Progress in Natural Science: Materials International最新文献

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Large pyroelectric current generation induced by droplet cooling 液滴冷却诱导产生大热释电电流
IF 4.8 2区 材料科学
Progress in Natural Science: Materials International Pub Date : 2024-10-01 DOI: 10.1016/j.pnsc.2024.07.006
Wanying Zhang , Modi Jiang , Yanming Liu , Weizheng Cheng , Yang Li , Kexian Song , Peng Tao , Chengyi Song , Benwei Fu , Tao Deng , Wen Shang
{"title":"Large pyroelectric current generation induced by droplet cooling","authors":"Wanying Zhang ,&nbsp;Modi Jiang ,&nbsp;Yanming Liu ,&nbsp;Weizheng Cheng ,&nbsp;Yang Li ,&nbsp;Kexian Song ,&nbsp;Peng Tao ,&nbsp;Chengyi Song ,&nbsp;Benwei Fu ,&nbsp;Tao Deng ,&nbsp;Wen Shang","doi":"10.1016/j.pnsc.2024.07.006","DOIUrl":"10.1016/j.pnsc.2024.07.006","url":null,"abstract":"<div><div><span>This paper demonstrates an alternative and simple approach for achieving a fast temperature change on a pyroelectric system through droplet cooling, which leads to enhancement in pyroelectric current generation. The pyroelectric system was composed of a pyroelectric layer of lithium tantalate (LiTaO</span><sub>3</sub>) that was sandwiched between two layers of gold/titanium (Au/Ti) as the top and bottom electrodes. Due to both high latent heat and sensible heat of water, there was a rapid heat exchange during the droplet cooling process, and the pyroelectric layer underwent a fast temperature change with the maximum rate of ∼725 ​°C/s. The induced pyroelectric current density reached as high as ∼8.8 ​μA/cm<sup>2</sup><span><span>. Such pyro-current density is among the highest reported so far. The pyroelectric response was also investigated by using the surfaces with different wettability. The </span>hydrophilic surfaces<span> underwent faster heat dissipation, leading to the generation of larger current than that of the hydrophobic surfaces<span> during the droplet cooling process. This work may help expand the utilization of pyroelectric materials in various applications that involve the current generation using pyroelectric effect.</span></span></span></div></div>","PeriodicalId":20742,"journal":{"name":"Progress in Natural Science: Materials International","volume":"34 5","pages":"Pages 888-894"},"PeriodicalIF":4.8,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141840574","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Molecular dynamics simulations of microstructure and dislocation evolution of single-crystal Ni-based superalloys under femtosecond laser loading 飞秒激光加载下单晶镍基超合金微观结构和位错演变的分子动力学模拟
IF 4.8 2区 材料科学
Progress in Natural Science: Materials International Pub Date : 2024-10-01 DOI: 10.1016/j.pnsc.2024.06.008
Peng Shen , Xuesong Mei , Tao Sun , Xueshi Zhuo , Xiaomao Sun , Wenjun Wang , Jianlei Cui , Zhengjie Fan
{"title":"Molecular dynamics simulations of microstructure and dislocation evolution of single-crystal Ni-based superalloys under femtosecond laser loading","authors":"Peng Shen ,&nbsp;Xuesong Mei ,&nbsp;Tao Sun ,&nbsp;Xueshi Zhuo ,&nbsp;Xiaomao Sun ,&nbsp;Wenjun Wang ,&nbsp;Jianlei Cui ,&nbsp;Zhengjie Fan","doi":"10.1016/j.pnsc.2024.06.008","DOIUrl":"10.1016/j.pnsc.2024.06.008","url":null,"abstract":"<div><div>In this paper, molecular dynamics simulations are employed to investigate the temperature, stress distribution, microstructure and evolution of dislocations in single-crystal Ni-based superalloys during femtosecond laser drilling of micro-holes. The results indicate that the temperature and stress variations in the model system increase with the increment of laser energy density. The pulse width has a relatively low effect on temperature and stress variations. At the same time, an increase in dislocations is primarily related to energy density and stress distribution. The number of dislocations increases with the energy density, with the 1/6&lt;112&gt; dislocation showing the highest increase ratio. The densest concentration of dislocations occurs at the hole walls. Dislocations and stacking faults gradually penetrate the precipitate phase under the influence of temperature and reach a stable state as the relaxation time increases. The above research findings provide important theoretical guidance for understanding the microstructure evolution and changes in the mechanical properties of single-crystal Ni-based superalloys during femtosecond laser processing of micro-holes.</div></div>","PeriodicalId":20742,"journal":{"name":"Progress in Natural Science: Materials International","volume":"34 5","pages":"Pages 942-954"},"PeriodicalIF":4.8,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141845555","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Biologically inspired shell-hollow particles for designing efficient passive all-sky radiative cooling 设计高效被动式全天空辐射冷却的生物壳空心微粒
