Maider Zarrabeitia, Javier Carretero-González, Michal Leskes, Henry Adenusi, Boyan Iliev, Thomas J. S. Schubert, Stefano Passerini, Elizabeth Castillo-Martínez
{"title":"Could potassium-ion batteries become a competitive technology?","authors":"Maider Zarrabeitia, Javier Carretero-González, Michal Leskes, Henry Adenusi, Boyan Iliev, Thomas J. S. Schubert, Stefano Passerini, Elizabeth Castillo-Martínez","doi":"10.20517/energymater.2023.41","DOIUrl":"https://doi.org/10.20517/energymater.2023.41","url":null,"abstract":"Potassium-ion batteries (PIBs) have attracted significant attention as a complement to lithium-ion and sodium-ion batteries (SIBs). PIBs can theoretically provide higher specific energy and power density than SIBs due to lower standard electrode potential of K/K+ and faster K+ ion diffusion, maintaining the benefits of low-cost and sustainability. However, research on PIBs is in its infancy; therefore, further efforts are necessary to enhance their performance and position them as a competitive technology. In this perspective, the remaining challenges and possible strategies to advance the development of PIBs are presented.","PeriodicalId":21863,"journal":{"name":"Solar Energy Materials","volume":"57 7","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135875135","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Theoretical evidence of self-intercalated 2D materials for battery and electrocatalytic applications","authors":"Ke Fan, Yuen Hong Tsang, Haitao Huang","doi":"10.20517/energymater.2023.43","DOIUrl":"https://doi.org/10.20517/energymater.2023.43","url":null,"abstract":"Covalently bonded two-dimensional (2D) self-intercalated transition metal chalcogenides (i.e., ic-2Ds) have been recently fabricated experimentally, and their properties are highly tunable by stoichiometry and composition. Inspired by this progress, we focus on the applications of ic-2Ds in the field of electrochemistry and systematically investigate their performance in lithium-ion batteries (LIBs) and electrocatalytic hydrogen evolution reactions (HER). By means of density functional theory calculations, seven 3d -metal ic-2Ds are confirmed to be thermodynamically, mechanically, and thermally stable. The metallicity and abundant active sites endow these ic-2Ds with the potential as excellent electrode materials and HER catalysts. Among them, Ti7S12 and V7S12 exhibit the potential as anode materials for LIBs, showing low Li diffusion energy barriers, suitable open-circuit voltages, and ultrahigh capacity of 745.6 and 723.9 mA hg-1, respectively; Cr7S12 and Co7S12 show promises for HER with moderate hydrogen adsorption strengths. This theoretical study provides a new avenue for the application of newly reported ic-2Ds in various electrochemical energy conversion and storage applications.","PeriodicalId":21863,"journal":{"name":"Solar Energy Materials","volume":"8 6","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135875716","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Seonghun Jeong, Van-Chuong Ho, Ohmin Kwon, Yuwon Park, Junyoung Mun
{"title":"High-stability room temperature ionic liquids: enabling efficient charge transfer in solid-state batteries by minimizing interfacial resistance","authors":"Seonghun Jeong, Van-Chuong Ho, Ohmin Kwon, Yuwon Park, Junyoung Mun","doi":"10.20517/energymater.2023.47","DOIUrl":"https://doi.org/10.20517/energymater.2023.47","url":null,"abstract":"Currently, intensive research is underway to develop stable electrolyte systems that can significantly enhance the performance of rechargeable batteries. Recent advances in solid electrolytes have led to new types of promising systems owing to their high conductivity. This has generated considerable interest in the practical applications of safe batteries. Considering the safety concerns associated with rechargeable batteries, solid electrolytes have become indispensable for the advancement of next-generation battery technologies. However, the increased interfacial resistance at solid-solid interfaces has become a critical challenge. To address this problem, room-temperature ionic liquids (RTILs) have been investigated as functional materials for mitigating the interfacial resistance in solid-state batteries (SSBs). The special properties of RTILs, such as their non-volatility, non-flammability, and high safety characteristics, make them highly promising candidates for safe