Transactions of the Indian Ceramic Society最新文献_第6页

Magnesium Aluminate Spinel: Structure, Properties, Synthesis and Applications 铝酸镁尖晶石的结构、性能、合成及应用

IF 1.2 4区材料科学

Transactions of the Indian Ceramic Society Pub Date : 2022-07-03 DOI: 10.1080/0371750X.2022.2137701

S. Sinhamahapatra, P. Das, K. Dana, Himanshu Tripathi

{"title":"Magnesium Aluminate Spinel: Structure, Properties, Synthesis and Applications","authors":"S. Sinhamahapatra, P. Das, K. Dana, Himanshu Tripathi","doi":"10.1080/0371750X.2022.2137701","DOIUrl":"https://doi.org/10.1080/0371750X.2022.2137701","url":null,"abstract":"Magnesium aluminate (MA) is a spinel group of material and rarely available in nature. It exhibits several advantageous thermal, thermo-mechanical, optical, chemical properties which renders it suitable for wide gamut applications starting from refractory to sensor to IR transmitting window. It has face centered cubic structure and has wide solubility to its end members at elevated temperatures. As a result of this solubility, non-stoichiometric compositions exist in the phase field of spinel in the phase diagram. Due to its unavailability in nature, MA spinels are synthetically prepared through different routes and using different starting materials. Among these, solid state reaction sintering or conventional mixed oxide (CMO) method is the most techno-economical viable process. However, the challenge lies with the preparation of dense MA spinel from its oxide precursors in a single stage process is the expansion due to spinellization. Several attempts have been made to overcome this deterring factor through improving the reactivity of the precursors, by controlling the processing parameters, or by using the mineralizers. In this paper crystal structure, stoichiometry in spinel composition, mechanism of spinel formation, different synthesis method, properties and applications are reviewed. GRAPHICAL ABSTRACT","PeriodicalId":23233,"journal":{"name":"Transactions of the Indian Ceramic Society","volume":"81 1","pages":"97 - 120"},"PeriodicalIF":1.2,"publicationDate":"2022-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43113797","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 3

Synthesis, Structural and Raman Investigations of PbNi1/3Nb2/3O3 Ceramics PbNi1/3Nb2/3O3陶瓷的合成、结构及拉曼光谱研究

IF 1.2 4区材料科学

Transactions of the Indian Ceramic Society Pub Date : 2022-07-03 DOI: 10.1080/0371750X.2022.2123045

Preeti, Adityanarayan H. Pandey, R. Selvamani, S. M. Gupta, C. Shekhar

引用次数: 0

Elaboration and Characterization of β-TCP/ZrO2 Cements for Dental Applications 牙科用β-TCP/ZrO2骨水泥的研制与表征

IF 1.2 4区材料科学

Transactions of the Indian Ceramic Society Pub Date : 2022-07-03 DOI: 10.1080/0371750X.2022.2109212

C. Ruiz-Aguilar, Esbeidy Eveline Godinez-Gamiño

{"title":"Elaboration and Characterization of β-TCP/ZrO2 Cements for Dental Applications","authors":"C. Ruiz-Aguilar, Esbeidy Eveline Godinez-Gamiño","doi":"10.1080/0371750X.2022.2109212","DOIUrl":"https://doi.org/10.1080/0371750X.2022.2109212","url":null,"abstract":"In the present study, four β-TCP/ZrO2 cement compositions were made, in which the zirconia was varied in different amounts at 0.25, 0.5, 0.75 and 1 wt%. The goals of this investigation were: (i) To analyze the effect of the mechanical properties of zirconia on the different samples of cement, (ii) To evaluate in vitro formation of hydroxyapatite in all cements at different times dipping in artificial saliva, and (iii) To analyze the interaction of glass-ionomer type I in all β-TCP/ZrO2 cement compositions. The results found were that the amount of zirconia added to the cement compositions did not significantly affect the mechanical properties’ values compared to the sample without zirconia. Nevertheless, ZrO2 helped to stabilize the demineralization of the types of cement in contact with artificial saliva at different times. On the other hand, the glass ionomer type I used to link the powder cement caused a change in the mechanical behavior, enhancing the plasticity in all the cement compositions. The in vitro test allowed an analysis of the cement samples dipping in artificial saliva, which showed a decrease of pH value from 7 to 3.8 at three days. GRAPHICAL ABSTRACT","PeriodicalId":23233,"journal":{"name":"Transactions of the Indian Ceramic Society","volume":"81 1","pages":"121 - 126"},"PeriodicalIF":1.2,"publicationDate":"2022-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49645174","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Structural and Electrical Properties of Gd Doped CeO2 (GDC) Nanoceramics for Solid Oxide Fuel Cell Applications 固体氧化物燃料电池用Gd掺杂CeO2（GDC）纳米陶瓷的结构和电学性能

