Soil SystemsPub Date : 2024-07-04DOI: 10.3390/soilsystems8030075
A. Kintl, Ján Šmeringai, Tomáš Lošák, I. Huňady, Julie Sobotková, Tadeáš Hrušovský, Ladislav Varga, Karel Vejražka, J. Elbl
{"title":"The Effect of Soil Heterogeneity on the Content of Macronutrients and Micronutrients in the Chickpea (Cicer arietinum L.)","authors":"A. Kintl, Ján Šmeringai, Tomáš Lošák, I. Huňady, Julie Sobotková, Tadeáš Hrušovský, Ladislav Varga, Karel Vejražka, J. Elbl","doi":"10.3390/soilsystems8030075","DOIUrl":"https://doi.org/10.3390/soilsystems8030075","url":null,"abstract":"Chickpea (Cicer arietinum L.) is one of the most important legumes currently grown. It is an important source of proteins and nutrients, such as calcium, potassium and iron. As a result, precise crop management is necessary for maximizing its production. The presented study deals with the effect of soil heterogeneity caused by variable contents of macro- and micronutrients on the uptake of nutrients by chickpea. The values measured (contents of macro- and micronutrients in plant samples) indicate that soil heterogeneity is an important factor for the contents of nutrients and soil reactions, which strongly affect the growth of chickpea. We investigated the soil heterogeneity in a chickpea field. Two zones (A and B) with different stand development were found in the model plot. Zone A showed a healthy (green) growth, while Zone B exhibited a yellow-coloured growth, indicating deficits in nutrient uptake. The contents of selected nutrients (P, K, Ca, Mg, Fe, Cu, Zn and Mn) in the soil and in the plant biomass (i.e., stems, leaves, pods and seeds) were analyzed. In the zone with the yellow-coloured biomass, the results showed significantly (p < 0.05) reduced contents of N, P, K, Mg, Fe, Mn, Cu and Zn in the leaves; higher values of soil reaction (pH); and higher contents of calcium and calcium carbonate in the soil. The uptake of nutrients by the plants and their translocation were affected by the above-mentioned soil parameters and by their mutual interactions. Therefore, it is possible to state that soil heterogeneity (caused by variable contents of nutrients in soil) should be taken into account in the precise crop management of chickpeas.","PeriodicalId":21908,"journal":{"name":"Soil Systems","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2024-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141680151","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Soil SystemsPub Date : 2024-07-03DOI: 10.3390/soilsystems8030074
S. Thai, L. Pavlů, Petra Vokurková, Bunthorn Thet, Kateřina Vejvodová, O. Drábek, V. Tejnecký
{"title":"Changes in the Composition of Soil Organic Matter after the Transformation of Natural Beech Stands into Spruce Monoculture","authors":"S. Thai, L. Pavlů, Petra Vokurková, Bunthorn Thet, Kateřina Vejvodová, O. Drábek, V. Tejnecký","doi":"10.3390/soilsystems8030074","DOIUrl":"https://doi.org/10.3390/soilsystems8030074","url":null,"abstract":"The composition of soil organic matter is considered to have a key influence on C sequestration and global climate change and can be associated with changes in vegetation cover in the terrestrial ecosystem. Our study aimed to evaluate the soil chemical structures and various organic components from available or reactive to more stable forms in forest soils affected by acidification and after conversion from fairly close to natural beech (Fagus sylvatica) stands to a spruce (Picea abies) monoculture. Our results revealed that the beech stands had higher contents of dissolved organic carbon and low molecular mass organic acid compared to the spruce stands. The aliphatic CH groups within the soluble alkaline-extractable organic substance (AEOS) gradually disappeared with deeper soil horizons under both forest species, while the presence of aliphatic CH groups in the low-solubility AEOS was more pronounced in the A horizon under spruce and relatively increased with depth under beech stands. The carboxylic groups were more prevalent in deeper soil horizons, while polysaccharide chains and nitrogen functional groups decreased with depth under both forest stands but were more prevalent under beech than under spruce stands. These findings suggest that the stability of organic matter through the forest soil profiles increased due to the transformation of various organic compounds from litter to more stable organic matter with higher amounts of lignin components to greater amounts of carboxylic groups and aromatic groups in deeper soil horizons. Furthermore, a higher number of mobile components of soil organic matter and carboxylic acids, together with lower pH and cation exchange capacity under spruce, resulted in the leaching of nutrients, releasing risk elements into the soil solution and accelerating the podzolization process.","PeriodicalId":21908,"journal":{"name":"Soil Systems","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2024-07-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141683422","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Soil SystemsPub Date : 2024-06-14DOI: 10.3390/soilsystems8020066