IF 4.8 2区 材料科学
Progress in Natural Science: Materials International Pub Date : 2024-10-01 DOI: 10.1016/j.pnsc.2024.08.009
Shangsheng Zhang , Zengzhi Zhang , Kai Chen , Shuman Xu , Xunkai Luo , Yang Liu , Jian Wang , Shijie Han , Yulian Li , Hongmei Du
{"title":"Biologically inspired shell-hollow particles for designing efficient passive all-sky radiative cooling","authors":"Shangsheng Zhang ,&nbsp;Zengzhi Zhang ,&nbsp;Kai Chen ,&nbsp;Shuman Xu ,&nbsp;Xunkai Luo ,&nbsp;Yang Liu ,&nbsp;Jian Wang ,&nbsp;Shijie Han ,&nbsp;Yulian Li ,&nbsp;Hongmei Du","doi":"10.1016/j.pnsc.2024.08.009","DOIUrl":"10.1016/j.pnsc.2024.08.009","url":null,"abstract":"<div><div>Passive radiation cooling (PRC), as the most promising technology to meet future cooling needs, has attracted great interest. However, there are still huge challenges in manufacturing high-efficiency and low-cost radiant coolers suitable for all-day use. Here, we report a secondary micro-nano shell-hollow structure based on blending method, inspired by the African white beetle Goliathus goliatus. Due to the difference in reflectance between the shell and the internal air, compared with the homogeneous particles, the scattered light has a changed optical path at the interface of the core (air) and the shell (SiO<sub>2</sub>), and most of the light escapes from the particles, showing strong total internal reflection. The design ingeniously deposits the nano-sized shell-hollow structure on the surface of the micron-sized shell-hollow structure, achieving high solar reflectance (95 ​%)and excellent long-wave infrared emissivity (94 ​%). Sub-ambient cooling of 7.8 and 4.7 ​°C can be achieved at night and daytime, respectively. Silica microspheres with shell and hollow structure can be prepared by soft template method, which is mature, reliable, simple and cheap.Our work provides new ideas for the design and manufacture of high-performance Passive all-day radiative cooling (PARC).</div></div>","PeriodicalId":20742,"journal":{"name":"Progress in Natural Science: Materials International","volume":"34 5","pages":"Pages 1093-1099"},"PeriodicalIF":4.8,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142571242","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Efficient and highly selective photocatalytic reduction of Cr(VI) by an active two-dimensional covalent organic framework 活性二维共价有机框架高效、高选择性地光催化还原六价铬
IF 4.8 2区 材料科学
Progress in Natural Science: Materials International Pub Date : 2024-10-01 DOI: 10.1016/j.pnsc.2024.09.004
Yuxuan Bai, Yunzi Wang, Junyu Chen, Keda Zhu, Jianjun Wang
{"title":"Efficient and highly selective photocatalytic reduction of Cr(VI) by an active two-dimensional covalent organic framework","authors":"Yuxuan Bai,&nbsp;Yunzi Wang,&nbsp;Junyu Chen,&nbsp;Keda Zhu,&nbsp;Jianjun Wang","doi":"10.1016/j.pnsc.2024.09.004","DOIUrl":"10.1016/j.pnsc.2024.09.004","url":null,"abstract":"<div><div>In this paper, a two-dimensional covalent organic framework material (named HDU-27) with thiazole structure and π-π conjugation has been successfully synthesized using the ligands tri acetaldehyde-based methoxyphenyl and benzo [1,2-d:4,5-d]thiazole-2,6-diamine in an ammonia-formaldehyde condensation reaction and applied to the photocatalytic reduction study of chromium (Cr). The photocatalytic experiments showed that HDU-27 had an excellent photocatalytic reduction of Cr(VI) with a high Cr(VI) reduction efficiency of 99.5 ​% at pH ​= ​2 for 60 ​min. In the presence of interfering ions, HDU-27 exhibited excellent selectivity for Cr(VI). Mechanistic experiments and electron spin resonance characterization identified e<sup>−</sup> and ·O<sub>2</sub><sup>−</sup> radicals as the main active species in Cr(VI) photocatalytic reduction. In addition, the photocatalytic rate of HDU-27 was significantly accelerated in the Cr(VI)/organic pollutant (RhB, MB, MO) mixed system due to the oxidation of the organic matter and the increase in the separation of photogenerated e<sup>−</sup>−h<sup>+</sup>. The cycling experiments demonstrated the excellent reduction stability and recyclability of HDU-27 in the photocatalytic reduction of Cr(VI). HDU-27 is an excellent photocatalyst with potential application for removing organic pollutants and heavy metal ions from contaminated wastewater.