Vietnam Journal of Catalysis and Adsorption最新文献

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Synthesis and application of biochar from agricultural by-products. Effect of pyrolysis temperature on the acid-base properties of biochar 利用农副产品合成生物炭及其应用。热解温度对生物炭酸碱特性的影响
Vietnam Journal of Catalysis and Adsorption Pub Date : 2024-07-02 DOI: 10.62239/jca.2024.044
Phung Thi Lan, Vu Tran The Hien, Phan Đinh Khanh Nguyen, Le Minh Cam
{"title":"Synthesis and application of biochar from agricultural by-products. Effect of pyrolysis temperature on the acid-base properties of biochar","authors":"Phung Thi Lan, Vu Tran The Hien, Phan Đinh Khanh Nguyen, Le Minh Cam","doi":"10.62239/jca.2024.044","DOIUrl":"https://doi.org/10.62239/jca.2024.044","url":null,"abstract":"Biochar was synthesized from banana peels using the pyrolysis method in a nitrogen gas environment. The pyrolysis temperature ranged from 100°C to 500°C with a heating rate of 5°C per minute and a pyrolysis time of 1.5 hours. The influence of the pyrolysis temperature on the acid-base properties of the biochar surface was evaluated through characteristic SEM and BET measurements. Boehm titration showed a gradual decrease in the total acid functional groups and an increase in the total base functional groups with the increasing pyrolysis temperature. Methylene Blue (MB) was used as a model substance to investigate the adsorption properties of the synthesized biochar. The Langmuir and Freundlich models were employed to describe the adsorption equilibrium. The kinetics of MB adsorption followed a pseudo-second-order kinetic equation. The adsorption capacity of MB by biological charcoal was influenced by the acid-base properties of the material, indicating the impact of the pyrolysis temperature.","PeriodicalId":23507,"journal":{"name":"Vietnam Journal of Catalysis and Adsorption","volume":"54 11","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141688336","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation of graphene from polyethylene terephthalate (PET) bottle wastes and its use for the removal of Methylene blue from aqueous solution 利用聚对苯二甲酸乙二酯(PET)瓶废料制备石墨烯并将其用于去除水溶液中的亚甲基蓝
Vietnam Journal of Catalysis and Adsorption Pub Date : 2024-07-02 DOI: 10.62239/jca.2024.030
Duy Khiem Nguyen, Thi Dung Nguyen, Hoang Sinh Le, Duong Duc La, Nguyen Thi Hong Phuong Phuong
{"title":"Preparation of graphene from polyethylene terephthalate (PET) bottle wastes and its use for the removal of Methylene blue from aqueous solution","authors":"Duy Khiem Nguyen, Thi Dung Nguyen, Hoang Sinh Le, Duong Duc La, Nguyen Thi Hong Phuong Phuong","doi":"10.62239/jca.2024.030","DOIUrl":"https://doi.org/10.62239/jca.2024.030","url":null,"abstract":"We present a method to produce graphene flakes (GFs) from polyethylene terephthalate (PET) bottle wastes by the pyrolysis method using modified bentonite as a catalyst. The as-synthesized GFs are analyzed in terms of crystal phase, morphology, and surface chemistry. The synthesized GFs have a porous, thin, and leaf-like morphology with a length ranging from a few hundred nanometers to a few tens of micrometers. The XRD and FT-IR results confirm the graphitization of PET and the presence of oxygen-containing functional groups on the surface of synthesized GFs. The obtained GFs are used as adsorbents for the removal of methylene blue (MB) from aqueous solution. The effects of various factors including, contact time, pH, and initial MB concentration, on the MB removal efficiency are examined. In addition, the adsorption isotherm models of Langmuir and Freundlich are studied. The best-fitting model is observed with the Freundlich isotherm model.","PeriodicalId":23507,"journal":{"name":"Vietnam Journal of Catalysis and Adsorption","volume":"30 34","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-07-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141684351","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Kinetics of 4‑nitrophenol reduction with NaBH4 over Ag/CuO nanomaterial catalyst Ag/CuO 纳米材料催化剂用 NaBH4 还原 4-硝基苯酚的动力学
