Jue Wang , Wenfang Shi , Wenqi Zhang , Hanxuan Zeng , Jing Deng , Haojie Zhang
{"title":"Ultrafast degradation of Cu(II)-EDTA by peroxymonosulfate activated with polyoxometalate clusters intercalated layered double hydroxides: Simultaneous decomplexation and resourcelization","authors":"Jue Wang , Wenfang Shi , Wenqi Zhang , Hanxuan Zeng , Jing Deng , Haojie Zhang","doi":"10.1016/j.colsurfa.2024.135835","DOIUrl":"10.1016/j.colsurfa.2024.135835","url":null,"abstract":"<div><div>Technologies used to handle metal pollution are often ineffective for complexed metals, which have refractory biodegradability, high solubility, and strong mobility, posing significant threats to the ecological environment. This work proposed a novel catalytic system for the proper disposal of Cu(II)-EDTA pollution. Polyoxometalate cluster intercalated CaFe layered double hydroxide (LDH-CoPW) prepared through a mild and convenience method was applied to activate peroxymonosulfate (PMS) for the degradation of Cu(II)-EDTA and the simultaneous immobilization of the released Cu(II). Compared to direct waste or complex regeneration of catalysts, the application of used LDH-CoPW in clean energy production was proposed to further reduce carbon emissions. Under the combination of 0.1 g/L of LDH CoPW and 0.1 mM of PMS, nearly 100 % of Cu(II)-EDTA was removed within 3 min of reaction time, and 49.6 % of Cu(II) was adsorbed within 60 min of reaction time. The second-order reaction kinetic constants of Co(IV) = O with various probes were confirmed by competition kinetics method. Based on this, Co(IV) = O was identified as the dominant RSs using a scientific probe-based kinetic model. Furthermore, CaFe-LDH did not directly activate PMS but ensured the reactivity of the catalytic system by promoting the redox cycle of cobalt species. Finally, due to the regulation of Cu on the electronic structure of the catalyst, the electrochemical performance of the used LDH-CoPW surpassed that of fresh LDH-CoPW and CaFe-LDH, showing great potential in clean energy production.</div></div>","PeriodicalId":278,"journal":{"name":"Colloids and Surfaces A: Physicochemical and Engineering Aspects","volume":"707 ","pages":"Article 135835"},"PeriodicalIF":4.9,"publicationDate":"2024-11-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142720247","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Metallic bilayer Kagome borophene as a promising anode material for Li and post-Li ion batteries","authors":"Zishuang Cheng , Heyun Gao , Zai-Fu Jiang , Xiaoming Zhang , Guifeng Chen","doi":"10.1016/j.colsurfa.2024.135832","DOIUrl":"10.1016/j.colsurfa.2024.135832","url":null,"abstract":"<div><div>For future breakthroughs in alkali metal ion batteries, it is essential to explore new anode materials with high storage capacity. Recently, a novel two-dimensional material, bilayer Kagome borophene (BK-borophene), consisting of lightweight elemental boron and having excellent metal conductivity, has been proposed. Thus, the structure, stability, electronic and electrochemical properties of BK-borophene are investigated using first-principles calculations to examine its feasibility as an anode material. Our results show that a single Li/Na/K can stably adsorb on the BK-borophene surface with adsorption energy values of −0.46/-0.25/-0.69 eV. Besides, the low diffusion barrier values (0.55/0.30/0.15 eV) ensure that Li/Na/K can migrate rapidly on its surface, and the low open circuit voltage values are favorable for increasing the operating voltage of the assembled battery. Most importantly, BK-borophene shows high theoretical storage capacities of 826 mA h g<sup>−1</sup> for Li, 1377 mA h g<sup>−1</sup> for Na, and 275 mA h g<sup>−1</sup> for K, which is much more favorable than other reported anode materials. Not only that, BK-borophene also exhibits good cycling stability. The above-mentioned findings suggest that BK-borophene can be a promising and convincing anode material for alkali metal ion batteries.</div></div>","PeriodicalId":278,"journal":{"name":"Colloids and Surfaces A: Physicochemical and Engineering Aspects","volume":"707 ","pages":"Article 135832"},"PeriodicalIF":4.9,"publicationDate":"2024-11-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142719556","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xia Li , Jiayin Zhao , Di Mei , Jingan Li , Shuijing Yu , Fei Liang , Xinyuan Wang , Liguo Wang , Shijie Zhu , Shaokang Guan
