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Front Cover: (Z. Anorg. Allg. Chem. 13‐14/2024) 封面： (Z. Anorg. Allg. Chem. 13-14/2024)
Zeitschrift für anorganische und allgemeine Chemie Pub Date : 2024-07-25 DOI: 10.1002/zaac.202481301
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引用次数: 0
White‐Light‐Emitting Ln‐MOF as Luminescent Probe for Selective Detection of Nitroaromatic Compounds 白光发光 Ln-MOF 作为选择性检测硝基芳香族化合物的发光探针
Zeitschrift für anorganische und allgemeine Chemie Pub Date : 2024-07-24 DOI: 10.1002/zaac.202400084
Yihui Wang, Xitong Xiao, Jiayi Liu, Zhenghong Dong, Fengqin Wang, Xiaoqing Wang
{"title":"White‐Light‐Emitting Ln‐MOF as Luminescent Probe for Selective Detection of Nitroaromatic Compounds","authors":"Yihui Wang, Xitong Xiao, Jiayi Liu, Zhenghong Dong, Fengqin Wang, Xiaoqing Wang","doi":"10.1002/zaac.202400084","DOIUrl":"https://doi.org/10.1002/zaac.202400084","url":null,"abstract":"Metal‐organic frameworks (MOFs) as an efficient and convenient sensing material for environmental pollutants have attracted widespread attention in recent years. Here in, we synthesized a series of lanthanide co‐doping MOFs, EuxTb1‐x‐MOFs (x=0, 0.005, 0.00667, 0.01, 0.02 and 1) under solvothermal conditions. The luminescence colors can be adjusted by changing metal molar mass ratios and altering excitation wavelength. Fortunately, a near white‐light‐emitting material Eu0.01Tb0.99‐MOF was obtained under the excitation at 350 nm, whose CIE coordinates of (0.3444, 0.3409) are very close to standard white light coordinates (0.3333, 0.3333). We further studied the fluorescence sensing performances of Eu‐MOF, Tb‐MOF and Eu0.01Tb0.99‐MOF towards NACs. The results indicate that all MOFs can selectively detect 4‐nitroaniline, 4‐nitrophenol and 2‐nitrophenol with good sensitivity and recyclability.","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"129 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141773031","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structural Studies of Piperidino‐Alanes with Halide, Amide and Hydride as further Ligands at Aluminum 以卤化物、酰胺和氢化物作为铝的进一步配体的哌啶烷结构研究
Zeitschrift für anorganische und allgemeine Chemie Pub Date : 2024-07-22 DOI: 10.1002/zaac.202400090
Michael Veith, Tatjana Kirs, Bernd Morgenstern, Volker Huch
{"title":"Structural Studies of Piperidino‐Alanes with Halide, Amide and Hydride as further Ligands at Aluminum","authors":"Michael Veith, Tatjana Kirs, Bernd Morgenstern, Volker Huch","doi":"10.1002/zaac.202400090","DOIUrl":"https://doi.org/10.1002/zaac.202400090","url":null,"abstract":"Nine different derivatives of piperidino alanes of the general formula (CH2)5N‐AlXY [X=Y= Cl (1), Br (2), I (3); X= (CH2)5N, Y= Cl (4), Br (5), I (6); X=H, Y= Cl (7), Br (8), I (9)] have been synthesized and compared with respect to their structures. All molecules form dimers with an Al2N2 central cycle and aluminum and nitrogen atoms in distorted tetrahedral environments as determined from X‐ray diffraction. The three dihalide derivatives 1, 2 and 3 have C2h (2/m) symmetries in solution of which they maintain the Centro symmetry in the crystal lattice. The bis(piperidino) derivatives 4, 5 and 6 have either C1 (1) symmetry with the bridging piperidino cycles oriented in the same direction (4, 5) or Ci (ī) point symmetry as found for 6 (in solution at least one other isomer is present). Whereas the chlorine derivative 7 has crystallographic Ci (ī) symmetry, the bromine 8 has almost C2 and the iodine 9 crystallographic C2 (2) point symmetry. In solution all derivatives 7, 8, 9 show equilibria between cis (C2) and trans (Ci) isomeric forms (27Al NMR). The longest Al‐N bond lengths within the rings are found for 5 (1.969(4) Å) and the shortest for 8 (1.940(4) Å).","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"60 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141773033","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Polyene and Arene [4 + 1] Cycloaddition at a Seven‐Membered Cyclic Alumanyl 多烯和烯烃在七元环丙氨酰的 [4 + 1] 环加成反应