</div></div>","PeriodicalId":20742,"journal":{"name":"Progress in Natural Science: Materials International","volume":"34 5","pages":"Pages 933-941"},"PeriodicalIF":4.8,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142571701","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hydrothermal-deposition synthesis of MnO2/MnS nanorods as high-performance asymmetric supercapacitor positive electrode materials 水热沉积合成 MnO2/MnS 纳米棒作为高性能不对称超级电容器正极材料
IF 4.8 2区 材料科学
Progress in Natural Science: Materials International Pub Date : 2024-10-01 DOI: 10.1016/j.pnsc.2024.07.023
Ziming Wang , Hanbo Wang , Dongyu Pei , Sheng Wan , Yan Wang , Mingrui Yu , Haiyan Lu
{"title":"Hydrothermal-deposition synthesis of MnO2/MnS nanorods as high-performance asymmetric supercapacitor positive electrode materials","authors":"Ziming Wang ,&nbsp;Hanbo Wang ,&nbsp;Dongyu Pei ,&nbsp;Sheng Wan ,&nbsp;Yan Wang ,&nbsp;Mingrui Yu ,&nbsp;Haiyan Lu","doi":"10.1016/j.pnsc.2024.07.023","DOIUrl":"10.1016/j.pnsc.2024.07.023","url":null,"abstract":"<div><div>Nanostructuring has shown promise in enhancing the performance of MnO<sub>2</sub> for energy storage in supercapacitors, highlighting its technological significance. This study introduces an innovative synthesis method, employing hydrothermal and constant-pressure deposition techniques, to produce nanostructured MnO<sub>2</sub>/MnS rod electrodes on nickel foam. The roded heterostructure enhances specific surface area, conductivity, and symbiotic effect between MnO<sub>2</sub> and MnS. With optimized material and structural advantages, the electrode reaches a capacitance of 977.6 ​F ​g<sup>−1</sup> at 1 ​A ​g<sup>−1</sup>, demonstrating extended cycling lifespan. Using MnO<sub>2</sub>/MnS-5h rods as the positive electrode and activated carbon as the negative electrode, the supercapacitor achieves an energy density of 122.23 ​Wh kg<sup>−1</sup> at 898.75 ​W ​kg<sup>−1</sup>. Notably, it maintains 91.55 ​% capacity retention after 5000 cycles at 10 ​A ​g<sup>−1</sup>, indicating outstanding cycling stability. This research presents a promising solution for efficient energy storage, emphasizing the potential application of the developed MnO<sub>2</sub>/MnS based supercapacitor in high-performance energy storage systems.</div></div>","PeriodicalId":20742,"journal":{"name":"Progress in Natural Science: Materials International","volume":"34 5","pages":"Pages 1057-1065"},"PeriodicalIF":4.8,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142571238","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A review of crystal defect-induced element segregation in multi-component alloy steels 多成分合金钢中晶体缺陷诱发的元素偏析综述
IF 4.8 2区 材料科学
Progress in Natural Science: Materials International Pub Date : 2024-10-01 DOI: 10.1016/j.pnsc.2024.07.016
Xinyuan Zhang , Dexin Zhu , Chaolei Zhang , Xiaoye Zhou , Hong-Hui Wu , Feiyang Wang , Shuize Wang , Guilin Wu , Junheng Gao , Hiatao Zhao , Jiaming Zhu , Xinping Mao
{"title":"A review of crystal defect-induced element segregation in multi-component alloy steels","authors":"Xinyuan Zhang ,&nbsp;Dexin Zhu ,&nbsp;Chaolei Zhang ,&nbsp;Xiaoye Zhou ,&nbsp;Hong-Hui Wu ,&nbsp;Feiyang Wang ,&nbsp;Shuize Wang ,&nbsp;Guilin Wu ,&nbsp;Junheng Gao ,&nbsp;Hiatao Zhao ,&nbsp;Jiaming Zhu ,&nbsp;Xinping Mao","doi":"10.1016/j.pnsc.2024.07.016","DOIUrl":"10.1016/j.pnsc.2024.07.016","url":null,"abstract":"<div><div>In multi-component alloy steels, the interplay of chemical interactions among elements and variations in atomic radius often results in element segregation towards defects, markedly influencing the macroscopic material properties. Despite many recent studies reporting defect-dependent element segregation in steel, a comprehensive overview is still