Vietnam Journal of Catalysis and Adsorption Pub Date : 2024-03-09 DOI: 10.62239/jca.2023.079
Nguyen Le My Linh, Dang Thi Thanh Nhan
{"title":"Kinetics of 4‑nitrophenol reduction with NaBH4 over Ag/CuO nanomaterial catalyst","authors":"Nguyen Le My Linh, Dang Thi Thanh Nhan","doi":"10.62239/jca.2023.079","DOIUrl":"https://doi.org/10.62239/jca.2023.079","url":null,"abstract":"In this paper, Ag/CuO nanomaterials were prepared via hydrothermal method combined with chemical reduction and used as catalysts in the reduction of 4-nitrophenol. Kinetic study of 4-nitrophenol (4-NP) reduction into 4-aminophenol (4-AP) by sodium borohydride revealed a first order reaction. The reaction rate constant k increased with amount of silver crystals introduced into CuO nanosheets, with Ag/CuO catalyst concentrations and with temperature. The thermodynamic activation parameters such as activation energy (Ea), enthalpy of activation (∆H#), entropy (∆S#) and Gibbs energy (∆G#) of activation were determined. The value of Ea, ∆H#, ∆S# and ∆G# were 72,33 kJ/mol, –69,86 kJ/mol, –24,28 J/K.mol and –62,50 kJ/mol (303K), respectivement. Ethanol and isopropanol were able to inhibit the 4-NP reduction with NaBH4 in the presence of Ag/CuO catalyst.","PeriodicalId":23507,"journal":{"name":"Vietnam Journal of Catalysis and Adsorption","volume":"201 S601","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140256364","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Adsorption properties of nanotube type halloysite clay mineral for La3+ ions 纳米管型埃洛石粘土矿物对 La3+ 离子的吸附特性
Vietnam Journal of Catalysis and Adsorption Pub Date : 2024-03-09 DOI: 10.62239/jca.2023.067
Le Thi Phuong Thao, Vo Thi Hanh, Bui Hoang Bac, Tran Thi Thu Huong, Chu Minh Hieu, Nguyen Ngoc Tinh, Nguyen Thi Phuong, Le Thi Duyen
{"title":"Adsorption properties of nanotube type halloysite clay mineral for La3+ ions","authors":"Le Thi Phuong Thao, Vo Thi Hanh, Bui Hoang Bac, Tran Thi Thu Huong, Chu Minh Hieu, Nguyen Ngoc Tinh, Nguyen Thi Phuong, Le Thi Duyen","doi":"10.62239/jca.2023.067","DOIUrl":"https://doi.org/10.62239/jca.2023.067","url":null,"abstract":"This paper presents the results of research on the adsorption capacity of La3+ ions from aqueous solution of nanotube-type halloysite. The influence of operational conditions such as contact time, initial concentration of La3+, initial pH of solution, halloysite mass and temperature on the adsorption of La3+ had also been examined. The results show that the optimal efficiency and adsorption capacity of La3+ reached 90.19% and 3.76 mg/g in the suitable conditions: haloysite mass 0.6 g/50 mL solution, initial La3+ ion concentration 50 mg/L, pH 5.8, contact time 60 minutes at room temperature (25oC). The adsorption isotherm was studied based on both Langmuir and Freundlich models. The adsorption kinetics were studied by both pseudo-first-order and pseudo-second-order kinetic models. These results open up prospects for the application of haloysite clay minerals to remove and recover La in polluted water.","PeriodicalId":23507,"journal":{"name":"Vietnam Journal of Catalysis and Adsorption","volume":"154 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140256484","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A novel adsorbent based electroplating sludge – rice husk char for removal of methylene blue and ciprofloxacin in aqueous solution 一种基于电镀污泥-稻壳炭的新型吸附剂,用于去除水溶液中的亚甲基蓝和环丙沙星
