Spectroscopy最新文献

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Hyperspectral Imaging Combined with Convolutional Neural Network for Rapid and Accurate Evaluation of Tilapia Fillet Freshness 高光谱成像与卷积神经网络相结合,快速准确地评估罗非鱼片的新鲜度
IF 0.5 4区 化学
Spectroscopy Pub Date : 2023-12-08 DOI: 10.56530/spectroscopy.ae4768d1
Shuqi Tang, Peng Li, Shenghui Chen, Chunhai Li, Ling Zhang, Nan Zhong
{"title":"Hyperspectral Imaging Combined with Convolutional Neural Network for Rapid and Accurate Evaluation of Tilapia Fillet Freshness","authors":"Shuqi Tang, Peng Li, Shenghui Chen, Chunhai Li, Ling Zhang, Nan Zhong","doi":"10.56530/spectroscopy.ae4768d1","DOIUrl":"https://doi.org/10.56530/spectroscopy.ae4768d1","url":null,"abstract":"The purpose of this work is to achieve rapid and nondestructive determination of tilapia fillets storage time associated with its freshness. Here, we investigated the potential of hyperspectral imaging (HSI) combined with a convolutional neural network (CNN) in the visible and near-infrared region (vis-NIR or VNIR, 397−1003 nm) and the shortwave near-infrared region (SWNIR or SWIR, 935−1720 nm) for determining tilapia fillets freshness. Hyperspectral images of 70 tilapia fillets stored at 4 ℃ for 0–14 d were collected. Various machine learning algorithms were employed to verify the effectiveness of CNN, including partial least-squares discriminant analysis (PLS-DA), K-nearest neighbor (KNN), support vector machine (SVM), and extreme learning machine (ELM). Their performance was compared from spectral preprocessing and feature extraction. The results showed that PLS-DA, KNN, SVM, and ELM require appropriate preprocessing methods and feature extraction to improve their accuracy, while CNN without the requirement of these complex processes achieved higher accuracy than the other algorithms. CNN achieved accuracy of 100% in the test set of VNIR, and achieved 87.30% in the test set of SWIR, indicating that VNIR HSI is more suitable for detection freshness of tilapia. Overall, HSI combined with CNN could be used to rapidly and accurately evaluating tilapia fillets freshness.","PeriodicalId":21957,"journal":{"name":"Spectroscopy","volume":"145 ","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-12-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139011139","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Raman Spectra Used to Understand the Origins of Banding in Spherulites 利用拉曼光谱了解球粒云母带状结构的起源
IF 0.5 4区 化学
Spectroscopy Pub Date : 2023-12-01 DOI: 10.56530/spectroscopy.wu2080k9
Fran Adar
{"title":"Raman Spectra Used to Understand the Origins of Banding in Spherulites","authors":"Fran Adar","doi":"10.56530/spectroscopy.wu2080k9","DOIUrl":"https://doi.org/10.56530/spectroscopy.wu2080k9","url":null,"abstract":"The formation of spherulites in polymers is a well-known phenomenon; when the polymer is crystallized by cooling from the melt, crystal lamellae grow out from a nucleation site in a spherical pattern. If the material is annealed on a planar surface, and viewed between crossed polarizers in a microscope, a Maltese cross with a banding pattern is observed. Where the crystals grow in a direction not parallel to the polarizers, the sample lights up. Often banding of the lit regions is observed, and is believed to be due to rotations of the crystal lamellae around the growth direction. Because it is well known that polarized Raman spectra respond to crystal orientation, we thought it would be interesting to try to document the relationship between the banding behavior and Raman polarization/orientation behavior. In this column I will show results of such an investigation of spherulites of poly(hydroxybutyate-co-hydroxyhexanoate) (PHBHx) with varying composition.","PeriodicalId":21957,"journal":{"name":"Spectroscopy","volume":" 20","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138620236","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-Resolution High-Speed LIBS Microscopy 高分辨率高速 LIBS 显微镜
IF 0.5 4区 化学
Spectroscopy Pub Date : 2023-12-01 DOI: 10.56530/spectroscopy.sr2771p7
A. Tercier, E. Vasileva, C. Alvarez-Llamas, C. Fabre, S. Hermelin, B. Soula, F. Trichard, C. Dujardin, V. Motto-Ros
