Progress in Natural Science: Materials International最新文献

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Superior triethylamine-sensing properties based on SnO2 hollow nanospheres synthesized via one-step process 基于一步法合成的 SnO2 中空纳米球的卓越三乙胺传感性能
IF 4.8 2区 材料科学
Progress in Natural Science: Materials International Pub Date : 2024-08-01 DOI: 10.1016/j.pnsc.2024.05.015
{"title":"Superior triethylamine-sensing properties based on SnO2 hollow nanospheres synthesized via one-step process","authors":"","doi":"10.1016/j.pnsc.2024.05.015","DOIUrl":"10.1016/j.pnsc.2024.05.015","url":null,"abstract":"<div><p>Due to serious harm of triethylamine (TEA) to environmental safety and human health, it is significant to synthesize gas-sensitive materials with high performance for TEA detection. However, it is still a challenge to achieve high-sensitivity detection of TEA at low temperature for a sensor synthesized through an economical and efficient method. In this work, hollow-structured SnO<sub>2</sub> (HS-SnO<sub>2</sub><span>) nanospheres<span><span> have been fabricated by a facile, low-cost hydrothermal method in one step, which exhibit superior TEA-sensing properties, including not only ultrahigh response (127.75) for 100 ​ppm TEA, good selectivity, but also fast response and recovery time (17/28 ​s), low detection threshold (1 ​ppm) and robust stability at a relatively low optimum operational temperature of 225 ​°C. The excellent gas-sensitizing performances are ascribed to porous hollow structures with rich </span>oxygen vacancies that provide abundant active sites for raising O</span></span><sub>2</sub> adsorption and reaction of TEA and oxygen species. This work offers an effective and economical strategy for fabricating high-performance TEA sensors for industrial applications.</p></div>","PeriodicalId":20742,"journal":{"name":"Progress in Natural Science: Materials International","volume":null,"pages":null},"PeriodicalIF":4.8,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141412513","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Zero thermal expansion in NiPt(CN)6 NiPt(CN)6 的零热膨胀
IF 4.8 2区 材料科学
Progress in Natural Science: Materials International Pub Date : 2024-08-01 DOI: 10.1016/j.pnsc.2024.06.010
{"title":"Zero thermal expansion in NiPt(CN)6","authors":"","doi":"10.1016/j.pnsc.2024.06.010","DOIUrl":"10.1016/j.pnsc.2024.06.010","url":null,"abstract":"<div><p>Nowadays, an increasing number of scientists attach more importance to zero thermal expansion (ZTE) materials which are uncommon yet highly significant in the field of solid-state materials. The key to explore new ZTE compounds is to understand the mechanism, while it remains unclear. Here, we utilize density functional theory calculations to elucidate the mechanisms of NiPt(CN)<sub>6</sub><span>. A joint study of bond nature, atomic mean-square displacements, phonon<span> dispersion curves, Grüneisen parameters, and phonon<span> vibrations to systematically analyze the ZTE mechanisms. The results suggest that the transverse vibrations of the –C≡N− groups are instrumental, particularly due to the involvement of the N atoms and the nature of the Ni–N and Pt–C bonds. Phonon modes with negative Grüneisen parameters at low frequencies play the mainly role to balance the positive thermal expansion from others frequency zone modes to obtain the ZTE behavior. This work demonstrates that NiPt(CN)</span></span></span><sub>6</sub><span> maintains substantial similarities with its trivalent-trivalent analogues, further enhancing our comprehension of NTE properties within open-framework structure.</span></p></div>","PeriodicalId":20742,"journal":{"name":"Progress in Natural Science: Materials International","volume":null,"pages":null},"PeriodicalIF":4.8,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141706321","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation of a novel ultra-high strength Al–Si–Cu–Ni alloy at room/elevated temperature by squeeze casting combined with a new heat treatment process 通过挤压铸造结合新型热处理工艺在室温/高温下制备新型超高强度铝-硅-铜-镍合金
IF 4.8 2区 材料科学
Progress in Natural Science: Materials International Pub Date : 2024-08-01 DOI: 10.1016/j.pnsc.2024.06.006
