环境科学研究Pub Date : 2020-09-01DOI: 10.13198/J.ISSN.1001-6929.2020.03.19
许江城, 康得军, 赵颖, 王宏亮, 龚天成, 陈其晓, 瞿聪, 杨天学
{"title":"Preparation and Adsorption Characteristics of Novel Molecular Sieve for High Efficiency Arsenic Removal","authors":"许江城, 康得军, 赵颖, 王宏亮, 龚天成, 陈其晓, 瞿聪, 杨天学","doi":"10.13198/J.ISSN.1001-6929.2020.03.19","DOIUrl":"https://doi.org/10.13198/J.ISSN.1001-6929.2020.03.19","url":null,"abstract":"In order to enhance the adsorption performance of 4A molecular sieve for arsenic in aqueous solution,using MS as a carrier,iron-loaded molecular sieves(FMS)and iron-manganese molecular sieves(FMMS)were prepared as adsorbents for arsenic removal by impregnation method.The MS and FMS were characterized by SEM,FT-IR and BET,and carried out batch experiments to investigate the adsorption and removal effects of FMS and FMMS for pentavalent arsenic(As^5+)and trivalent arsenic(As^3+).The adsorption kinetics,isothermal adsorption test and adsorption thermodynamics of the FMS adsorption process were performed.The results show that the specific surface area of FMS is significantly increased and the surface structure of the material is improved.The specific surface area and pore volume of the FMS increased from^27.38 m^2 g and 0.068 cm^3 g to 281.25 m^2 g and 0.16 cm^3 g,respectively.Meanwhile,the average pore size decreased from 9.93 nm to 2.21 nm.This could cause the dense coarse particles to become an adsorbent with loose porous microstructure.FT-IR analysis shows that iron oxide formed in the iron salt impregnation process is mainly combined with O-H,Al-O and Si-O in the molecular sieve structure.The results of batch experiments with 4 mg L As^5+indicate that the removal rate increases by about 70%after the material modification.Moreover,the adsorption process is in accordance with the quasi second-order adsorption kinetics,and the correlation coefficient(R 2)is 0.99,indicating that the chemical adsorption plays an important role in the adsorption process.The Freundlich isotherm adsorption model fits the adsorption data well with a correlation coefficient(R 2)is 0.98,and the maximum adsorption capacity is calculated to be 9.9 mg g.Furthermore,the calculation of thermodynamic parametersΔG,ΔH andΔS find that temperature increase is favorable for adsorption,and the disorder degree between solid and liquid on the surface of the material increases during the reaction.Compared with FMS,FMMS can effectively improve the removal performance of As^3+.The initial concentrationof coexistence conditions wereρ(As^3+As^5+)=2.0,4.0,6.0 mg L,the removal rate of FMMS is increased by about 26.34%,28.06%and 28.09%,respectively.The research shows that the use of iron salt impregnation method to modify MS can effectively increase the adsorption capacity of As^5+and As^3+,and can give full play to the practical application value of the material.","PeriodicalId":21108,"journal":{"name":"环境科学研究","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2020-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44038089","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
环境科学研究Pub Date : 2020-09-01DOI: 10.13198/J.ISSN.1001-6929.2020.06.08
李志鹏, 韩冰, 李志刚, 赵峰, 魏永杰
{"title":"Research Progress on the Effects of Atmospheric PM2.5 and High-Fat Diet on the Incidence of Asthma","authors":"李志鹏, 韩冰, 李志刚, 赵峰, 魏永杰","doi":"10.13198/J.ISSN.1001-6929.2020.06.08","DOIUrl":"https://doi.org/10.13198/J.ISSN.1001-6929.2020.06.08","url":null,"abstract":"Atmospheric PM2.5 exposure is associated with respiratory diseases,and a high-fat diet is also one of the triggers of asthma.In recent years,the prevalence of asthma has been on the rise in China.Discussion on the effects of atmospheric PM2.5,high-fat diet,and their synergistic effects on the prevalence of asthma may provide a new ideas for the interventional treatment of asthma.The present study summarized the effects of PM2.5 exposure and high-fat diet on asthma and the pathogenesis of asthma,and pointed out:(1)The particulate matter exposure can trigger the inflammatory response in the body and increase the risk of asthma.(2)A high-fat diet can cause inflammation through metabolic activation of immune-related signaling pathways in the body.(3)Both can affect asthma inflammation through the MyD88/ TLRs signaling pathway and Th1 /Th2.The study reveals:the mechanism of action of PM2.5 and high-fat diet on asthma is consistent,which may have a synergistic effect on human health.","PeriodicalId":21108,"journal":{"name":"环境科学研究","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2020-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47094188","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
环境科学研究Pub Date : 2020-08-01DOI: 10.13198/J.ISSN.1001-6929.2020.05.36
杨荣金, 孙美莹, 张乐, 张钰莹, 刘伟玲, 李莹杰
{"title":"Strategic Issues of Ecological Environment Protection in the Yangtze River Economic Belt","authors":"杨荣金, 孙美莹, 张乐, 张钰莹, 刘伟玲, 李莹杰","doi":"10.13198/J.ISSN.1001-6929.2020.05.36","DOIUrl":"https://doi.org/10.13198/J.ISSN.1001-6929.2020.05.36","url":null,"abstract":"The development of the Yangtze River Economic Belt is one of the major strategies for coordinated regional development of the country. It is required to protect the ecological environment,and take the road of ecological priority and green development. At present,the economic growth rate of the Yangtze River Economic Belt has slowed down. The industrial structure is continuously optimized. The urbanization is already in the late stage of rapid development. The emission intensity of major pollutants in the Yangtze River Economic Belt continued to decline. The water environment quality has improved significantly,but the water ecology situation is worrying. The continuous and steady improvement of the ecological environment quality has entered a critical period. Through the study of the situation of social economy and ecological environment,this paper proposes the strategic needs and strategic objectives of the future ecological environment protection of the Yangtze River Economic Belt,and puts forward four categories of strategies. The results showed that: (1) The strategic demands for ecological environmental protection in the Yangtze River Economic Belt are to shift from a single element,a single indicator,and some areas to a systematic protection and comprehensive restoration of water ecological environment. (2) The strategic objectives of ecological environmental protection are to shift from water environment quality improvement to water ecological environment security promotion. In the future,the goal will gradually turn to improving the ecological environment health. (3) The spatial control strategy needs to integrate multiple regional plans,and construct a unified division system of ecological environment spatial units in the Yangtze River Economic Belt with basin-region coordination,water-land integration,and mountain-sea unification. (4) The core of the industrial green development strategy is to strengthen prevention and control in related industries that affect the water ecological environment security. (5) The scientific and technological innovation strategy should highlight the role of research platforms to promote the collection and innovation of data,talents,technologies and achievements,and achieve the transformation of ecological environmental protection from investment-driven to technological innovation-driven. (6) The modern governance improvement strategy requires the Yangtze River Economic Belt to build a pilot demonstration belt of ecological civilization,take the lead in improving the system of ecological civilization,construct an ecological environment governance system and improve the capacity of ecological environment governance. According to the research,grasping the strategic demands and objectives of ecological environmental protection,implementing the strategies of spatial control, industrial green development, scientific and technological innovation, and modern governance improvement can more effectively support the in","PeriodicalId":21108,"journal":{"name":"环境科学研究","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2020-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42788895","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}