ACS Physical Chemistry Au最新文献

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Ultrafast Nuclear Magnetic Resonance as a Tool to Detect Rapid Chemical Change in Solution 将超快核磁共振作为检测溶液中快速化学变化的工具
IF 3.7
ACS Physical Chemistry Au Pub Date : 2024-07-24 DOI: 10.1021/acsphyschemau.4c0004210.1021/acsphyschemau.4c00042
Ben. J. Tickner*, Kawarpal Singh*, Vladimir V. Zhivonitko* and Ville-Veikko Telkki*, 
{"title":"Ultrafast Nuclear Magnetic Resonance as a Tool to Detect Rapid Chemical Change in Solution","authors":"Ben. J. Tickner*,&nbsp;Kawarpal Singh*,&nbsp;Vladimir V. Zhivonitko* and Ville-Veikko Telkki*,&nbsp;","doi":"10.1021/acsphyschemau.4c0004210.1021/acsphyschemau.4c00042","DOIUrl":"https://doi.org/10.1021/acsphyschemau.4c00042https://doi.org/10.1021/acsphyschemau.4c00042","url":null,"abstract":"<p >Ultrafast nuclear magnetic resonance (NMR) uses spatial encoding to record an entire two-dimensional data set in just a single scan. The approach can be applied to either Fourier-transform or Laplace-transform NMR. In both cases, acquisition times are significantly shorter than traditional 2D/Laplace NMR experiments, which allows them to be used to monitor rapid chemical transformations. This Perspective outlines the principles of ultrafast NMR and focuses on examples of its use to detect fast molecular conversions <i>in situ</i> with high temporal resolution. We discuss how this valuable tool can be applied in the future to study a much wider variety of novel reactivity.</p>","PeriodicalId":29796,"journal":{"name":"ACS Physical Chemistry Au","volume":null,"pages":null},"PeriodicalIF":3.7,"publicationDate":"2024-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acsphyschemau.4c00042","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142318357","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ultrafast Nuclear Magnetic Resonance as a Tool to Detect Rapid Chemical Change in Solution 将超快核磁共振作为检测溶液中快速化学变化的工具
ACS Physical Chemistry Au Pub Date : 2024-07-24 DOI: 10.1021/acsphyschemau.4c00042
Ben. J. Tickner, Kawarpal Singh, Vladimir V. Zhivonitko, Ville-Veikko Telkki
{"title":"Ultrafast Nuclear Magnetic Resonance as a Tool to Detect Rapid Chemical Change in Solution","authors":"Ben. J. Tickner, Kawarpal Singh, Vladimir V. Zhivonitko, Ville-Veikko Telkki","doi":"10.1021/acsphyschemau.4c00042","DOIUrl":"https://doi.org/10.1021/acsphyschemau.4c00042","url":null,"abstract":"Ultrafast nuclear magnetic resonance (NMR) uses spatial encoding to record an entire two-dimensional data set in just a single scan. The approach can be applied to either Fourier-transform or Laplace-transform NMR. In both cases, acquisition times are significantly shorter than traditional 2D/Laplace NMR experiments, which allows them to be used to monitor rapid chemical transformations. This Perspective outlines the principles of ultrafast NMR and focuses on examples of its use to detect fast molecular conversions <i>in situ</i> with high temporal resolution. We discuss how this valuable tool can be applied in the future to study a much wider variety of novel reactivity.","PeriodicalId":29796,"journal":{"name":"ACS Physical Chemistry Au","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141770741","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Reactive CaCO3 Formation from CO2 and Methanolic Ca(OH)2 Dispersions: Transient Methoxide Salts, Carbonate Esters and Sol–Gels 二氧化碳和甲醇 Ca(OH)2 分散液反应生成 CaCO3:瞬时甲氧基盐、碳酸酯和溶胶
ACS Physical Chemistry Au Pub Date : 2024-07-23 DOI: 10.1021/acsphyschemau.4c00041
Thokozile A. Kathyola, Elizabeth A. Willneff, Colin J. Willis, Peter J. Dowding, Sven L. M. Schroeder
