Surface Innovations最新文献

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Characterization and linear/nonlinear optical properties of polymer nanocomposite films for optoelectronics applications 用于光电子应用的聚合物纳米复合薄膜的表征及其线性/非线性光学性能
IF 3.5 4区 材料科学
Surface Innovations Pub Date : 2022-04-01 DOI: 10.1680/jsuin.22.00026
B. M. Alotaibi, H. Al-Yousef, N. Alsaif, A. Atta
{"title":"Characterization and linear/nonlinear optical properties of polymer nanocomposite films for optoelectronics applications","authors":"B. M. Alotaibi, H. Al-Yousef, N. Alsaif, A. Atta","doi":"10.1680/jsuin.22.00026","DOIUrl":"https://doi.org/10.1680/jsuin.22.00026","url":null,"abstract":"Polymer nanocomposite films combining of polyaniline (PANI) and lead sulfide (PbSNPs) were effectively synthesized using a casting solution approach for used in optical energy applications. Transmission microscope (TEM), X-ray diffraction (XRD), and infra-red spectroscopy (FT-IR) methods demonstrate that PbSNPs is successfully introduced into the PANI matrix. Scanning electron microscope (SEM) images reveal that the PbS is homogenously loaded and distributed in PANI chain. Using UV-Vis optical absorbance, the optical parameters of PANI/PbSNPs were evaluated, including absorption edge (Ed), band gap (Eg), carbon cluster number (N) and Urbach energies (Eu). PbSNPs has been investigated for their impact on PANI polymer linear optical (LO) as well as nonlinear optical (NLO) characteristics including refractive index, nonlinear susceptibility, and dielectric parameter’s. When comparing the PANI/PbSNPs film to the pure PANI film, the band gap of the PANI/PbSNPs samples was found to be significantly reduced. However, the addition of PbSNPs increased the predicted amount of optical conductivity and carbon cluster number. The addition of PbSNPs to the PANI polymer improved its optical characteristics, resulting in a synthetic composite that can be used in energy applications as well as optoelectronics devices.","PeriodicalId":22032,"journal":{"name":"Surface Innovations","volume":" ","pages":""},"PeriodicalIF":3.5,"publicationDate":"2022-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43621955","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
Carbon nanofiber aerogel/silicon oxycarbide composites for enhanced electromagnetic interference shielding 增强电磁干扰屏蔽的纳米碳纤维气凝胶/碳化硅复合材料
IF 3.5 4区 材料科学
Surface Innovations Pub Date : 2022-04-01 DOI: 10.1680/jsuin.22.00001
Wenxia Zhu, Zhengkai Tian, Xiao-xia Yan, Dong Su
{"title":"Carbon nanofiber aerogel/silicon oxycarbide composites for enhanced electromagnetic interference shielding","authors":"Wenxia Zhu, Zhengkai Tian, Xiao-xia Yan, Dong Su","doi":"10.1680/jsuin.22.00001","DOIUrl":"https://doi.org/10.1680/jsuin.22.00001","url":null,"abstract":"Lightweight electromagnetic interference (EMI) shielding materials under harsh environments are in urgent need to tackle the increasing electromagnetic pollution and hazards. Herein, carbon nanofiber aerogel (CNFA) modified silicon oxycarbide (CNFA/SiOC) composites were prepared following a precursor infiltration pyrolysis procedure by using three-dimensional CNFA as a skeleton. Their structures and mass densities (0.28-1.35 g cm−3) were tunable by adjusting the content of polysiloxane precursor in impregnating solution. The lightweight CNFA/SiOC composite featured with continuous conductive network and highly porous structure in SiOC matrix, resulting in high specific shielding effectiveness (up to 68.9 dB·cm3 g−1 with SETotal of 19.3 dB) due to enhanced conductance loss and multi reflection/scattering. When increasing the density, the CNFA/SiOC composite can deliver EMI shielding effectiveness as high as 27.5 dB due to the generation of defective carbon and carbon dangling bonds as well as abundant interfaces between CNFs and SiOC which induce polarization loss. Moreover, the CNFA/SiOC composite exhibits good oxidation resistance with SETotal retention of above 98% after heat treatment at 600°C for 2 h in air, which arises from the effective protection of CNFs by SiOC.","PeriodicalId":22032,"journal":{"name":"Surface Innovations","volume":" ","pages":""},"PeriodicalIF":3.5,"publicationDate":"2022-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46429545","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Preparation and characterization of air sprayed silk fibroin/silica-based thermal-insulation coatings on catheters for cerebral hypothermia therapy 空气喷涂丝素/二氧化硅基脑低温治疗导管隔热涂层的制备与表征
IF 3.5 4区 材料科学
Surface Innovations Pub Date : 2022-03-28 DOI: 10.1680/jsuin.22.00022
Yuan Gao, Miaowen Jiang, L. Bao, Zhichen Yin, Jicheng Zhang, Guangzhen Pan, Shiqiang Zheng, Yufeng Zheng, Chuanjie Wu, Ming Li, Xu Ji
