ACS Sustainable Chemistry & Engineering最新文献_第4页

Greener Synthesis of the Polymer of Intrinsic Microporosity PIM-1 for Gas Separation

IF 8.4 1区化学

ACS Sustainable Chemistry & Engineering Pub Date : 2024-12-31 DOI: 10.1021/acssuschemeng.4c08475

Alisha Ayyaz, Andrew B. Foster, Levente Cseri, Gyorgy Szekely, Peter M. Budd

{"title":"Greener Synthesis of the Polymer of Intrinsic Microporosity PIM-1 for Gas Separation","authors":"Alisha Ayyaz, Andrew B. Foster, Levente Cseri, Gyorgy Szekely, Peter M. Budd","doi":"10.1021/acssuschemeng.4c08475","DOIUrl":"https://doi.org/10.1021/acssuschemeng.4c08475","url":null,"abstract":"Polymers of intrinsic microporosity (PIMs) are studied as membranes for energy-efficient and environmentally friendly separation technologies, but greener polymerization methods are desirable for further scale up. This work aimed to synthesize the prototypical PIM (PIM-1) via a greener synthetic route by changing the solvent system to methyl-5-(dimethylamino)-2,2-dimethyl-5-oxopentanoate (MDDOP), a structural analogue of the green solvent Rhodiasolv PolarClean. Mass-based green metrics analysis was performed on MDDOP, determining atom economy, complete environmental factor, and total carbon intensity, comparing each to synthetic routes to PolarClean. Green metrics analysis found MDDOP synthesis produced less waste than PolarClean. MDDOP solvent capabilities were exemplified via PIM-1 polymerizations using 5,5′,6,6′-tetrahydroxy-3,3,3′,3′-tetramethyl-1,1′-spirobisindane (TTSBI) with either tetrafluoroterephthalonitrile (TFTPN) or tetrachloroterephthalonitrile (TCTPN), varying the temperature (120–160 °C) and reaction duration (50 min–6 h). Recovery of methanol and MDDOP post PIM-1 synthesis reduced solvent waste by 22%. Reactions using TCTPN produced polymers with higher molar masses than those produced using TFTPN. All samples showed varied topology, with evidence of branching and colloidal network. The polymer from the most successful reaction conditions (TCTPN, T = 140 °C, 6 h) was fabricated into thick film membranes and tested with pure gases for CO2/CH4 and CO2/N2 gas pairs, performing comparably with PIM-1 synthesized using conventional solvent systems.","PeriodicalId":25,"journal":{"name":"ACS Sustainable Chemistry & Engineering","volume":"71 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2024-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142908289","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Production of Succinic Acid Directly from Tartaric Acid by Iodine-Mediated Transfer Hydrogenation

IF 8.4 1区化学

ACS Sustainable Chemistry & Engineering Pub Date : 2024-12-31 DOI: 10.1021/acssuschemeng.4c06345

Xinge Miao, Pengxin Yu, Mingzhi Du, Yongsheng Yuan, Jianyu Han, Jingen Long, Lingzhao Kong, Junju Mu, Weiran Yang

引用次数: 0

Preparation of Defective Niobium-Based Catalysts to Address the “Seesaw Effect” in Phenol Hydrodeoxygenation

IF 8.4 1区化学

ACS Sustainable Chemistry & Engineering Pub Date : 2024-12-31 DOI: 10.1021/acssuschemeng.4c06155

Shilong Liu, Gege Pan, MiaoMiao Wei, Baoyan Zhi, Yanchang Zhang, Chengjun Hu, Hao Li

