Reactive PolymersPub Date : 1994-11-01DOI: 10.1016/0923-1137(94)90133-3
A. Syamal, M. Singh
{"title":"Synthesis and characterization of polystyrene-supported chelating resin containing an ON donor bidentate Schiff base and its copper(II), nickel(II), cobalt(II), iron(III), zinc(II), molybdenum(VI) and uranium(VI) complexes","authors":"A. Syamal, M. Singh","doi":"10.1016/0923-1137(94)90133-3","DOIUrl":"https://doi.org/10.1016/0923-1137(94)90133-3","url":null,"abstract":"","PeriodicalId":20864,"journal":{"name":"Reactive Polymers","volume":"73 1","pages":"27-34"},"PeriodicalIF":0.0,"publicationDate":"1994-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86078160","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Reactive PolymersPub Date : 1994-10-01DOI: 10.1016/0923-1137(94)90022-1
L. Menard, L. Fontaine, J. Brosse
{"title":"Synthesis and preliminary evaluation of chelating resins containing α-aminoalkylphosphonic groups","authors":"L. Menard, L. Fontaine, J. Brosse","doi":"10.1016/0923-1137(94)90022-1","DOIUrl":"https://doi.org/10.1016/0923-1137(94)90022-1","url":null,"abstract":"","PeriodicalId":20864,"journal":{"name":"Reactive Polymers","volume":"27 1","pages":"201-212"},"PeriodicalIF":0.0,"publicationDate":"1994-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74574516","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Reactive PolymersPub Date : 1994-10-01DOI: 10.1016/0923-1137(94)90028-0
D.C. Sherrington
{"title":"Polymers to the year 2000 and beyond: A Memorial Symposium for Herman F. Marks","authors":"D.C. Sherrington","doi":"10.1016/0923-1137(94)90028-0","DOIUrl":"https://doi.org/10.1016/0923-1137(94)90028-0","url":null,"abstract":"","PeriodicalId":20864,"journal":{"name":"Reactive Polymers","volume":"23 2","pages":"Page 261"},"PeriodicalIF":0.0,"publicationDate":"1994-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0923-1137(94)90028-0","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91676397","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Reactive PolymersPub Date : 1994-10-01DOI: 10.1016/0923-1137(94)90018-3
M. Petro, D. Berek, I. Novák
{"title":"Composite sorbents for liquid chromatography. A size exclusion study of dextran gel incorporated into porous solid particles","authors":"M. Petro, D. Berek, I. Novák","doi":"10.1016/0923-1137(94)90018-3","DOIUrl":"https://doi.org/10.1016/0923-1137(94)90018-3","url":null,"abstract":"","PeriodicalId":20864,"journal":{"name":"Reactive Polymers","volume":"23 1","pages":"173-182"},"PeriodicalIF":0.0,"publicationDate":"1994-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"82020516","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Reactive PolymersPub Date : 1994-10-01DOI: 10.1016/0923-1137(94)90026-4
K. Gokul Chandra, Man Mohan Sharma
{"title":"Cation exchange resins in the synthesis of tert-alkyl ethers of 2-phenylethanol","authors":"K. Gokul Chandra, Man Mohan Sharma","doi":"10.1016/0923-1137(94)90026-4","DOIUrl":"https://doi.org/10.1016/0923-1137(94)90026-4","url":null,"abstract":"<div><p>Two useful perfumery compounds, <em>tert</em>-butyl ether and <em>tert</em>-amyl ether of 2-phenylethanol (PEA) were synthesized by the etherification of PEA with isobutylene gas and isoamylene, respectively, in the presence of macroreticular cation exchange resin as catalyst. A low reaction temperature and a clean method of synthesis and separation of the perfumery compounds have been shown by this work.</p></div>","PeriodicalId":20864,"journal":{"name":"Reactive Polymers","volume":"23 2","pages":"Pages 239-247"},"PeriodicalIF":0.0,"publicationDate":"1994-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0923-1137(94)90026-4","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90013934","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Reactive PolymersPub Date : 1994-10-01DOI: 10.1016/0923-1137(94)90018-3
M. Petro , D. Berek , I. Novák