Muhammad Qaswar, Danyal Bustan, A. M. Mouazen
{"title":"Economic and Environmental Assessment of Variable Rate Nitrogen Application in Potato by Fusion of Online Visible and Near Infrared (Vis-NIR) and Remote Sensing Data","authors":"Muhammad Qaswar, Danyal Bustan, A. M. Mouazen","doi":"10.3390/soilsystems8020066","DOIUrl":"https://doi.org/10.3390/soilsystems8020066","url":null,"abstract":"Addressing within-field spatial variability for nitrogen (N) management to avoid over and under-use of nitrogen is crucial for optimizing crop productivity and ensuring environmental sustainability. In this study, we investigated the economic, environmental, and agronomic benefits of variable rate nitrogen application in potato (Solanum tuberosum L.). An online visible and near-infrared (vis-NIR) spectroscopy sensor was utilized to predict soil moisture content (MC), pH, total organic carbon (TOC), extractable phosphorus (P), potassium (K), magnesium (Mg), and cation exchange capacity (CEC) using a partial least squares regression (PLSR) models. The crop’s normalized difference vegetation index (NDVI) from Sentinel-2 satellite images was incorporated into online measured soil data to derive fertility management zones (MZs) maps after homogenous raster and clustering analyses. The MZs maps were categorized into high fertile (VR-H), medium–high fertile (VR-MH), medium–low fertile (VR-ML), and low fertile (VR-L) zones. A parallel strip experiment compared variable rate nitrogen (VR-N) with uniform rate (UR) treatments, adjusting nitrogen levels based on fertility zones as 50% less for VR-H, 25% less for VR-MH, 25% more for VR-ML, and 50% more for VR-L zones compared to the UR treatment. The results showed that the VR-H zone received a 50% reduction in N fertilizer input and demonstrated a significantly higher crop yield compared to the UR treatment. This implies a potential reduction in negative environmental impact by lowering fertilizer costs while maintaining robust crop yields. In total, the VR-N treatment received an additional 1.2 Kg/ha of nitrogen input, resulting in a crop yield increase of 1.89 tons/ha. The relative gross margin for the VR-N treatment compared to the UR treatment is 374.83 EUR/ha, indicating substantial profitability for the farmer. To further optimize environmental benefits and profitability, additional research is needed to explore site-specific applications of all farm resources through precision agricultural technologies.","PeriodicalId":21908,"journal":{"name":"Soil Systems","volume":null,"pages":null},"PeriodicalIF":3.5,"publicationDate":"2024-06-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141343543","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Soil SystemsPub Date : 2024-06-13DOI: 10.3390/soilsystems8020064
D. Bharti, Santosh Kumar, C. K. Basuri, A. La Terza
{"title":"Ciliated Protist Communities in Soil: Contrasting Patterns in Natural Sites and Arable Lands across Italy","authors":"D. Bharti, Santosh Kumar, C. K. Basuri, A. La Terza","doi":"10.3390/soilsystems8020064","DOIUrl":"https://doi.org/10.3390/soilsystems8020064","url":null,"abstract":"This study represents the first investigation of soil ciliate diversity and community structure in the Marche region, Italy, encompassing both natural sites and agro-ecosystems. The main aims were (i) to assess the ability of ciliates to discriminate between different types of land uses, i.e., arable lands and possible farming management practices [organic (ORG) vs. conventional (CON)], and forest (FOR) sites; and (ii) to investigate the relationships among ciliate communities and abiotic parameters at the studied sites. Soil samples were collected twice from 10 sites (5 forest (FOR) (natural soils) and 5 arable lands under different agricultural management systems (3 ORG (minimum tillage) and 2 CON (sod seeding)). Ciliate communities were studied using qualitative (non-flooded Petri dish) and quantitative methods (ciliate counts from permanent slides). Soil chemical–physical (texture, CEC, N, OM, C/N) parameters were also measured. Qualitative ciliate analysis allowed us to identify a total of 59 species representing 33 genera, 20 families, 13 orders, and 7 classes. ORG sites were the richest in species followed by CON and FOR. Multivariate analysis showed statistically significant differences between natural sites (FOR) and agricultural sites, and between ORG and CON management farming systems. CCA analysis revealed a positive correlation between the ciliate