Ruthenium - an Element Loved by Researchers [Working Title]最新文献

Mechanisms of Photoisomerization and Water Oxidation Catalysis of Ruthenium(II) Aquo Complexes 钌(II)水基配合物的光异构化和水氧化催化机理

Ruthenium - an Element Loved by Researchers [Working Title] Pub Date : 2021-09-06 DOI: 10.5772/intechopen.99730

Yuta Tsubonouchi, Eman A. Mohamed, Zaki N. Zahran, M. Yagi

引用次数: 0

Ruthenium-Tris-Bipyridine Derivatives as a Divine Complex for Electrochemiluminescence Based Biosensor Applications 钌-三联吡啶衍生物作为电化学发光生物传感器的神圣配合物

Ruthenium - an Element Loved by Researchers [Working Title] Pub Date : 2021-05-21 DOI: 10.5772/INTECHOPEN.96819

Chikkili Venkateswara Raju, Mathavan Sornambigai, Shanmugam Senthil Kumar

引用次数: 1

Ruthenium Catalyst for Epoxidation Reaction 环氧化反应用钌催化剂

Ruthenium - an Element Loved by Researchers [Working Title] Pub Date : 2021-05-11 DOI: 10.5772/INTECHOPEN.96466

R. Alsaiari

引用次数: 0

Recent Advances in Ru Catalyzed Transfer Hydrogenation and Its Future Perspectives 钌催化转移加氢研究进展及展望

Ruthenium - an Element Loved by Researchers [Working Title] Pub Date : 2021-05-07 DOI: 10.5772/INTECHOPEN.96464

N. Tyagi, Gongutri Borah, Pitambar Patel, D. Ramaiah

{"title":"Recent Advances in Ru Catalyzed Transfer Hydrogenation and Its Future Perspectives","authors":"N. Tyagi, Gongutri Borah, Pitambar Patel, D. Ramaiah","doi":"10.5772/INTECHOPEN.96464","DOIUrl":"https://doi.org/10.5772/INTECHOPEN.96464","url":null,"abstract":"Over the past few decades, Ru catalyzed transfer hydrogenation (TH) and asymmetric transfer hydrogenation (ATH) reactions of unsaturated hydrocarbons, imine, nitro and carbonyl compounds have emerged as economic and powerful tools in organic synthesis. These reactions are most preferred processes having applications in the synthesis of fine chemicals to pharmaceuticals due to safe handling as these do not require hazardous pressurized H2 gas. The catalytic activity and selectivity of Ru complexes were investigated with a variety of ligands based on pincer NHC, cyclophane, half-sandwich, organophosphine etc. These ligands coordinate to Ru center in a proper orientation with a labile group replaced by H-source (like methanol, isopropanol, formic acid, dioxane, THF), which facilitate the β-hydrogen transfer to generate metal hydride species (Ru-H) and produce desired reduced product. This chapter describes the recent advances in TH and ATH reactions with homogeneous and heterogeneous Ru catalysts having different ligand environments and mechanistic details leading to their sustainable industrial applications.","PeriodicalId":21336,"journal":{"name":"Ruthenium - an Element Loved by Researchers [Working Title]","volume":"5 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82692586","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 2

Hydrogenation and Hydrogenolysis with Ruthenium Catalysts and Application to Biomass Conversion 钌催化剂的加氢和氢解及其在生物质转化中的应用

Ruthenium - an Element Loved by Researchers [Working Title] Pub Date : 2021-04-16 DOI: 10.5772/INTECHOPEN.97034

T. Müller

引用次数: 1

Surface-Confined Ruthenium Complexes Bearing Benzimidazole Derivatives: Toward Functional Devices 含苯并咪唑衍生物的表面限定钌配合物:迈向功能器件

Ruthenium - an Element Loved by Researchers [Working Title] Pub Date : 2021-04-08 DOI: 10.5772/INTECHOPEN.97071

Masa-aki Haga

{"title":"Surface-Confined Ruthenium Complexes Bearing Benzimidazole Derivatives: Toward Functional Devices","authors":"Masa-aki Haga","doi":"10.5772/INTECHOPEN.97071","DOIUrl":"https://doi.org/10.5772/INTECHOPEN.97071","url":null,"abstract":"Substitutionally inert ruthenium complexes bearing benzimidazole derivatives have unique electrochemical and photochemical properties. In particular, proton coupled electron transfer (PCET) in ruthenium–benzimidazole complexes leads to rich redox chemistry, which allows e.g. the tuning of redox potentials or switching by deprotonation. Using the background knowledge from acquired from their solution-state chemistry, Ru complexes immobilized on electrode surfaces have been developed and these offer new research directions toward functional molecular devices. The integration of surface-immobilized redox-active Ru complexes with multilayer assemblies via the layer-by-layer (LbL) metal coordination method on ITO electrodes provides new types of functionality. To control the molecular orientation of the complexes on the ITO surface, free-standing tetrapodal phosphonic acid anchor groups were incorporated into tridentate 2,6-bis(benzimidazole-2-yl)pyridine or benzene ligands. The use of the LbL layer growth method also enables “coordination programming” to fabricate multilayered films, as a variety of Ru complexes with different redox potentials and pKa values are available for incorporation into homo- and heterolayer films. Based on this strategy, many functional devices, such as scalable redox capacitors for energy storage, photo-responsive memory devices, proton rocking-chair-type redox capacitors, and protonic memristor devices have been successfully fabricated. Further applications of anchored Ru complexes in photoredox catalysis and dye-sensitized solar cells may be possible. Therefore, surface-confined Ru complexes exhibit great potential to contribute to the development of advanced functional molecular devices.","PeriodicalId":21336,"journal":{"name":"Ruthenium - an Element Loved by Researchers [Working Title]","volume":"88 17 1","pages":""},"PeriodicalIF":0.0,"publicationDate":"2021-04-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"84066701","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0