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Aminated cellulose-GO-Doped manganese ferrite Nanosorbent with Enhanced adsorption properties of Diclofenac: Isotherm, kinetic, and Thermodynamic Study 具有增强双氯芬酸吸附特性的掺锰铁氧体纤维素纳米吸附剂:等温线、动力学和热力学研究
IF 2.8 4区 工程技术
Separation Science and Technology Pub Date : 2023-11-16 DOI: 10.1080/01496395.2023.2279948
Maryam Malmir, F. Shemirani
{"title":"Aminated cellulose-GO-Doped manganese ferrite Nanosorbent with Enhanced adsorption properties of Diclofenac: Isotherm, kinetic, and Thermodynamic Study","authors":"Maryam Malmir, F. Shemirani","doi":"10.1080/01496395.2023.2279948","DOIUrl":"https://doi.org/10.1080/01496395.2023.2279948","url":null,"abstract":"ABSTRACT Biomagnifications of emergent contamination with diclofenac in aquatic media exert adverse effects on ecosystems and the environment. Hence, employing an effective remediation route, especially magnetic adsorption, is highly beneficial to eliminating hazardous pharmaceutical wastes. In this research, an efficient magnetic nanoadsorbent derived from aminated manganese ferrite, cellulose, and graphene oxide (GO) has been characterized and employed for diclofenac (DF) removal. Results of EDX analysis showed that aminopropyltriethoxysilane, as an amine source, have been anchored on the magnetic adsorbent surface with high density. Moreover, FESEM and TEM images, as well as the XRD pattern, confirmed that the nanocomposite is a three-component adsorbent. Response surface methodology was adopted to optimize effective parameters for DF adsorption. Solution pH, contact time, adsorbent amount, and concentration of NaNO3 were four variables that have been optimized. Kinetic and isotherm studies for the adsorption experiments showed that diclofenac adsorption followed the pseudo-second-order kinetic model and Langmuir adsorption isotherm. Moreover, the thermodynamic study indicated that the adsorption process is spontaneous and follows an exothermic path. With a high maximum adsorption capacity of 439.0 mg.g−1 and an adequate removal efficiency of 98.0%, the aminated MnFe2O4-cellulose-GO is a suitable candidate to mitigate the side effects of DF in aqueous media.","PeriodicalId":21680,"journal":{"name":"Separation Science and Technology","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2023-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139268525","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recovering AlN from secondary aluminum ash using a novel triboelectric separation 利用新型三电分离法从二次铝灰中回收 AlN
IF 2.8 4区 工程技术
Separation Science and Technology Pub Date : 2023-11-16 DOI: 10.1080/01496395.2023.2282956
Zhenxing Zhang, Jilan Shi, Haifeng Wang, Yongqiang Xu, Jiahui Niu, Zihui Zhang, Juan Hao
{"title":"Recovering AlN from secondary aluminum ash using a novel triboelectric separation","authors":"Zhenxing Zhang, Jilan Shi, Haifeng Wang, Yongqiang Xu, Jiahui Niu, Zihui Zhang, Juan Hao","doi":"10.1080/01496395.2023.2282956","DOIUrl":"https://doi.org/10.1080/01496395.2023.2282956","url":null,"abstract":"ABSTRACT Secondary aluminum ash is a byproduct in the aluminum industry that contains valuable components, such as aluminum nitride (AlN) and aluminum oxide (Al2O3). AlN has excellent thermal and electrical properties and is widely used in various applications, making the recovery of AlN from secondary aluminum ash essential for both economic and environmental reasons. In this study, we developed a novel triboelectric separation technique to recover AlN from aluminum ash by investigating the tribocharging characteristics of the main components of secondary aluminum ash, Al2O3 and AlN. We studied the effects of tribocharging ball ratio, friction time, and stirring speed on the tribocharging of pure Al2O3 and AlN, using various materials such as polytef (PTFE), polypropylene (PP), polyvinyl chloride (PVC), copper (Cu), and stainless steel (SS) as tribocharging materials. We also examined the effects of friction medium ball ratio, friction medium material, rotational speed, and voltage on the triboelectric separation process. Our results showed that the charge-to-mass ratio for Al2O3 and AlN was 1.96 and −15.56 nC/g, respectively, the