions between polyoxometalates (POMs) and pNIPAM microgels of varying cross-linking densities and sizes are investigated in aqueous suspensions and at liquid/liquid interfaces. The ability of microgels to stabilize oil-in-water emulsions is assessed by evaluating their kinetic stability and flow characteristics, with POMs introduced either before or after emulsification. Cryogenic electron microscopy (cryo-EM) is employed to directly visualize the microgel-stabilized emulsions. The adsorption of microgels, at a model interface and the resulting interfacial elasticity with various POM concentrations, are also studied using the oscillating pendant drop method.</div></div><div><h3>Findings</h3><div>POMs act as physical cross-linkers that promotes microgel deswelling. For large microgels, this effect increases their stiffness. and thus adding POMs reduces the stability of the emulsions. In contrast, small POM-loaded microgels produce highly stable emulsions that resist coalescence under mechanical stress or temperature increase. The same is true for large microgels supplemented in POMs after emulsification. Indeed, POMs enhance interfacial elasticity by promoting both intra-particle and inter-particle crosslinking at the interface. Lastly, by connecting microgel monolayers between neighboring droplet surfaces, POMs promote adhesion between droplets. All levels of the multiscale structure within Pickering emulsions are controlled by interactions between POMs and pNIPAM.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"699 ","pages":"Article 138257"},"PeriodicalIF":9.4,"publicationDate":"2025-06-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144523550","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pengjun Yuan , Yujing Wang , Ao Wang , Jinhui Lin , Xingzhu Chen , Xiyu Liu , Yingrui Zhang , Wenjuan Gao , Peiyuan Wang , Guilong Zhang , Lu Liu
{"title":"Synergistic cancer treatment with PCuLu nanocatalysts by inducing cuproptosis and enhancing radiotherapy","authors":"Pengjun Yuan , Yujing Wang , Ao Wang , Jinhui Lin , Xingzhu Chen , Xiyu Liu , Yingrui Zhang , Wenjuan Gao , Peiyuan Wang , Guilong Zhang , Lu Liu","doi":"10.1016/j.jcis.2025.138260","DOIUrl":"10.1016/j.jcis.2025.138260","url":null,"abstract":"<div><div>The X-ray-induced photodynamic therapy (X-PDT) has brought significant promise for treating deeply seated cancers in clinical settings. However, the clinical application of X-PDT remains limited, primarily due to the issues related to cancer cells' intrinsic antioxidant mechanisms and radiotherapy's low efficacy. To address these issues, this study presents a nanocatalyst-based radiosensitizer PCuLu, which is meticulously designed and constructed to enhance the effectiveness of X-PDT combined with copper-induced cell death (Cuproptosis) for tumor treatment. Leveraging the unique properties of the rare-earth element lutetium, PCuLu effectively absorbs X-rays and deposits the radiation energy, causing irreversible damage to the deoxyribonucleic acid (DNA) of cancer cells. The PCuLu nanocatalyst also promotes enhanced cuproptosis, further amplifying the therapeutic effects of X-PDT. Our findings reveal the beneficial role of enhancing copper toxicity in radiotherapy (RT), offering a new strategy for the synergistic integration of cuproptosis with radiation therapy. This work broadens the scope of copper-mediated cancer treatment. It provides a promising approach to overcoming the current limitations in X-PDT, potentially leading to more effective clinical outcomes in tumor treatment.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"699 ","pages":"Article 138260"},"PeriodicalIF":9.4,"publicationDate":"2025-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144480418","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Pengbo Ding , Qitao Lian , Dan Xing , Lixiu Guan , Zhuoao Li , Shuo Zhang , Junguang Tao