species and silt, clay, and pH in ORG sites, and sand, organic carbon, organic matter, total nitrogen, C/N ratio, and CEC (cation exchange capacity) in FOR sites, suggesting the significance of these parameters in shaping the ciliate communities. Altogether, these results showed the bioindicative potential of ciliate communities in discriminating between natural sites (FOR) and arable lands, and their capacity to discriminate, at least preliminarily, between different soil management systems (ORG vs. CON). Furthermore, this study highlights the high diversity of soil ciliates and their response to habitat variability.","PeriodicalId":21908,"journal":{"name":"Soil Systems","volume":null,"pages":null},"PeriodicalIF":3.5,"publicationDate":"2024-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141349191","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Soil SystemsPub Date : 2024-06-13DOI: 10.3390/soilsystems8020065
Melania Merlo Ziviani, É. F. M. Pinheiro, Marcos Bacis Ceddia, Ana Carolina Souza Ferreira, Frederico Santos Machado
{"title":"Carbon and Nitrogen Stocks and Soil Organic Matter Persistence under Native Vegetation along a Topographic and Vegetation Gradient in the Central Amazon Region","authors":"Melania Merlo Ziviani, É. F. M. Pinheiro, Marcos Bacis Ceddia, Ana Carolina Souza Ferreira, Frederico Santos Machado","doi":"10.3390/soilsystems8020065","DOIUrl":"https://doi.org/10.3390/soilsystems8020065","url":null,"abstract":"The Amazon Forest has a soil organic carbon stock (SOCS) potential of 126 to 141 Tg year−1 and it depends on soil organic matter (SOM) accumulation factors and stabilization mechanisms. This study aimed to evaluate SOCS, soil nitrogen stocks (SNS), SOM fractions under the Amazon Forest along a topographic and vegetation gradient (Terra Firme, River Plain, and Terraces), and to evaluate the main mechanisms responsible for SOM stabilization. The study was developed using 35 study points (35 profiles) in Coari County, Amazon State, Brazil. In each profile, soil samples were collected from soil horizon for soil analysis. Of the 35 soil profiles, 10 were selected to evaluate the contribution of free light fractions (FLF) and intra-aggregate light fractions (ILF), C and N contents, and SOCS and SNS up to 1 m soil depth. SOCS and SNS are influenced by topographic and vegetation gradient, being statistically equal in the Terra Firme and River Plains areas (median of 92.5 and 92.2 Mg C ha−1, respectively), but Terraces presented a greater median (157.9 Mg C ha−1). There are relationships between SOCS and SNS and C, N, Al, clay content, t value, FLF, and ILF. SOCS, SNS, and SOM stabilization in Amazon soils are influenced by soil properties and landscape position. SOCS in the Terrace is mainly in FLF form. If vegetation cover loss continues, an amount of up to 98.05 Mg C ha−1 of FLF can be lost, causing soil degradation and global warming.","PeriodicalId":21908,"journal":{"name":"Soil Systems","volume":null,"pages":null},"PeriodicalIF":3.5,"publicationDate":"2024-06-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141349430","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Soil SystemsPub Date : 2024-06-12DOI: 10.3390/soilsystems8020063
Natal’ya V. Matveeva, Andrei V. Garmash, Mikhail A. Shishkin, A. Dymov, O. Rogova, D. S. Volkov, M. Proskurnin
{"title":"Fast High-Resolution pKa Spectrotitrimetry for Quantification of Surface Functional Groups of Retisols","authors":"Natal’ya V. Matveeva, Andrei V. Garmash, Mikhail A. Shishkin, A. Dymov, O. Rogova, D. S. Volkov, M. Proskurnin","doi":"10.3390/soilsystems8020063","DOIUrl":"https://doi.org/10.3390/soilsystems8020063","url":null,"abstract":"Potentiometric titration in a fast and simultaneously high-resolution modality was proposed for the identification and quantification of protolytic groups of variable strength at the surface of primary soil particles. The method is implemented by titrimetric data processing as multicomponent spectra (pKa spectrotitrimetry). Due to the high resolution, the error of acidity-constant assessment (3–5%) is lower, compared to existing approaches; due to the fast titration, the effect of soil hydrolysis is minimized. The soil profiles for acidic Retisols (podzolic soils)—under a spruce crown and in the intercrown space—were studied. These soils, which have similar bulk properties and genesis but developed under different plant covers, were distinguished by pKa spectral features at 4–5; 5.5–6.5; 6.5–8.5; 7.5–8.5; and 9–10, as well as total group concentrations. Differences in acidic and basic-group distribution (carboxyl groups, amorphous aluminosilicates, carbonate species, amino groups, soluble (poly)phenolic compounds, phospholipids) and Al and Fe complex compounds within the same soil profiles and between two Retisols were