difference is largest, with a PTFE ball, a 1:5 ratio, a stirring speed of 290 n/min, and a tribocharging duration of 30 s. The triboelectric sequence of these friction materials was (+)PTFE, PP, Al2O3, SS, Cu, PVC, and AlN (-). To recover AlN from aluminum ash, PTFE should be chosen as the friction medium, and a friction medium ball ratio of 1:3, rpm rotation speed of 50, and voltage of 40kV should be used, resulting in an AlN grade of 89.25% and a significant increase in the recovery rate of AlN in the positive and negative electrode. Our findings demonstrate the feasibility of effective triboelectric separation of Al2O3 and AlN.","PeriodicalId":21680,"journal":{"name":"Separation Science and Technology","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2023-11-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139269070","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study on vapor-liquid equilibrium and azeotropic distillation simulation of fluorene- dibenzofuran system 芴-二苯并呋喃体系的汽液平衡和共沸蒸馏模拟研究
IF 2.8 4区 工程技术
Separation Science and Technology Pub Date : 2023-11-15 DOI: 10.1080/01496395.2023.2259603
Qiulian Chang, Guofeng He, Haiyong Sun
{"title":"Study on vapor-liquid equilibrium and azeotropic distillation simulation of fluorene- dibenzofuran system","authors":"Qiulian Chang, Guofeng He, Haiyong Sun","doi":"10.1080/01496395.2023.2259603","DOIUrl":"https://doi.org/10.1080/01496395.2023.2259603","url":null,"abstract":"ABSTRACT This study is centered on the separation of the fluorene-dibenzofuran system through binary phase equilibrium experiments and azeotropic distillation simulations. An enhanced Othmer equilibrium still was employed to conduct phase equilibrium experiments, and the obtained data were correlated to determine the missing binary interaction parameters. The resulting experimental data demonstrated thermodynamic consistency and reliability. Subsequent correlation using the NRTL, UNIQUAC, and Wilson models highlighted the UNIQUAC model’s exceptional agreement with experimental values. This underscores the model’s capability to precisely characterize the fluorene-dibenzofuran system’s phase behavior. The phase equilibrium study provided pivotal parameters and predictions, forming the groundwork for subsequent separation process simulations and equipment development. Azeotropic simulations, employing ethylene glycol as a co-boiling solvent and simulated via Aspen software, yielded high-purity fluorene products with a minimum purity of ≥ 98%. These findings emphasize the potency of azeotropic distillation in achieving high-purity separation within the fluorene-dibenzofuran system, with promising implications for industrial applications.","PeriodicalId":21680,"journal":{"name":"Separation Science and Technology","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2023-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139275647","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Experimental investigation of reactive extraction of p-hydroxybenzoic acid using TOA in toluene, petroleum ether and MIBK 在甲苯、石油醚和 MIBK 中使用 TOA 反应萃取对羟基苯甲酸的实验研究
IF 2.8 4区 工程技术
Separation Science and Technology Pub Date : 2023-11-15 DOI: 10.1080/01496395.2023.2279945
A. N. Joshi, A. Chandrakar, K. Wasewar, R. S. Thakur
{"title":"Experimental investigation of reactive extraction of p-hydroxybenzoic acid using TOA in toluene, petroleum ether and MIBK","authors":"A. N. Joshi, A. Chandrakar, K. Wasewar, R. S. Thakur","doi":"10.1080/01496395.2023.2279945","DOIUrl":"https://doi.org/10.1080/01496395.2023.2279945","url":null,"abstract":"ABSTRACT p-hydroxybenzoic acid (p-HBA) remains present in various industrial effluents, it has various industrial applications and excellent medicinal properties, on the contrary, it degrades the fertility of soil if discharged in atmosphere hence, retrieval of p-HBA from effluent is a mandate. In past decades, reactive extraction has arisen as an efficient and attractive separation technique. Therefore, in the present study, the reactive extraction of p-HBA, using Tri-n-octylamine diluted in toluene, petroleum ether, and methyl isobutyl ketone, has been investigated. The results have been reported in