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Comparative assessment of air pollutant emissions from brick manufacturing 制砖过程中空气污染物排放的比较评估
Romanian Journal of Ecology & Environmental Chemistry Pub Date : 2020-10-14 DOI: 10.21698/rjeec.2020.222
V. Danciulescu, E. Bucur, M. Petrescu, M. Bratu, A. Cozea, G. Tanase
{"title":"Comparative assessment of air pollutant emissions from brick manufacturing","authors":"V. Danciulescu, E. Bucur, M. Petrescu, M. Bratu, A. Cozea, G. Tanase","doi":"10.21698/rjeec.2020.222","DOIUrl":"https://doi.org/10.21698/rjeec.2020.222","url":null,"abstract":"In this paper, a comparison is made of the level of air pollution between two brick production lines that apply different technologies, one old and one new, and more efficient. The main pollutants emitted in the air from the baking kilns are CO, SO2, NO2, HCl, HF, and dust. The monitoring of emissions was performed with a Testo 350 flue gas analyzer – the automatic method. A Paul Gothe isokinetic sampler was used to take dust, HCl, and HF sampling, and the analysis was performed in the laboratory using gravimetric and spectrophotometric analytical methods. The results of the tests performed showed a reduction in the level of pollution by applying the new and BAT technologies by up to 90% for all monitored pollutants, compared to the pollution produced by old and non-re-technologized line. At the same time, energy consumption is lower per unit of product, which results in a significant decrease in production costs.","PeriodicalId":21370,"journal":{"name":"Romanian Journal of Ecology & Environmental Chemistry","volume":"35 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87172271","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Determination of phosphorus in different types of waste using the ICP-MS technique 电感耦合等离子体质谱法测定不同类型废物中的磷
Romanian Journal of Ecology & Environmental Chemistry Pub Date : 2020-10-14 DOI: 10.21698/rjeec.2020.217
G. Catrina, Lidia Kim, A. Serbanescu, I. Cristea, M. Barbu, I. Nicolescu, G. Vasile
{"title":"Determination of phosphorus in different types of waste using the ICP-MS technique","authors":"G. Catrina, Lidia Kim, A. Serbanescu, I. Cristea, M. Barbu, I. Nicolescu, G. Vasile","doi":"10.21698/rjeec.2020.217","DOIUrl":"https://doi.org/10.21698/rjeec.2020.217","url":null,"abstract":"The research aimed to provide an optimized method for the determination of phosphorous concentration in different types of solid waste using inductive coupled plasma mass spectrometry (ICP-MS) technique. The analyzed waste matrices are: a) vegetable waste (P1), b) ash from the incineration of medical waste (P2) c) sewage sludge (P3) and d) sludge from the meat processing industry (P4). The results obtained by the ICP-MS method were compared with the UV-VIS spectrophotometric method for the determination of total phosphorus. In the case of using the colorimetric method by UV-VIS technique, lower results were obtained compared to the ICP-MS method due to the interferences given by the reagents used to determine the total phosphorus. The interferences given by other elements (metals) were also investigated and the performance parameters were determined such as detection limit, quantification limit, recovery and expandend incertainty using ICP-MS technique.","PeriodicalId":21370,"journal":{"name":"Romanian Journal of Ecology & Environmental Chemistry","volume":"105 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"85882571","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comparative testing of Ag/Au/Pt graphene electromodified electrodes in electrochemical detection of tetracycline-emerging pollutant Ag/Au/Pt石墨烯修饰电极在四环素新兴污染物电化学检测中的对比测试
Romanian Journal of Ecology & Environmental Chemistry Pub Date : 2020-10-14 DOI: 10.21698/rjeec.2020.219
S. Negrea, L. A. Diaconu, V. Nicorescu, D. Neidoni, A. Baciu, Claudia Licurici, F. Manea
{"title":"Comparative testing of Ag/Au/Pt graphene electromodified electrodes in electrochemical detection of tetracycline-emerging pollutant","authors":"S. Negrea, L. A. Diaconu, V. Nicorescu, D. Neidoni, A. Baciu, Claudia Licurici, F. Manea","doi":"10.21698/rjeec.2020.219","DOIUrl":"https://doi.org/10.21698/rjeec.2020.219","url":null,"abstract":"This study aimed to obtain new electrochemically modified electrodes with graphene and Au, Pt, Ag particles considering graphite (GP) and glassy carbon (GC) substrate by applying the chronoamperometry technique to develop the detection protocol of tetracycline (TC) considered as an emerging pollutant in water, using cyclic voltammetry (CV) technique. The graphite-based substrate used for Ag/ Au/ Pt electrodeposition led to the electrode compositions