{"title":"Reactive CaCO3 Formation from CO2 and Methanolic Ca(OH)2 Dispersions: Transient Methoxide Salts, Carbonate Esters and Sol–Gels","authors":"Thokozile A. Kathyola, Elizabeth A. Willneff, Colin J. Willis, Peter J. Dowding, Sven L. M. Schroeder","doi":"10.1021/acsphyschemau.4c00041","DOIUrl":"https://doi.org/10.1021/acsphyschemau.4c00041","url":null,"abstract":"A combination of <i>ex situ</i> and <i>in situ</i> characterization techniques was used to determine the mechanism of calcium carbonate (CaCO<sub>3</sub>) formation from calcium hydroxide (Ca(OH)<sub>2</sub>) dispersions in methanol/water (CH<sub>3</sub>OH/H<sub>2</sub>O) systems. Mid-infrared (mid-IR) analysis shows that in the absence of carbon dioxide (CO<sub>2</sub>) Ca(OH)<sub>2</sub> establishes a reaction equilibrium with CH<sub>3</sub>OH, forming calcium hydroxide methoxide (Ca(OH)(OCH<sub>3</sub>)) and calcium methoxide (Ca(OCH<sub>3</sub>)<sub>2</sub>). Combined <i>ex situ</i> mid-IR, thermogravimetric analysis (TGA), X-ray diffraction (XRD), X-ray absorption spectroscopy and scanning electron microscopy examination of the reaction product formed in the presence of CO<sub>2</sub> reveals the formation of calcium dimethylcarbonate (Ca(OCOOCH<sub>3</sub>)<sub>2</sub>). This strongly suggests that carbonation takes place by reaction with the Ca(OCH<sub>3</sub>)<sub>2</sub> formed from a Ca(OH)<sub>2</sub> and CH<sub>3</sub>OH reaction. Time-resolved XRD indicates that in the presence of H<sub>2</sub>O the Ca(OCOOCH<sub>3</sub>)<sub>2</sub> ester releases CH<sub>3</sub>OH and CO<sub>2</sub>, forming ACC, which subsequently transforms into vaterite and then calcite. TGA reveals that thermal decomposition of Ca(OCOOCH<sub>3</sub>)<sub>2</sub> in the absence of H<sub>2</sub>O mainly leads to the reformation of Ca(OCH<sub>3</sub>)<sub>2</sub>, but this is accompanied by a significant parallel reaction that releases dimethylether (CH<sub>3</sub>OCH<sub>3</sub>) and CO<sub>2</sub>. CaCO<sub>3</sub> is the final product in both decomposition pathways. For CH<sub>3</sub>OH/H<sub>2</sub>O mixtures containing more than 50 mol % H<sub>2</sub>O, direct formation of calcite from Ca(OH)<sub>2</sub> becomes the dominant pathway, although the formation of some Ca(OCOOCH<sub>3</sub>)<sub>2</sub> was still evident in the <i>in situ</i> mid-IR spectra of 20 and 40 mol % CH<sub>3</sub>OH systems. In the presence of ≤20 mol % H<sub>2</sub>O, hydrolysis of the ester led to the formation of an ACC sol–gel. In both the 90 and 100 mol % CH<sub>3</sub>OH systems, diffusion-limited ACC → vaterite → calcite transformations were observed. Traces of aragonite were also detected. We believe that this is the first time that these reaction pathways during the carbonation of Ca(OH)<sub>2</sub> in a methanolic phase have been systematically and experimentally characterized.","PeriodicalId":29796,"journal":{"name":"ACS Physical Chemistry Au","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141770900","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Reactive CaCO3 Formation from CO2 and Methanolic Ca(OH)2 Dispersions: Transient Methoxide Salts, Carbonate Esters and Sol–Gels 二氧化碳和甲醇 Ca(OH)2 分散液反应生成 CaCO3:瞬时甲氧基盐、碳酸酯和溶胶
IF 3.7
ACS Physical Chemistry Au Pub Date : 2024-07-23 DOI: 10.1021/acsphyschemau.4c0004110.1021/acsphyschemau.4c00041
Thokozile A. Kathyola, Elizabeth A. Willneff, Colin J. Willis, Peter J. Dowding and Sven L. M. Schroeder*, 
