Xin Zhao , Lin Wang , Qinfei Li , Heng Chen , Shuangrong Liu , Pengkun Hou , Jiayuan Ye , Yan Pei , Xu Wu , Jianfeng Yuan , Haozhong Gao , Bo Yang
{"title":"3D microstructural generation from 2D images of cement paste using generative adversarial networks","authors":"Xin Zhao , Lin Wang , Qinfei Li , Heng Chen , Shuangrong Liu , Pengkun Hou , Jiayuan Ye , Yan Pei , Xu Wu , Jianfeng Yuan , Haozhong Gao , Bo Yang","doi":"10.1016/j.cemconres.2024.107726","DOIUrl":"10.1016/j.cemconres.2024.107726","url":null,"abstract":"<div><div>Establishing a realistic three-dimensional (3D) microstructure is a crucial step for studying microstructure development of hardened cement pastes. However, acquiring 3D microstructural images for cement often involves high costs and quality compromises. This paper proposes a generative adversarial networks-based method for generating 3D microstructures from a single two-dimensional (2D) image, capable of producing high-quality and realistic 3D images at low cost. In the method, a framework (CEM3DMG) is designed to synthesize 3D images by learning microstructural information from a 2D cross-sectional image. Experimental results show that CEM3DMG can generate realistic 3D images of large size. Visual observation confirms that the generated 3D images exhibit similar microstructural features to the 2D images, including similar pore distribution and particle morphology. Furthermore, quantitative analysis reveals that reconstructed 3D microstructures closely match the real 2D microstructure in terms of gray level histogram, phase proportions, and pore size distribution.</div></div>","PeriodicalId":266,"journal":{"name":"Cement and Concrete Research","volume":"187 ","pages":"Article 107726"},"PeriodicalIF":10.9,"publicationDate":"2024-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142642665","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Unveiling the key factors for clinker reactivity and cement performance: A physic-chemical and performance investigation of 40 industrial clinkers","authors":"J.S. Andrade Neto , I.C. Carvalho , P.J.M. Monteiro , P.R. de Matos , A.P. Kirchheim","doi":"10.1016/j.cemconres.2024.107717","DOIUrl":"10.1016/j.cemconres.2024.107717","url":null,"abstract":"<div><div>This study assessed 40 industrial clinkers from 16 cement plants, determining their physical, chemical, and mineralogical properties and the corresponding cements' strength development and hydration kinetics. Pearson's statistical analysis identified key factors influencing clinker and cement properties. Clinker composition ranged within 56.5–73.9% C₃S, 4.1–24.5% C₂S, 0.8–8.4% C₃A, and 7.4–13.9% C₄AF. The sulfate-alkali ratio significantly impacted C₃A content and polymorphism. Alite crystal size was directly influenced by the CaO content and the sulfate-alkali ratio and inversely by the MgO, K₂O, and F<sup>−</sup> contents. Clinker grindability was directly affected by the C₃S crystal size and the sulfate-alkali ratio while inversely impacted by the MgO and K₂O contents. Key parameters for early cement hydration included fineness and K₂O content (positive) and C₃S crystal size (negative); larger C<sub>3</sub>S crystal size negatively affected cement early strength, while MnO<sub>2</sub> and K<sub>2</sub>O presence improved 1-day strength. For 28-day strength, increasing cement fineness and K<sub>2</sub>O content were detrimental.</div></div>","PeriodicalId":266,"journal":{"name":"Cement and Concrete Research","volume":"187 ","pages":"Article 107717"},"PeriodicalIF":10.9,"publicationDate":"2024-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142637244","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Zengliang Yue , Zixian Su , Partha P. Paul , Alastair T.M. Marsh , Alice Macente , Marco Di Michiel , John L. Provis , Philip J. Withers , Susan A. Bernal