{"title":"Preparation and characterization of air sprayed silk fibroin/silica-based thermal-insulation coatings on catheters for cerebral hypothermia therapy","authors":"Yuan Gao, Miaowen Jiang, L. Bao, Zhichen Yin, Jicheng Zhang, Guangzhen Pan, Shiqiang Zheng, Yufeng Zheng, Chuanjie Wu, Ming Li, Xu Ji","doi":"10.1680/jsuin.22.00022","DOIUrl":"https://doi.org/10.1680/jsuin.22.00022","url":null,"abstract":"Clinical practice of therapeutic hypothermia for neuroprotection in acute cerebral ischemia has been hindered by warming effect on the cold infusate along pathway, which results from the poor thermal resistance of traditional interventional catheter. In this study, thermal insulation coatings with different spray parameters and coating suspension compositions were prepared via air-spraying on Nylon substrate for biomedical application. The surface morphology and microstructure of coatings were investigated by scanning electron microscope (SEM), X-ray diffraction (XRD), Fourier Transform infrared spectroscopy (FTIR), respectively. Silk fibroin (SF) and hollow silica based nanospheres (HSBNS) were successfully sprayed on Nylon substrate. The thermal conductivity of coating measured by light flash apparatus is down to 0.00105 W/(m·K). The tape test indicates that coatings containing SF, HSBNS and glyceryl have good adhesion which is a promising method to enhance the thermal insulation performance of traditional catheter for cerebral hypothermia therapy.","PeriodicalId":22032,"journal":{"name":"Surface Innovations","volume":" ","pages":""},"PeriodicalIF":3.5,"publicationDate":"2022-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44956847","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Thin layer wicking experiments using magnetically treated water 磁处理水的薄层芯吸实验
IF 3.5 4区 材料科学
Surface Innovations Pub Date : 2022-03-28 DOI: 10.1680/jsuin.22.00999
A. Szcześ, E. Chibowski, E. Rzeźnik
{"title":"Thin layer wicking experiments using magnetically treated water","authors":"A. Szcześ, E. Chibowski, E. Rzeźnik","doi":"10.1680/jsuin.22.00999","DOIUrl":"https://doi.org/10.1680/jsuin.22.00999","url":null,"abstract":"Thin layer wicking experiments were carried out using a magnetically treated water and non-treated one. Two types of magnets of different construction and strength of the magnetic field (B=15 mT and B=0.27 T) were used. It was found that water circulated in the presence of magnetic field penetrated faster into the porous layer of silica gel. This is reflected also in the changes of electron donor and electron acceptor parameters of the surface free energy of the silica gel as calculated from the van Oss et al. approach. Based on this finding it is hypothesized that changes in the water structure occurs, i.e. the water flow destroys somehow the network of hydrogen bonds in liquid water while the magnetic field action promotes its formation.","PeriodicalId":22032,"journal":{"name":"Surface Innovations","volume":" ","pages":""},"PeriodicalIF":3.5,"publicationDate":"2022-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42560056","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Triboinformatics: Machine Learning algorithms and Data Topology methods for surface roughness, friction, and wear 摩擦学:表面粗糙度、摩擦和磨损的机器学习算法和数据拓扑方法
IF 3.5 4区 材料科学
Surface Innovations Pub Date : 2022-03-10 DOI: 10.1680/jsuin.22.00027
Md Syam Hasan, Michael Nosonovsky
{"title":"Triboinformatics: Machine Learning algorithms and Data Topology methods for surface roughness, friction, and wear","authors":"Md Syam Hasan, Michael Nosonovsky","doi":"10.1680/jsuin.22.00027","DOIUrl":"https://doi.org/10.1680/jsuin.22.00027","url":null,"abstract":"Friction and wear are very common phenomena found virtually everywhere. However, it is very difficult to predict the tribological (i.e., related to friction and wear) structure-properties relationships from the fundamental physical principles. Consequently, tribology remains a data-driven, mostly empirical discipline. With the advent of new Machine Learning (ML) and Artificial Intelligence (AI) methods, it becomes possible to establish new correlations in tribological data to better predict and control the tribological behavior of novel materials. Hence the new area of triboinformatics has emerged combining tribology with Data Science. We review ML algorithms used to establish correlations between the structure of metallic alloys and composite materials, tribological test conditions, friction, and wear. We also discuss novel methods of surface roughness analysis involving the concept of data topology in multi-dimensional data space, as applied to the macro- and nanoscale roughness. Other triboinformatic approaches are considered as well.","PeriodicalId":22032,"journal":{"name":"Surface Innovations","volume":" ","pages":""},"PeriodicalIF":3.5,"publicationDate":"2022-03-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43958445","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Functionally oriented high-temperature composite materials for aerospace use 航空航天用功能取向高温复合材料