Vietnam Journal of Catalysis and Adsorption Pub Date : 2024-03-09 DOI: 10.62239/jca.2023.069
Dao Van Hien, Tran Thi Huong, Nguyen Thi Mai, Nguyen Thi Anh Tuyet, Dang Van Thanh, Pham Van Hao, Tran Thi Minh Hang, Nguyen Manh Khai
{"title":"A novel adsorbent based electroplating sludge – rice husk char for removal of methylene blue and ciprofloxacin in aqueous solution","authors":"Dao Van Hien, Tran Thi Huong, Nguyen Thi Mai, Nguyen Thi Anh Tuyet, Dang Van Thanh, Pham Van Hao, Tran Thi Minh Hang, Nguyen Manh Khai","doi":"10.62239/jca.2023.069","DOIUrl":"https://doi.org/10.62239/jca.2023.069","url":null,"abstract":"The adsorbent based electroplating sludge and rice husk char (CR) was prepared by ultrasonication method for adsorption of methylene blue (MB) and Ciprofloxacin (CIP) in water. The characteristics of adsorbent such as surface morphology, specific surface area, functional groups, element components was confirmed by SEM, BET, FT-IR, XRD and EDX. The results showed the adsorbent is porous structure with BET surface area of 175.22 m2/g, most of pore width belonged meso section. Removal effectiveness of MB and CIP were 99.89% and 74.96%, respectively after 90 min of adsorption. The experiment was implemented with the mockup model containing of methylene blue and ciprofloxacin in NH3.","PeriodicalId":23507,"journal":{"name":"Vietnam Journal of Catalysis and Adsorption","volume":"274 3","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140255815","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Graphite surface modification by quasi-periodically structured diazonium monolayer 准周期结构重氮单层石墨表面改性
Vietnam Journal of Catalysis and Adsorption Pub Date : 2024-03-09 DOI: 10.62239/jca.2023.073
Huynh Thi Mien Trung, Phan Thanh Hai
{"title":"Graphite surface modification by quasi-periodically structured diazonium monolayer","authors":"Huynh Thi Mien Trung, Phan Thanh Hai","doi":"10.62239/jca.2023.073","DOIUrl":"https://doi.org/10.62239/jca.2023.073","url":null,"abstract":"In this study, a novel functionalization protocol of highly oriented pyrolytic graphite (HOPG) was proposed, in which a two dimensional (2D) porous network formed by alkoxy-substituted dehydrobenzo[12]annulene (DBA-OC12) was served as a sacrificial template for electrografting of 3,5-terbutyl diazonium (3,5-TBD). The 2D DBA-OC12 porous network was synthesized by drop-casting of the corresponding precursor followed by a drying process. The structural and electrochemical properties of pristine as well as functionalized HOPG surfaces were investigated by means of cyclic voltammetry (CV) and scanning tunneling microscopy (STM).","PeriodicalId":23507,"journal":{"name":"Vietnam Journal of Catalysis and Adsorption","volume":"193 1‐6","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140256032","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation of nanocomposite material based on Porphyrin and electrochemical analysis for green fuel production 制备基于卟啉的纳米复合材料并进行电化学分析以生产绿色燃料
Vietnam Journal of Catalysis and Adsorption Pub Date : 2024-03-09 DOI: 10.62239/jca.2023.062
Dang Trung Dung, Nguyen Thi Xuan Quynh, Mai Tien Dat, Nguyen Thi Anh Thu, Nguyen Thanh Tung, Tran Van Chinh, Nguyen Thi Giang, La Duc Duong