{"title":"A ZnO and calcium phosphate co-deposited coating on magnesium alloy for better antibacterial property, cytocompatibility and corrosion resistance","authors":"Xia Li , Jiayin Zhao , Di Mei , Jingan Li , Shuijing Yu , Fei Liang , Xinyuan Wang , Liguo Wang , Shijie Zhu , Shaokang Guan","doi":"10.1016/j.colsurfa.2024.135834","DOIUrl":"10.1016/j.colsurfa.2024.135834","url":null,"abstract":"<div><div>The widespread applications of magnesium alloys in the biomedical field are hindered by their susceptibility to corrosion in physiological environments. This study aims to improve the antibacterial, bone growth promoting and corrosion resistance properties of magnesium alloys by depositing a ZnO nanoparticles and calcium phosphate (CaP) co-deposited coating (CaP@ZnO) on their surfaces via a step-by-step electrochemical approach. The coating was characterized for surface morphology, chemical composition, corrosion resistance, biocompatibility, and antibacterial properties. The results showed that the CaP@ZnO coating exhibited significant antibacterial performance, effectively inhibiting the growth of Staphylococcus aureus and Escherichia coli. Furthermore, the CaP@ZnO coating promoted the proliferation of osteoblasts, thereby facilitating new bone formation and regeneration. The coating also demonstrated excellent corrosion resistance, significantly delaying the corrosion rate of the magnesium alloy in pseudo-physiological environments. The proposed composite coating in this study is beneficial for promoting the practical application of magnesium alloys in the orthopedic field.</div></div>","PeriodicalId":278,"journal":{"name":"Colloids and Surfaces A: Physicochemical and Engineering Aspects","volume":"706 ","pages":"Article 135834"},"PeriodicalIF":4.9,"publicationDate":"2024-11-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142720804","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jiankun Li , Shang Wu , Jincai Yang , Shuo Tian , Xin Sun , Jiajia Wang , Lulu Han , Xia Wang , Shuhe Kang , Quanlu Yang
{"title":"The application of S, N co-doped biomass carbon-based FeCoNi bifunctional electrocatalysis in zinc-air battery","authors":"Jiankun Li , Shang Wu , Jincai Yang , Shuo Tian , Xin Sun , Jiajia Wang , Lulu Han , Xia Wang , Shuhe Kang , Quanlu Yang","doi":"10.1016/j.colsurfa.2024.135844","DOIUrl":"10.1016/j.colsurfa.2024.135844","url":null,"abstract":"<div><div>The development of efficient Oxygen reduction reaction (ORR) and oxygen evolution reaction (OER) bifunctional catalysts from biomass is of significant importance for the commercial application of zinc-air batteries (ZABs). Herein, a bifunctional catalyst (FeCoNi@SNC) is successfully synthesized through introducing Fe, Co and Ni atoms, fish scale-derived carbon (C<sub>FS</sub>) as the precursor, thiourea and dicyandiamide (DCDA) as the S and N sources, respectively. More importantly, FeCoNi@SNC is identified as a composite material containing FeCo, FeNi<sub>3</sub> and metal sulfides. A large number of fluffy carbon nanotubes are induced to grow on the C<sub>FS</sub> surface by metal nanoparticles, while M-N, M-O and M-S are formed. The catalytic performance is positively influenced by the unique morphology and different active sites of FeCoNi@SNC. To our delight, FeCoNi@SNC exhibits excellent catalytic activity in both ORR (E<sub>1/2</sub>=0.85 V) and OER (E<sub>j=10</sub>= 1.556 V). As a cathode in zinc-air batteries, FeCoNi@SNC possesses significant potential with a peak power density of 146.9 mW cm<sup>−2</sup>, a specific capacity of 706.9 mAh g<sup>−1</sup>, and an open circuit voltage of 1.525 V. A novel approach is provided by this work for designing biomass-derived ORR/OER bifunctional catalysts and their application in zinc-air batteries.</div></div>","PeriodicalId":278,"journal":{"name":"Colloids and Surfaces A: Physicochemical and Engineering Aspects","volume":"707 ","pages":"Article 135844"},"PeriodicalIF":4.9,"publicationDate":"2024-11-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142745025","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Weiqiang Han , Lan Yu , Fengyu Liu , Qi Zhang , Hongjuan Li , Yongqian Xu , Shiguo Sun