{"title":"Preparation of a novel ultra-high strength Al–Si–Cu–Ni alloy at room/elevated temperature by squeeze casting combined with a new heat treatment process","authors":"","doi":"10.1016/j.pnsc.2024.06.006","DOIUrl":"10.1016/j.pnsc.2024.06.006","url":null,"abstract":"<div><p><span><span><span>In this paper, the microstructure evolution and properties of squeeze-cast Al–8Si-1.5Cu–1Ni-0.5Mg-0.5Mn-0.2V-0.2Ti-0.2Zr alloy (hereafter, Al–Si–Cu–Ni alloy for short) were investigated under various solution processes, evaluating the mechanical properties at room and elevated temperatures for both as-cast and T6-treated states. The results showed that following the optimal two-stage solution (i.e., solution at 510 ​°C for 6 ​h ​+ ​solution at 530 ​°C for 8 ​h) and subsequent aging at 190 ​°C for 10 ​h, referred to as the S530-T6 treatment, the Al–Si–Cu–Ni alloy exhibited excellent room/high temperature performance. The </span>ultimate tensile strength<span> (UTS), yield strength (YS) and elongation of the alloy at room temperature were 410 ​MPa, 368 ​MPa and 1.5 ​%, and the UTS, YS and elongation of alloy at 300 ​°C were 177 ​MPa, 170 ​MPa and 6 ​%, respectively. The increase in strength at room temperature is mainly attributed to the spheroidization of </span></span>eutectic<span> silicon and the precipitate strengthening aroused from uniformly dispersed nano-sized Q-Al</span></span><sub>4</sub>Cu<sub>2</sub>Mg<sub>8</sub>Si<sub>7</sub>, σ-Al<sub>5</sub>Cu<sub>6</sub>Mg<sub>2</sub> and θ′-Al<sub>2</sub><span><span>Cu phases, while the increase in strength at high temperature is due to the formation of heat-resistant Ni-rich phases and the improvement of the micromorphology of high melting point </span>intermetallic compounds.</span></p></div>","PeriodicalId":20742,"journal":{"name":"Progress in Natural Science: Materials International","volume":null,"pages":null},"PeriodicalIF":4.8,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142041173","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A regeneration strategy based on synchronous utilization in surface impurities of degradation nickel-rich material 基于同步利用降解富镍材料表面杂质的再生战略
IF 4.8 2区 材料科学
Progress in Natural Science: Materials International Pub Date : 2024-08-01 DOI: 10.1016/j.pnsc.2024.06.002
{"title":"A regeneration strategy based on synchronous utilization in surface impurities of degradation nickel-rich material","authors":"","doi":"10.1016/j.pnsc.2024.06.002","DOIUrl":"10.1016/j.pnsc.2024.06.002","url":null,"abstract":"<div><p>The LiNi<sub>0.83</sub>Co<sub>0.12</sub>Mn<sub>0.05</sub>O<sub>2</sub><span><span> (Ni-rich NCM) cathode materials have been widely studied owing to their high </span>energy density and excellent rate capability. However, Ni-rich NCM is prone to form large amounts of lithium impurities and causes structural decline, resulting in inconvenient material storage. To this end, Li</span><sub>4</sub>SiO<sub>4</sub>/SiO<sub>2</sub> was used as a structural regulator to eliminate the residual lithium and convert the irreversible phase. The Li<sub>4</sub>SiO<sub>4</sub>/SiO<sub>2</sub> protective coating effectively suppresses the corrosion of the electrolyte by blocking the direct contact between the electrode and the electrolyte, while having a high air stability under the hydrophobic action. In addition, SiO<sub>2</sub><span> has excellent corrosion resistance, which further enhances the cyclic stability of the material. The obtained regenerated NCM material displayed a great capacity of 198.6 mAh g</span><sup>−1</sup><span> at 0.3 ​C and long cycling stability (capacity retention of 82.2 ​% after 250 cycles). This simple repair strategy significantly reduces the loss rate in industrial production and enhances the electrochemical performance while achieving material reuse.</span></p></div>","PeriodicalId":20742,"journal":{"name":"Progress in Natural Science: Materials International","volume":null,"pages":null},"PeriodicalIF":4.8,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142041175","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Visualisation study on water management of cathode dead-ended PEMFC under pressure-swing operation 压力摆动运行下阴极死端 PEMFC 水管理的可视化研究
IF 4.8 2区 材料科学
Progress in Natural Science: Materials International Pub Date : 2024-08-01 DOI: 10.1016/j.pnsc.2024.07.010