{"title":"High-Resolution High-Speed LIBS Microscopy","authors":"A. Tercier, E. Vasileva, C. Alvarez-Llamas, C. Fabre, S. Hermelin, B. Soula, F. Trichard, C. Dujardin, V. Motto-Ros","doi":"10.56530/spectroscopy.sr2771p7","DOIUrl":"https://doi.org/10.56530/spectroscopy.sr2771p7","url":null,"abstract":"Laser-induced breakdown spectroscopy (LIBS) imaging instruments typically utilize lasers with repetition rates below 100 Hz since in most cases this regime provides a good balance of sampling frequency and laser pulse energy. However, measuring large sample areas of a several cm2 with high spatial resolution (<10 μm), at this frequency rate would be very time consuming since millions of spectral data points need to be collected in order to create a high-resolution image (3 h–15 h per cm2). In this work, we explore the approach to reduce, the acquisition time for high resolution LIBS imaging, or so-called μ-LIBS imaging, by using a laser operating in the kHz pulse repetition frequency (PRF) range. As a result, we describe and demonstrate a μ-LIBS imaging microscope which can image >6 cm2 sample areas with about 10 μm resolution in significantly shorter time (<20 min/cm2). The developed system opens a potential for variety of application fields where knowledge of elemental composition and elemental distribution is needed to perform conclusive analysis.","PeriodicalId":21957,"journal":{"name":"Spectroscopy","volume":" 76","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138611977","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Inorganics I: Introduction 无机物 I:导论
IF 0.5 4区 化学
Spectroscopy Pub Date : 2023-12-01 DOI: 10.56530/spectroscopy.rp3780c4
Brian C. Smith
{"title":"Inorganics I: Introduction","authors":"Brian C. Smith","doi":"10.56530/spectroscopy.rp3780c4","DOIUrl":"https://doi.org/10.56530/spectroscopy.rp3780c4","url":null,"abstract":"Despite what some people think, inorganics do have mid-infrared spectra. In this column, we will prove this and discuss what inorganic compounds are and describe the general characteristics of their infrared spectra.","PeriodicalId":21957,"journal":{"name":"Spectroscopy","volume":" 10","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-12-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138616734","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Frontiers of NIR Imaging 近红外成像前沿
IF 0.5 4区 化学
Spectroscopy Pub Date : 2023-11-01 DOI: 10.56530/spectroscopy.xg9883t4
Yukihiro Ozaki, M. Ishigaki
{"title":"Frontiers of NIR Imaging","authors":"Yukihiro Ozaki, M. Ishigaki","doi":"10.56530/spectroscopy.xg9883t4","DOIUrl":"https://doi.org/10.56530/spectroscopy.xg9883t4","url":null,"abstract":"After a brief introduction to the technique, this review will discuss the state-of-the-art NIR imaging instrumentation and its applications, including applications of an ordinary NIR imaging system to solvent diffusion into a polymer. Other imaging applications discussed include the use of a portable NIR imaging system in the pharmaceutical industry, high-speed and wide-area monitoring of polymers, and imaging for fish embryos development research. Also discussed is an imaging-type two-dimensional Fourier spectroscopy (ITFS) system and its application to medaka (Japanese rice fish, Oryzias latipes) egg development. Finally, general perspectives on NIR imaging will be provided.","PeriodicalId":21957,"journal":{"name":"Spectroscopy","volume":"16 1","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139291654","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Raman Scattering for Label-Free Chemical Imaging 用于无标记化学成像的拉曼散射
IF 0.5 4区 化学
Spectroscopy Pub Date : 2023-11-01 DOI: 10.56530/spectroscopy.uj1082r1
Zachary D. Schultz
{"title":"Raman Scattering for Label-Free Chemical Imaging","authors":"Zachary D. Schultz","doi":"10.56530/spectroscopy.uj1082r1","DOIUrl":"https://doi.org/10.56530/spectroscopy.uj1082r1","url":null,"abstract":"Raman spectroscopy provides chemical information by detecting light scattered from a monochromatic source (such as a laser) at energies that correspond to molecular vibrations. Because Raman spectroscopy commonly uses visible lasers, the spatial resolution is approximately the same as what can be seen with an optical microscope. First demonstrated in the 1970s, coupling Raman spectroscopy with microscopes enabled the chemical information to be obtained from a focused laser spot. By moving the laser across the sample and recording the Raman spectrum at each location, images can be generated from changes in intensity at different Raman shifts that spatially characterize the molecules present. From the development of the Raman microprobe to today, advances in instrumentation have increased the speed, sensitivity, and spatial resolution of Raman microscopy. This article covers the fundamentals of Raman microscopy and how technological advances are enabling a variety of applications.","PeriodicalId":21957,"journal":{"name":"Spectroscopy","volume":"5 1","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139297317","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Identification and Classification of Degradation-Indicator Grass Species in a Desertified Steppe Based on HSI-UAV 基于 HSI-UAV 的荒漠化草原退化指示草种的识别与分类
IF 0.5 4区 化学