{"title":"3D crystalline phase and pore structure evolution upon CO2 exposure in sodium sulfate-activated cement pastes","authors":"Zengliang Yue , Zixian Su , Partha P. Paul , Alastair T.M. Marsh , Alice Macente , Marco Di Michiel , John L. Provis , Philip J. Withers , Susan A. Bernal","doi":"10.1016/j.cemconres.2024.107716","DOIUrl":"10.1016/j.cemconres.2024.107716","url":null,"abstract":"<div><div>The effects of CO<sub>2</sub> exposure on sodium sulfate-activated blast furnace slag cement paste have been characterised by X-ray (attenuation) computed tomography revealing changes in micron-scale pore structure, and X-ray diffraction computed tomography (XRD-CT) elucidating changes in the spatial distribution of crystalline and semi-crystalline phases. Accelerated carbonation reduced ettringite volumes and induced formation of hydrotalcite, demonstrating the critical role of Mg-Al-SO<sub>4</sub>-layered double hydroxide phases in the CO<sub>2</sub> uptake of these cements. These changes yield a refinement of small pores and increase the overall porosity, reaching values comparable to those of blended Portland cements. Formation factor values were determined considering the pore solution electrical resistivity, calculated from thermodynamic modelling, and the porosity. A correlation between simulated tortuosity and porosity is proposed to estimate the diffusion tortuosity and formation factor of sodium sulfate-activated slag pastes. This approach represents a significant step forward for assessing carbonation resistance and CO<sub>2</sub> uptake capacity of cementitious pastes.</div></div>","PeriodicalId":266,"journal":{"name":"Cement and Concrete Research","volume":"187 ","pages":"Article 107716"},"PeriodicalIF":10.9,"publicationDate":"2024-11-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142596497","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nana Wen , Ziyou Yu , Vincent Hallet , Arne Peys , Dimitrios Sakellariou , Yiannis Pontikes
{"title":"Degradation of alkali-activated Fe-rich slag in acetic acid","authors":"Nana Wen , Ziyou Yu , Vincent Hallet , Arne Peys , Dimitrios Sakellariou , Yiannis Pontikes","doi":"10.1016/j.cemconres.2024.107715","DOIUrl":"10.1016/j.cemconres.2024.107715","url":null,"abstract":"<div><div>Alkali-activated Fe-rich non-ferrous metallurgical slags (AA-NFMS) emerge as a novel, sustainable cementitious binder, but durability performance is one of the crucial parameters to assess their success. This paper investigates the degradation mechanisms of AA-NFMS in 4 wt% acetic acid (AcH) solutions, commonly found in agricultural industries. The results indicated that upon AcH exposure, the amorphous structure of AA-NFMS is changed. This process is accompanied by the release of crucial elements, including Ca, Fe, and a smaller amount of Al and Si, resulting in the formation of a more polymerized network. Fe could precipitate near the formed cracks. EPMA and micro-CT revealed the important role of crack formation and the initial permeability of AA-NFMS on the degradation process. Additionally, strength change does not correlate with mass change but is closely related to the permeability. Notably, AA-NFMS with 10 wt% CaO demonstrates the highest strength after AcH exposure.</div></div>","PeriodicalId":266,"journal":{"name":"Cement and Concrete Research","volume":"187 ","pages":"Article 107715"},"PeriodicalIF":10.9,"publicationDate":"2024-11-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142596502","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Maximilian Löher , Neven Ukrainczyk , Andreas Bogner , Astrid Hirsch , Frank Dehn , Eduardus Koenders
{"title":"Reactive transport modeling of acetic acid-induced degradation in portland cement paste","authors":"Maximilian Löher , Neven Ukrainczyk , Andreas Bogner , Astrid Hirsch , Frank Dehn , Eduardus Koenders","doi":"10.1016/j.cemconres.2024.107704","DOIUrl":"10.1016/j.cemconres.2024.107704","url":null,"abstract":"<div><div>A reactive transport model was employed to investigate the influence of multiple hydrate phases during acetic acid attack on Portland cement paste. The simulation accounted for the dissolution of primary cement hydrates like Ettringite, Portlandite and C-S-H, along with the formation of silica gel products impacting diffusivity. The simulations primarily utilized independent material parameters, though the effective specific surface area of C-S-H phases required adjustment, indicating that only a small fraction is active in bulk paste compared to experimental values obtained from powders. Experiments involved exposing hardened cement paste samples to acetic acid (pH = 3) for durations ranging from 35 to 84 days. The model predicted changes in mineral assemblages, porosity, and pore solution chemistry versus degradation depth and time. Comparison of calculated Ca and Si-contents with experimentally obtained values from <span><math><mi>μ</mi></math></span>XRF analysis demonstrated good agreement of within 6% error, highlighting the importance of considering multiple minerals.