found and quantified. The acidity constants and group concentrations found by pKa spectrotitrimetry were compared with conventional soil-composition indicators (total organic carbon, oxalate-soluble Fe and Al, and phosphorus), using principal component analysis. The main correlations are between the concentrations of oxalate-soluble Al and groups with pKa values of 5.0–6.5 and 8.5; oxalate-soluble Fe and pKa values of 9.0–10.0; and P2O5 and pKa values of 4.0–6.0 and 6.5–8.5. The method provides a set of major acidity values without a priori information on a soil sample and can be used for screening and identifying similar soils.","PeriodicalId":21908,"journal":{"name":"Soil Systems","volume":null,"pages":null},"PeriodicalIF":3.5,"publicationDate":"2024-06-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141353827","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effectiveness of Bacillus paramycoides for Improving Zinc Nutrition of Rice Irrigated with Alkali Water","authors":"Awtar Singh, Arvind Kumar Rai, Madhu Choudhary, Arijit Barman, R. K. Fagodiya, Rajender Kumar Yadav, Prakash Kumar Jha, Pankaj Kumar Gupta","doi":"10.3390/soilsystems8020062","DOIUrl":"https://doi.org/10.3390/soilsystems8020062","url":null,"abstract":"Worldwide zinc deficiency in the soil under cereal production is a common problem affecting the yield and nutritional value of several crops. Bioaugmentation of soil zinc with zinc-solubilizing bacteria can be a promising option for increasing the zinc nutrition to crops. The objectives of the study were to evaluate Bacillus paramycoides for improving yield, zinc nutrition, and zinc availability in rice grown under sodicity stress caused by alkali water irrigation. Treatments included T1: control, T2: substrate, T3: Bacillus paramycoides, T4: control (T1) + zinc sulphate, T5: substrate (T2) + zinc sulphate, and T6: Bacillus paramycoides (T3) + zinc sulphate. Rice yield, zinc content, and uptake, and apparent zinc recovery were not altered by Bacillus paramycoides. The different fractions of zinc measured after 30 and 60 days after transplanting of the rice remain unaffected by the inoculation of Bacillus paramycoides. Further, an equal number of zinc-solubilizing bacteria present in the rice rhizosphere of control plots after 30 days of transplanting suggests the importance of the native rhizospheric microbiome in zinc nutrition. It is concluded that the application of Bacillus paramycoides in sodicity-stressed rice did not provided additional benefits in terms of zinc nutrition and yield. Further investigation will be required to improve the apparent zinc recovery of crops in those areas, where alkali water is continuously utilized for irrigation.","PeriodicalId":21908,"journal":{"name":"Soil Systems","volume":null,"pages":null},"PeriodicalIF":3.5,"publicationDate":"2024-06-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141376888","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Soil SystemsPub Date : 2024-05-21DOI: 10.3390/soilsystems8020058
A. Šimonovičová, E. Pauditsová, S. Nosalj, Medetbay Oteuliev, Nikola Klištincová, Francesca Maisto, L. Kraková, Jelena Pavlović, Katarína Šoltys, D. Pangallo
{"title":"Fungal and Prokaryotic Communities in Soil Samples of the Aral Sea Dry Bottom in Uzbekistan","authors":"A. Šimonovičová, E. Pauditsová, S. Nosalj, Medetbay Oteuliev, Nikola Klištincová, Francesca Maisto, L. Kraková, Jelena Pavlović, Katarína Šoltys, D. Pangallo","doi":"10.3390/soilsystems8020058","DOIUrl":"https://doi.org/10.3390/soilsystems8020058","url":null,"abstract":"Due to the falling water level in the Aral Sea and Muynak Lake, the content of salts dissolved in the water has gradually increased, and toxic elements have been deposited at the lake’s bottom and subsequently washed into the Aral region by the river. Bacteria, archaea and fungi are crucial for the cycling of several important inorganic nutrients in soils. From 15 genera and 31 species of recovered microscopic filamentous fungi, a big group was melanized, of which most of them were also phytopathogenic. The second group consisted of keratinophilic species. Isolated bacteria mainly included members of the genera Arthrobacter, Bacillus, Massilia, Rhodococcus and Nocardiopsis. High-throughput sequencing analysis permitted a better view of the mycobiome and prokaryotic communities (comprising archaea). The cultivation and sequencing approaches were shown to be complementary. The aim of the work was to identify soil microorganisms, including the order Halobacteriales, and to discover the differences in species diversity depending on soil salinity and the presence of PTEs in soil.","PeriodicalId":21908,"journal":{"name":"Soil Systems","volume":null,"pages":null},"PeriodicalIF":3.5,"publicationDate":"2024-05-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141114573","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Soil SystemsPub Date : 2024-05-17DOI: 10.3390/soilsystems8020057