{"title":"External electric field modulation of cation-induced interfacial potential during hydrogen evolution on polycrystalline platinum surfaces","authors":"Pengbo Ding , Qitao Lian , Dan Xing , Lixiu Guan , Zhuoao Li , Shuo Zhang , Junguang Tao","doi":"10.1016/j.jcis.2025.138259","DOIUrl":"10.1016/j.jcis.2025.138259","url":null,"abstract":"<div><div>The impact of alkaline media on the hydrogen evolution reaction (HER) rate is crucial for water electrolysis. This study provides new insights into how alkali metal cations (AM<sup>+</sup>) influence the HER performance of Pt electrodes. We quantified interfacial potential drops modulated by an external electric field and discovered that the local surface concentration of AM<sup>+</sup> is 5.0 to 8.6 times higher than in the bulk solution. The accumulation of AM<sup>+</sup> in the outer Helmholtz plane (OHP) diminishes the interaction between H<sub>2</sub>O and Pt surface, thereby impeding H<sub>2</sub>O dissociation. The external electric field drives AM<sup>+</sup> away from the OHP, mitigating this effect. Theoretical calculations indicate that AM<sup>+</sup> enhance proton transfer by reorganizing interfacial water, with Li<sup>+</sup> orienting surrounding O<img>H bonds favorably towards the Pt surface, thus facilitating the HER process. Our combined experimental and theoretical studies elucidate the role of AM<sup>+</sup> in the HER by influencing double-layer potential and interfacial water formation.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"699 ","pages":"Article 138259"},"PeriodicalIF":9.4,"publicationDate":"2025-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144480422","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Max Hohenschutz , Hannes Luhmann , Amina Ledinic , Jasmin Simons , Martin Dulle , Carlos G. Lopez
{"title":"Chaotropic or hydrophobic effect: Distinct binding signatures of nano-ions to a non-ionic polymer","authors":"Max Hohenschutz , Hannes Luhmann , Amina Ledinic , Jasmin Simons , Martin Dulle , Carlos G. Lopez","doi":"10.1016/j.jcis.2025.138256","DOIUrl":"10.1016/j.jcis.2025.138256","url":null,"abstract":"<div><div>The nanometric ions (nano-ions) SiW<sub>12</sub>O<sub>40</sub><sup>4−</sup> (SiW) and B(C<sub>6</sub>H<sub>5</sub>)<sub>4</sub><sup>−</sup> (BPh<sub>4</sub>) are considered as a superchaotropic and a hydrophobic ion, respectively, extending the chaotropic side of the Hofmeister series. We show by measurement of the viscosity <em>B</em>-coefficient of SiW (and other nano-ions such as dodecaborates and Keggin POMs) and of ion binding to the non-ionic polymer hydroxypropylcellulose (HPC), how chaotropic, superchaotropic and hydrophobic ions can be unambiguously distinguished. The <em>B</em>-coefficient of the superchaotropic SiW is positive as for hydrophobic ions, and distinct from chaotropic ions with negative <em>B</em>. In HPC-solution, SiW or BPh<sub>4</sub> bind to the polymer, dramatically increasing the viscosity and the cloud point. Heating induces characteristically distinct responses for the two nano-ions: The viscosity decreases for SiW and rises for BPh<sub>4</sub>. These effects arise from nano-ion induced aggregation and electric charging of HPC, which, upon heating, become weaker for SiW and stronger for BPh<sub>4</sub> as shown by Small Angle X-ray Scattering. Isothermal Titration Calorimetry revealed striking thermochemical differences between SiW and BPh<sub>4</sub>. Heating decreases the binding constant for SiW and increases it for BPh<sub>4</sub> arising respectively from an enthalpically favorable, exothermic, chaotropic binding process or an enthalpically unfavorable, endothermic, hydrophobic binding process. Importantly, superchaotropic binding can be stronger or weaker than hydrophobic binding depending on temperature.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"699 ","pages":"Article 138256"},"PeriodicalIF":9.4,"publicationDate":"2025-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144557256","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Liangyao Xue , Wenjuan Shi , Dian Song , Xiaoxiong Huang , Jiaqi Zhang , Yexuan Zhang , Wuning Yuan , Shuanglong Huang , Kai Sun , Lirong Zheng , Youyong Li , Cheng Liu , Bo Zhang
