Reaktor最新文献_第10页

The Kinetics of Calcium Oxide Catalyzed Esterification of Glycerol with Free Fatty Acids Using Pseudo-homogeneous Model Approach 用伪均相模型法研究氧化钙催化甘油与游离脂肪酸酯化反应动力学

Reaktor Pub Date : 2018-05-28 DOI: 10.14710/REAKTOR.18.1.1-6

M. Megawati, D. Hartanto, Catur Rini Widyastuti, Diyah Saras Wati, Eny Nurhayati

{"title":"The Kinetics of Calcium Oxide Catalyzed Esterification of Glycerol with Free Fatty Acids Using Pseudo-homogeneous Model Approach","authors":"M. Megawati, D. Hartanto, Catur Rini Widyastuti, Diyah Saras Wati, Eny Nurhayati","doi":"10.14710/REAKTOR.18.1.1-6","DOIUrl":"https://doi.org/10.14710/REAKTOR.18.1.1-6","url":null,"abstract":"Abstract This research aims to study the reaction kinetics of esterification reaction of glycerol with free fatty acid (FFA) using calcium oxide catalyst to produce mono-diacylglycerol (MDAG) using pseudo-homogeneous approach. The effects of time and temperature on the reaction conversion were investigated simultaneously. The FFA used was from the waste of cocoa production process, while the solid catalyst used was calcium oxide from eggshell ash. The results show that the cocoa based FFA was composed of palmitic acid (49.24%), methyl stearate (1.05%), oleic acid (25.39%), and stearic acid (24.32%). The calcium oxide content in the eggshell ash was 60% w/w. At all temperatures studied (60, 70, and 80oC), as the reaction time increased, the conversion increased sharply in the first 5 minute followed by a gradual raise to an almost constant value after 20 minutes (0.844; 0.845; and 0.854, respectively). Pseudo-homogeneous second order model can describe the reaction kinetics satisfactorily. The reaction constants (k) at 60, 70, and 80oC were 0.00384, 0.003401, and 0.003518 (L/mole.minute), respectively. The effects of temperature on reaction rate obey the Arrhenius’ equation with collision factor (A) is 0.2659 (L/mole.minute) and activation energy (Ea) is 3544 J/mol. Keywords: calcium oxide; free fatty acid; glycerol; pseudo-homogeneous approach","PeriodicalId":20874,"journal":{"name":"Reaktor","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"78885669","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1

Influence of Microwave Irradiation on Extraction of Chitosan from Shrimp Shell Waste 微波辐照对虾壳废渣中壳聚糖提取的影响

Reaktor Pub Date : 2018-05-28 DOI: 10.14710/REAKTOR.18.1.45-50

Dwi Apriyanti, H. Susanto, N. Rokhati

{"title":"Influence of Microwave Irradiation on Extraction of Chitosan from Shrimp Shell Waste","authors":"Dwi Apriyanti, H. Susanto, N. Rokhati","doi":"10.14710/REAKTOR.18.1.45-50","DOIUrl":"https://doi.org/10.14710/REAKTOR.18.1.45-50","url":null,"abstract":"Chitosan is natural polysaccharides which is nontoxic, biodegradable, and biocompatible and have many advantages in various kinds of fields including health, food, agriculture, and industry. Chitosan usually take long time to extract by conventional method for deacetylation process of chitin. Raw material for chitosan can be found in shrimp shell waste. Chitosan manufactures usually need high temperatures and chemicals in large quantities and it takes much time and consumes a lot of energy where will give bad effect to the environment. Recently microwave irradiation as nonconventional energy sources is widely used in chemical reactions. To reduce the impact of environmental pollution due to excessive use of chemical treatment, the objective of this work is processing chitosan under microwave irradiation. Expected production of chitosan with the same mass requires fewer chemicals than conventional heating. In particular, the study will examine the effect of making the chitosan and adding chemicals, reaction time and operating temperature and degree of deacetylation in chitosan with conventional heating methods that the results will be compared using a microwave. In this research will be developed to the design and fabrication of prototype scale extractor for manufacturing chitosan from shrimp shell waste after optimum results obtained from the research laboratory scale. From the research we can conclude that microwave will speed up reaction time. FTIR also showed functional group of chitosan formed from microwave irradiation have same results. Keywords: chitosan, shrimp shells, microwave","PeriodicalId":20874,"journal":{"name":"Reaktor","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"89320328","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 11

