Transactions of The Faraday Society最新文献_第4页

Chemistry of aliphatic unconjugated nitramines. Part 5.—Primary photochemical processes in polycrystalline RDX 脂肪族非共轭硝胺化学。第5部分。-多晶RDX的主要光化学过程

Transactions of The Faraday Society Pub Date : 1971-01-01 DOI: 10.1039/TF9716701749

J. Stals, A. Buchanan, C. G. Barraclough

引用次数: 12

Origin and role of rehybridization moments in determining infra-red intensities 再杂化矩在确定红外强度中的起源和作用

Transactions of The Faraday Society Pub Date : 1971-01-01 DOI: 10.1039/TF9716701894

G. Jalsovszky, W. J. Orville-Thomas

引用次数: 26

Thermodynamic study on aqueous dilute solutions of organic compounds. Part 2.—Cyclic ethers 有机化合物稀水溶液的热力学研究。第2部分。环醚

Transactions of The Faraday Society Pub Date : 1971-01-01 DOI: 10.1039/TF9716701943

S. Cabani, G. Conti, L. Lepori

引用次数: 57

Ring disc electrodes. Part 14.—Kinetic and transient parameters 环形圆盘电极。部分14。-动力学和瞬态参数

Transactions of The Faraday Society Pub Date : 1971-01-01 DOI: 10.1039/TF9716702162

W. Albery, J. S. Drury, M. Hitchman

引用次数: 10

Electron-diffraction investigations of gaseous sulphur dioxide and trioxide 气态二氧化硫和三氧化物的电子衍射研究

Transactions of The Faraday Society Pub Date : 1971-01-01 DOI: 10.1039/TF9716702216

A. Clark, B. Beagley

{"title":"Electron-diffraction investigations of gaseous sulphur dioxide and trioxide","authors":"A. Clark, B. Beagley","doi":"10.1039/TF9716702216","DOIUrl":"https://doi.org/10.1039/TF9716702216","url":null,"abstract":"Electron-diffraction intensity data have been collected for gaseous sulphur dioxide (250 K) and rioxide (300 K) at camera lengths of 50 and 25 cm. Least squares refinement led to the following ra distances, root-mean-square amplitudes of vibration, and estimated standard deviations; for SO2, rS–O= 1.431 ± 0.002 A, rO‥O= 2.460±0.012 A, uS–O= 0.041±0.003 A, and uO‥O= 0.053±0.012 A, for SO3, rS–O= 1.418±0.003 A, rO‥O= 2.457±0.009 A, uS–O= 0.048±0.005 A and uO‥O= 0.067±0.010 A. The corresponding value for the angle in the dioxide is 118.5±1.0°, whilst the trioxide is planar within experimental error. For both molecules, spectroscopic estimates of the vibrational amplitudes have been made from force-constant data, and for SO2 these are in satisfactory agreement with the diffraction results. For SO3, however, agreement is poorer and this may indicate the presence of a small amount of S3O9 trimer in the diffracting vapour. Mean-square parallel and perpendicular amplitudes of vibration and centrifugal distortion corrections have also been calculated for both molecules and the electron-diffraction ra parameters converted to equilibrium (re), and zero-point-average (r°α), values. For SO2, these structures differ insignificantly from corresponding microwave re and rz estimates.","PeriodicalId":23290,"journal":{"name":"Transactions of The Faraday Society","volume":"67 1","pages":"2216-2224"},"PeriodicalIF":0.0,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1039/TF9716702216","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"57626408","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 41

Dielectric relaxation in non aqueous solutions. Part 2.—Solutions of tri(n-butyl)ammonium picrate and iodide in polar solvents 非水溶液中的介电弛豫。第2部分。-苦味酸三(正丁基)铵和碘化物在极性溶剂中的溶液

Transactions of The Faraday Society Pub Date : 1971-01-01 DOI: 10.1039/TF9716702225

E. Cavell, P. Knight, M. A. Sheikh

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引用次数: 76

Radiation-induced dechlorination of pentachloroethane and sym-tetrachloroethane. Reactions of 1,1,2,2-tetrachloroethyl and 1,2,2-trichloroethyl radicals 辐射诱发的五氯乙烷和正四氯乙烷脱氯。1,1,2,2-四氯乙基和1,2,2-三氯乙基自由基的反应

Transactions of The Faraday Society Pub Date : 1971-01-01 DOI: 10.1039/TF9716702354

M. Katz, A. Horowitz, L. Rajbenbach

引用次数: 17

Ultra-violet absorption spectra of germanium monobromide and tin monobromide 单溴化锗和单溴化锡的紫外吸收光谱

Transactions of The Faraday Society Pub Date : 1971-01-01 DOI: 10.1039/TF9716702499

G. Oldershaw, K. Robinson

引用次数: 6

Apparent molar volumes of electrolytes. Part 4.—KCl in formamide at 25°C 电解质的表观摩尔体积。第4部分——25°C下甲酰胺中的KCl

Transactions of The Faraday Society Pub Date : 1971-01-01 DOI: 10.1039/TF9716702525

L. Dunn

引用次数: 6

E.m.f. studies of electrolytic dissociation. Part 11.—The bisulphate ion at 25°C 电解解离的电磁效应研究。第11部分。- 25°C的硫酸氢离子

Transactions of The Faraday Society Pub Date : 1971-01-01 DOI: 10.1039/TF9716702652

C. E. Evans, C. Monk

引用次数: 4