lacking. In this work, element segregation at various defects and their influence on steel performance are examined. It specifically delves into the influences of element segregation at dislocation, grain boundary, phase boundary, and precipitate phase interface on the mechanical performance of steel. For each type of crystal defect-induced element segregation, this review discusses the crystallographic structure, segregated microstructure, element segregation distribution, and the corresponding influence of element segregation on the mechanical performance of steel. Finally, this review extensively explores the scientific issues and challenges of element segregation research in steel. It provides valuable insights into the behavior of element segregation in steel and inspires new research directions in other multi-component alloys.</div></div>","PeriodicalId":20742,"journal":{"name":"Progress in Natural Science: Materials International","volume":"34 5","pages":"Pages 840-858"},"PeriodicalIF":4.8,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142571246","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhanced electrochemical oxidation of benzene and toluene in aqueous environments using Sb–SnO2-doped TiO2 nanotubes modified by hydrophobic polytetrafluoroethylene (PTFE) 使用疏水性聚四氟乙烯 (PTFE) 修饰的 Sb-SnO2 掺杂 TiO2 纳米管增强水环境中苯和甲苯的电化学氧化能力
IF 4.8 2区 材料科学
Progress in Natural Science: Materials International Pub Date : 2024-10-01 DOI: 10.1016/j.pnsc.2024.07.017
Yameng Li , Shuo Zhang , Peizhen Yang , Yilin Yang , Fei Chen , Xiang Liu , Miao Li
{"title":"Enhanced electrochemical oxidation of benzene and toluene in aqueous environments using Sb–SnO2-doped TiO2 nanotubes modified by hydrophobic polytetrafluoroethylene (PTFE)","authors":"Yameng Li ,&nbsp;Shuo Zhang ,&nbsp;Peizhen Yang ,&nbsp;Yilin Yang ,&nbsp;Fei Chen ,&nbsp;Xiang Liu ,&nbsp;Miao Li","doi":"10.1016/j.pnsc.2024.07.017","DOIUrl":"10.1016/j.pnsc.2024.07.017","url":null,"abstract":"<div><div>The presence of benzene and toluene in groundwater poses a serious threat to both aquatic ecosystems and human health. The electrochemical removal of these contaminants is primarily hindered by the low generation yield of reactive oxygen species (ROS). Herein, polytetrafluoroethylene (PTFE) was electrodeposited onto the surface of Sb–SnO<sub>2</sub>-doped TiO<sub>2</sub> nanotubes (TNT/Sb–SnO<sub>2</sub>/5PTFE-300) to enhance electrochemical activity. The resulting nanoelectrode achieved removal efficiencies of 96.2 ​% for benzene and 97.6 ​% for toluene. The minimal variation in the degradation of benzene and toluene following 8 cycles of use verified its stability. Experiments confirmed that •OH was the primary ROS. Hydrophobic surface of the nanoelectrode promoted the one-electron reaction of H<sub>2</sub>O oxidation, leading to •OH concentrations that were 54.0 and 27.5 times higher, respectively, than those produced by Ti/Sb–SnO<sub>2</sub>, and 4.7 and 2.0 times higher, respectively, than those produced by TNT/Sb–SnO<sub>2</sub>-300. Moreover, intermediate products suggested the ring-opening of benzene and toluene, yielding easily degradable small organic molecules. The electrochemical oxidation (EO) process revealed a competitive relationship between benzene and toluene, with toluene exhibiting stronger competitive effects (kinetic constant was 2.1 times that of benzene). The efficient nanoelectrode provide a novel approach for the removal of benzene and toluene from aquatic environments through EO.</div></div>","PeriodicalId":20742,"journal":{"name":"Progress in Natural Science: Materials International","volume":"34 5","pages":"Pages 1009-1020"},"PeriodicalIF":4.8,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142571316","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Kelp-derived porous carbon for capacitive deionization: Trade-off effect of activation temperature 用于电容去离子的海带多孔碳:活化温度的权衡效应
IF 4.8 2区 材料科学
Progress in Natural Science: Materials International Pub Date : 2024-10-01 DOI: 10.1016/j.pnsc.2024.08.008
Changle Li , Shiwei Sun , Wenjie Wu , Dan Luo , Kaidan Zheng , Zhibin Pang , Zeinhom M. El-Bahy , Zhengtong Li , Xingtao Xu