{"title":"Visualisation study on water management of cathode dead-ended PEMFC under pressure-swing operation","authors":"","doi":"10.1016/j.pnsc.2024.07.010","DOIUrl":"10.1016/j.pnsc.2024.07.010","url":null,"abstract":"<div><p><span>Dead-ended proton exchange membrane fuel cells (PEMFC) using pure hydrogen oxygen can improve fuel efficiency and simplify fuel cell systems have been wildly used for a closed space. But the dead-ended operation of the PEMFC will cause difficulties in water management, especially in the </span>cathode side<span>, resulting in deteriorating of fuel cell stability. For this reason, gravity assisted drainage method, static drainage method are designed to migrate the water out of the cell. However, even with these methods, the reliability of the water removing from the cell remains questionable. Therefore, this paper introduces a novel water removal method to solve these problems and visualisation techniques were used to a more comprehensive knowledge of water transport mechanisms in dead-ended PEMFCs. A pressure-swing operation is realized by controlling the inlet of PEMFC solenoid valve to remove water and recycle oxygen during purging. The dynamic response characteristics of this system under different current densities, pressure differences, cell temperature and purging intervals are experimentally investigated in detail. It found that the water removal rate of the cathode flow channel of dead-ended PEMFC was as high as 99.25 ​%, and the fuel utilisation of the cell was close to 100 ​% in this water management mode.</span></p></div>","PeriodicalId":20742,"journal":{"name":"Progress in Natural Science: Materials International","volume":null,"pages":null},"PeriodicalIF":4.8,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141851837","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Dual-phase competitive behavior in N-type Sn–Bi–Te thermoelectric films achieving high thermoelectric performance 实现高热电性能的 N 型锡-铋-碲热电薄膜中的双相竞争行为
IF 4.8 2区 材料科学
Progress in Natural Science: Materials International Pub Date : 2024-08-01 DOI: 10.1016/j.pnsc.2024.07.008
{"title":"Dual-phase competitive behavior in N-type Sn–Bi–Te thermoelectric films achieving high thermoelectric performance","authors":"","doi":"10.1016/j.pnsc.2024.07.008","DOIUrl":"10.1016/j.pnsc.2024.07.008","url":null,"abstract":"<div><p>The dual-phase competitive behavior is introduced as an effective strategy to optimize the physical and chemical properties of N-type Bi<sub>2</sub>Te<sub>3</sub> thermoelectric (TE) materials. Controllable SnTe-embedded Bi<sub>2</sub>Te<sub>3</sub><span> nanocomposites can be synthesized with the addition of excessive Sn into Bi</span><sub>2</sub>Te<sub>3</sub> by tuning the crystallization behavior under proper thermal heating temperature. Notably, the precipitation temperature of Bi<sub>2</sub>Te<sub>3</sub> increases from 473 ​K for Sn<sub>20.9</sub>(Bi<sub>2</sub>Te<sub>3</sub>)<sub>79.1</sub> to 573 ​K for Sn<sub>34.4</sub>(Bi<sub>2</sub>Te<sub>3</sub>)<sub>65.6</sub><span>, expanding the controllable temperature span for the presence of SnTe phase. The second-phase nanoprecipitate SnTe can improve electrical conductivity by competing with the Bi</span><sub>2</sub>Te<sub>3</sub><span><span> phase, achieving an increase of four orders of magnitude at the critical temperature of ∼500 ​K. Simultaneously, it increases the interfacial energy filtration effect between </span>nanocrystalline<span> grains, decoupling electrical parameters between conductivity and Seebeck coefficient. Consequently, the high power factor of ∼147 ​μW/mK</span></span><sup>2</sup> at 650 ​K for optimized Sn<sub>26.6</sub>(Bi<sub>2</sub>Te<sub>3</sub>)<sub>73.4</sub> films can be obtained, which is more than twice that of the pure Bi<sub>2</sub>Te<sub>3</sub> material. Our work demonstrates a new physical mechanism to unravel the complicated structure-property relationship by dual-phase competitive behavior during phase transition. This study fills the gap in knowledge on the effects of the SnTe phase regarding the Bi<sub>2</sub>Te<sub>3</sub><span> system and provides guidance for the innovative design of high-performing inorganic thermoelectrics.</span></p></div>","PeriodicalId":20742,"journal":{"name":"Progress in Natural Science: Materials International","volume":null,"pages":null},"PeriodicalIF":4.8,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141697302","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A modified maxwell-pulse thermoplastic constitutive model of in-situ Ta-particle reinforced Zr-based bulk metallic glass composites 原位 Ta 粒子增强 Zr 基块状金属玻璃复合材料的修正麦克斯韦脉冲热塑性结构模型
IF 4.8 2区 材料科学
Progress in Natural Science: Materials International Pub Date : 2024-08-01 DOI: 10.1016/j.pnsc.2024.07.004