Zeitschrift für anorganische und allgemeine Chemie Pub Date : 2024-07-22 DOI: 10.1002/zaac.202400125
Michael Stephen Hill, Han-Ying Liu, Mary F. Mahon
{"title":"Polyene and Arene [4 + 1] Cycloaddition at a Seven‐Membered Cyclic Alumanyl","authors":"Michael Stephen Hill, Han-Ying Liu, Mary F. Mahon","doi":"10.1002/zaac.202400125","DOIUrl":"https://doi.org/10.1002/zaac.202400125","url":null,"abstract":"The reactivity of [{SiNDipp}AlK]2, which comprises a formally anionic Al(I) centre, has been examined towards a variety of 1,3‐dienic molecules, including 2,3‐dimethylbutadiene, cyclooctatetraene, anthracene and tetracene. In each case, the alumanyl derivative experiences oxidative addition across the Al(I) centre to provide the corresponding potassium aluminacyclopentene, aluminacyclopropene or aluminanorbornadiene products of [4 + 1] cycloaddition.","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"14 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141773027","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and Characterization of Alkali Metal Hypersilyl Borates 碱金属超硅硼酸盐的合成与表征
Zeitschrift für anorganische und allgemeine Chemie Pub Date : 2024-07-22 DOI: 10.1002/zaac.202400054
Thomas Lainer, Christoph Walkner, Nina M. Tasch, Roland C. Fischer, Ana Torvisco, Harald Stueger, Michael Haas
{"title":"Synthesis and Characterization of Alkali Metal Hypersilyl Borates","authors":"Thomas Lainer, Christoph Walkner, Nina M. Tasch, Roland C. Fischer, Ana Torvisco, Harald Stueger, Michael Haas","doi":"10.1002/zaac.202400054","DOIUrl":"https://doi.org/10.1002/zaac.202400054","url":null,"abstract":"This study focuses on the synthesis of H‐ and MeO‐ functionalized alkali metal hypersilyl borates. Consequently, two distinct silanides were used as polysilane frameworks for our chemical manipulations. Tris(silyl)silanide (1) and tris(trimethoxysilyl)silanide (2) react in the same manner with the BH<jats:sub>3</jats:sub> ⋅ SMe<jats:sub>2</jats:sub> complex to obtain two new alkali metal hypersilyl borates [(R<jats:sub>3</jats:sub>Si)<jats:sub>3</jats:sub>SiBH<jats:sub>3</jats:sub>M (M=alkali metal; R=H, (3), R=MeO, (4 a–c))] in good to excellent yields. NMR spectroscopy for all compounds and single‐crystal X‐ray crystallography for 3 and 4 a, b enabled a clear structural characterization. Single crystal X‐ray analysis of 3 showed a dimeric structure, where two THF‐molecules and three hydrides from the BH<jats:sub>3</jats:sub>‐group contribute to the coordination sphere of the lithium atom. Interestingly, crystals suitable for X‐ray analysis of 4 a and 4 b showed a solvent‐free cluster formation, due to the coordination of the MeO groups. Both species form coordination polymers with different coordination modes depending on the nature of the alkali metal. Attempted hydride abstraction reactions of 3 and 4 with various reagents under the formation of the free boranes proceeded unselectively.","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"53 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141773026","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
On the structure of Tl2Pb(SO4)2 and crystal chemistry of thallium‐containing sulfates 论 Tl2Pb(SO4)2 的结构和含铊硫酸盐的晶体化学性质
Zeitschrift für anorganische und allgemeine Chemie Pub Date : 2024-07-22 DOI: 10.1002/zaac.202400072
Pengyun Chen
{"title":"On the structure of Tl2Pb(SO4)2 and crystal chemistry of thallium‐containing sulfates","authors":"Pengyun Chen","doi":"10.1002/zaac.202400072","DOIUrl":"https://doi.org/10.1002/zaac.202400072","url":null,"abstract":"Single crystal of a thallium‐containing sulfate Tl2Pb(SO4)2 was prepared through hydrothermal crystallization starting from Tl2CO3, Pb(NO3)2 and H2SO4. The crystal structure was solved from single‐crystal X‐ray diffraction data: Tl2Pb(SO4)2 crystallizes in space group R[[EQUATION]]m with lattice parameters of a = 5.5955(2) Å, c = 22.1001(9) Å, and Z = 3, which is also corroborated by Rietveld refinement on X‐ray powder data. The crystal structure can be regarded as [Pb(SO4)2]2‐ sheets intercalated by double layers of Tl+ along the c‐axis. From a