batteries. Various approaches have been explored for the effective utilization of ionic liquids in SSBs. This review provides a comprehensive discussion on the application of RTILs as electrolytes, considering their electrochemical properties and incorporation into composites to minimize resistance in SSBs.","PeriodicalId":21863,"journal":{"name":"Solar Energy Materials","volume":"42 7","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-11-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135934760","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Protective behavior of phosphonate-functionalized imidazolium ionic liquid and its impact on the Li-ion battery performance","authors":"Kaisi Liao, Jingbo Song, Jiawen Ge, Jia Si, Yinxiao Cai, Zijuan Luo, Mingjiong Zhou, Hongze Liang, Ya-Jun Cheng, Marija Milanovic, Atsushi Inoishi, Shigeto Okada","doi":"10.20517/energymater.2023.33","DOIUrl":"https://doi.org/10.20517/energymater.2023.33","url":null,"abstract":"The commercial lithium-ion batteries (LIBs) rely on lithium hexafluorophosphate (LiPF6), which is extremely sensitive to moisture and liable to thermal decomposition. Lithium bis (trifluoro methane sulfonyl) imide (LiTFSI), as a promising electrolyte salt, possesses high thermal stability and excellent moisture tolerance. However, LiTFSI is closely related to severe corrosion of the aluminum (Al) current collector at high voltage. Herein, phosphonate-functionalized imidazolium ionic liquid (PFIL) is developed and utilized as an electrolyte co-solvent to inhibit the oxidative dissolution of the Al current collector. PFIL can suppress Al corrosion by participating in the interface reaction and forming a stable and reliable protective film on the surface of Al foils, as confirmed by X-ray photoelectron spectroscopy. Thanks to the corrosion suppression of the Al current collector, the Li||LiNi0.8Mn0.1Co0.1O2 (NCM811) cells with PFIL-containing electrolytes exhibit better cycling performance and improved capacity retention. This work proposes an effective strategy for the advancement of high-voltage LIBs and contributes to promoting the widespread use of the sulfone imide-based lithium salts.","PeriodicalId":21863,"journal":{"name":"Solar Energy Materials","volume":"5 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136291810","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Shifei Kang, Jinmin Cheng, Weikang Gao, Lifeng Cui
{"title":"Toward safer lithium metal batteries: a review","authors":"Shifei Kang, Jinmin Cheng, Weikang Gao, Lifeng Cui","doi":"10.20517/energymater.2023.24","DOIUrl":"https://doi.org/10.20517/energymater.2023.24","url":null,"abstract":"The energy density of conventional graphite anode batteries is insufficient to meet the requirement for portable devices, electric cars, and smart grids. As a result, researchers have diverted to lithium metal anode batteries. Lithium metal has a theoretical specific capacity (3,860 mAh·g-1) significantly higher than that of graphite. Additionally, it has a lower redox potential of -3.04 V compared to standard hydrogen electrodes. These properties make high-energy lithium metal batteries a promising candidate for next-generation energy storage devices, which have garnered significant interest for several years. However, the high activity of lithium metal anodes poses safety risks (e.g., short circuits and thermal runaway) that hinder their commercial growth. Currently, modification of reversible lithium anodes is the primary focus of lithium metal batteries. This article presents conceptual models and numerical simulations that address failure processes and offer specific techniques to mitigate the challenges of lithium metal anodes, including electrolyte design, interface engineering, and electrode modification. It is expected that lithium metal batteries will recover and become a feasible energy storage solution.","PeriodicalId":21863,"journal":{"name":"Solar Energy Materials","volume":"46 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135094804","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Lei Yang, Jingwei Chen, Sangbaek Park, Huanlei Wang