{"title":"Preparation of nanocomposite material based on Porphyrin and electrochemical analysis for green fuel production","authors":"Dang Trung Dung, Nguyen Thi Xuan Quynh, Mai Tien Dat, Nguyen Thi Anh Thu, Nguyen Thanh Tung, Tran Van Chinh, Nguyen Thi Giang, La Duc Duong","doi":"10.62239/jca.2023.062","DOIUrl":"https://doi.org/10.62239/jca.2023.062","url":null,"abstract":"In the current environmental pollution situation, using green fuel sources such as H2 gas to overcome the challenge of pollution and resource depletion is a useful solution. This research used the acid-base neutralization method with the recombination process to successfully fabricate CuFe2O4/TCPP nanocomposites. The morphological and structural properties of the materials were evaluated by scanning electron microscopy (SEM), X-ray diffraction (XRD) which show that the resulting material has a structure consisting of TCPP filaments with a diameter of about 20-30 nm and a length of µm, interspersed with CuFe2O4 particles with sizes in the range of 100 nm. The electrochemical properties of the as-prepared material film were investigated by Cyclic Voltammetry (CV) and electrochemical impedance spectroscopy (EIS) on a glassy carbon electrode with a 3-electrodes system. The results show the appearance of electrochemical characteristics of copper ferrite/porphyrin hybrid materials and especially the change of electrochemical characteristics when this nanocomposite was irradiated by an external light source. These results are expecting to apply this material in the photocatalytic process to produce green fuel H2 from water.","PeriodicalId":23507,"journal":{"name":"Vietnam Journal of Catalysis and Adsorption","volume":"191 S529","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140256180","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis of AgNPs/MnO2/rGO composite materials with adsorption properties and their application in analysis of anti-inflammatory and antibiotic agents 具有吸附特性的 AgNPs/MnO2/rGO 复合材料的合成及其在消炎药和抗生素分析中的应用
Vietnam Journal of Catalysis and Adsorption Pub Date : 2024-03-09 DOI: 10.62239/jca.2023.065
Ho Xuan Anh Vu, Le Trung Hieu, Nguyen Hai Phong
{"title":"Synthesis of AgNPs/MnO2/rGO composite materials with adsorption properties and their application in analysis of anti-inflammatory and antibiotic agents","authors":"Ho Xuan Anh Vu, Le Trung Hieu, Nguyen Hai Phong","doi":"10.62239/jca.2023.065","DOIUrl":"https://doi.org/10.62239/jca.2023.065","url":null,"abstract":"In this article, AgNPs and MnO2 were successively synthesized on the Graphene oxide (GO) substrate using an in situ method. The AgNPs/MnO2/GO nanocomposite material was modified onto the surface of a glassy carbon electrode (GCE) and the material was electrochemically reduced on the electrode surface. The material obtained after reduction was called AgNPs/MnO2/rGO, which was confirmed by X-Ray diffraction (XRD) and Fourier transform infrared spectroscopy (FT-IR) to examine the chemical bonding and by scanning electron microscopy (SEM) combined with energy-dispersive spectroscopy (EDS) to demonstrate the elemental characteristics of the material. In addition, X-ray photoelectron spectroscopy (XPS) analysis was performed to determine the elemental composition, chemical state, and electronic state of the elements on the surface of the material. The application of the reduced material was for the analysis of Piroxicam and Ofloxacin using the differential pulse anodic stripping voltammetry (DP-ASV) method. The investigation of pH and scan rate (v) indicated that the synthesized material had adsorption properties and was applied for the analysis of the anti-inflammatory drug Piroxicam and the antibiotic Ofloxacin.","PeriodicalId":23507,"journal":{"name":"Vietnam Journal of Catalysis and Adsorption","volume":"202 S609","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140256334","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation of Metal - Organic Framework MIL-88B(Fe)-NH2 for Efficient Adsorption of Congo Red in Aqueous Environment 制备用于在水环境中高效吸附刚果红的金属有机框架 MIL-88B(Fe)-NH2