mineralogical perspective, Tl2Pb(SO4)2 belongs to the palmierite family and can further be classified within palmierite‐supergroup. Validation of the structure models was carried out utilizing various concepts including Bond Valence (BV), Charge Distribution (CD) and Madelung Part of Lattice Energy (MAPLE). Notably, a contrast in stereochemical activity of 6s2 lone electron pair (LEP) between Tl+ and Pb2+ is interpreted in terms of bonding behaviours as well as Wang‐Liebau Eccentricity (WLE) parameters. Moreover, an extensive investigation into the crystal chemistry of thallium‐containing sulfates was conducted for the first time, focusing on the coordination environment and bonding behaviour of Tl+ and corresponding WLE parameters. A comparative analysis of these structurally related compounds including Tl2Pb(SO4)2, Tl3H(SO4)2, TlBi(SO4)2, TlIn(SO4)2, TlRh(SO4)2, and TlAl(SO4)2 was delineated.","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"44 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141773025","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Retraction: Porous GdIII‐Organic Framework as a Dual‐Functional Material for Cyanosilylation of Aldehydes and Ablation of Human Liver Cancer Cells 撤稿：多孔钆Ⅲ-有机框架作为醛的氰硅烷化和人类肝癌细胞消融的双功能材料
Zeitschrift für anorganische und allgemeine Chemie Pub Date : 2024-07-19 DOI: 10.1002/zaac.202400105
{"title":"Retraction: Porous GdIII‐Organic Framework as a Dual‐Functional Material for Cyanosilylation of Aldehydes and Ablation of Human Liver Cancer Cells","authors":"","doi":"10.1002/zaac.202400105","DOIUrl":"https://doi.org/10.1002/zaac.202400105","url":null,"abstract":"","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"130 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141744577","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Retraction: Encapsulation of 5‐Fluorouracil in a Copper(II)‐based Porous Metal‐organic Framework: Drug Delivery and Inhibiting Human Spinal Cord Tumor Cells 撤回：铜(II)基多孔金属有机框架中的5-氟尿嘧啶包囊：给药和抑制人脊髓肿瘤细胞
Zeitschrift für anorganische und allgemeine Chemie Pub Date : 2024-07-19 DOI: 10.1002/zaac.202400107
{"title":"Retraction: Encapsulation of 5‐Fluorouracil in a Copper(II)‐based Porous Metal‐organic Framework: Drug Delivery and Inhibiting Human Spinal Cord Tumor Cells","authors":"","doi":"10.1002/zaac.202400107","DOIUrl":"https://doi.org/10.1002/zaac.202400107","url":null,"abstract":"","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"7 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141744575","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Retraction: Synthesis, Crystal Structures, and Anti‐cervical Cancer Activity Evaluation of Three Trinuclear Transition Metal(II) Complexes with N,O‐Donor Schiff Base Ligand 撤回：含 N,O-单体席夫碱配体的三种三核过渡金属(II)配合物的合成、晶体结构和抗宫颈癌活性评估
Zeitschrift für anorganische und allgemeine Chemie Pub Date : 2024-07-19 DOI: 10.1002/zaac.202400103
{"title":"Retraction: Synthesis, Crystal Structures, and Anti‐cervical Cancer Activity Evaluation of Three Trinuclear Transition Metal(II) Complexes with N,O‐Donor Schiff Base Ligand","authors":"","doi":"10.1002/zaac.202400103","DOIUrl":"https://doi.org/10.1002/zaac.202400103","url":null,"abstract":"","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"130 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141744572","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Retraction: Two Zinc(II) and Nickel(II)‐based Complexes: Anti Breast Cancer Activity 撤回：两种锌(II)和镍(II)基配合物：抗乳腺癌活性
Zeitschrift für anorganische und allgemeine Chemie Pub Date : 2024-07-19 DOI: 10.1002/zaac.202400102
{"title":"Retraction: Two Zinc(II) and Nickel(II)‐based Complexes: Anti Breast Cancer Activity","authors":"","doi":"10.1002/zaac.202400102","DOIUrl":"https://doi.org/10.1002/zaac.202400102","url":null,"abstract":"","PeriodicalId":23934,"journal":{"name":"Zeitschrift für anorganische und allgemeine Chemie","volume":"41 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141744576","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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