{"title":"Preparation of Defective Niobium-Based Catalysts to Address the “Seesaw Effect” in Phenol Hydrodeoxygenation","authors":"Shilong Liu, Gege Pan, MiaoMiao Wei, Baoyan Zhi, Yanchang Zhang, Chengjun Hu, Hao Li","doi":"10.1021/acssuschemeng.4c06155","DOIUrl":"https://doi.org/10.1021/acssuschemeng.4c06155","url":null,"abstract":"Cyclohexanone, a product of phenol hydrogenation, is a very reactive intermediate, which can easily generate byproducts such as cyclohexanol and cyclohexane, and there is a difficult-to-regulate “seesaw effect”. In this paper, a defective catalyst, Pd/Nb2O5-800-AP, was synthesized by the hydrothermal method at 170 °C and 1 MPa H2, aiming to break the difficult equilibrium between the high conversion of phenol and the high selectivity of cyclohexanone, which has a good industrial prospect. By changing the calcination temperature of the carrier to control the surface defect content, Pd was placed in an electron-rich state, which promoted the activation of hydrogen molecules and adsorption of phenol in a “nonplanar” manner, which was favorable for the generation of cyclohexanone as a product. In addition, the formation of electron-deficient oxygen defects and low-valent Nb4+ on the surface of the AP-treated catalysts promoted the adsorption and activation of oxygen-containing functional groups, which enhanced the activity of the phenol HDO reaction.","PeriodicalId":25,"journal":{"name":"ACS Sustainable Chemistry & Engineering","volume":"4 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2024-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142908287","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Spontaneous Catalytic Paal–Knorr Reactions for N-Substituted Pyrrole Synthesis by Microdroplet Chemistry

IF 8.4 1区化学

ACS Sustainable Chemistry & Engineering Pub Date : 2024-12-31 DOI: 10.1021/acssuschemeng.4c08638

Jiayao Li, Jiannan Sun, Yizhou Wang, Jinhua Liu, Heyong Cheng

{"title":"Spontaneous Catalytic Paal–Knorr Reactions for N-Substituted Pyrrole Synthesis by Microdroplet Chemistry","authors":"Jiayao Li, Jiannan Sun, Yizhou Wang, Jinhua Liu, Heyong Cheng","doi":"10.1021/acssuschemeng.4c08638","DOIUrl":"https://doi.org/10.1021/acssuschemeng.4c08638","url":null,"abstract":"It is well recognized in recent studies that water molecules at the gas–liquid interface of microdroplets spontaneously dissociate into hydronium and hydroxide and form superacids/superbases and reactive species (hydrated electrons, hydroxide radicals, hydrogen peroxide, water radical cations/anions, etc.) due to the 109 V m–1 electric field. In contrast to extensive interest in spontaneous redox reactions by the reactive species in microdroplet studies, limited attention has been attracted by gram-scale organic synthesis catalyzed by the spontaneously formed superacids/superbases. This study demonstrates spontaneous organic catalysis of the superacids for Paal–Knorr reactions, one of the most classic pathways to construct N-substituted pyrroles with biologically and pharmaceutically important roles. Paal–Knorr reactions can proceed well with no external catalysts in isopropanol microdroplets within 10 min at room temperature. Sixteen N-substituted pyrroles were synthesized using the microdroplet method with 83–99% yields, several orders of magnitude reaction acceleration (a typical rate acceleration factor of 1.18 × 103 based on the ratio of the rate constants), and a scale-up rate of 5.50 g h–1. By avoiding external catalysts, thermal irradiation, long reaction times, and problematic solvents required by conventional Paal–Knorr methods, the microdroplet method was a green, efficient, and attractive alternative for the construction of pyrroles and their derivatives.","PeriodicalId":25,"journal":{"name":"ACS Sustainable Chemistry & Engineering","volume":"26 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2024-12-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142908290","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Lignin Quaternary Ammonium Phosphotungstate as a Recycle Catalyst for Oxidative Cleavage of Unsaturated Fatty Acids and Soybean Oil

IF 8.4 1区化学

ACS Sustainable Chemistry & Engineering Pub Date : 2024-12-30 DOI: 10.1021/acssuschemeng.4c05655