IF 1.2 4区材料科学

Transactions of the Indian Ceramic Society Pub Date : 2022-07-03 DOI: 10.1080/0371750X.2022.2115400

Taranveer Kaur, Raman Kumar, Savidh Khan, Kulvir Singh, J. Kolte

引用次数: 2

Thermo Physical and Mechanical Characterization of Lightweight Porous Ceramics Produced from Porcelain Polishing Residues 陶瓷抛光残留物制备轻质多孔陶瓷的热物理力学性能

IF 1.2 4区材料科学

Transactions of the Indian Ceramic Society Pub Date : 2022-04-03 DOI: 10.1080/0371750X.2022.2096696

Derya Kırsever, H. Toplan

{"title":"Thermo Physical and Mechanical Characterization of Lightweight Porous Ceramics Produced from Porcelain Polishing Residues","authors":"Derya Kırsever, H. Toplan","doi":"10.1080/0371750X.2022.2096696","DOIUrl":"https://doi.org/10.1080/0371750X.2022.2096696","url":null,"abstract":"Traditional porcelain tile companies worldwide produce large amounts of residues during the polishing process. The recycling of these porcelain polishing residue becomes more critical. This study evaluates the incorporation of porcelain polishing residues as a raw material to produce lightweight porous ceramics as a new insulation material. Also, cellulose was used as the pore-making additive. The effect of sintering temperature and cellulose additive on the sintering behavior of porous ceramics, such as bulk density, linear shrinkage, water absorption were investigated. Flexural strength of the fired specimens was measured by three-point bending method. Thermal conductivities of the porous ceramics were predicted using laser flash method. Microstructural and phase observations were performed by scanning electron microscopy and X-ray diffractometry. Relatively low thermal conductivity of the samples sintered at 1100°C was obtained at 0.097 W.m–1.K–1 when 2.5 wt% cellulose additive was added, with low bulk density (<1 g.cm–3), water absorption (0.7%) and flexural strength (3.09 Mpa). These results indicate that the porcelain polishing residues could be used for lightweight porous ceramics production, thus giving rise to a new possibility for an environmental management of this abundant waste. GRAPHICAL ABSTRACT","PeriodicalId":23233,"journal":{"name":"Transactions of the Indian Ceramic Society","volume":"81 1","pages":"84 - 91"},"PeriodicalIF":1.2,"publicationDate":"2022-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45718263","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1

Permeation Behavior of Oxide Bonded SiC Ceramics at High Temperature and Prediction of Pressure Drop in Candle Filters 氧化物结合SiC陶瓷在高温下的渗透行为及滤筒压降预测

IF 1.2 4区材料科学

Transactions of the Indian Ceramic Society Pub Date : 2022-04-03 DOI: 10.1080/0371750X.2022.2064918

Atanu Dey, N. Kayal, O. Chakrabarti, M. Innocentini

引用次数: 1

Effects of SiO2 Addition on Phase Transition and Microstructure Evolution of Alumina Fibers Prepared Using the Sol-Gel Method 添加SiO2对溶胶-凝胶法制备氧化铝纤维相变和微观结构演变的影响

IF 1.2 4区材料科学

Transactions of the Indian Ceramic Society Pub Date : 2022-04-03 DOI: 10.1080/0371750X.2022.2064920

Qiang Liu, Juan Wang, Wensheng Liu, Lingjiao Zhan, S. Peng, Shuwei Yao, Yunzhu Ma