{"title":"Constructing a multisite catalyst for achieving efficient and highly selective borohydride oxidation reaction","authors":"Liangyao Xue , Wenjuan Shi , Dian Song , Xiaoxiong Huang , Jiaqi Zhang , Yexuan Zhang , Wuning Yuan , Shuanglong Huang , Kai Sun , Lirong Zheng , Youyong Li , Cheng Liu , Bo Zhang","doi":"10.1016/j.jcis.2025.138253","DOIUrl":"10.1016/j.jcis.2025.138253","url":null,"abstract":"<div><div>It is crucial to develop efficient and inexpensive borohydride oxidation reduction (BOR) electrocatalysts for the practical application of direct borohydride fuel cells (DBFCs). However, until now, there is still rare electrocatalyst that can simultaneously achieve a high BOR rate, high faradaic efficiency, and low BOR onset potential. In this work, we reported an efficient multisite catalyst CoFe&AuC, with a peak power density of 580 mW/cm<sup>2</sup> in DBFC (Air as oxidant), which is 2.8 and 4.3 times higher than CoFe&C (210 mW/cm<sup>2</sup>) and AuC (136 mW/cm<sup>2</sup>), respectively. Meanwhile, CoFe&AuC also shows a peak power density of 1371 mW/cm<sup>2</sup> in DBFC with O<sub>2</sub> used as an oxidant. Notably, CoFe&AuC exhibits a high electron transfer number (5.4) and fuel efficiency (65.6 %), suggesting the high selectivity for BOR. In situ spectroscopy combined with density functional theory (DFT) calculations indicate that the enhanced BOR activity can be attributed to the tandem effect between different components: the rapid adsorption and initial oxidation of BH<sub>4</sub><sup>−</sup> to BH<sub>3</sub> species on CoFe LDH and the further oxidation of BH<sub>3</sub> species on Au nanoparticles, which efficiently break the bottleneck of Au catalyzing BH<sub>4</sub><sup>−</sup>. This work provides a novel pathway for designing multisite electrocatalysts with high BOR activity and selectivity.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"699 ","pages":"Article 138253"},"PeriodicalIF":9.4,"publicationDate":"2025-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144514143","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Confined cerium oxide clusters induced interface engineering enhance platinum nanoparticles for efficient ethanol oxidation reaction","authors":"Haoran Jiang , Zhirang Liu , Zichen Wang , Wangbin Zhu , Qiliang Wei , Fei Guo , Wei Chen , Yinghui Jiang , Heng Zhu , Niancai Cheng","doi":"10.1016/j.jcis.2025.138254","DOIUrl":"10.1016/j.jcis.2025.138254","url":null,"abstract":"<div><div>Direct ethanol fuel cells (DEFCs) have been extensively studied as promising energy conversion devices due to their non-toxicity, low corrosivity, and high energy and power densities. However, developing highly active and durable catalysts for the ethanol oxidation reaction (EOR) at the anode remains a significant challenge. Herein, we modulate the intermediate affinity on Pt nanoparticles (NPs) to achieve highly efficient EOR performance through precise optimization of the Pt-CeO<sub>2</sub> interface. The well-defined and fully exposed Pt-CeO<sub>2</sub> interface was engineered through controlled incorporation of CeO<sub>2</sub> nanoclusters within the hierarchical pore structure of nitrogen-doped porous carbon (NPC). The high electrical conductivity and abundant pore structure of NPC not only accelerate the charge transfer rate but also enhance the stability of CeO<sub>2</sub> through confinement effects. Importantly, experimental and theoretical analyses reveal that the interaction between CeO<sub>2</sub> and Pt NPs strengthens the stability of Pt NPs, modulates the surface charge distribution of Pt, and provides additional adsorbed hydroxyl species (OH<sub>ads</sub>), further boosting the ethanol oxidation capability of Pt. The Pt/CeO<sub>2</sub>@NPC-300 catalyst not only delivers a maximum mass activity of 1207 mA mg<sub>Pt</sub><sup>−1</sup> and retains 64.7 % of its initial performance after 500 cycles, but also exhibits excellent CO tolerance. This study proposes an innovative catalyst structural design strategy to advance the development of DEFCs and other sustainable energy technologies.