</div></div>","PeriodicalId":266,"journal":{"name":"Cement and Concrete Research","volume":"187 ","pages":"Article 107704"},"PeriodicalIF":10.9,"publicationDate":"2024-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142596504","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"The Cement and Concrete Research Le Chatelier Awards","authors":"Robert J. Flatt","doi":"10.1016/j.cemconres.2024.107689","DOIUrl":"10.1016/j.cemconres.2024.107689","url":null,"abstract":"","PeriodicalId":266,"journal":{"name":"Cement and Concrete Research","volume":"186 ","pages":"Article 107689"},"PeriodicalIF":10.9,"publicationDate":"2024-10-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142415772","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Petra Engelmann, Anne Toussaint, Marylyn M Addo, Thomas Theo Brehm, Ansgar W Lohse, Angelika Weigel, Michelle Thompson, Bernd Löwe
{"title":"Predictors of somatic symptom burden in healthcare professionals during the COVID-19 pandemic: an 8-week follow-up study.","authors":"Petra Engelmann, Anne Toussaint, Marylyn M Addo, Thomas Theo Brehm, Ansgar W Lohse, Angelika Weigel, Michelle Thompson, Bernd Löwe","doi":"10.1080/09638237.2022.2069709","DOIUrl":"10.1080/09638237.2022.2069709","url":null,"abstract":"<p><strong>Background: </strong>Literature investigating the impact of COVID-19 on healthcare professionals barely addresses predictors of somatic symptom burden during the COVID-19 pandemic.</p><p><strong>Aims: </strong>As biopsychosocial models propose that not only the disease but also sociodemographic and psychosocial factors contribute to the development and maintenance of symptoms, this study investigates the predictive value of these factors for bothersome somatic symptoms in SARS-CoV-2 negative healthcare professionals.</p><p><strong>Methods: </strong>German healthcare professionals were assessed with self-rating questionnaires and underwent SARS-CoV-2 IgG antibody tests at baseline and 8 weeks later between April and August 2020. Differences in psychosocial variables between the time points were analyzed and regression analyses were performed to predict somatic symptoms at follow-up.</p><p><strong>Results: </strong>1185 seronegative healthcare professionals completed both assessments. Previous somatic symptom burden, higher levels of anxiety, being a nurse, younger age, higher psychological symptom burden, lower efficiency, and higher fatigability at baseline predicted somatic symptom burden at follow-up. Comparisons between baseline and follow-up showed a significant improvement in psychological impairment and deterioration of physical exhaustion.</p><p><strong>Conclusions: </strong>Our study applies a biopsychosocial perspective to bothersome somatic symptoms during the COVID-19 pandemic and contributes to the identification of potential risk factors as a starting point for future interventions that could support the handling of symptoms.</p>","PeriodicalId":266,"journal":{"name":"Cement and Concrete Research","volume":"55 ","pages":"1111-1121"},"PeriodicalIF":3.3,"publicationDate":"2023-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41273849","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Alexander German , Frank Winnefeld , Pietro Lura , Daniel Rentsch , Barbara Lothenbach
{"title":"Hydrous carbonate-containing brucite (HCB) in MgO/hydromagnesite blends","authors":"Alexander German , Frank Winnefeld , Pietro Lura , Daniel Rentsch , Barbara Lothenbach","doi":"10.1016/j.cemconres.2023.107304","DOIUrl":"10.1016/j.cemconres.2023.107304","url":null,"abstract":"<div><p>The hydration of reactive MgO in presence of hydromagnesite was investigated using analyses of the solid and the liquid phase. A brucite-like phase with low crystallinity was identified as hydration product. A partial destabilization of hydromagnesite was observed and it is suggested that the carbonate was taken up by the brucite-like phase. Furthermore, it was evidenced by thermogravimetry that this phase contained loosely bound “gel water”. Thus, a hypothetical <em>hydrous carbonate</em>-containing <em>brucite</em> (HCB) phase is proposed with a tentative composition MgCO<sub>3</sub>·35Mg(OH)<sub>2</sub>·H<sub>2</sub>O derived from mass balance calculations. Based on the solution chemistry and other considerations, its thermodynamic data were determined. Thermodynamic modeling of the hydrate assemblage of MgO/hydromagnesite blends confirmed the stability of HCB in the presence of hydromagnesite and brucite.