{"title":"Effects of SiO2 Addition on Phase Transition and Microstructure Evolution of Alumina Fibers Prepared Using the Sol-Gel Method","authors":"Qiang Liu, Juan Wang, Wensheng Liu, Lingjiao Zhan, S. Peng, Shuwei Yao, Yunzhu Ma","doi":"10.1080/0371750X.2022.2064920","DOIUrl":"https://doi.org/10.1080/0371750X.2022.2064920","url":null,"abstract":"In order to optimize the phase composition and grain size of alumina fibers, 0-3 wt% SiO2 were induced to prepare alumina fibers using sol-gel method with the reaction of aluminium powder, formic acid, acetic acid, nitric acid and SiO2 sol. Effects of low SiO2 content on the phase transition and microstructure of alumina fibers were investigated. X-ray diffraction analysis and differential scanning calorimetry results showed that the addition of silica delayed the formation of α-Al2O3, and the phase transformation path of alumina was changed from amorphous alumina → γ-Al2O3 → α-Al2O3 to amorphous alumina → γ-Al2O3 → θ-Al2O3 → α-Al2O3. Moreover, scanning electron microscopy and transmission electron microscopy results confirmed that the addition of SiO2 reduced the grain size and was beneficial for the dense structure. Fine-grained dense alumina fibers composed of α-Al2O3 phase and transitional alumina phase were obtained by adding 1 wt% and 3 wt% silica after sintering at 1200°C for 1 h. GRAPHICAL ABSTRACT","PeriodicalId":23233,"journal":{"name":"Transactions of the Indian Ceramic Society","volume":"81 1","pages":"68 - 75"},"PeriodicalIF":1.2,"publicationDate":"2022-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46037142","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Influence of the SrO Insertion to a Binary PbO-B2O3 Glass System: Mechanical Properties and Radiation Shielding Study SrO插入对二元PbO-B2O3玻璃体系的影响:机械性能和辐射屏蔽研究

IF 1.2 4区材料科学

Transactions of the Indian Ceramic Society Pub Date : 2022-04-03 DOI: 10.1080/0371750X.2022.2064919

H. Alrebdi, A. Almuqrin, M. Hanfi, M. Sayyed, K. Mahmoud

{"title":"Influence of the SrO Insertion to a Binary PbO-B2O3 Glass System: Mechanical Properties and Radiation Shielding Study","authors":"H. Alrebdi, A. Almuqrin, M. Hanfi, M. Sayyed, K. Mahmoud","doi":"10.1080/0371750X.2022.2064919","DOIUrl":"https://doi.org/10.1080/0371750X.2022.2064919","url":null,"abstract":"Mechanical features have been investigated to the glass system with the chemical composition xSrO-10PbO-(90–x)B2O3 with various concentrations of x = 20, 25, 30, 35, 40 and 45 mol%. Based on the Makishima-Mackenzie model, the elastic modulus has been predicted for the SrPbB glasses. The obtained results illustrate that elastic moduli reduced with the addition of SrO concentrations in the lead borate glass. The highest values of Young’s (89.03 GPa), bulk (68.36 GPa), shear (4.69 GPa), and longitudinal (114.63 GPa) moduli have been detected in the SrPbB20 glass with 20 molar fraction of SrO and low density of 3.29 g.cm−3. The radiation shielding properties have also been studied for the discussed glasses. Among the shielding parameters, the transmission factor and the mean free path have been detected according to the linear attenuation coefficient values which have been simulated utilizing the Monte Carlo simulation code MCNP5. Successively, the exposure buildup factors and the energy absorption buildup factor have been predicted using the BXCOM programme to appreciate the photons accumulation inwards the studied glass material as well as the effective atomic number (Zeff ) and the equivalent atomic number (Zeq ). Finally, it has been concluded that the present synthetical glasses are preferred to be utilized in various radiation shielding applications. GRAPHICAL ABSTRACT","PeriodicalId":23233,"journal":{"name":"Transactions of the Indian Ceramic Society","volume":"81 1","pages":"76 - 83"},"PeriodicalIF":1.2,"publicationDate":"2022-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46844399","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Colloidal Shaping of Transparent Spinel through Slip Casting Using Contamination Free Spinel Moulds 用无污染尖晶石模具滑移铸造透明尖晶石的胶体成形