Process Parameters Optimization in Membrane Fabrication for Produced Water Treatment Using Response Surface Methodology (RSM) and Central Composite Design (CCD) 基于响应面法和中心复合设计的采出水膜处理工艺参数优化

Reaktor Pub Date : 2018-05-28 DOI: 10.14710/REAKTOR.18.1.7-15

T. Kusworo, D. P. Utomo, Annizah Rahmatya Gerhana, H. A. Putra

{"title":"Process Parameters Optimization in Membrane Fabrication for Produced Water Treatment Using Response Surface Methodology (RSM) and Central Composite Design (CCD)","authors":"T. Kusworo, D. P. Utomo, Annizah Rahmatya Gerhana, H. A. Putra","doi":"10.14710/REAKTOR.18.1.7-15","DOIUrl":"https://doi.org/10.14710/REAKTOR.18.1.7-15","url":null,"abstract":"Produced water is wastewater from oil production that must be treated well. Membrane is one alternative to water treatment technology based on filtration method. But, in the use of a membrane, there’s no exact variable optimal that influences performance of the membrane. This underlying research to assess factors that influences the performance of membrane to be more optimal. Therefore, the objectives of this study determine the optimum variable through Respond Surface Methodology and Central Composite Design. After getting the optimal condition then will check the stability of the membrane. This experiment of optimization of produced water with asymmetric membrane's Polyether sulfone (PES) using Response Surface is done with varying the Zeolite concentration by low level 1% weight and 3% weight, length of UV irradiation time low level 2 minutes and high level 6 minutes, thermal annealing low level 160 ºC and high-level 180ºC. An analyzer done in this research was by processing data research to make table and charts of the relationship between the result of this experiment with changed variable, namely variation of PES concentration, time of UV ray and thermal annealing by using Response Surface Methodology (RSM) and Central Composite Design (CCD).","PeriodicalId":20874,"journal":{"name":"Reaktor","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"80348645","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 2

THE KINETICS OF CaO ASSISTED PATTUKKU CHARCOAL STEAM GASIFICATION CaO辅助巴土库炭蒸汽气化动力学研究

Reaktor Pub Date : 2018-05-28 DOI: 10.14710/REAKTOR.18.1.16-21

T. Syarif, H. Sulistyo, W. B. Sediawan, Budhijanto Budhijanto

{"title":"THE KINETICS OF CaO ASSISTED PATTUKKU CHARCOAL STEAM GASIFICATION","authors":"T. Syarif, H. Sulistyo, W. B. Sediawan, Budhijanto Budhijanto","doi":"10.14710/REAKTOR.18.1.16-21","DOIUrl":"https://doi.org/10.14710/REAKTOR.18.1.16-21","url":null,"abstract":"Abstract Coal is a solid fuel that can be converted into syngas through gasification process. To obtain optimum gasification process design and operation, in-depth understanding of the influential parameters is required. This study aims to investigate the effect of temperature on the gasification process and to obtain its kinetics parameters. The study was carried out in a tubular reactor equipped with a heater and a condenser. Steam was used as gasifying agent, while CaO was employed as a CO2 adsorbent. The charcoal from coal was subjected to gasification at temperatures of 600°C, 700°C, and 800°C. The ratio of charcoal and CaO was 1:1. The gasification process lasted for 60 minutes with gas sample was taken every 15 minutes for composition analysis. The results showed that a temperature increase of 100°C caused a proportional increase of conversion of about 75% higher. The value of activation energy (Ea) and exponential factor (ko) were 46.645kJ/mole and 328.3894/min, respectively. For mass transfer parameters, values of activation energy for surface diffusion (Es) and surface diffusivity factor (as) were 81.126 kJ/mole and 0.138/min, respectively. Keywords: gasification; mathematical model; Pattukku coal char; steam; Thin Reaction Zone Model","PeriodicalId":20874,"journal":{"name":"Reaktor","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75592296","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Lactic Acid Production From Cocoa Pod Husk by Studying Further the Influence of Alkaloids on Fermentation Process using Lactobacillus Plantarum Bacteria 植物乳杆菌发酵过程中生物碱对可可豆荚壳产乳酸影响的进一步研究