Vietnam Journal of Catalysis and Adsorption Pub Date : 2024-03-09 DOI: 10.62239/jca.2023.063
Hoang Thi Linh Giang, Dang Thi Minh Hue, Tran Thi Luyen, Tran Vinh Hoang, Huynh Dang Chinh
{"title":"Preparation of Metal - Organic Framework MIL-88B(Fe)-NH2 for Efficient Adsorption of Congo Red in Aqueous Environment","authors":"Hoang Thi Linh Giang, Dang Thi Minh Hue, Tran Thi Luyen, Tran Vinh Hoang, Huynh Dang Chinh","doi":"10.62239/jca.2023.063","DOIUrl":"https://doi.org/10.62239/jca.2023.063","url":null,"abstract":"MIL-88B(Fe)-NH2 material was prepared by a simple solvothermal method. Various techniques were performed to investigate material characteristics including X-ray diffraction (XRD), scanning electron spectroscopy (SEM), transmission electron microscopy (TEM) and Brunauer-Emmett-Teller (BET) surface area. The result indicates that the particle shape is a bipyramidal hexagonal prism having a porous surface, and the BET surface area is 13.43 m2/g. Adsorption of congo red (CR) onto MIL-88B(Fe)-NH2 was studied as well. The adsorption equilibrium of the material is reached rapidly after 10 minutes with excellent adsorption efficiency (98.02%). Adsorption kinetic conforms to Langmuir isothermal adsorption model with the high maximum capacity of 333.33 mg/g.","PeriodicalId":23507,"journal":{"name":"Vietnam Journal of Catalysis and Adsorption","volume":"189 S517","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140256192","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The Me(almIM)2 structural ZIFs: Synthesis, characterization and application Me(almIM)2 结构 ZIF:合成、表征和应用
Vietnam Journal of Catalysis and Adsorption Pub Date : 2024-03-09 DOI: 10.62239/jca.2023.060
Ta Ngoc Don, Le Van Duong, Nguyen Thi Hong Phuong, Nguyen Thi Minh Thu, Nguyen Thi Thu Huyen, Ta Ngoc Thien Huy, Nguyen Van Thanh, Danh Mu, Ngu Trong Nghia, Pham Thi Mai Huong, Nguyen Thi Linh, Ha Thi Lan Anh, Bui Thi Thanh Ha, Tran Anh Vy, Trinh Thi Hai
{"title":"The Me(almIM)2 structural ZIFs: Synthesis, characterization and application","authors":"Ta Ngoc Don, Le Van Duong, Nguyen Thi Hong Phuong, Nguyen Thi Minh Thu, Nguyen Thi Thu Huyen, Ta Ngoc Thien Huy, Nguyen Van Thanh, Danh Mu, Ngu Trong Nghia, Pham Thi Mai Huong, Nguyen Thi Linh, Ha Thi Lan Anh, Bui Thi Thanh Ha, Tran Anh Vy, Trinh Thi Hai","doi":"10.62239/jca.2023.060","DOIUrl":"https://doi.org/10.62239/jca.2023.060","url":null,"abstract":"The Me(almIM)2 structural ZIFs are formed from the metal ions Me2+ and the linker 4-methyl-5-imidazolecarboxaldehyde (HalmIM), with the Me–almIM–Me bond angle similar to the Si–O–Si angle in zeolites (145o). Depending on the type of bond formed, Me(almIM)2 material has RHO or SOD structure with good thermal and chemical stability.\u0000With pore diameter of about 3.0-3.7 Å connected to large cavities with sizes from 9.1-17.9 Å and a structural frameworks containing two groups –CH3 and –CHO with hydrophilic properties, when the –CHO groups is modified by amine groups through imine condensation reaction, we can create hydrophobic materials for diverse applications in adsorption, separation, sensing, biomedical and catalysis.\u0000This review report collects results from more than 100 research papers related to Me(almIM)2 from 2010 to present and provides some recommendations on their synthesis, characterization and application in the future.","PeriodicalId":23507,"journal":{"name":"Vietnam Journal of Catalysis and Adsorption","volume":"209 S649","pages":""},"PeriodicalIF":0.0,"publicationDate":"2024-03-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140256289","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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