{"title":"电解解离的电磁效应研究。第11部分。- 25°C的硫酸氢离子","authors":"C. E. Evans, C. Monk","doi":"10.1039/TF9716702652","DOIUrl":null,"url":null,"abstract":"A Pt,H2—AgCl,Ag e.m.f. cell is described whereby accurate measurements may be obtained from additions of stock solutions. Measurements with HCl + H2SO4 mixtures are used to evaluate the dissociation constant of the HSO–4 ion at 25°C. A method of extrapolation is described which aims at reducing uncertainties due to the ion size parameter. Some previous measurements with e.m.f. cells are also re-examined.","PeriodicalId":23290,"journal":{"name":"Transactions of The Faraday Society","volume":"67 1","pages":"2652-2658"},"PeriodicalIF":0.0000,"publicationDate":"1971-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1039/TF9716702652","citationCount":"4","resultStr":"{\"title\":\"E.m.f. studies of electrolytic dissociation. Part 11.—The bisulphate ion at 25°C\",\"authors\":\"C. E. Evans, C. Monk\",\"doi\":\"10.1039/TF9716702652\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A Pt,H2—AgCl,Ag e.m.f. cell is described whereby accurate measurements may be obtained from additions of stock solutions. Measurements with HCl + H2SO4 mixtures are used to evaluate the dissociation constant of the HSO–4 ion at 25°C. A method of extrapolation is described which aims at reducing uncertainties due to the ion size parameter. Some previous measurements with e.m.f. cells are also re-examined.\",\"PeriodicalId\":23290,\"journal\":{\"name\":\"Transactions of The Faraday Society\",\"volume\":\"67 1\",\"pages\":\"2652-2658\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1971-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1039/TF9716702652\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Transactions of The Faraday Society\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1039/TF9716702652\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Transactions of The Faraday Society","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1039/TF9716702652","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
E.m.f. studies of electrolytic dissociation. Part 11.—The bisulphate ion at 25°C
A Pt,H2—AgCl,Ag e.m.f. cell is described whereby accurate measurements may be obtained from additions of stock solutions. Measurements with HCl + H2SO4 mixtures are used to evaluate the dissociation constant of the HSO–4 ion at 25°C. A method of extrapolation is described which aims at reducing uncertainties due to the ion size parameter. Some previous measurements with e.m.f. cells are also re-examined.
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