{"title":"Recent progress on metal-organic framework derived carbon and their composites as anode materials for potassium-ion batteries","authors":"Lei Yang, Jingwei Chen, Sangbaek Park, Huanlei Wang","doi":"10.20517/energymater.2023.29","DOIUrl":"https://doi.org/10.20517/energymater.2023.29","url":null,"abstract":"Potassium-ion batteries (PIBs) are considered as promising alternatives to lithium-ion batteries (LIBs) due to their abundant potassium resources, cost-effectiveness, and comparable electrochemical performance to LIBs. However, the practical application of PIBs is hindered by the slow dynamics and large volume expansion of anode materials. Owing to their unique morphology, rich pores, abundant active sites, and tunable composition, metal-organic framework (MOF)-derived carbon and its composites have been widely studied and developed as PIB anodes. In this review, the basic configuration, performance evaluation indicators, and energy storage mechanisms of PIBs were first introduced, followed by a comprehensive summary of the research progress in MOF-derived carbon and its composites, especially the design strategies and different types of composites. Moreover, the advances of in situ characterization techniques to understand the electrochemical mechanism during potassiation/depotassiation were also highlighted, which is crucial for the directional optimization of the electrochemical performance of PIBs. Finally, the challenges and development prospects of MOF-derived carbon and its composites for PIBs are prospected. It is envisioned that this review will guide and inspire more research efforts toward advanced MOF-derived PIB anode materials in the future.","PeriodicalId":21863,"journal":{"name":"Solar Energy Materials","volume":"3 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135197526","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Highly fluorinated co-solvent enabling ether electrolyte for high-voltage lithium ion batteries with graphite anode","authors":"Ruo Wang, Haonan Wang, Huajun Zhao, Mingman Yuan, Zhongbo Liu, Guangzhao Zhang, Tong Zhang, Yunxian Qian, Jun Wang, Iseult Lynch, Yonghong Deng","doi":"10.20517/energymater.2023.28","DOIUrl":"https://doi.org/10.20517/energymater.2023.28","url":null,"abstract":"Conventional ether electrolytes are generally considered unsuitable for use with graphite anodes and high-voltage cathodes due to their co-intercalation with graphite and poor oxidation stability, respectively. In this work, a highly fluorinated ether molecule, 1,1,1-trifluoro-2-[(2,2,2-trifluoroethoxy) methoxy] ethane (TTME), is introduced as a co-solvent into the conventional ether system to construct a fluorinated ether electrolyte, which not only avoids the co-intercalation with graphite but also is compatible with high-voltage cathodes. Li||graphite half-cells using the fluorinated ether electrolyte deliver stable cycling with a capacity retention of 91.7% for 300 cycles. Moreover, LiNi0.8Co0.1Mn0.1O2 (NCM811)||graphite and LiCoO2 (LCO)||graphite full-cells (cathode loadings are ≈3 mAh/cm2) with the fluorinated ether electrolyte show capacity retentions of > 90% over 200 cycles with a charge cut-off voltage of 4.4 V and > 97% for 100 cycles with a charge cut-off voltage of 4.5 V, respectively. The dense and firm solid electrolyte interphase (SEI) and cathode electrolyte interphase (CEI) formed by the fluorinated ether electrolyte on the anode and cathode, respectively, are key to excellent cell performance. These results have significance for the subsequent application of ether electrolytes for high-voltage lithium ion batteries (up to 4.5 V) with graphite anodes.","PeriodicalId":21863,"journal":{"name":"Solar Energy Materials","volume":"1789 1","pages":"0"},"PeriodicalIF":0.0,"publicationDate":"2023-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135253609","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
M. Salado, Marco Amores, C. Pozo‐Gonzalo, Maria Forsyth, S. Lanceros‐Méndez
{"title":"Advanced and sustainable functional materials for potassium-ion batteries","authors":"M. Salado, Marco Amores, C. Pozo‐Gonzalo, Maria Forsyth, S. Lanceros‐Méndez","doi":"10.20517/energymater.2023.36","DOIUrl":"https://doi.org/10.20517/energymater.2023.36","url":null,"abstract":"Rechargeable potassium-ion batteries (PIBs) have gained attention as sustainable, environmentally friendly, and cost-effective large-scale stationary energy storage technology. However, although this technology was assumed to perform in a manner similar to that of its monovalent counterparts, huge anode volume expansion and sluggish kinetics are posing challenges in up-scaling it. Apart from the efforts to develop and optimise