{"title":"Composite sorbents for liquid chromatography. A size exclusion study of dextran gel incorporated into porous solid particles","authors":"M. Petro , D. Berek , I. Novák","doi":"10.1016/0923-1137(94)90018-3","DOIUrl":"https://doi.org/10.1016/0923-1137(94)90018-3","url":null,"abstract":"<div><p>The novel class of column packings for high-performance liquid chromatography was prepared. These materials are formed by silica-, polyhydroxyethylmethacrylate-, or carbon-based macroporous solid particles with pores filled by a soft dextran network. They were examined by inverse size-exclusion chromatography. The analytes, which are small enough to penetrate the dextran network, can interact selectively with the support surface. Such interactions may be either suppressed by an appropriate deactivation of the support surface prior to dextran incorporation or utilized for special applications in which retention of small molecules of analytes is combined with steric exclusion of large molecules of interference.</p></div>","PeriodicalId":20864,"journal":{"name":"Reactive Polymers","volume":"23 2","pages":"Pages 173-182"},"PeriodicalIF":0.0,"publicationDate":"1994-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0923-1137(94)90018-3","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"90013935","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Reactive PolymersPub Date : 1994-10-01DOI: 10.1016/0923-1137(94)90019-1
Z. Plichta, J. Lenfeld, M. Beneš, W. Scouten
{"title":"Preparation of gelatin spherical microparticles in aqueous polymer suspension","authors":"Z. Plichta, J. Lenfeld, M. Beneš, W. Scouten","doi":"10.1016/0923-1137(94)90019-1","DOIUrl":"https://doi.org/10.1016/0923-1137(94)90019-1","url":null,"abstract":"","PeriodicalId":20864,"journal":{"name":"Reactive Polymers","volume":"56 1","pages":"183-186"},"PeriodicalIF":0.0,"publicationDate":"1994-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88121242","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Reactive PolymersPub Date : 1994-10-01DOI: 10.1016/0923-1137(94)90016-7
N. Yoshino, H. Nakaseko, Y. Yamamoto
{"title":"Syntheses and reactions of metal organics, XX. Syntheses of silane-coupling agents having end-branch fluorocarbon chain and surface modification of glass","authors":"N. Yoshino, H. Nakaseko, Y. Yamamoto","doi":"10.1016/0923-1137(94)90016-7","DOIUrl":"https://doi.org/10.1016/0923-1137(94)90016-7","url":null,"abstract":"","PeriodicalId":20864,"journal":{"name":"Reactive Polymers","volume":"67 1","pages":"157-163"},"PeriodicalIF":0.0,"publicationDate":"1994-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"87176995","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Reactive PolymersPub Date : 1994-10-01DOI: 10.1016/0923-1137(94)90002-7
B.N. Kolarz , J. Jezierska , D. Bartkowiak , A. Gontarczyk
{"title":"Acrylic resins with complexes of guanidyl groups and copper(II)","authors":"B.N. Kolarz , J. Jezierska , D. Bartkowiak , A. Gontarczyk","doi":"10.1016/0923-1137(94)90002-7","DOIUrl":"10.1016/0923-1137(94)90002-7","url":null,"abstract":"<div><p>Heating of acrylonitrile, vinyl acetate and divinylbenzene porous copolymers (AN-VA-DVB) with aminoguanidine salts in alkaline medium leads to aminolysis and hydrolysis of the nitrile groups and hydrolysis of acetyl groups. As a result, an amphoteric chelating resin with guanidyl and carboxyl groups at a concentration of <em>ca</em>. 13and 2–4 mmol/g, respectively, is obtained. The resin possesses a porous structure with a mean pore radius of 5.6 nm in swollen state. The sorption of Cu(II) ions increases with increasing content of functional groups, and reaches 120–170 mg/g at pH 5. The equilibrium sorption is attained after 300 min. The infrared (IR) spectra of resins confirm that both guanidyl and carboxyl groups form complexes with Cu(II) ions. From analysis of the sorption degree of Cu(II) ions it can be concluded that statistically two groups (carboxyl or/and guanidyl) participate in the complexation. Electron paramagnetic resonance (EPR) spectra of the resins suggest that at low pH the complexes of Cu(II) ions with carboxyl groups dominate. At the pH range 3–8 the formation of Cu(II) complexes with carboxyl and guanidyl groups is evident. At pH > 9 three or four nitrogen atoms participate in coordination sphere around Cu(II).</p></div>","PeriodicalId":20864,"journal":{"name":"Reactive Polymers","volume":"23 2","pages":"Pages 53-61"},"PeriodicalIF":0.0,"publicationDate":"1994-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0923-1137(94)90002-7","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73578454","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}