Spectroscopy Pub Date : 2023-11-01 DOI: 10.56530/spectroscopy.dr5881c1
Xinchao Gao, Fei Hao, W. Pi, Xiangbing Zhu, Tao Zhang, Yuge Bi, Yanbin Zhang
{"title":"Identification and Classification of Degradation-Indicator Grass Species in a Desertified Steppe Based on HSI-UAV","authors":"Xinchao Gao, Fei Hao, W. Pi, Xiangbing Zhu, Tao Zhang, Yuge Bi, Yanbin Zhang","doi":"10.56530/spectroscopy.dr5881c1","DOIUrl":"https://doi.org/10.56530/spectroscopy.dr5881c1","url":null,"abstract":"The emergence and number of grassland degradation-indicator grass species are important in evaluating the extent of grassland degradation. Plant populations in desertified steppe are distributed randomly and at low density. Specifically, degradation-indicator grass species mainly exist as individuals, making spectrum-based identification difficult. Here, a low-altitude unmanned aerial vehicle (UAV) hyperspectral remote-sensing system was constructed to identify the typical degradation-indicator grass species of a desertified steppe in China. The ASI index (Artemisia frigida Willd. and Stipa breviflora Grisb. index) and classification rules were proposed and applied. We implemented a comprehensive application of amplified differences in spectral characteristics between vegetation communities and assigned plant senescence reflectance-index bands, using the characteristics of the plant populations under observation and UAV hyperspectral remote-sensing data, to solve the problems resulting from high similarity while identifying ground objects. Our results lay a solid foundation for monitoring and evaluating desertified steppe degradation-indicator grass species based on remote sensing.","PeriodicalId":21957,"journal":{"name":"Spectroscopy","volume":"191 1","pages":""},"PeriodicalIF":0.5,"publicationDate":"2023-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139305090","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Key Steps in the Workflow to Analyze Raman Spectra 关键步骤在工作流程中分析拉曼光谱
4区 化学
Spectroscopy Pub Date : 2023-10-01 DOI: 10.56530/spectroscopy.fl6984w5
Shuxia Guo, Jürgen Popp, Thomas Bocklitz
{"title":"Key Steps in the Workflow to Analyze Raman Spectra","authors":"Shuxia Guo, Jürgen Popp, Thomas Bocklitz","doi":"10.56530/spectroscopy.fl6984w5","DOIUrl":"https://doi.org/10.56530/spectroscopy.fl6984w5","url":null,"abstract":"","PeriodicalId":21957,"journal":{"name":"Spectroscopy","volume":"146 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134935051","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Review and Prospect: Applications of Exponential Signals with Machine Learning in Nuclear Magnetic Resonance 回顾与展望:指数信号与机器学习在核磁共振中的应用
4区 化学
Spectroscopy Pub Date : 2023-09-01 DOI: 10.56530/spectroscopy.yx1073b8
Di Guo, Xianjing Chen, Mengli Lu, Wangfeng He, Sihui Luo, Yanqin Lin, Yuqing Huang, Lizhi Xiao, Xiaobo Qu
{"title":"Review and Prospect: Applications of Exponential Signals with Machine Learning in Nuclear Magnetic Resonance","authors":"Di Guo, Xianjing Chen, Mengli Lu, Wangfeng He, Sihui Luo, Yanqin Lin, Yuqing Huang, Lizhi Xiao, Xiaobo Qu","doi":"10.56530/spectroscopy.yx1073b8","DOIUrl":"https://doi.org/10.56530/spectroscopy.yx1073b8","url":null,"abstract":"Nuclear magnetic resonance (NMR) spectroscopy presents an important analytical tool for composition analysis, molecular structure elucidation, and dynamic study in the fields of chemistry, biomedicine, food science, energy and more. As a basic function, exponential functions can be applied to model NMR signals of free induction decay, relaxation, and diffusion. In this paper, we will review Fourier and Laplace NMR exponential signals separately, as well as the performance of state-of-the-art machine learning on NMR applications.","PeriodicalId":21957,"journal":{"name":"Spectroscopy","volume":"77 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135255511","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Guess Who’s Coming to Inspect R&D? 猜猜谁要来视察研发部门了?
4区 化学
Spectroscopy Pub Date : 2023-09-01 DOI: 10.56530/spectroscopy.cv2490n6
R.D. McDowall
{"title":"Guess Who’s Coming to Inspect R&amp;D?","authors":"R.D. McDowall","doi":"10.56530/spectroscopy.cv2490n6","DOIUrl":"https://doi.org/10.56530/spectroscopy.cv2490n6","url":null,"abstract":"A new revision to the U.S. Food and Drug Administration (FDA)’s Compliance Program Guide for Pre-Approval Inspections (PAIs) has added a fourth objective: Commitment to Quality in Pharmaceutical Development. PAIs are going to be very interesting now.....","PeriodicalId":21957,"journal":{"name":"Spectroscopy","volume":"13 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135255639","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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