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"699 ","pages":"Article 138254"},"PeriodicalIF":9.4,"publicationDate":"2025-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144491170","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Changcheng Lin , Huaibao Tang , Jun Xu , Dongmeng Chen , Xueqin Zuo , Qun Yang , Zhong Jin , Haifeng Xu , Guang Li
{"title":"Natural superoxide dismutase inspired Heterostructural N, S-Codoped CoFe₂O₄/MoC Electrocatalyst for highly efficient water splitting","authors":"Changcheng Lin , Huaibao Tang , Jun Xu , Dongmeng Chen , Xueqin Zuo , Qun Yang , Zhong Jin , Haifeng Xu , Guang Li","doi":"10.1016/j.jcis.2025.138249","DOIUrl":"10.1016/j.jcis.2025.138249","url":null,"abstract":"<div><div>Current research on heterojunctions as catalysts for the oxygen evolution reaction (OER) and hydrogen evolution reaction (HER) primarily emphasizes the electron transfer processes at the heterojunction interface. However, the regulatory role of doped elements within heterostructures remains inadequately explored, despite its significant scientific implications for the advancement of efficient catalysts. Inspired by the catalytic superoxide dismutation reaction of superoxide dismutase (SOD) observed in nature, this study presents a novel heterostructural N and S co-doped CoFe<sub>2</sub>O<sub>4</sub>/MoC electrocatalyst. The incorporation of N and S induces a distinctive ‘electron-dragging’ effect within the CoFe₂O₄/MoC heterostructural system, selectively modulating the reception and release of electrons during HER and OER processes, thereby ensuring an optimal electron density at various active sites. The designed N, S-CoFe₂O₄/MoC-NS electrocatalyst achieves a total hydrolysis current density of 100 mA cm<sup>−2</sup> at a potential as low as 1.47 V and maintains stable output for 300 h without degradation. Theoretical calculations and in-situ Raman spectroscopy suggest that the formation of the heterostructure and the ‘electron-dragging ‘effect are crucial in regulating different active sites, providing new insights into the balance between catalyst activity and stability.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"699 ","pages":"Article 138249"},"PeriodicalIF":9.4,"publicationDate":"2025-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144471189","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Anchoring ruthenium single atoms into the carbon nanotubes-supported nickel-based sulfides for enhanced electrocatalytic oxygen evolution","authors":"Shaohua Yang, Yueyang Wang, Yaqiong Gong","doi":"10.1016/j.jcis.2025.138255","DOIUrl":"10.1016/j.jcis.2025.138255","url":null,"abstract":"<div><div>Engineering single atoms anchored on nanoparticles with maximal atom utilization efficiency and tunable coordination character holds a great promise for applications in water splitting and energy storage. Herein, Ruthenium (Ru) single atoms embedded in nickel subsulfide‑nickel sulfide (Ni<sub>3</sub>S<sub>2</sub>-NiS) nanoparticles supported on carbon nanotubes (CNTs) are fabricated via economical approach and utilized as chemical catalysts towards oxygen evolution reaction (OER). The unique architecture of Ru@Ni<sub>3</sub>S<sub>2</sub>-NiS/CNTs provides substantial surface area exposure, facilitating electron transport and revealing numerous active sites. In particular, Ru@Ni<sub>3</sub>S<sub>2</sub>-NiS/CNTs demonstrates remarkable OER catalytic capability, with a reduced overpotential of 221 mV at 10 mA cm<sup>−2</sup> and decreased Tafel slope of 74.1 mV dec<sup>−1</sup> in