</p></div>","PeriodicalId":266,"journal":{"name":"Cement and Concrete Research","volume":"173 ","pages":"Article 107304"},"PeriodicalIF":11.4,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0008884623002181/pdfft?md5=1582310352468aefdd44cbe6f6d36966&pid=1-s2.0-S0008884623002181-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43678379","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Martin Schneider, Volker Hoenig, Johannes Ruppert, Jörg Rickert
{"title":"The cement plant of tomorrow","authors":"Martin Schneider, Volker Hoenig, Johannes Ruppert, Jörg Rickert","doi":"10.1016/j.cemconres.2023.107290","DOIUrl":"10.1016/j.cemconres.2023.107290","url":null,"abstract":"<div><p><span>Cement plants of tomorrow will have to implement all CO</span><sub>2</sub><span><span> abatement and saving measures to the best extent possible. Reducing the clinker factor, optimising the reactivity of the clinker, substituting fossil fuels by alternative fuels<span> and using alternative raw materials are pathways which will still play a growing role in future cement production<span>. Digitalisation, artificial intelligence, and also new grinding setups will support the </span></span></span>manufacturing process.</span></p><p>Once all of these measures have been implemented, the remaining CO<sub>2</sub> will be captured at the clinker plant. Different capture technologies exist and are about to be further developed to a high degree of maturity. The most important policy ask aims at a respective infrastructure for the transport, storage and use of CO<sub>2</sub>.</p><p>Finally, the relevant markets for future cements need to be developed. This not only requires the respective standards to be amended, but also that procurement schemes are implemented.</p></div>","PeriodicalId":266,"journal":{"name":"Cement and Concrete Research","volume":"173 ","pages":"Article 107290"},"PeriodicalIF":11.4,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45551581","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Carlos Rodriguez-Navarro, Teodora Ilić, Encarnación Ruiz-Agudo, Kerstin Elert
{"title":"Carbonation mechanisms and kinetics of lime-based binders: An overview","authors":"Carlos Rodriguez-Navarro, Teodora Ilić, Encarnación Ruiz-Agudo, Kerstin Elert","doi":"10.1016/j.cemconres.2023.107301","DOIUrl":"10.1016/j.cemconres.2023.107301","url":null,"abstract":"<div><p>The reaction of slaked lime with atmospheric CO<sub>2</sub> in the presence of humidity leads to the formation of cementing carbonate phases in traditional aerial lime mortars and plasters. This carbonation reaction also affects the setting and degradation of hydraulic lime mortars and modern cement. Here, we present an overview of the existing knowledge on carbonation of lime-based binders, which are experiencing a revival as compatible material for the conservation of the built heritage and new sustainable construction. First, the carbonation reaction is defined and its importance in a range of technical and natural processes is outlined. This sets the ground for presenting a review of existing mechanistic models for the carbonation of lime-based materials, including the recent interface-coupled dissolution-precipitation model, and the understanding of carbonation in terms of non-classical crystallization theory. Kinetics models and experimental results for carbonation of lime-based binders (crystals and powder, as well as mortars/plasters) and its acceleration are presented and discussed. Finally, conclusions and future research directions are indicated.</p></div>","PeriodicalId":266,"journal":{"name":"Cement and Concrete Research","volume":"173 ","pages":"Article 107301"},"PeriodicalIF":11.4,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S0008884623002156/pdfft?md5=222e0966ea0483711640397fb5888002&pid=1-s2.0-S0008884623002156-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48665900","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}