{"title":"Microneedle-mediated multifunctional nano-transdermal therapy system for in situ synergistic treatment of melanoma","authors":"Weiqiang Han , Lan Yu , Fengyu Liu , Qi Zhang , Hongjuan Li , Yongqian Xu , Shiguo Sun","doi":"10.1016/j.colsurfa.2024.135838","DOIUrl":"10.1016/j.colsurfa.2024.135838","url":null,"abstract":"<div><div>Traditional drug delivery methods and treatments often lack efficacy in eradicating melanoma and can cause significant toxicity to healthy tissues. Combining microneedle (MN)-based transdermal drug delivery (TDD) with in situ synergistic therapy is crucial for overcoming these challenges. Thus, a novel multifunctional nano-TDD system was developed by integrating polyvinyl alcohol (PVA) MN with hyaluronic acid (HA)-functionalized calcium peroxide/copper peroxide @ zeolitic imidazolate framework (CaO<sub>2</sub>/CuO<sub>2</sub>@ZIF-8) nanocapsule co-loaded with 1-methyltryptophan (1-MT) and disulfiram (DSF). Nanomedicines reach deeper skin layers via MNs and targeted to the melanoma site by HA. Subsequently, ZIF-8 protective layer releases 1-MT and DSF in response to the acidic tumor microenvironment. The exposed CaO<sub>2</sub>/CuO<sub>2</sub> nanoparticles decompose into Cu<sup>2+</sup>, Ca<sup>2+</sup> and hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>). Cu<sup>2+</sup> catalyzes the generation of hydroxyl radical (•OH) from H<sub>2</sub>O<sub>2</sub> to turn on chemodynamic therapy (CDT), and the efficiency of •OH generation can be further enhanced by depleting glutathione (GSH). Benefiting from the in-situ chelation reaction of DSF with Cu<sup>2+</sup>, CuET chemotherapy drugs with strong toxicity are generated. In addition, the produced Cu<sup>+</sup> can further enhance the efficacy of CDT. The massive influx of Ca<sup>2+</sup> exacerbates the damage to mitochondria. Ultimately, combining 1-MT to reverse the tumor's immunosuppressive microenvironment with chemotherapy and CDT-induced immunogenic cell death offers a promising and safe strategy for melanoma treatment.</div></div>","PeriodicalId":278,"journal":{"name":"Colloids and Surfaces A: Physicochemical and Engineering Aspects","volume":"707 ","pages":"Article 135838"},"PeriodicalIF":4.9,"publicationDate":"2024-11-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142745027","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Experimental and computational insights into the design of pH-responsive sodium alginate-coated nanoparticles for targeted mesalazine delivery","authors":"Roufaida Merir , Milad Baitiche , Ferhat Djerboua , Giuseppe Lazzara , Mokhtar Boutahala","doi":"10.1016/j.colsurfa.2024.135843","DOIUrl":"10.1016/j.colsurfa.2024.135843","url":null,"abstract":"<div><div>Halloysite-alginate beads loaded with mesalazine or 5-amino salicylic acid (5-ASA), a model anti-inflammatory drug, were investigated for their ability to protect the drug from acidic degradation during gastrointestinal transit. X-ray fluorescence (XRF) analysis confirmed the composition of the halloysite nanotubes, while zeta potential analysis corroborated their colloidal stability. Fourier transform infrared (FT-IR) spectroscopy, thermogravimetric analysis (TGA), and X-ray diffraction (XRD) investigations confirmed the effective production of the nanocomposite and provided insights into the interactions between its components and crystalline structure. The structure and homogeneous size distribution of the halloysite nanotubes (HNT) were examined using transmission electron microscopy (TEM). Additionally, scanning electron microscopy (SEM) images indicated a spherical shape and a relatively rough bead surface. Upon initial incubation in a simulated gastric medium (pH 1.2), the beads remained unchanged. In contrast, incubation in a simulated intestinal medium (pH 6.8) led to bead swelling, floating, and erosion. Furthermore, the formulation exhibited a smart, pH-sensitive release mechanism, achieving complete drug release over 750 minutes, highlighting its potential for sustained and targeted drug delivery. Release data for 5-ASA were well-fitted to the Korsmeyer-Peppas and Higuchi models, indicating distinct mechanisms governing the release from the composite material. Density functional theory (DFT) analyses revealed specific interactions between 5-ASA and halloysite, characterized by strong hydrogen bonding and Lewis acid-base interactions with aluminol sites, alongside reduced van der Waals forces in the hydrophobic siloxane regions.</div></div>","PeriodicalId":278,"journal":{"name":"Colloids and Surfaces A: Physicochemical and Engineering Aspects","volume":"707 ","pages":"Article 135843"},"PeriodicalIF":4.9,"publicationDate":"2024-11-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142745550","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sijun Xu , Huilong Jian , Yufeng Chen , Fang Gao , Xinchao Wang , Hongru Li