terms of efficiency, distribution coefficient, equilibrium complexation constant, and loading ratio. The order of diluents, with respect to extraction given, is MIBK (93.43%) > toluene (92.57%)> petroleum ether (91.43%). The relative basicity model is used to for the interpretation and is found suitable for explaining the results. The diffusion coefficient was also found using Reddy Doraiswamy equation and Wilke Chang equation. Further, minimum number of stages of counter current extraction column and solvent to feed ratio were also calculated to investigate the feasibility of the process.","PeriodicalId":21680,"journal":{"name":"Separation Science and Technology","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2023-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139272806","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Smart dual responsive alginate grafted copolymeric hydrogel for sorption of recalcitrant methylene green from water 智能双响应藻酸酯接枝共聚水凝胶从水中吸附顽固性亚甲基绿
4区 工程技术
Separation Science and Technology Pub Date : 2023-11-14 DOI: 10.1080/01496395.2023.2279516
Hanif Subhan, Sultan Alam, None Uzma, Mohib Ullah, Luqman Ali Shah
{"title":"Smart dual responsive alginate grafted copolymeric hydrogel for sorption of recalcitrant methylene green from water","authors":"Hanif Subhan, Sultan Alam, None Uzma, Mohib Ullah, Luqman Ali Shah","doi":"10.1080/01496395.2023.2279516","DOIUrl":"https://doi.org/10.1080/01496395.2023.2279516","url":null,"abstract":"ABSTRACTThe sorptive removal of recalcitrant dyes from aquatic media holds paramount significance in the contemporary research. The pressing problem has been addressed by facile fabrication and subsequent sorption studies on sodium alginate grafted poly (N-isopropyl acrylamide-co-acrylic acid) [Na-Alg-g-p(NIPAm-co-AAc)] hydrogel for sorption of methylene green (MG). The sorbent achieved equilibrium in 30 minutes, whereas highest sorption capacity was noted at optimum pH 5. At 25°C, the sorbed quantity of the adsorbate enhanced with the rise in initial concentration. The data of isothermal studies fitted well into the Langmuir isotherm as suggested by relatively higher R2 of ≈ 0.98. The sorption obeyed pseudo-second-order kinetics as evidenced by exceptionally higher R2 (0.999) and substantial agreement in experimentally obtained and theoretically calculated second-order rate constant. The validity of Langmuir isotherm and pseudo-second-order kinetic models imply the occurrence of chemisorption between anionic [Na-Alg-g-p(NIPAm-co-AAc)] sorbent and cationic MG. Moreover, the material exhibits dual (pH and temperature) responsive nature because the amount sorbed undergoes variation with change in temperature and pH. The results signify potential candidature of the fabricated sorbent for the reclamation of dye contaminated water and related applications.KEYWORDS: Sorptive removalrecalcitrant dyesfacile fabricationpolymeric hydrogelsorption experiments Supplemental dataSupplemental data for this article can be accessed online at https://doi.org/10.1080/01496395.2023.2279516Disclosure statementNo potential conflict of interest was reported by the author(s).Novelity statementDual responsive sodium alginate grafted poly (N-Isopropyl acrylamide-co-acrylic acid) [Na-Alg-g-p(NIPAm-co-AAc)] hydrogel was fabricated by free radical polymerization method.Sorption behaviour of the graft co-polymeric material was explored in batch adsorption experiments by using methylene green (MG) as a probe dye.The sorption kinetics and isotherm were probed by applying different kinetic and isotherm models.The MG loaded sorbent was regenerated by adopting solvent extraction route using acetoneThe recycling behaviour of the spent sorbent was inspected for six successive sorption-desorption runs.The results signify potential candidature of the fabricated sorbent for the reclamation of dye contaminated water and related applications.","PeriodicalId":21680,"journal":{"name":"Separation Science and Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134954452","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and characterization of pectin-xanthate and their application in heavy metal and lignin enriched paper industry wastewater treatment 果胶黄药的合成、表征及其在重金属和木质素富集造纸废水处理中的应用