on which TC oxidation process was not diffusion-controlled and as consequence, TC detection failed. TC detection protocols were developed for all Ag/Au /Pt electrodeposited GC and GCGP electrodes. Better limits of TC detection was achieved for Ag electrodeposited on GC-GP at the cathodic potential of 0.460 V/SCE.","PeriodicalId":21370,"journal":{"name":"Romanian Journal of Ecology & Environmental Chemistry","volume":"33 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79079435","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Graphical and computational methods for determining the stability constants of mono- and polynuclear complexes with a common intersection point of the family of formation curves 确定具有形成曲线族共同交点的单核和多核配合物稳定性常数的图解和计算方法
Romanian Journal of Ecology & Environmental Chemistry Pub Date : 2020-10-14 DOI: 10.21698/rjeec.2020.210
I. Povar, O. Spînu, B. Pintilie
{"title":"Graphical and computational methods for determining the stability constants of mono- and polynuclear complexes with a common intersection point of the family of formation curves","authors":"I. Povar, O. Spînu, B. Pintilie","doi":"10.21698/rjeec.2020.210","DOIUrl":"https://doi.org/10.21698/rjeec.2020.210","url":null,"abstract":"Aqueous polynuclear systems have been analyzed, for which the family of formation curves intersects at a common point. The analyzed graphical and computational method for determining the stability constants can be used as initial values within the iterative calculation process. In some cases, the stability constants are calculated using only the coordinates of the common intersection point. The obtained equations could be of special interest when the experimental data can be interpreted in several models. In these cases, given the large volume of experimental data, the calculation is simple and the model can certainly be chosen with high safety. The obtained equations may also be applied for critical evaluation of tabular data if the coordinates of the intersection point are known. A series of real polynuclear systems have been analyzed and useful conclusions have been made.","PeriodicalId":21370,"journal":{"name":"Romanian Journal of Ecology & Environmental Chemistry","volume":"125 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74136022","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Cavitation action on the cocci bacteria 对球菌的空化作用
Romanian Journal of Ecology & Environmental Chemistry Pub Date : 2020-10-14 DOI: 10.21698/rjeec.2020.206
I. Koval, A. Hajiali
{"title":"Cavitation action on the cocci bacteria","authors":"I. Koval, A. Hajiali","doi":"10.21698/rjeec.2020.206","DOIUrl":"https://doi.org/10.21698/rjeec.2020.206","url":null,"abstract":"Features of growth of microorganisms on a nutrient medium and their microscopic researches were studied. Cavitation treatment (22 kHz, 91 W, 1.65 W/сm3) of water with the simultaneous action of bubbled inert gases (argon and helium) on the viability of microbial cells (Diplococcus and Sarcina) are presented. The highest water disinfection was obtained for water samples with Sarcina lutea cells for both used gases under cavitation conditions. Both investigated types of cocci bacteria were destroyed faster under Ar/US-action after comparison of the effectiveness of the gas nature action on the water disinfection.","PeriodicalId":21370,"journal":{"name":"Romanian Journal of Ecology & Environmental Chemistry","volume":"33 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88902535","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
LDH-GO composites as catalysts for the oxidative removal of indigo carminedye from wastewater LDH-GO复合材料氧化脱除废水中靛蓝胭脂红的催化剂研究
Romanian Journal of Ecology & Environmental Chemistry Pub Date : 2020-10-14 DOI: 10.21698/rjeec.2020.201
Alexandra-Elisabeta Stamate, R. Zăvoianu, O. Pavel, A. Cruceanu, M. Corobea, M. Osiac, N. Cioateră
{"title":"LDH-GO composites as catalysts for the oxidative removal of indigo carmine\u0000dye from wastewater","authors":"Alexandra-Elisabeta Stamate, R. Zăvoianu, O. Pavel, A. Cruceanu, M. Corobea, M. Osiac, N. Cioateră","doi":"10.21698/rjeec.2020.201","DOIUrl":"https://doi.org/10.21698/rjeec.2020.201","url":null,"abstract":"Herein, we present the results of our researches focused on obtaining composites with enhanced affinity for indigo carmine (IC) by combining two different 2D materials e.g. graphene oxide (GO) and a Cerium modified layered double hydroxide (LDH), which could act as catalysts for the oxidative removal of IC, both under ultrasonic irradiation and under conventional stirring, using H2O2 as oxidation agent. Three Mg3Al0.75Ce0.25 LDH-GO composites bearing different concentrations of GO in the range of 5-15 wt.