Bo Li, Xiao Yu, Zhongjian Tian, Yuqin Jiang, Tengfei Niu

{"title":"Lignin Quaternary Ammonium Phosphotungstate as a Recycle Catalyst for Oxidative Cleavage of Unsaturated Fatty Acids and Soybean Oil","authors":"Bo Li, Xiao Yu, Zhongjian Tian, Yuqin Jiang, Tengfei Niu","doi":"10.1021/acssuschemeng.4c05655","DOIUrl":"https://doi.org/10.1021/acssuschemeng.4c05655","url":null,"abstract":"Using H2O2 for oxidative cleavage of renewable unsaturated fatty acids (UFA) or plant oil is a green method for preparing biobased mono- and dicarboxylic acids. However, due to the insolubility of UFA or oil in water, organic solvents or unrecyclable surfactants are usually needed to promote the contact between substrates and H2O2, which does not meet the Sustainable Development Goals. In this work, a series of lignin quaternary ammonium-supported phosphotungstate catalysts has been designed and prepared. Among these catalysts, HPW-AL6500-QAS16 showed the best catalytic activity for the oxidative cleavage of oleic acid (OA) and soybean oil (SBO) using H2O2 as the oxidant without a solvent and additive. This lignin-based catalyst afforded 100% OA and SBO conversion and up to 96.2% azelaic acid (AA), 94.6% nonanoic acid (NA) selectivities for OA and 91.8% AA, and 85.2% NA selectivities for SBO. More importantly, the lignin-based catalyst could be easily recovered and reused at least 5 times without a significant loss in its catalytic activity. These characteristics make the oxidative cleavage of OA and SBO more efficient and environmentally friendly, which may be beneficial for industry applications.","PeriodicalId":25,"journal":{"name":"ACS Sustainable Chemistry & Engineering","volume":"77 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2024-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142905348","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Supporting Porous Metal–Organic Frameworks on Carboxylated-Wood Sponges for Direct Air Capture and Highly Selective CO2/CH4 Separation

IF 8.4 1区化学

ACS Sustainable Chemistry & Engineering Pub Date : 2024-12-30 DOI: 10.1021/acssuschemeng.4c05232

Xupeng Zhang, Kaiqian Li, Longxin Guo, Zhiping Xu, Shuduan Deng, Ying Liu, Gang Zhu

{"title":"Supporting Porous Metal–Organic Frameworks on Carboxylated-Wood Sponges for Direct Air Capture and Highly Selective CO2/CH4 Separation","authors":"Xupeng Zhang, Kaiqian Li, Longxin Guo, Zhiping Xu, Shuduan Deng, Ying Liu, Gang Zhu","doi":"10.1021/acssuschemeng.4c05232","DOIUrl":"https://doi.org/10.1021/acssuschemeng.4c05232","url":null,"abstract":"To effectively mitigate the global warming problem caused by excessive CO2 emissions, the implementation of direct air capture (DAC) technology has emerged as one of the most promising strategies for capturing CO2 from the atmosphere. The key to DAC technology hinges on the development of high-performance solid sorbent materials that demonstrate high CO2 adsorption capacity and gas separation selectivity, particularly under low CO2 partial pressure conditions. Herein, we have successfully developed a class of MOF@carboxylated wood sponge (MOF@CWS) hybrid sorbents, capable of efficient CO2 capture from low-concentration (less than 10,000 ppm) CO2 sources, achieved by embedding the porous MOF into carboxylated wood sponges (CWS) substrate via an in situ growth route. Within the MOF@CWS series, the CO2 uptake capacity of Mg-MOF-74@CWS is 3.61 and 2.65 mmol/g at 1 bar, 273 and 298 K, respectively, significantly higher than those of CWS and HKUST-1@CWS. Moreover, this material exhibited outstanding DAC performance, with the CO2 sorption capacity at 273 K up to 0.56 mmol/g from ambient air (ca. 400 ppm of CO2), surpassing most other solid sorbents. The obtained Mg-MOF-74@CWS also demonstrated exceptional CO2/CH4 separation performance, primarily due to the unique pore structure and augmented interaction between the CO2 molecules and the hybrid sorbents. The results of this study indicate that Mg-MOF-74@CWS has potential as an efficient solid sorbent for the DAC of CO2.","PeriodicalId":25,"journal":{"name":"ACS Sustainable Chemistry & Engineering","volume":"344 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2024-12-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142905347","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Enhancing Oxygen Reduction Reaction Performance Through Abundant Single Fe Atoms for Advanced Zinc–Air Batteries

IF 8.4 1区化学

ACS Sustainable Chemistry & Engineering Pub Date : 2024-12-26 DOI: 10.1021/acssuschemeng.4c07276