alkaline electrolyte, outstripping commercially available Ir/C catalyst. The atomically dispersed Ru sites were identified and the Ru single atoms confined within the Ni<sub>3</sub>S<sub>2</sub>-NiS lattice of it to induce Ru-S-Ni bonding, serving as catalytic centers to elevate the inherent activity towards OER. Furthermore, the electronic characteristic of Ni<sub>3</sub>S<sub>2</sub>-NiS was modulated with the doping of isolated Ru atoms. Density functional theory (DFT) calculations have illustrated the presence of atomically dispersed Ru into Ni<sub>3</sub>S<sub>2</sub>-NiS strengthens both chemical adsorption and OER catalytic activities. This study broadens significant insights into the field of single-atom catalysts and offers valuable perspectives for designing advanced materials in sustainable energy applications.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"699 ","pages":"Article 138255"},"PeriodicalIF":9.4,"publicationDate":"2025-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144365302","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Chenchen Yue , Zhao Liang , Yong Xu , Qiao Liu , Qiliang Wei , Dongjiang Yang , Jingjing Du , Weiyou Yang , Qing Shi
{"title":"Synergistic heterojunctions of CoSe2 and NiFe layed double hydroxide: bridging in situ phase evolution and charge redistribution as bifunctional catalysts for water splitting","authors":"Chenchen Yue , Zhao Liang , Yong Xu , Qiao Liu , Qiliang Wei , Dongjiang Yang , Jingjing Du , Weiyou Yang , Qing Shi","doi":"10.1016/j.jcis.2025.138252","DOIUrl":"10.1016/j.jcis.2025.138252","url":null,"abstract":"<div><div>Electrolytic hydrogen production is fundamentally constrained by the sluggish kinetics of both the hydrogen evolution reaction (HER) at the cathode and the oxygen evolution reaction (OER) at the anode. To address this challenge, the development of efficient, durable, and economically viable bifunctional electrocatalysts is critical for advancing sustainable water splitting technologies. In this work, we present a rationally designed composite nanoflake heterostructure comprising CoSe<sub>2</sub> and NiFe layered double hydroxide (LDH) anchored on nickel foam (CoSe<sub>2</sub>@NiFe-LDH/NF), synthesized via a facile two-step electrodeposition. This integrated architecture exhibits exceptional bifunctional catalytic activity for both HER and OER. In situ Raman spectroscopy analysis demonstrated that Co<img>Se bond cleavage induces cobalt oxidation and selenium leaching, while the CoSe<sub>2</sub>/NiFe-LDH interface orchestrates electron redistribution to drive NiFeOOH formation, synergistically enhancing OER activity through coupled electronic modulation and structural reconstruction dynamics. Structural characterization and theoretical calculations show that the charge redistribution at the heterojunction interface optimizes the adsorption energy of the reaction intermediates, thus improving the OER and HER performance. As a result, the optimized CoSe<sub>2</sub>@NiFe-LDH/NF demonstrates a modest overpotential of 227 mV@50 mA cm<sup>−2</sup> for HER and 266 mV@100 mA cm<sup>−2</sup> for OER. Furthermore, the CoSe<sub>2</sub>@NiFe-LDH/NF composite material employed in the overall water splitting cell demonstrates remarkable stability by maintaining a current density of 100 mA cm<sup>−2</sup> at an applied voltage of 1.75 V for an extended duration of 100 h. This study not only presents a simple and convenient strategy for synthesizing cost-effective and high-efficiency bifunctional electrocatalysts but also establishes novel pathways for advancing the performance of non-precious metal electrocatalysts.</div></div>","PeriodicalId":351,"journal":{"name":"Journal of Colloid and Interface Science","volume":"699 ","pages":"Article 138252"},"PeriodicalIF":9.4,"publicationDate":"2025-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144365087","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}