{"title":"Reactive CaCO3 Formation from CO2 and Methanolic Ca(OH)2 Dispersions: Transient Methoxide Salts, Carbonate Esters and Sol–Gels","authors":"Thokozile A. Kathyola,&nbsp;Elizabeth A. Willneff,&nbsp;Colin J. Willis,&nbsp;Peter J. Dowding and Sven L. M. Schroeder*,&nbsp;","doi":"10.1021/acsphyschemau.4c0004110.1021/acsphyschemau.4c00041","DOIUrl":"https://doi.org/10.1021/acsphyschemau.4c00041https://doi.org/10.1021/acsphyschemau.4c00041","url":null,"abstract":"<p >A combination of <i>ex situ</i> and <i>in situ</i> characterization techniques was used to determine the mechanism of calcium carbonate (CaCO<sub>3</sub>) formation from calcium hydroxide (Ca(OH)<sub>2</sub>) dispersions in methanol/water (CH<sub>3</sub>OH/H<sub>2</sub>O) systems. Mid-infrared (mid-IR) analysis shows that in the absence of carbon dioxide (CO<sub>2</sub>) Ca(OH)<sub>2</sub> establishes a reaction equilibrium with CH<sub>3</sub>OH, forming calcium hydroxide methoxide (Ca(OH)(OCH<sub>3</sub>)) and calcium methoxide (Ca(OCH<sub>3</sub>)<sub>2</sub>). Combined <i>ex situ</i> mid-IR, thermogravimetric analysis (TGA), X-ray diffraction (XRD), X-ray absorption spectroscopy and scanning electron microscopy examination of the reaction product formed in the presence of CO<sub>2</sub> reveals the formation of calcium dimethylcarbonate (Ca(OCOOCH<sub>3</sub>)<sub>2</sub>). This strongly suggests that carbonation takes place by reaction with the Ca(OCH<sub>3</sub>)<sub>2</sub> formed from a Ca(OH)<sub>2</sub> and CH<sub>3</sub>OH reaction. Time-resolved XRD indicates that in the presence of H<sub>2</sub>O the Ca(OCOOCH<sub>3</sub>)<sub>2</sub> ester releases CH<sub>3</sub>OH and CO<sub>2</sub>, forming ACC, which subsequently transforms into vaterite and then calcite. TGA reveals that thermal decomposition of Ca(OCOOCH<sub>3</sub>)<sub>2</sub> in the absence of H<sub>2</sub>O mainly leads to the reformation of Ca(OCH<sub>3</sub>)<sub>2</sub>, but this is accompanied by a significant parallel reaction that releases dimethylether (CH<sub>3</sub>OCH<sub>3</sub>) and CO<sub>2</sub>. CaCO<sub>3</sub> is the final product in both decomposition pathways. For CH<sub>3</sub>OH/H<sub>2</sub>O mixtures containing more than 50 mol % H<sub>2</sub>O, direct formation of calcite from Ca(OH)<sub>2</sub> becomes the dominant pathway, although the formation of some Ca(OCOOCH<sub>3</sub>)<sub>2</sub> was still evident in the <i>in situ</i> mid-IR spectra of 20 and 40 mol % CH<sub>3</sub>OH systems. In the presence of ≤20 mol % H<sub>2</sub>O, hydrolysis of the ester led to the formation of an ACC sol–gel. In both the 90 and 100 mol % CH<sub>3</sub>OH systems, diffusion-limited ACC → vaterite → calcite transformations were observed. Traces of aragonite were also detected. We believe that this is the first time that these reaction pathways during the carbonation of Ca(OH)<sub>2</sub> in a methanolic phase have been systematically and experimentally characterized.</p>","PeriodicalId":29796,"journal":{"name":"ACS Physical Chemistry Au","volume":null,"pages":null},"PeriodicalIF":3.7,"publicationDate":"2024-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acsphyschemau.4c00041","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142318356","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
p-Sulfonatocalix[6]arene-Functionalized Gold Nanoparticles: Applications in Drug Delivery and Bioimaging 对磺酰羰基六[6]炔功能化金纳米粒子:在药物输送和生物成像中的应用
IF 3.7
ACS Physical Chemistry Au Pub Date : 2024-07-22 DOI: 10.1021/acsphyschemau.4c0002710.1021/acsphyschemau.4c00027
Suprotim Koley, Paacha Kandy Risla Sherin, Minati Nayak, Nilotpal Barooah, Achikanath C. Bhasikuttan* and Jyotirmayee Mohanty*, 