Zirui Wu, Tieyu Hu, Zihui Fan, Yongying Wang, Yi Li, Juan Yang

{"title":"Enhancing Oxygen Reduction Reaction Performance Through Abundant Single Fe Atoms for Advanced Zinc–Air Batteries","authors":"Zirui Wu, Tieyu Hu, Zihui Fan, Yongying Wang, Yi Li, Juan Yang","doi":"10.1021/acssuschemeng.4c07276","DOIUrl":"https://doi.org/10.1021/acssuschemeng.4c07276","url":null,"abstract":"Iron- and nitrogen-codoped carbon (Fe–N–C) catalysts with Fe–N4 active sites offer a promising alternative to noble metal-based materials for the oxygen reduction reaction (ORR), which is essential for energy storage and conversion in applications such as fuel cells and metal–air batteries. This study presents a straightforward and scalable method to synthesize an efficient ORR electrocatalyst that consists of nitrogen-doped carbon and a high density of atomically dispersed single iron atoms, created through the pyrolysis of Fe-zeolitic imidazolate framework (Fe-ZIF-8) precursors. The Fe-ZIF-8 framework effectively restricts the migration and agglomeration of iron species, resulting in obtained Fe–N–C with conductive, mesoporous carbon structures and abundant Fe–N4 sites. This structure provides excellent electrocatalytic activity for the ORR, demonstrated by a positive onset potential of 0.985 V vs RHE and a half-wave potential of 0.905 V vs the reversible hydrogen electrode (RHE) in alkaline media, outperforming commercial Pt/C. Additionally, when used as the cathode in a zinc–air battery, the Fe–N–C catalyst delivers high maximum power densities of 170.1 mW cm–2, showcasing its potential for practical energy storage applications.","PeriodicalId":25,"journal":{"name":"ACS Sustainable Chemistry & Engineering","volume":"80 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2024-12-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142886781","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Scalable Preparation and Precise Control of Carbon Materials via Molten Salt Liquid Seal Strategy in Air

IF 8.4 1区化学

ACS Sustainable Chemistry & Engineering Pub Date : 2024-12-25 DOI: 10.1021/acssuschemeng.4c08670

Ming Liu, Huimin Li, Bin Zhang, Yanzi Lei, Luyao Luo, Hai Wang

{"title":"Scalable Preparation and Precise Control of Carbon Materials via Molten Salt Liquid Seal Strategy in Air","authors":"Ming Liu, Huimin Li, Bin Zhang, Yanzi Lei, Luyao Luo, Hai Wang","doi":"10.1021/acssuschemeng.4c08670","DOIUrl":"https://doi.org/10.1021/acssuschemeng.4c08670","url":null,"abstract":"Revealing the relations between the physical and chemical properties of carbon materials with defined composition and structure is an important topic. However, traditional organic carbon precursor-derived carbon materials lack effective fine-tuning methods due to the uncontrollable temperature changes. Herein, a novel strategy termed a “molten salt liquid seal” is introduced to address this issue. Impressively, the uppermost KBr layer in the provided configuration effectively contains the release of carbon organic precursor at low temperatures and forms a protective barrier at high temperatures, thereby inhibiting the oxidation of carbon materials in air. Furthermore, we propose a corresponding “liquid seal” mechanism by monitoring the temperature-dependent morphological evolution of molten salts and carbon materials. Remarkably, the heteroatoms, defects, etc., in the carbon material can be precisely controlled within the range of 100 °C and 0.5 h per interval. Moreover, the carbonization yield is close to or even higher than that of the conventional process under an Ar atmosphere. We also validate the advantages of the resultant carbon materials as anodes in sodium-ion batteries. This innovative approach not only minimizes the reliance of inert atmospheres but also enables the high-yield fabrication of carbon materials in air, significantly advancing the field toward more sustainable practices.","PeriodicalId":25,"journal":{"name":"ACS Sustainable Chemistry & Engineering","volume":"65 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2024-12-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142886782","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Oil-Based Fast Ultralow Friction Achieved by Semisolid Lubricant Domained by Poly-α-Olefins-Subnanowire–Stearic Acid at Steel/PTFE Interface

IF 8.4 1区化学

ACS Sustainable Chemistry & Engineering Pub Date : 2024-12-24 DOI: 10.1021/acssuschemeng.4c08069

Runhao Zheng, Liqiang Zhang, Liucheng Wang, Changhe Du, Kunpeng Li, Shoukui Gao, Linxu Fang, Qiang Wang, Daoai Wang