electrode materials, recent research endeavours have also focussed on the essential role of sustainability. These attempts have often relied on bio-derived and bio-inspired materials to mimic the effectiveness of nature. Furthermore, the use of materials with self-healing properties can alleviate electrode degradation after cycling and augment its electrochemical performance. This review summarises the development of smart materials with self-healing properties that aid in overcoming the present issues of PIBs and highlights the relevance of the interphases. In addition, state-of-the-art design strategies for bio-derived and bio-inspired materials are presented and discussed. The incorporation of recycled and sustainable materials into the manufacturing of PIBs is expected to contribute towards the ultimate goal of achieving truly circular economy ecosystems. Finally, perspectives for further advancements are provided to kindle new ideas and open questions regarding the use of new-generation materials in the development of PIBs.","PeriodicalId":21863,"journal":{"name":"Solar Energy Materials","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"81928886","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
V. Shipitsyn, Nicholas Antrasian, Vijayendra Soni, Linqin Mu, Lin Ma
{"title":"Fundamentals and perspectives of electrolyte additives for non-aqueous Na-ion batteries","authors":"V. Shipitsyn, Nicholas Antrasian, Vijayendra Soni, Linqin Mu, Lin Ma","doi":"10.20517/energymater.2023.22","DOIUrl":"https://doi.org/10.20517/energymater.2023.22","url":null,"abstract":"Despite extensive research efforts to develop non-aqueous sodium-ion batteries (SIBs) as alternatives to lithium-based energy storage battery systems, their performance is still hindered by electrode-electrolyte side reactions. As a feasible strategy, the engineering of electrolyte additives has been regarded as one of the effective ways to address these critical problems. In this review, we provide a comprehensive overview of recent progress in electrolyte additives for non-aqueous SIBs. We classify the additives based on their effects on specific electrode materials and discuss the functions and mechanisms of each additive category. Finally, we propose future directions for electrolyte additive research, including studies on additives for improving cell performance under extreme conditions, optimizing electrolyte additive combinations, understanding the effect of additives on cathode-anode interactions, and understanding the characteristics of electrolyte additives.","PeriodicalId":21863,"journal":{"name":"Solar Energy Materials","volume":"41 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84962153","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Junli Shi, Huu‐Dat Nguyen, Zhen Chen, Rui Wang, Dominik Steinle, L. Barnsley, Jie Li, H. Frielinghaus, D. Bresser, C. Iojoiu, Elie Paillard
{"title":"Nanostructured block copolymer single-ion conductors for low-temperature, high-voltage and fast charging lithium-metal batteries","authors":"Junli Shi, Huu‐Dat Nguyen, Zhen Chen, Rui Wang, Dominik Steinle, L. Barnsley, Jie Li, H. Frielinghaus, D. Bresser, C. Iojoiu, Elie Paillard","doi":"10.20517/energymater.2023.27","DOIUrl":"https://doi.org/10.20517/energymater.2023.27","url":null,"abstract":"Herein, a single-ion polymer electrolyte is reported for high-voltage and low-temperature lithium-metal batteries that enables suppressing the growth of dendrites, even at high current densities of 2 mA cm-2. The nanostructured electrolyte was introduced into the cell by mechanically processing the polymer powder via an easily scalable process. Important for the potential application in commercial battery cells is the finding that it does not induce aluminum corrosion at high voltages and leads to low interfacial resistance with lithium metal. These beneficial characteristics, in combination with its high single-ion conductivity and its high anodic stability, allow for the stable cycling of state-of-the-art lithium-ion cathodes, such as NMC111 and NMC622, in combination with a lithium metal anode at 20 °C and even 0 °C for several hundred cycles.","PeriodicalId":21863,"journal":{"name":"Solar Energy Materials","volume":"59 3 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2023-07-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89754488","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}