{"title":"Inspired corrosion resistance of copper mediated by multiple ethoxy units linker included indazole based bis-Schiff base dyes in NaCl solution","authors":"Sijun Xu , Huilong Jian , Yufeng Chen , Fang Gao , Xinchao Wang , Hongru Li","doi":"10.1016/j.colsurfa.2024.135842","DOIUrl":"10.1016/j.colsurfa.2024.135842","url":null,"abstract":"<div><div>In this study, hydrophilic multiple ethoxy units linkage chain included bis-Schiff base dyes (<strong>SBs 1–3</strong>) were designed and synthesized for strengthening corrosion resistance of copper in NaCl solution. The corrosion resistance and corrosion inhibition mechanism of the target dyes for copper were investigated in 3.0 wt% NaCl solution. The adsorption of these dyes on copper surface was revealed by Fourier transform infrared spectroscopy (FT-IR) and X-ray photoelectron spectroscopy (XPS) revealed the adsorption of these dyes containing C<img>N double bonds on copper surface, achieving excellent corrosion inhibition efficiency. The electrochemistry shows that the dyes were able to inhibit the corrosion of copper in sodium chloride solution, and the corrosion inhibition efficiency reached the peak value at a concentration of 1.00 mM. It is noted that the corrosion inhibition efficiency increased with the number increase of ethoxy units. The kinetic potential polarization curves indicate that the dyes were anodic corrosion inhibitors, which could inhibit the anodic reaction process of corrosion. The adsorption of corrosion inhibitor these dyes on copper surface followed Langmuir isothermal adsorption model.</div></div>","PeriodicalId":278,"journal":{"name":"Colloids and Surfaces A: Physicochemical and Engineering Aspects","volume":"707 ","pages":"Article 135842"},"PeriodicalIF":4.9,"publicationDate":"2024-11-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142745621","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Preparation of composite hydrogel with mechanical stability and temperature response for tea polyphenol release","authors":"Liya Fan, Xiaoxuan Xi, Xiaoyan Zhao, Xiao Zhu","doi":"10.1016/j.colsurfa.2024.135831","DOIUrl":"10.1016/j.colsurfa.2024.135831","url":null,"abstract":"<div><div>The method of adding additives at once not only increases costs, but also poses a risk of excessive consumption. Therefore, the slow-release technology was employed for improving the utilization efficiency and edible safety of additives in this work. The poly (N-isopropylacrylamide) (PNIPAM) and polylactic acid (PLA) composite hydrogels with sheath-core structure were fabricated by in-situ spinning method. The mechanical bearing capacity of PNIPAM hydrogel was improved by controlling the structure of PLA electrospun fiber membrane. The results showed that the compression resistance of the samples coated with PLA was increased 931 % at 50 % deformation. In addition, the surface wettability of samples was studied to ensure the stable water permeability. The composite hydrogel was used for the sustained release of tea polyphenol (TP) antioxidant. The release effect of TP at different temperatures, and radical scavenging effect of 2, 2′-azino-bis(3-ethylbenzothiazoline-6-sulfonic acid) (ABTS) and 2-Phenyl-4,4,5,5-tetraMethyliMidazoline-3-oxide-1-oxyl) (PTIO) were investigated. It was found that the release rate for TP could reach to 77.8 % at 30 °C. The radical clearance rates of ABTS and PTIO were 99.2 % and 46.6 %, respectively. This work provides effective ideas for the use of antioxidants in food preservation processes.</div></div>","PeriodicalId":278,"journal":{"name":"Colloids and Surfaces A: Physicochemical and Engineering Aspects","volume":"707 ","pages":"Article 135831"},"PeriodicalIF":4.9,"publicationDate":"2024-11-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142720241","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Leming Zhen , Zhaofu Meng , Qiyuan Qin , Wenhui Liu , Na Sun , Jingbing Xue , Jialong Lv