{"title":"p-Sulfonatocalix[6]arene-Functionalized Gold Nanoparticles: Applications in Drug Delivery and Bioimaging","authors":"Suprotim Koley,&nbsp;Paacha Kandy Risla Sherin,&nbsp;Minati Nayak,&nbsp;Nilotpal Barooah,&nbsp;Achikanath C. Bhasikuttan* and Jyotirmayee Mohanty*,&nbsp;","doi":"10.1021/acsphyschemau.4c0002710.1021/acsphyschemau.4c00027","DOIUrl":"https://doi.org/10.1021/acsphyschemau.4c00027https://doi.org/10.1021/acsphyschemau.4c00027","url":null,"abstract":"<p >Surface-functionalized noble metal nanoparticles with macrocyclic hosts have attracted enormous research interest owing to their applications in drug delivery, catalysis, bioimaging, etc. Stable <i>p</i>-sulfonatocalix[6]arene-functionalized gold nanoparticles (SCx6AuNPs) of the sizes ∼7.5 nm have been synthesized and characterized by using UV–vis absorption, transmission electron microscopy, and surface-enhanced Raman spectroscopy measurements. The efficient uptake and stimuli-responsive release of doxorubicin (Dox), an anticancer drug, by the SCx6AuNPs have been established for targeted drug delivery application. The decreased cytotoxicity of Dox loaded on SCx6AuNPs, especially toward normal cell lines, and its multistimuli responsive release validated in both cancerous (A549) and normal (W126) cell lines find promising for selectively targeted drug delivery applications toward cancer cells. At the cellular level, this study also establishes the efficient uptake of the SCx6AuNP nanoconjugates, and its validation has been done by bioimaging measurement by using thioflavin T (ThT) dye loaded on to SCx6AuNPs instead of Dox as the fluorescent tracking probe. The bright fluorescence microscopic image of ThT-SCx6AuNP-stained cancerous cell lines corroborates the uptake of SCx6AuNPs by the cell lines and its projected utility for drug delivery and bioimaging applications.</p>","PeriodicalId":29796,"journal":{"name":"ACS Physical Chemistry Au","volume":null,"pages":null},"PeriodicalIF":3.7,"publicationDate":"2024-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acsphyschemau.4c00027","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142318355","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
p-Sulfonatocalix[6]arene-Functionalized Gold Nanoparticles: Applications in Drug Delivery and Bioimaging 对磺酰羰基六[6]炔功能化金纳米粒子:在药物输送和生物成像中的应用
ACS Physical Chemistry Au Pub Date : 2024-07-22 DOI: 10.1021/acsphyschemau.4c00027
Suprotim Koley, Paacha Kandy Risla Sherin, Minati Nayak, Nilotpal Barooah, Achikanath C. Bhasikuttan, Jyotirmayee Mohanty
{"title":"p-Sulfonatocalix[6]arene-Functionalized Gold Nanoparticles: Applications in Drug Delivery and Bioimaging","authors":"Suprotim Koley, Paacha Kandy Risla Sherin, Minati Nayak, Nilotpal Barooah, Achikanath C. Bhasikuttan, Jyotirmayee Mohanty","doi":"10.1021/acsphyschemau.4c00027","DOIUrl":"https://doi.org/10.1021/acsphyschemau.4c00027","url":null,"abstract":"Surface-functionalized noble metal nanoparticles with macrocyclic hosts have attracted enormous research interest owing to their applications in drug delivery, catalysis, bioimaging, etc. Stable <i>p</i>-sulfonatocalix[6]arene-functionalized gold nanoparticles (SCx6AuNPs) of the sizes ∼7.5 nm have been synthesized and characterized by using UV–vis absorption, transmission electron microscopy, and surface-enhanced Raman spectroscopy measurements. The efficient uptake and stimuli-responsive release of doxorubicin (Dox), an anticancer drug, by the SCx6AuNPs have been established for targeted drug delivery application. The decreased cytotoxicity of Dox loaded on SCx6AuNPs, especially toward normal cell lines, and its multistimuli responsive release validated in both cancerous (A549) and normal (W126) cell lines find promising for selectively targeted drug delivery applications toward cancer cells. At the cellular level, this study also establishes the efficient uptake of the SCx6AuNP nanoconjugates, and its validation has been done by bioimaging measurement by