4区 工程技术
Separation Science and Technology Pub Date : 2023-11-10 DOI: 10.1080/01496395.2023.2279942
Arbind Chaurasiya, Poorn Prakash Pande, Ravi Shankar, Amar Nath, Narendra Pratap Tripathi
{"title":"Synthesis and characterization of pectin-xanthate and their application in heavy metal and lignin enriched paper industry wastewater treatment","authors":"Arbind Chaurasiya, Poorn Prakash Pande, Ravi Shankar, Amar Nath, Narendra Pratap Tripathi","doi":"10.1080/01496395.2023.2279942","DOIUrl":"https://doi.org/10.1080/01496395.2023.2279942","url":null,"abstract":"ABSTRACTThree grades of pectin xanthates (PX1, PX2, and PX3) have been prepared by the reaction of pectin with carbon disulfide (CS2) in an alkaline medium using NaOH, via the xanthation process. The percentage yield of prepared pectin xanthates has been found to be 87.06%, 90.38%, and 93.80% for PX1, PX2, and PX3, respectively. Prepared pectin xanthates and raw pectin were utilized for heavy metals (Cu(II) and Ni(II)) and lignin enriched paper industry wastewater (LEPIW) treatment. The removal percentage of pectin, PX1, P X2, and PX3 for Cu removal at optimum condition (adsorbent dose: 5.14 g/L, pH: 5 for Cu and 7 for Ni, optimum temperature: 50°C and time: 80 min for Cu(II) and 100 min for Ni(II)) has been found as 85%, 92.33%, 93.5%, and 94.66% and 76.66%, 89.44%, 91.66%, and 93.33%, respectively, for Ni removal. The LEPIW treatment efficacy for pectin, PX1, PX2, and PX3 has been found to be 54%, 77%, 83%, and 86% for the initial COD: 2000 mg/L, pH: 7, optimum temperature: 40°C in 105 min operation time. Adsorption isotherm studies suggest that Langmuir isotherm is most appropriate which indicates adsorption follows chemisorption. The adsorption capacities of PX1, PX2, and PX3 are found as 309.59, 352.11, and 380.22 mg/g for Cu(II) and 299.40, 315.45, and 328.94 mg/g and for Ni(II), respectively, which is very high in comparison with many other recent literature studies.KEYWORDS: Xanthateadsorptionpaper wastewaterheavy metalCOD removal Disclosure statementNo potential conflict of interest was reported by the author(s).Manuscript’s most relevant contributions Synthesis and characterization of three grade pectin xanthate for wastewater treatment.Cu removal in the range of 85–95% for an initial load of 2000 mg/L.Ni removal in the range of 76–93% for an initial load of 2000 mg/L.Adsorption capacities are found between 309 and 380 mg/g for Cu removal.Adsorption capacities are found between 299 and 329 mg/g for Ni removal.LEPIW treatment efficiency in the range of 54–76% for an initial COD of 2000 mg/L.","PeriodicalId":21680,"journal":{"name":"Separation Science and Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135137733","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimization of isotopic binary and multi-component separation cascades using a novel nature-inspired horse herd algorithm 利用新颖的自然启发的马群算法优化同位素二元和多组分分离级联
4区 工程技术
Separation Science and Technology Pub Date : 2023-10-19 DOI: 10.1080/01496395.2023.2261076
K. Salimi, S. Dadashzadeh, M. Aghaie
{"title":"Optimization of isotopic binary and multi-component separation cascades using a novel nature-inspired horse herd algorithm","authors":"K. Salimi, S. Dadashzadeh, M. Aghaie","doi":"10.1080/01496395.2023.2261076","DOIUrl":"https://doi.org/10.1080/01496395.2023.2261076","url":null,"abstract":"ABSTRACTThe gas centrifuge process is widely used in the world to separate binary and multi component mixtures of isotopes. The majority of a plant cost is related to the number of centrifuges in a cascade. The cascade should be built so that it uses the fewest possible centrifuges for a given product and waste concentrations. Minimizing the number of centrifuges and the total flow rates, is a key point in designing and optimizing isotope separation cascades. The main purpose of this paper is to present a novel swarm intelligence based algorithm to solve these kinds of problems. This novel algorithm, called the Horse Herd Optimization Algorithm (HOA), is inspired by the behavioral patterns of horses in their habitats. In this work, it is demonstrated that