% abbreviated as HT3Ce-xGO where x stands for the concentration of GO (x=5,10,15% wt. GO) have been prepared and characterized by XRD, SEM, Raman and DRIFT spectroscopy. The XRD patterns of HT3Ce-xGO solids have revealed the formation of nanocomposites with fine particles of CeO2 (Scherrer dimensions around 3 nm) embedded in the 2D layered structure of LDH-GO. CeO2 phase was favored by the increase in GO content for all investigated composites. The size decrease of the solid particles with the increase of GO content was proved both by SEM and DRIFT analyses. Raman spectra proved the incorporation of GO in all composites. The results of the catalytic tests showed, without any doubt the activation effect of the ultrasonic irradiation which allowed doubling the dye removal percentage (DR%) in the first 30 minutes of reaction time. For the most active catalyst, HT3Ce-15GO, the COD after 30 minutes reaction time under ultrasonic irradiation was 221 mgO2/L, while TOC was 93 mgC/L marking a decay of 61.6% for COD and 46.2% for TOC.","PeriodicalId":21370,"journal":{"name":"Romanian Journal of Ecology & Environmental Chemistry","volume":"24 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75443082","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Municipal solid waste (MSW) - competitive raw materials for combustible materials obtaining 城市固体废物(MSW) -获得可燃材料的竞争性原料
Romanian Journal of Ecology & Environmental Chemistry Pub Date : 2020-10-14 DOI: 10.21698/rjeec.2020.221
A. Serbanescu, M. Barbu, I. Cristea, Lidia Kim, G. Catrina, Georgiana Cernica, I. Nicolescu
{"title":"Municipal solid waste (MSW) - competitive raw materials for combustible materials obtaining","authors":"A. Serbanescu, M. Barbu, I. Cristea, Lidia Kim, G. Catrina, Georgiana Cernica, I. Nicolescu","doi":"10.21698/rjeec.2020.221","DOIUrl":"https://doi.org/10.21698/rjeec.2020.221","url":null,"abstract":"Waste-to-energy projects can be classified as a complementary technology for energy recovery from nonrecyclable municipal waste fractions and should therefore not compete with measures to reduce, reuse, and recycle materials. The article presents the characterization of some treated municipal solid wastes as competitive raw materials for combustible materials obtaining. Samples with lignocellulosic and polymeric composition were analyzed, namely 3 samples of SRFs (solid recovered fuels) used as secondary raw material in cement plants, SRF1, SRF2, SRF3; a sample of RDF, consisting of household waste; a sample of fluff (a homogeneous mixture of non-hazardous waste - selected, mechanically treated and dried) used as a secondary raw material in cement plants; 4 samples of municipal solid waste, fractions smaller than 100 mm, after a bio-drying process, with composition: paper and cardboard (70-80%), wood (6-15%), plastic (6-10%), glass and metal (3-14%), MBU1, MBU2, MBU3, MBU4. The waste samples were characterized in terms of technical and elementary characteristics and the ash (obtained by the sample incineration) behavior in the combustion process. The mineral matter was investigated by the X-ray fluorescence analytical technique using the Rigaku CG X-ray Spectrofluorimeter. The analysis of the indices used for the slagging and deposit formation risks evaluation shows that the analyzed samples present an obvious risk of melt formation and deposits, due to a high content of base oxides and silicon oxide.","PeriodicalId":21370,"journal":{"name":"Romanian Journal of Ecology & Environmental Chemistry","volume":"28 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74604373","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
New ion-chromatography method for detection of chlorite, chlorate, and bromate in drinking water 离子色谱法检测饮用水中亚氯酸盐、氯酸盐和溴酸盐的新方法
Romanian Journal of Ecology & Environmental Chemistry Pub Date : 2020-10-14 DOI: 10.21698/rjeec.2020.207
I. Paun, V. Iancu, F. Chiriac, Nicoleta Vasilache, F. Pirvu, M. Niculescu, T. Galaon
{"title":"New ion-chromatography method for detection of chlorite, chlorate, and bromate in drinking water","authors":"I. Paun, V. Iancu, F. Chiriac, Nicoleta Vasilache, F. Pirvu, M. Niculescu, T. Galaon","doi":"10.21698/rjeec.2020.207","DOIUrl":"https://doi.org/10.21698/rjeec.2020.207","url":null,"abstract":"A direct ion chromatographic method for the determination of chlorite, chlorate, and bromate in the presence of fluoride, chloride, nitrate, nitrite, and bromide in treated drinking waters was described. Separation of target analytes was achieved using an AS19-HC analytical column (250 mm x 4 mm), AG 19- HC guard column (50 mm x 4 mm), and KOH 25 mmol/L as mobile phase. Inorganic analytes were eluted using a flow rate of 1 mL/min. The column temperature was set up and maintained at 300C. The analyte ions\u0000were quantified using a suppressed conductivity detector.","PeriodicalId":21370,"journal":{"name":"Romanian Journal of Ecology & Environmental Chemistry","volume":"93 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80441800","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Relationships between land use, predicted pollution loadings, and ecotoxicological assays in constructed wetlands 人工湿地中土地利用、预测污染负荷和生态毒理学分析之间的关系