{"title":"A modified maxwell-pulse thermoplastic constitutive model of in-situ Ta-particle reinforced Zr-based bulk metallic glass composites","authors":"","doi":"10.1016/j.pnsc.2024.07.004","DOIUrl":"10.1016/j.pnsc.2024.07.004","url":null,"abstract":"<div><p><span>The impact of different Ta contents on the mechanical properties and thermoplastic<span> forming ability of in-situ Ta-particle reinforced Zr–Cu–Al–Ni bulk metallic glass composites was studied. The composition (Zr</span></span><sub>55</sub>Cu<sub>30</sub>Al<sub>10</sub>Ni<sub>5</sub>)<sub>94</sub>Ta<sub>6</sub><span><span> with the best comprehensive performance was chose for a systematic investigation into its thermoplastic behavior<span> in the supercooled liquid region (SLR), with quantitative analysis conducted by the strain rate sensitivity<span><span> index and activation volume<span>. The steady-state flow stress and the stress overshoot intensity were augmented with deformation temperature decreasing, </span></span>strain rate increasing, and the addition of the secondary phase, leading to a transition from Newtonian to non-Newtonian flow regime. The addition of the secondary phase deteriorated the rheological properties of the material. To solve the problem that the Maxwell-Pulse constitutive model showed an inability to accurately describe the steady-state flow process. A modified constitutive relationship, introducing the effect of the volume fraction of Ta particles on </span></span></span>viscosity<span> and elastic modulus<span><span> in the steady-state flow process which was ignored in Maxwell-pulse model, was established. The fitting results of the true stress-strain curves of the modified Maxwell-pulse constitutive model were in better agreement with the experimental date than those of the Maxwell-pulse constitutive model, with higher prediction accuracy. The modified constitutive model well predicted the thermoplastic </span>deformation behavior of (Zr</span></span></span><sub>55</sub>Cu<sub>30</sub>Al<sub>10</sub>Ni<sub>5</sub>)<sub>94</sub>Ta<sub>6</sub><span>. The influence mechanism of Ta particles on the flow behavior was explained that Ta particles increased the viscosity of amorphous matrix, thereby hindering its flow and ultimately leading to an increase in flow stress.</span></p></div>","PeriodicalId":20742,"journal":{"name":"Progress in Natural Science: Materials International","volume":null,"pages":null},"PeriodicalIF":4.8,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141708259","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
From waste to added-value product: A case of efficient separation and recovery of zinc and iron from spent galvanizing acid 从废物到增值产品:从废镀锌酸中高效分离和回收锌和铁的案例
IF 4.8 2区 材料科学
Progress in Natural Science: Materials International Pub Date : 2024-08-01 DOI: 10.1016/j.pnsc.2024.06.005
{"title":"From waste to added-value product: A case of efficient separation and recovery of zinc and iron from spent galvanizing acid","authors":"","doi":"10.1016/j.pnsc.2024.06.005","DOIUrl":"10.1016/j.pnsc.2024.06.005","url":null,"abstract":"<div><p><span><span><span>Spent galvanizing acid solution contains high concentrations of zinc salts, ferrous salts, and residual acids, exhibiting extremely high value-added recovery potential. However, achieving the efficient extraction and separation of Zn over Fe becomes particularly challenging under elevated Zn </span>ion concentration<span>. Here, the key extraction parameters, such as modifier ratio, Cyanex 923 concentration and ratio of organic phase to aqueous phase (O/A), are investigated. The stripping and regeneration of extractant, extraction mechanism, as well as high-value recovery of Zn and Fe resources are also comprehensively expounded. After the two-stage extraction, the extraction efficiency of Zn and Fe is 98.92 ​% and 2.09 ​%, respectively. Moreover, the stripping efficiency of Zn reaches 92.3 ​% with O/A ratio of 1 : 2, using </span></span>oxalic acid as stripping agent. The predominant extracted species is confirmed to be </span><span><math><mrow><mtext>Zn</mtext><msubsup><mtext>Cl</mtext><mn>3</mn><mo>−</mo></msubsup></mrow></math></span>, resulting in the formation of <span><math><mrow><mtext>HZn</mtext><msub><mtext>Cl</mtext><mn>3</mn></msub><mo>∙</mo><msub><mi>R</mi><mn>3</mn></msub><mtext>PO</mtext></mrow></math></span><span> complex. More importantly, the regenerated extractant can be recycled back into the extraction process, and the reproduced HCl, high-value recovered ZnO and Fe</span><sub>2</sub>O<sub>3</sub> can be used for different industrial fields. These findings lay a solid foundation for the efficient separation and comprehensive recovery of high-concentration spent galvanizing acid solution.</p></div>","PeriodicalId":20742,"journal":{"name":"Progress in Natural Science: Materials International","volume":null,"pages":null},"PeriodicalIF":4.8,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142041174","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microscopic strengthening and failure mechanisms of graphene/Al composite: A molecular dynamics study 石墨烯/铝复合材料的微观强化和失效机理:分子动力学研究