the suggested algorithm can solve complicated multidimensional problems. HOA is tested by some test functions of high-dimensions and the results are compared with the strongest available optimization algorithms. In next, the proposed algorithm is used to optimize gas centrifuge cascades for the separation of binary and multicomponent mixtures of isotopes in several cases. Also, ideal and optimum cascades are compared in different separating regimes of the stages, using this method. Considering the performance of HOA in solving multidimensional problems, this algorithm is proposed for the optimization of long cascades.KEYWORDS: Swarm intelligenceHOAgas CentrifugecascadeOptimization Disclosure statementNo potential conflict of interest was reported by the author(s).","PeriodicalId":21680,"journal":{"name":"Separation Science and Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-10-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135667872","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study of plutonium recovery from acidic feed using polyethersulfone encapsulating TBP, DEHPA, and mixture of TBP and DEHPA beads 聚醚砜包封TBP、DEHPA及TBP与DEHPA混球回收酸性饲料中钚的研究
4区 工程技术
Separation Science and Technology Pub Date : 2023-10-09 DOI: 10.1080/01496395.2023.2266562
Satya Ranjan Guchhait, Kankan Patra, Kartikey K. Yadav, D.K. Singh, Arijit Sengupta, T. P. Valsala, D.B. Sathe, R.B. Bhatt
{"title":"Study of plutonium recovery from acidic feed using polyethersulfone encapsulating TBP, DEHPA, and mixture of TBP and DEHPA beads","authors":"Satya Ranjan Guchhait, Kankan Patra, Kartikey K. Yadav, D.K. Singh, Arijit Sengupta, T. P. Valsala, D.B. Sathe, R.B. Bhatt","doi":"10.1080/01496395.2023.2266562","DOIUrl":"https://doi.org/10.1080/01496395.2023.2266562","url":null,"abstract":"ABSTRACTPolyethersulfone (PES) composite beads encapsulating the extractants di-(2-ethylhexyl) phosphoric acid (DEHPA), tributyl phosphoric acid (TBP), and mixture of DEHPA & TBP were synthesized. The synthesis was carried out using phase inversion method. Subsequently, these PES beads were applied for the recovery of plutonium [Pu (IV)] from different aqueous acidic medium. In kinetic studies, the extraction of Pu (IV) was found to be fast and equilibrium was attained within 5 minutes. In batch sorption studies, the role of aqueous acidity and nitrate ion concentration on extraction efficiency was evaluated. Also, the effects of variation of acid medium, concentration of metal ion, extractant concentration were examined for Pu (IV) recovery. Back extraction was effectively carried out using oxalic acid. The reusability of the PES beads was tested for 10 extraction – stripping cycles.KEYWORDS: Polyethersulfone composite beadsDEHPATBPsorptiondesorptionnitric acidplutoniumsorption studies AcknowledgmentsAuthors acknowledge U. Dani, C.E, NRB, BARCDisclosure statementNo potential conflict of interest was reported by the author(s).","PeriodicalId":21680,"journal":{"name":"Separation Science and Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135045891","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Selective removal and simultaneous immobilization of Pb cations from solutions 溶液中Pb阳离子的选择性去除和同时固定化
4区 工程技术
Separation Science and Technology Pub Date : 2023-09-30 DOI: 10.1080/01496395.2023.2262745
Yunchul Cho, Jing Wang, Sungpyo Kim, Huaibin Zhang, Wenyan Huang, Sridhar Komarneni
{"title":"Selective removal and simultaneous immobilization of Pb cations from solutions","authors":"Yunchul Cho, Jing Wang, Sungpyo Kim, Huaibin Zhang, Wenyan Huang, Sridhar Komarneni","doi":"10.1080/01496395.2023.2262745","DOIUrl":"https://doi.org/10.1080/01496395.2023.2262745","url":null,"abstract":"ABSTRACTThe aim of this study was to develop a layered ammonium tin phosphate as a potential sorbent for removal of Pb2+ ions by exchange/sorption or other mechanism from contaminated solutions. A layered ammonium tin phosphate (NH4-SnP), δ-SnP – NH4 was synthesized using the hydrothermal process. XRD pattern of the NH4-SnP revealed that the final product obtained was δ-tin (IV) phosphate with the d(001)-spacing of about 14.8 Å containing ammonium ions and water molecules in the interlayers. In