Romanian Journal of Ecology & Environmental Chemistry Pub Date : 2020-10-14 DOI: 10.21698/rjeec.2020.215
S. G. Roy, T. Ehlinger
{"title":"Relationships between land use, predicted pollution loadings, and ecotoxicological assays in constructed wetlands","authors":"S. G. Roy, T. Ehlinger","doi":"10.21698/rjeec.2020.215","DOIUrl":"https://doi.org/10.21698/rjeec.2020.215","url":null,"abstract":"Environmental degradation related to uncontrolled development resulted in the passage of the United States Clean Water Act (CWA) in 1972, with the stated purpose “to restore and maintain the integrity of the nation’s waters”. Implementation of the CWA leads to increased research to develop multimetric indicators to better measure and understand the complex patterns of ecological responses to stress occurring across levels of biological, spatial, and temporal organization. One area of research is the use of integrated indices of chemical risk, ecotoxicological risk, and ecological risk to assess the impact of human activity across disturbance gradients of urbanization. Selecting relevant metrics for constructing a multimetric index requires identifying bioindicator organisms with capacities to detect signals from anthropogenic disturbances. This study explored the potential efficacy of a suite of higher plant ecotoxicological assays for use as bioindicators in ecological risk assessment along a gradient of urbanization in a wetland ecosystem. The study was conducted in the Pike River watershed (Racine, Wisconsin, USA) in six wetlands selected across a gradient of dominant land-use types (agricultural, commercial, residential, undeveloped, and industrial). MicroBioTest PhytotoxkitTM ecotoxicological assays, based on growth inhibition of three plants (Sinapis, Sorghum, and Lepidium) were used to assess sediment toxicity. The relationships between Phytotoxkit™ responses and predicted pollutant loadings calculated from surrounding land use provided clear signals of stress from watershed pollutants draining into the wetland sites. The potential for these ecotoxicological indicators to serve as biological response signatures is strong, and further research and calibration in field and microcosms studies will assist in calibrating responses for use in integrated monitoring efforts.","PeriodicalId":21370,"journal":{"name":"Romanian Journal of Ecology & Environmental Chemistry","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88138997","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Assessment of the level of noise and chemical air pollution in two distinct urban areas 评估两个不同城市地区的噪音和化学空气污染水平
Romanian Journal of Ecology & Environmental Chemistry Pub Date : 2020-10-14 DOI: 10.21698/rjeec.2020.216
M. Bratu, E. Bucur, V. Danciulescu, M. Petrescu, G. Tanase, O. Vasile
{"title":"Assessment of the level of noise and chemical air pollution in two distinct urban areas","authors":"M. Bratu, E. Bucur, V. Danciulescu, M. Petrescu, G. Tanase, O. Vasile","doi":"10.21698/rjeec.2020.216","DOIUrl":"https://doi.org/10.21698/rjeec.2020.216","url":null,"abstract":"In the paper are presented the results of tests on the evaluation of the level of noise and chemical air pollution in two distinct urban areas: an industrial area and an area characterized by heavy road traffic, with a focus on the novelty elements introduced by the regulations in force on the measurement and management of the level of ambient and industrial noise by periodically developing specific noise maps. The results of direct tests and noise maps developed in the case of the studied areas indicated higher values of the indicators measured near the road artery compared to the other measuring points, highlighting the influence of vegetation in urban areas to reduce noise levels and reduce air pollution.","PeriodicalId":21370,"journal":{"name":"Romanian Journal of Ecology & Environmental Chemistry","volume":"1 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2020-10-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86472102","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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