IF 4.8 2区 材料科学
Progress in Natural Science: Materials International Pub Date : 2024-08-01 DOI: 10.1016/j.pnsc.2024.06.009
{"title":"Microscopic strengthening and failure mechanisms of graphene/Al composite: A molecular dynamics study","authors":"","doi":"10.1016/j.pnsc.2024.06.009","DOIUrl":"10.1016/j.pnsc.2024.06.009","url":null,"abstract":"<div><p><span><span>This study focused on the microscopic strengthening and failure mechanisms of the Al matrix reinforced by graphene (Gr), and the effects of number of layers, </span>chirality<span>, and arrangement of Gr were calculated based on the molecular dynamics simulation. The results revealed that the Young's modulus and yield strength were significantly enhanced by the addition of Gr. In Gr/Al composites with monolayer Gr, the zigzag Gr exhibited a better ultimate strain than the armchair Gr, indicating that the </span></span>plastic deformation<span><span><span> was affected by the chirality, and the dislocation hindrance and load transfer were the dominated strengthening mechanisms. The crack in the armchair Gr was limited to follow straight paths, while that in zigzag Gr extended in a petal-like manner across multiple directions. In Gr/Al composite with multilayer Gr, the dispersing Gr showed a stronger </span>strengthening effect than the stacking Gr, and the strengthening effect increased with increasing the volume fraction of Gr. The dispersing Gr strongly hindered the movement of dislocations, while the Al matrix in the composite with stacking Gr could retard the folding of Gr. Moreover, Gr </span>nanosheets fractured layer by layer rather than simultaneously fractured in the Gr/Al composites with multilayer Gr.</span></p></div>","PeriodicalId":20742,"journal":{"name":"Progress in Natural Science: Materials International","volume":null,"pages":null},"PeriodicalIF":4.8,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141712150","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Promoted reverse water-gas shift activity on transition metals-incorporated iron-cerium oxide solid solution catalyst 促进过渡金属掺杂氧化铁铈固溶体催化剂的反向水气变换活性
IF 4.8 2区 材料科学
Progress in Natural Science: Materials International Pub Date : 2024-08-01 DOI: 10.1016/j.pnsc.2024.05.011
{"title":"Promoted reverse water-gas shift activity on transition metals-incorporated iron-cerium oxide solid solution catalyst","authors":"","doi":"10.1016/j.pnsc.2024.05.011","DOIUrl":"10.1016/j.pnsc.2024.05.011","url":null,"abstract":"<div><p><span>Earth-abundant Fe oxide-based catalysts, renowned for their broad-spectrum light absorption, hold promise for driving the photothermal RWGS reaction—a promising strategy for converting CO</span><sub>2</sub><span> emissions into valuable carbonaceous feedstocks. However, traditional Fe oxide-based catalysts exhibit limited activity due to their constrained H</span><sub>2</sub> dissociation and CO<sub>2</sub> activation capabilities, especially at lower temperatures. This study introduces Co, Ni, and Cu-doped Ce<sub>0.7</sub>Fe<sub>0.3</sub>O<sub>2</sub> solid-solution catalysts. Incorporation of Fe into CeO<sub>2</sub> enhances CO<sub>2</sub> dissociation while preserving extensive light adsorption up to 2500 ​nm. Notably, Co doping enhances H<sub>2</sub> dissociation and promotes CO<sub>2</sub> activation. Subsequent investigations reveal that a catalyst doped with 5 ​mol% Co exhibits the highest photothermal catalytic activity, attaining a ∼50 ​% CO<sub>2</sub> conversion under 300 ​W Xe-lamp irradiation with excellent selectivity and stability over 10 reaction cycles spanning 10 ​h. These results underscore the potential of designing CeO<sub>2</sub><span><span>-based solid solution catalysts with synergistic metal </span>dopants for efficient and selective CO</span><sub>2</sub> conversion under moderate conditions.</p></div>","PeriodicalId":20742,"journal":{"name":"Progress in Natural Science: Materials International","volume":null,"pages":null},"PeriodicalIF":4.8,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141842861","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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