order to investigate the removal efficiency of Pb2+ cations by the NH4-SnP, batch-type of sorption experiments were carried out with 2 days of equilibration time at room temperature. Also, the kinetics of reaction was performed at room temperature to determine equilibrium time. The sorption isotherms for Pb2+ cations indicated that NH4-SnP showed high affinity for these ions with all the concentrations used. In addition, kinetic data showed preference for Pb2+ cations between NH4+ cation on the exchanger and Pb2+metal cation in solution. Based on these results, NH4-SnP can be proposed as an excellent sorbent for not only removal but also immobilization of Pb2+ ions from water and wastewater. Pb2+ ions were found to be immobilized as insoluble pyromorphite, Pb5(PO4)Cl after high uptakes.KEYWORDS: Pb2+ reactionPb2+ immobilizationpyromorphitePb2+ isothermδ-tin (IV) phosphate Disclosure statementNo potential conflict of interest was reported by the author(s).Additional informationFundingThis research was supported by the College of Agricultural Sciences under Station Research Project No. PEN04705.","PeriodicalId":21680,"journal":{"name":"Separation Science and Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"136342383","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Gold recovery from electronic wastes using a solvent extraction/selective back-extraction strategy 利用溶剂萃取/选择性反萃取策略从电子废弃物中回收黄金
4区 工程技术
Separation Science and Technology Pub Date : 2023-09-26 DOI: 10.1080/01496395.2023.2260945
Zahra Raeisi, Bahman Farajmand, Parvaneh Nakhostin Panahi, Mohammad Reza Yaftian
{"title":"Gold recovery from electronic wastes using a solvent extraction/selective back-extraction strategy","authors":"Zahra Raeisi, Bahman Farajmand, Parvaneh Nakhostin Panahi, Mohammad Reza Yaftian","doi":"10.1080/01496395.2023.2260945","DOIUrl":"https://doi.org/10.1080/01496395.2023.2260945","url":null,"abstract":"ABSTRACTThe present lab-scale investigation describes a simple and efficient approach to the selective solvent extraction and recovery of gold, and copper as a by-product, from Waste Printed Circuit Boards (WPCBs) of different brands of used computers. The process comprised of three steps; leaching of scraps in aqua regia, solvent extraction process under optimized conditions, and ultimately selective back-extraction. The analysis of leach solution by inductively coupled plasma revealed, in addition to gold (0.14 wt%), copper (40.0 wt%), tin (11.9 wt%), and Ni (2.3 wt%) were the other main metals in the WPCBs. A solvent extraction procedure using trioctylamine, as extractant, dissolved in kerosene was employed for the extraction of gold as its anionic chloride-complexes from the leach liquor. The parameters affecting this process including hydrochloric acid concentration, equilibrium time, extractant concentration, initial gold concentration in the sample solution, and the aqueous/organic volume ratio were optimized by means of the statistical technique response surface methodology (RSM). Under the optimized extraction conditions, 99.6% of gold and 23.4% of copper were transferred into the organic phase, while the extracted percentage of other metal ions were negligible. Selective back-extraction by the solution 0.1 M NaOH resulted in the selective precipitation of copper, while the raffinate contained just gold ions.KEYWORDS: Goldcopperrecyclingsolvent extractionselective back-extractiontrioctylamineresponse surface methodology optimization Disclosure statementThe authors declare no conflict of interest.Statement of NoveltyThe present paper aims to report a new, low-cost, efficient, and simple solvent extraction method, using a solution of trioctylamine dissolved in kerosene, followed by a selective back-extraction procedure method, for efficient recovery of gold from leach liquor of Waste Printed Circuit Boards (WPCBs). The presented method allowed also to obtain metallic copper as the by-product","PeriodicalId":21680,"journal":{"name":"Separation Science and Technology","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134886624","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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