IF 3.5 4区 材料科学
Surface Innovations Pub Date : 2022-03-10 DOI: 10.1680/jsuin.22.00016
P. Rusinov, Z. Blednova, R. Plomodyalo, A. P. Yurkova, Anastasia A Rusinova, Maxim D Ignatiev, Maxim Semadeni
{"title":"Functionally oriented high-temperature composite materials for aerospace use","authors":"P. Rusinov, Z. Blednova, R. Plomodyalo, A. P. Yurkova, Anastasia A Rusinova, Maxim D Ignatiev, Maxim Semadeni","doi":"10.1680/jsuin.22.00016","DOIUrl":"https://doi.org/10.1680/jsuin.22.00016","url":null,"abstract":"The authors developed technology for obtaining surface composite materials. This technology includes high-energy mechanical treatment, HVOF in a protective atmosphere, subsequent thermomechanical and thermal treatment of ZrCuNiCoTi, cBNNi3AlSiCCoY layers in a protective atmosphere. The processing allowed to increase the adhesive strength of the surface composites, reduce their porosity and improve their functional and operational properties. Staged methods of heat treatment and plastic deformation of surface layers have been developed. These methods stabilize material structure while reducing residual stresses. On the basis of complex X-ray diffraction and electron microscopic studies, the structural parameters of surface composites were determined. It was shown that the ZrCuNiCoTi alloy is in the austenitic-martensitic state and has a nanocrystalline structure with a grain size of 80–120 nm. Meanwhile, the cBNNi3AlSiCCoY alloy consists of many intermetallic phases and inclusions and has a nanosized structure with a grain size of 100–200 nm. A microhardness study of the surface layers in ZrCuNiCoTi – cBNNi3AlSiCCoY composite showed that thermomechanical treatment increases microhardness. The experimental data were statistically processed. As a result, empirical mathematical dependences of the stress amplitude on cyclic durability were compiled. Mechanical tests included tests of NiCoTiZrHf – cBNCoMo, ZrCuNiCoTi – cBNNi3AlSiCCoY, TiNiZrHfCoCu – cBNCoNiAlY composites for multi-cycle fatigue during bending with rotation.","PeriodicalId":22032,"journal":{"name":"Surface Innovations","volume":" ","pages":""},"PeriodicalIF":3.5,"publicationDate":"2022-03-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41983406","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High electrical conductivity of Cu wires cladded by Gr/Cu coating Gr/Cu涂层包覆铜线的高导电性
IF 3.5 4区 材料科学
Surface Innovations Pub Date : 2022-03-10 DOI: 10.1680/jsuin.22.00014
K. Wei, Shao Peng Wang, Wei Wei, X. An, Danyang Wang, I. Alexandrov
{"title":"High electrical conductivity of Cu wires cladded by Gr/Cu coating","authors":"K. Wei, Shao Peng Wang, Wei Wei, X. An, Danyang Wang, I. Alexandrov","doi":"10.1680/jsuin.22.00014","DOIUrl":"https://doi.org/10.1680/jsuin.22.00014","url":null,"abstract":"Graphene/copper (Gr/Cu) coating-cladded Cu wires with high electrical conductivity and low surface roughness were successfully prepared from copper sulfate pentahydrate (CuSO4·5 H2O) containing Gr ranging from 0 to 2.0 g/L by direct current electrodeposition. The Gr defect density, surface morphology, surface roughness and electrical conductivity of Gr/Cu coating-cladded Cu wires were investigated. The results revealed that with the increasing Gr concentration the surface roughness and electrical conductivity of Gr/Cu coating-cladded Cu wires were enhanced simultaneously. When the Gr concentration was 1.2 g/L, Gr/Cu coating-cladded Cu wires possessed the lowest surface roughness of 4.241 μm and the highest electrical conductivity of 105.5% IACS. Compared with the counterpart without Gr, the surface roughness was reduced by 10.7%, and the electrical conductivity was increased by 5.4%, respectively. The models were developed to evaluate the surface roughness and electrical conductivity of Gr/Cu coating-cladded Cu wires.","PeriodicalId":22032,"journal":{"name":"Surface Innovations","volume":" ","pages":""},"PeriodicalIF":3.5,"publicationDate":"2022-03-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43480086","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study of surface-enhanced Raman spectroscopy combined with green catalytic derivation scheme for the determination of methanol in alcoholic beverages 表面增强拉曼光谱结合绿色催化衍生方案测定酒精饮料中甲醇的研究