{"title":"Oil-Based Fast Ultralow Friction Achieved by Semisolid Lubricant Domained by Poly-α-Olefins-Subnanowire–Stearic Acid at Steel/PTFE Interface","authors":"Runhao Zheng, Liqiang Zhang, Liucheng Wang, Changhe Du, Kunpeng Li, Shoukui Gao, Linxu Fang, Qiang Wang, Daoai Wang","doi":"10.1021/acssuschemeng.4c08069","DOIUrl":"https://doi.org/10.1021/acssuschemeng.4c08069","url":null,"abstract":"Liquid lubricants can reduce the friction and wear of two relative moving surfaces. However, there are still great challenges to achieve anticreep and superlubricity of liquid lubricants at the same time. In this study, a novel semisolid lubricant (P30SSA) was designed by fixing poly-α-olefins 30 (PAO30) base oil in a three-dimensional network structure constructed by subnanowires (SNW) and stearic acid (SA), avoiding the creep problem of base oil and achieving ultralow friction (0.006–0009) at steel/polytetrafluoroethylene (PTFE) interfaces in a short period (∼6 s). Compared with dry friction, the wear rate of the PTFE was reduced by 98%. Moreover, the friction coefficient remains below 0.01 after more than 150,000 cycles. The ultralow friction behavior is attributed to the increasing bearing ability caused by the three-dimensional network structure in P30SSA, the reduced internal friction of P30SSA generated by the shear thinning of the lubricant during the friction process, and the physisorption film formed on the surface of friction pairs. The P30SSA solves the problem of liquid lubricant creeping and achieves ultralow friction on the surface of steel/PTFE. This work opens up a new direction for semisolid lubricants and provides a new idea for the study of the ultralow friction mechanism.","PeriodicalId":25,"journal":{"name":"ACS Sustainable Chemistry & Engineering","volume":"25 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2024-12-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142880255","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Ecofriendly Reductive Amination of a Levulinic Acid Platform Molecule for the Synthesis of 5-Methyl-N-Aryl-Pyrrolidones Exploiting Formic Acid as an LOHC

IF 8.4 1区化学

ACS Sustainable Chemistry & Engineering Pub Date : 2024-12-23 DOI: 10.1021/acssuschemeng.4c08368

Parvin Holakooei, Federica Valentini, Luigi Vaccaro

{"title":"Ecofriendly Reductive Amination of a Levulinic Acid Platform Molecule for the Synthesis of 5-Methyl-N-Aryl-Pyrrolidones Exploiting Formic Acid as an LOHC","authors":"Parvin Holakooei, Federica Valentini, Luigi Vaccaro","doi":"10.1021/acssuschemeng.4c08368","DOIUrl":"https://doi.org/10.1021/acssuschemeng.4c08368","url":null,"abstract":"The unsustainable exploitation of fossil feedstocks for energy and chemical production has led, in the past few years, to the modern energy and environmental crisis, thus stimulating increased awareness in the definition of more sustainable alternatives. Among the transformations of biomass-derived levulinic acid, recognized as one of the top 10 platform molecules, the production of 5-methylpyrrolidinones is of great importance in diverse industrial fields. In this work, we defined a waste-minimized protocol for the production of N-aryl 5-methylpyrrolidinones, aiming both at the synergistic employment of a benign H-source and reaction media and at the optimization of the workup and purification step. The choice of formic acid as the hydrogen carrier and water as the solvent was beneficial for the replacement of gaseous hydrogen typically used in the synthesis of N-aryl 5-methylpyrrolidinones. Moreover, the safety and economic advantages of formic acid as a benign LOHC for this transformation were further confirmed by a comparison, with other H-sources, of the Ecoscale penalty points. The optimized extraction workup protocol allowed an E-factor reduction of 63% compared to a simple filtration for purification method. To further evidence the environmental improvement, Ecoscale was exploited, highlighting the benefits of our process in comparison to available literature protocols.","PeriodicalId":25,"journal":{"name":"ACS Sustainable Chemistry & Engineering","volume":"28 1","pages":""},"PeriodicalIF":8.4,"publicationDate":"2024-12-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142880252","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0