Reaktor Pub Date : 2018-05-28 DOI: 10.14710/REAKTOR.18.1.51-56

Dodi Irwanto, Wiratni Wiratni, R. Rochmadi, S. Syamsiah

{"title":"Lactic Acid Production From Cocoa Pod Husk by Studying Further the Influence of Alkaloids on Fermentation Process using Lactobacillus Plantarum Bacteria","authors":"Dodi Irwanto, Wiratni Wiratni, R. Rochmadi, S. Syamsiah","doi":"10.14710/REAKTOR.18.1.51-56","DOIUrl":"https://doi.org/10.14710/REAKTOR.18.1.51-56","url":null,"abstract":"Cocoa Pod Husk (CPH) is the biomass waste from cocoa industry, generated after the digestion process. It accounts for about 70-75% of the cocoa fresh fruit. CPH contains active compounds of alkaloids that are thought to be the inhibitors of the lactic acid fermentation process using microorganisms. This study aims to produce Lactic Acid from CPH by studying further the influence of alkaloids on fermentation process using Lactobacillus plantarum bacteria. Fermentation using Lactobacillus plantarum bacteria was carried out at 50°C and with agitation at 100 rpm in incubator shaker for 48 h. This process was conducted to determine the effect of the addition of alkaloids by analyzing through the comparison between the consumption of substrate (glucose), dry weight of the cell, and the production of lactic acid. Evaluation of the differences in the performance of microorganisms at various treatments was performed based on the parameters values of the kinetic models prepared for the case studied. The kinetic model fitting results showed that the presence of alkaloids alters the growth patterns of products from growth-associated products into mixed patterns because the products were formed during slow growth and stationary phases. The maximum growth rate (μm) and substrate inhibition constant (Ks) obtained on each variation of inhibitor addition were likely to remain constant at the values of 0.69 h-1 and 3.89 g/L respectively, as these parameters were unaffected by the addition of inhibitor","PeriodicalId":20874,"journal":{"name":"Reaktor","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88021378","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 2

THE DEVELOPMENT OF TRANSESTERIFICATION PROCESS OF COTTON SEED OIL BY USING MICROWAVE 微波棉籽油酯交换工艺的研究进展

Reaktor Pub Date : 2018-05-28 DOI: 10.14710/REAKTOR.18.1.27-30

A. Suryanto, H. W. Z. Sabara, A. Artiningsih, H. Ismail

引用次数: 1

Recovery of Aluminum from Aluminum Coated Plastic Waste using Pyrolysis Process 热解法从包铝废塑料中回收铝

Reaktor Pub Date : 2018-05-28 DOI: 10.14710/REAKTOR.18.1.38-44

C. Irawan, R. Jelita, I. F. Nata

{"title":"Recovery of Aluminum from Aluminum Coated Plastic Waste using Pyrolysis Process","authors":"C. Irawan, R. Jelita, I. F. Nata","doi":"10.14710/REAKTOR.18.1.38-44","DOIUrl":"https://doi.org/10.14710/REAKTOR.18.1.38-44","url":null,"abstract":"This study aims to separate aluminum metal in aluminum coated plastic waste so that it is known the obtained aluminum characteristics, to study the effects of temperature on the yield of solids and aluminum, and to get the kinetic parameters that describe the effects of temperature on pyrolysis process rate. Plastic waste was cleaned, dried, cut, and weighed as much as 100 grams. Pyrolysis lasted in room temperature in 2 hours after the pyrolysis temperature was reached, i.e. 450oC. The formed smoke was condensed and weighed every 10 minutes from the first droplet until the pyrolysis time was completed. The remaining solids in the reactor were taken after the pyrolysis was completed and reactor temperature reached room temperature. The aluminum mixture was subsequently melted, molded and cooled. Experiments were repeated in various pyrolysis temperature variations (500°C, 550°C, 600°C and 650°C). The results show that the increase of pyrolysis temperature will decrease the yield of solids, while the aluminum yield remains. The obtained aluminum metal is 5.3% against the initial plastic mass in purity of 95.80%. The kinetic model representing plastic pyrolysis process is a single reaction model with the value of kinetic parameters of pre-exponential factor (A) 18.2689 min-1 and the activation energy value (E) 40.2310 kJ/mole. Keywords: aluminum, pyrolysis, plastic wastes, temperature, kinetic parameter","PeriodicalId":20874,"journal":{"name":"Reaktor","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2018-05-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75889758","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 1