Bayezid M. Khan, M. Ferdous Alam, Zinnat A. Begum, Ismail M. M. Rahman
{"title":"Growth Responses of Holcus lanatus L. (Velvet Grass) in Soils Contaminated with Cesium or Strontium","authors":"Bayezid M. Khan, M. Ferdous Alam, Zinnat A. Begum, Ismail M. M. Rahman","doi":"10.3390/soilsystems8020057","DOIUrl":"https://doi.org/10.3390/soilsystems8020057","url":null,"abstract":"Radiocesium (r-Cs) and radiostrontium (r-Sr) released from nuclear accidents (e.g., Chornobyl, Fukushima) and routine operations (reactors, reprocessing) pose environmental and health concerns. Their primary pathway to humans is through plant uptake and subsequent bioaccumulation within the food chain. While soil amendments with potassium (K) and calcium (Ca) are known to mitigate r-Cs and r-Sr uptake, respectively, the impact on plant growth remains unclear. This study investigates the effects of Cs and Sr on the growth of Holcus lanatus L. seedlings under hydroponic and soil conditions with varying Cs and Sr concentrations. Stable isotopes of Cs and Sr served as non-radioactive analogs. Seedling growth was assessed across a range of Cs and Sr concentrations (≤1 and ≥4 mg L⁻¹). The impact of the addition of K and Ca on Cs/Sr uptake in amended soils was also evaluated. Additionally, this study examined how Cs and Sr amendments affected the influx rates of other nutrients in H. lanatus. Higher Cs and Sr concentrations (≥4 mg L⁻¹) significantly inhibited seedling growth, while lower concentrations had no effect. Notably, H. lanatus exhibited moderate Cs tolerance and strong Sr tolerance. Furthermore, K and Ca supplementation in Cs/Sr-amended soils demonstrably reduced plant uptake of these elements. This study also observed alterations in the uptake rates of other nutrients within H. lanatus due to Cs/Sr addition. This study suggests that H. lanatus exhibits moderate tolerance to Cs and Sr contamination, potentially making it suitable for revegetation efforts in contaminated grasslands. Additionally, K and Ca amendments show promise as a strategy to mitigate plant uptake of these radioisotopes further. These findings contribute to the development of safer revitalization strategies for areas impacted by nuclear accidents.","PeriodicalId":21908,"journal":{"name":"Soil Systems","volume":null,"pages":null},"PeriodicalIF":3.5,"publicationDate":"2024-05-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140962499","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Soil SystemsPub Date : 2024-05-17DOI: 10.3390/soilsystems8020056
Shayan Kabiri, Nick M. Holden, Rory P. Flood, Jonathan N. Turner, Sharon M. O’Rourke
{"title":"X-ray Fluorescence Core Scanning for High-Resolution Geochemical Characterisation of Soils","authors":"Shayan Kabiri, Nick M. Holden, Rory P. Flood, Jonathan N. Turner, Sharon M. O’Rourke","doi":"10.3390/soilsystems8020056","DOIUrl":"https://doi.org/10.3390/soilsystems8020056","url":null,"abstract":"X-ray fluorescence (XRF) core scanners are commonly used for fine-scale geochemical analysis in sediment studies, but data are semi-quantitative and require calibration to convert geochemical element counts to concentrations. Application of XRF core scanning in soil science remains largely untapped. This study employed an ITRAX core scanner to scan grassland soil cores and developed a novel calibration method based on a chemometric approach to characterise soil geochemistry. As soil samples are collected based on depth sampling, this study investigated whether higher resolution element concentrations could be inferred from lower resolution reference samples and if regression models from multiple cores could apply to a new core at the same resolution. Reference concentrations were obtained for all cores at 10 cm intervals, with validation conducted at 1 cm for a single core. Two calibration curve types were proposed: one based on the single core’s 10 cm data to validate references at 1 cm intervals; and another using all cores, with each core serving as a test item after exclusion from the training set. Various preprocessing measures and feature selection techniques were tested. Results showed successful calibration for elements Ca, P, Zn, Sr, and S, with high R2 values of 0.94, 0.93, 0.93, 0.92 and 0.91, respectively. The study presents a novel method for calibrating XRF core scanning element counts, demonstrating its potential for high-resolution soil analysis.","PeriodicalId":21908,"journal":{"name":"Soil Systems","volume":null,"pages":null},"PeriodicalIF":3.5,"publicationDate":"2024-05-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141126626","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}