using thioflavin T (ThT) dye loaded on to SCx6AuNPs instead of Dox as the fluorescent tracking probe. The bright fluorescence microscopic image of ThT-SCx6AuNP-stained cancerous cell lines corroborates the uptake of SCx6AuNPs by the cell lines and its projected utility for drug delivery and bioimaging applications.","PeriodicalId":29796,"journal":{"name":"ACS Physical Chemistry Au","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141754209","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Aggregation in Deep Eutectic Solvents (DESs): Formation of Polar DES-in-Nonpolar DES Microemulsions 深共晶溶剂 (DES) 中的聚合:极性 DES-非极性 DES 微乳液的形成
ACS Physical Chemistry Au Pub Date : 2024-07-18 DOI: 10.1021/acsphyschemau.4c00031
Anushis Patra, Anjali, Siddharth Pandey
{"title":"Aggregation in Deep Eutectic Solvents (DESs): Formation of Polar DES-in-Nonpolar DES Microemulsions","authors":"Anushis Patra, Anjali, Siddharth Pandey","doi":"10.1021/acsphyschemau.4c00031","DOIUrl":"https://doi.org/10.1021/acsphyschemau.4c00031","url":null,"abstract":"The versatility of environmentally benign and inexpensive deep eutectic solvents (DESs) lies in their widely varying physicochemical properties. Depending on its constituents, a DES may be highly polar or nonpolar in nature. This offers an enticing possibility of formation of novel nonaqueous microemulsions (MEs). Evidence of the presence of polar DES-in-nonpolar DES MEs is presented with reline (formed by mixing choline chloride and urea in 1 : 2 mol ratio) as the polar DES forming the ME pools, Thy : DA [formed by mixing thymol (Thy) and <i>n</i>-decanoic acid (DA) in 1 : 1 mol ratio] nonpolar DES as the bulk oil phase and nonionic surfactant Brij-35 as the emulsifying agent. While only sparingly miscible in Thy : DA, as high as 2.5 M reline can be solubilized in this DES in the presence of 100 mM Brij-35; reline loading (<i>w</i><sub>Rel</sub> = [reline]/[Brij-35]) as high as 25 can be achieved. The ternary phase diagram of the Thy : DA/Brij-35/reline system reveals a clear and transparent single-phase region where MEs may be forming. Dynamic light scattering confirms the presence of MEs of 2–10 nm size. Even as up to 2.5 M (ca. 0.35 mole fraction) reline, whose dynamic viscosity (η) and electrical conductivity (κ) are very high, is added to 100 mM Brij-35 solution of Thy : DA, the η and κ values of the solution increase insignificantly, thus conforming to the formation of MEs in the solution. Fourier transform infrared (FTIR) absorbance spectra and fluorescence probe responses further indicate that reline is not dispersed in the medium but rather forms polar pools of the MEs. These novel nonaqueous polar DES-in-nonpolar DES MEs will not only expand the application potential of DESs but also offer a new class of organized media with widespread potential.","PeriodicalId":29796,"journal":{"name":"ACS Physical Chemistry Au","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141737450","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Aggregation in Deep Eutectic Solvents (DESs): Formation of Polar DES-in-Nonpolar DES Microemulsions 深共晶溶剂 (DES) 中的聚合:极性 DES-非极性 DES 微乳液的形成
IF 3.7
ACS Physical Chemistry Au Pub Date : 2024-07-18 DOI: 10.1021/acsphyschemau.4c0003110.1021/acsphyschemau.4c00031
Anushis Patra,  Anjali and Siddharth Pandey*, 