IF 3.5 4区 材料科学
Surface Innovations Pub Date : 2022-03-04 DOI: 10.1680/jsuin.21.00068
Yaping Tian, Xinming Nie, Xun Wang, Zhengyi Chen, Si Chen, Shasha Lv, Shoufeng Tang
{"title":"Study of surface-enhanced Raman spectroscopy combined with green catalytic derivation scheme for the determination of methanol in alcoholic beverages","authors":"Yaping Tian, Xinming Nie, Xun Wang, Zhengyi Chen, Si Chen, Shasha Lv, Shoufeng Tang","doi":"10.1680/jsuin.21.00068","DOIUrl":"https://doi.org/10.1680/jsuin.21.00068","url":null,"abstract":"There are two main challenges in completing the surface-enhanced Raman spectroscopy (SERS) detection. One is the small Raman scattering cross section of methanol and the other is the derivatization strategy. They were solved by coupling the catalytic strategy with a thermal purge separation and enrichment device. In this study, the quantitative analysis of methanol in alcoholic beverages was performed as methanol was catalyzed to formaldehyde. For detecting methanol in low alcoholic beverages, the acetaldehyde derivatives generated by the interaction of ethanol-catalyzed oxide acetaldehyde with 3-Methyl 2-benzothiazolinonehydrazone Hydrochlide Hydrate (MBTH) during the catalytic process will not cause large interference with the SERS signal of formaldehyde. In this case, the MBTH with higher sensitivity is selected for the derivatization operation. In the analysis of methanol in high alcoholic beverages, acetylacetonate derivatization without interaction with acetaldehyde was used to avoid the interference of acetaldehyde generated from ethanol. Based on the detection of formaldehyde in methanol standard solutions, methanol was detected in wine and sake as well as in high-alcohol beverages. Thus, a convenient and rapid method was achieved for the detection of methanol in alcoholic beverages.","PeriodicalId":22032,"journal":{"name":"Surface Innovations","volume":" ","pages":""},"PeriodicalIF":3.5,"publicationDate":"2022-03-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45503951","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Editorial 编辑
IF 3.5 4区 材料科学
Surface Innovations Pub Date : 2022-03-01 DOI: 10.1680/jsuin.2022.10.2.87
J. Drelich, L. Boinovich, Ziqi Sun
{"title":"Editorial","authors":"J. Drelich, L. Boinovich, Ziqi Sun","doi":"10.1680/jsuin.2022.10.2.87","DOIUrl":"https://doi.org/10.1680/jsuin.2022.10.2.87","url":null,"abstract":"","PeriodicalId":22032,"journal":{"name":"Surface Innovations","volume":" ","pages":""},"PeriodicalIF":3.5,"publicationDate":"2022-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"46509140","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tailoring the structural and dielectric properties of low energy ion beam irradiated polymer/silver nanocomposite films 低能离子束辐照聚合物/银纳米复合薄膜的结构和介电性能
IF 3.5 4区 材料科学
Surface Innovations Pub Date : 2022-02-28 DOI: 10.1680/jsuin.22.00010
N. Althubiti, A. Atta, B. M. Alotaibi, M. M. Abdelhamied
{"title":"Tailoring the structural and dielectric properties of low energy ion beam irradiated polymer/silver nanocomposite films","authors":"N. Althubiti, A. Atta, B. M. Alotaibi, M. M. Abdelhamied","doi":"10.1680/jsuin.22.00010","DOIUrl":"https://doi.org/10.1680/jsuin.22.00010","url":null,"abstract":"In this work, flexible nanocomposite films, which are comprised of silver nanoparticles (AgNPs), polyaniline (PANI), and methylcellulose (MC), were manufactured using casting solution fabrication technique. The manufactured films were characterized using X-ray diffraction (XRD) and Fourier transformation infrared (FTIR), which supported the preparation of the composite samples. The MC/PANI/Ag films were then irradiated with oxygen-ion beams at a range of fluence (8x1017, 16x1017, and 24x1017 ions.cm−2). The electrical conductivity, complex impedance behavior, electric modulus, and energy density of pure and irradiated films are determined throughout frequency range of 100 Hz - 5 MHz. The oxygen-beam-irradiation of MC/PANI/Ag films caused a significant modification in dielectric parameters. Also, the dielectric constant ε′ improved from 0.68 to 3.17, and conductivity was modified from 1.47x10−6 S/cm to 25.9x10−6 S/cm. The present study’s findings pave the way for the use of irradiated MC/PANI/Ag nanocomposite films in a variety of applications, including microelectronic devices, batteries, and supercapacitors.","PeriodicalId":22032,"journal":{"name":"Surface Innovations","volume":" ","pages":""},"PeriodicalIF":3.5,"publicationDate":"2022-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41687881","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 6
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