{"title":"Coadsorption behaviour and mechanism of TiO2 NPs and OTC on different size particle components of Lou soil","authors":"Leming Zhen , Zhaofu Meng , Qiyuan Qin , Wenhui Liu , Na Sun , Jingbing Xue , Jialong Lv","doi":"10.1016/j.colsurfa.2024.135841","DOIUrl":"10.1016/j.colsurfa.2024.135841","url":null,"abstract":"<div><div>The wide application of antibiotics and nanoparticles has made their coexistence in soil a new environmental problem, and the coexistence of multiple pollutants in soil may impact their environmental behaviour. In this study, by dividing soil into coarse particle (CP) and fine particle (FP) phases via differential centrifugation, oxytetracycline (OTC) and TiO<sub>2</sub> nanoparticles (NPs) were selected as two typical pollutants to study their coadsorption behaviour on Lou soil. The coadsorption mechanism of OTC and TiO<sub>2</sub> NPs on Lou soil was discussed through their morphology and characteristics by using SEM, XRD, BET specific surface, XPS and FT-IR analyses. The adsorption capacity of OTC on the FP phase was much greater than that on the CP phase. Hydrogen bonding and charge attraction are the main adsorption mechanisms of OTC on both the CP and FP phases. π-π interactions are another main adsorption mechanism of OTC sorption on the FP phase. Hydrogen bonding and charge attraction are the main mechanisms of TiO<sub>2</sub> NPs sorption on soil. OTC and TiO<sub>2</sub> NPs compete on the surface of soil particles through charge attraction and hydrogen bonding, thus inhibiting their adsorption.</div></div>","PeriodicalId":278,"journal":{"name":"Colloids and Surfaces A: Physicochemical and Engineering Aspects","volume":"707 ","pages":"Article 135841"},"PeriodicalIF":4.9,"publicationDate":"2024-11-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142720237","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jing Jing , Lina Ren , Xiguang Zhang , Yuxin Fu , Chijia Wang , Meiling Li , Huaiyuan Wang , Zhanjian Liu
{"title":"Robust waterborne superhydrophobic PAI/PTFE/GO@TP anion-release coating with anti-corrosion and anti-scaling performance","authors":"Jing Jing , Lina Ren , Xiguang Zhang , Yuxin Fu , Chijia Wang , Meiling Li , Huaiyuan Wang , Zhanjian Liu","doi":"10.1016/j.colsurfa.2024.135836","DOIUrl":"10.1016/j.colsurfa.2024.135836","url":null,"abstract":"<div><div>In oil well field production, fluids cause mechanical damage and chemical corrosion, increasing the demands on the adaptability and durability of superhydrophobic materials. For this purpose, a superhydrophobic/superoleophilic polyamideimide (PAI)/polytetrafluoroethylene (PTFE)/graphene oxide@tourmaline powder (GO@TP) anion-release coating was successfully developed using a combination of hydrothermal synthesis and spraying technology. The crosslinked network formed by the PAI and PTFE endowed the coating with exceptional mechanical durability and adhesion, maintaining a water contact angle of 151.5 ± 1.8° after enduring 800 wear cycles under 125 kPa of pressure. The homogeneous lamellar micro/-nanostructure provided a stable air barrier that shields the coating surface from contact with corrosive substances, ultimately enhancing its anti-corrosion performance. Following a 30-day soaking period, the coating demonstrated an impressive impedance modulus at low frequency, |Z|<sub>0.01 Hz</sub> value of 10<sup>11</sup> Ω cm<sup>2</sup>. The slow release of hydroxyl anions from the tourmaline powder electrically neutralized, cations in water to form soluble salts, preventing the nucleation of the scale. The oil layer on the PAI/PTFE/GO@TP coating surface synergistically reduced water scale adhesion, resulting in only 0.23 mg/cm<sup>2</sup> of scaling after 7 days. Moreover, the internal migration and surface arrangement of functional groups significantly improved the chemical stability and weather resistance of the coating. This study presented a feasible approach to expand the functional application of superhydrophobic coatings for anti-scaling and anti-corrosion.</div></div>","PeriodicalId":278,"journal":{"name":"Colloids and Surfaces A: Physicochemical and Engineering Aspects","volume":"707 ","pages":"Article 135836"},"PeriodicalIF":4.9,"publicationDate":"2024-11-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142745030","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}