{"title":"Aggregation in Deep Eutectic Solvents (DESs): Formation of Polar DES-in-Nonpolar DES Microemulsions","authors":"Anushis Patra,&nbsp; Anjali and Siddharth Pandey*,&nbsp;","doi":"10.1021/acsphyschemau.4c0003110.1021/acsphyschemau.4c00031","DOIUrl":"https://doi.org/10.1021/acsphyschemau.4c00031https://doi.org/10.1021/acsphyschemau.4c00031","url":null,"abstract":"<p >The versatility of environmentally benign and inexpensive deep eutectic solvents (DESs) lies in their widely varying physicochemical properties. Depending on its constituents, a DES may be highly polar or nonpolar in nature. This offers an enticing possibility of formation of novel nonaqueous microemulsions (MEs). Evidence of the presence of polar DES-in-nonpolar DES MEs is presented with reline (formed by mixing choline chloride and urea in 1 : 2 mol ratio) as the polar DES forming the ME pools, Thy : DA [formed by mixing thymol (Thy) and <i>n</i>-decanoic acid (DA) in 1 : 1 mol ratio] nonpolar DES as the bulk oil phase and nonionic surfactant Brij-35 as the emulsifying agent. While only sparingly miscible in Thy : DA, as high as 2.5 M reline can be solubilized in this DES in the presence of 100 mM Brij-35; reline loading (<i>w</i><sub>Rel</sub> = [reline]/[Brij-35]) as high as 25 can be achieved. The ternary phase diagram of the Thy : DA/Brij-35/reline system reveals a clear and transparent single-phase region where MEs may be forming. Dynamic light scattering confirms the presence of MEs of 2–10 nm size. Even as up to 2.5 M (ca. 0.35 mole fraction) reline, whose dynamic viscosity (η) and electrical conductivity (κ) are very high, is added to 100 mM Brij-35 solution of Thy : DA, the η and κ values of the solution increase insignificantly, thus conforming to the formation of MEs in the solution. Fourier transform infrared (FTIR) absorbance spectra and fluorescence probe responses further indicate that reline is not dispersed in the medium but rather forms polar pools of the MEs. These novel nonaqueous polar DES-in-nonpolar DES MEs will not only expand the application potential of DESs but also offer a new class of organized media with widespread potential.</p>","PeriodicalId":29796,"journal":{"name":"ACS Physical Chemistry Au","volume":null,"pages":null},"PeriodicalIF":3.7,"publicationDate":"2024-07-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.acs.org/doi/epdf/10.1021/acsphyschemau.4c00031","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142318345","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tailor-Made Design of Three-Dimensional Batteries Using a Simple, Accurate Geometry Optimization Scheme 利用简单精确的几何优化方案量身定制三维电池设计
IF 3.7
ACS Physical Chemistry Au Pub Date : 2024-07-15 DOI: 10.1021/acsphyschemau.4c00039
Kaito Miyamoto
{"title":"Tailor-Made Design of Three-Dimensional Batteries Using a Simple, Accurate Geometry Optimization Scheme","authors":"Kaito Miyamoto","doi":"10.1021/acsphyschemau.4c00039","DOIUrl":"https://doi.org/10.1021/acsphyschemau.4c00039","url":null,"abstract":"","PeriodicalId":29796,"journal":{"name":"ACS Physical Chemistry Au","volume":null,"pages":null},"PeriodicalIF":3.7,"publicationDate":"2024-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141644668","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Effect of Mixtures and Additives on Dissolving Surfactant Lamellar Phases 混合物和添加剂对溶解表面活性剂层状相的影响
IF 3.7
ACS Physical Chemistry Au Pub Date : 2024-07-15 DOI: 10.1021/acsphyschemau.4c00013
Mitha Aljabri, Thomas L Rodgers
{"title":"The Effect of Mixtures and Additives on Dissolving Surfactant Lamellar Phases","authors":"Mitha Aljabri, Thomas L Rodgers","doi":"10.1021/acsphyschemau.4c00013","DOIUrl":"https://doi.org/10.1021/acsphyschemau.4c00013","url":null,"abstract":"","PeriodicalId":29796,"journal":{"name":"ACS Physical Chemistry Au","volume":null,"pages":null},"PeriodicalIF":3.7,"publicationDate":"2024-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141644362","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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