IF 1.2 4区材料科学

Transactions of the Indian Ceramic Society Pub Date : 2022-01-02 DOI: 10.1080/0371750X.2022.2054473

S. Singh, P. Biswas, Roy Johnson

{"title":"Colloidal Shaping of Transparent Spinel through Slip Casting Using Contamination Free Spinel Moulds","authors":"S. Singh, P. Biswas, Roy Johnson","doi":"10.1080/0371750X.2022.2054473","DOIUrl":"https://doi.org/10.1080/0371750X.2022.2054473","url":null,"abstract":"Shaping transparent ceramics through slip casting on plaster of Paris (PoP) moulds offers improved transparency compared to compacted samples due to better homogeneity in colloidal processing. However, the contamination due to CaSO4 originated from the PoP contact is a primary concern. Therefore, it demands the machining of several layers from the cast surface that results in post-green machining defects. To address this concern, a magnesium aluminate (MgAl2O4) spinel mould was fabricated with indigenously synthesized spinel powder with optimum porosity of 45-50% and flexural strength of ∼16 MPa. The fabricated spinel mould was used to demonstrate the casting using water-based spinel slurry. The cast spinel blanks were found contamination free as confirmed by Fourier transform infrared studies. Microstructures of spinel moulds revealed the interconnectivity of the pores obtained by field emission scanning electron microscopy. Specimens cast on spinel and on PoP moulds, after post machining, were sintered (1650°C) and hot isostatically pressed (at 1800°C and 1950 bar) under identical conditions. Casting on spinel moulds demonstrated a contamination free surface of the samples. Its properties are at par with the samples cast on PoP moulds, however, with improved casting rate and minimum rejection. GRAPHICAL ABSTRACT","PeriodicalId":23233,"journal":{"name":"Transactions of the Indian Ceramic Society","volume":"81 1","pages":"30 - 36"},"PeriodicalIF":1.2,"publicationDate":"2022-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41833802","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Microstructure, Mechanical and Thermal Insulation Properties of Potassium Hexatitanate Whiskers Thermal Insulation Materials 六酸钾晶须保温材料的微观结构、力学性能和保温性能

IF 1.2 4区材料科学

Transactions of the Indian Ceramic Society Pub Date : 2022-01-02 DOI: 10.1080/0371750X.2022.2028267

Hao Liu, Wenyuan Liu, Zhou Wang, Yan Ma, Xitang Wang

{"title":"Microstructure, Mechanical and Thermal Insulation Properties of Potassium Hexatitanate Whiskers Thermal Insulation Materials","authors":"Hao Liu, Wenyuan Liu, Zhou Wang, Yan Ma, Xitang Wang","doi":"10.1080/0371750X.2022.2028267","DOIUrl":"https://doi.org/10.1080/0371750X.2022.2028267","url":null,"abstract":"Potassium hexatitanate whiskers (PTW) materials have attracted much attention in thermal insulation fields. Nevertheless, the low mechanical properties limited the development and application of PTW thermal insulation materials. In this work, low density, high mechanical properties and high thermal insulation capacity of PTW thermal insulation materials can be obtained through mesocarbon microbeads (MCMB) adopted as pore-forming agent. The pyrolysis and oxidation of MCMB promoted the development of whiskers during the calcination process, rendering the increased materials porosity. The as-prepared PTW materials heat treated at 1000°C possessed low thermal conductivity of 0.043-0.035 W.m−1.K−1 from room temperature to 900°C and a low bulk density of 0.52 g.cm−3. Owing to the point of contact between whiskers with developed diameter and aspect ratio, comperssive strength of PTW materials heat treated at 900° and 1000°C was 1.92 and 2.51 MPa, respectively, maintaining high resilience rates of above 70% at 5% compressive strain. The elevated heat-treatment temperature (above 1100°C) led to the sintering between whiskers and the resultant enhanced compressive strength of higher than 4.23 MPa. The researched low density, high mechanical properties and thermal insulation PTW materials exhibit huge prospects as insulation linings in thermal insulation fields. GRAPHICAL ABSTRACT","PeriodicalId":23233,"journal":{"name":"Transactions of the Indian Ceramic Society","volume":"81 1","pages":"1 - 6"},"PeriodicalIF":1.2,"publicationDate":"2022-01-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41629384","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 3