{"title":"Kelp-derived porous carbon for capacitive deionization: Trade-off effect of activation temperature","authors":"Changle Li ,&nbsp;Shiwei Sun ,&nbsp;Wenjie Wu ,&nbsp;Dan Luo ,&nbsp;Kaidan Zheng ,&nbsp;Zhibin Pang ,&nbsp;Zeinhom M. El-Bahy ,&nbsp;Zhengtong Li ,&nbsp;Xingtao Xu","doi":"10.1016/j.pnsc.2024.08.008","DOIUrl":"10.1016/j.pnsc.2024.08.008","url":null,"abstract":"<div><div>In this paper, a series of kelp-derived porous carbon (KPC) materials were prepared from kelp by using a pyrolysis-activation method, where KOH with a fixed ratio was applied as the activator under varying activation temperature. Eventually, the KPC-based capacitive deionization (CDI) system showed excellent desalination performance, and the desalination capacity of KPC with an activation temperature of 800 ​°C was highest, reaching 51.33 mg<sub>NaCl</sub> g<sup>−1</sup> at 1.2 ​V. This work implies the trade-off effect of the activation temperature for the preparation and application of biomass-derived carbon materials, and provides some insights for carbon-based CDI materials.</div></div>","PeriodicalId":20742,"journal":{"name":"Progress in Natural Science: Materials International","volume":"34 5","pages":"Pages 907-912"},"PeriodicalIF":4.8,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142571698","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Super tensile ductility in an as-cast TiVNbTa refractory high-entropy alloy 铸态 TiVNbTa 难熔高熵合金的超强拉伸延展性
IF 4.8 2区 材料科学
Progress in Natural Science: Materials International Pub Date : 2024-10-01 DOI: 10.1016/j.pnsc.2024.08.002
Chao Guo , Yuan Xing , Pan Wu , Ruitao Qu , Kexing Song , Feng Liu
{"title":"Super tensile ductility in an as-cast TiVNbTa refractory high-entropy alloy","authors":"Chao Guo ,&nbsp;Yuan Xing ,&nbsp;Pan Wu ,&nbsp;Ruitao Qu ,&nbsp;Kexing Song ,&nbsp;Feng Liu","doi":"10.1016/j.pnsc.2024.08.002","DOIUrl":"10.1016/j.pnsc.2024.08.002","url":null,"abstract":"<div><div>Refractory high-entropy alloy (RHEA) usually exhibits a high melting point and hence a very high deformation resistance at high temperatures. However, the relatively poor plasticity at room temperature, i.e., only few RHEAs displaying as-cast tensile ductility, strongly limits the applications of RHEAs as engineering materials. In this work, we show a huge tensile ductility observed in an as-cast TiVNbTa RHEA (∼40 ​% fracture elongation) accompanying with a high yield strength (∼800 ​MPa), which are rarely reported properties for RHEAs. The as-cast alloy shows a simple body-centered cubic (BCC) structure with dendrites. Ductile fracture with many dimples is the main fracture mechanism, while no twinning and deformation induced phase transition was observed. The uniform plastic deformation mainly relies on the planar and cross-slip of dislocations. The present result suggests the huge ductility potentials for RHEAs, providing a clue for designs future high performance RHEAs with good ductility.</div></div>","PeriodicalId":20742,"journal":{"name":"Progress in Natural Science: Materials International","volume":"34 5","pages":"Pages 1076-1084"},"PeriodicalIF":4.8,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142571240","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation of porous (Mo2/3Y1/3)2AlC and its hydrogen evolution reaction performance 多孔 (Mo2/3Y1/3)2AlC 的制备及其氢进化反应性能
IF 4.8 2区 材料科学
Progress in Natural Science: Materials International Pub Date : 2024-10-01 DOI: 10.1016/j.pnsc.2024.09.002
Siwei Tan, Junsheng Yang, Jie Li, Gan Xiao, Baogang Wang, Wenkai Jiang, Heng Zhang, Xuejin Yang
{"title":"Preparation of porous (Mo2/3Y1/3)2AlC and its hydrogen evolution reaction performance","authors":"Siwei Tan,&nbsp;Junsheng Yang,&nbsp;Jie Li,&nbsp;Gan Xiao,&nbsp;Baogang Wang,&nbsp;Wenkai Jiang,&nbsp;Heng Zhang,&nbsp;Xuejin Yang","doi":"10.1016/j.pnsc.2024.09.002","DOIUrl":"10.1016/j.pnsc.2024.09.002","url":null,"abstract":"<div><div>Porous (Mo<sub>2/3</sub>Y<sub>1/3</sub>)<sub>2</sub>AlC MAX phase ceramic was prepared by reaction sintering method using Mo, Y, Al, and graphite powder as raw materials. The influence of changes in Al content on the purity of the obtained samples was investigated using X-ray diffraction (XRD), scanning electron microscopy (SEM), Archimedes method, and bubble point method. The conditions for obtaining a pure phase were identified, and the transformation path of the phase during sintering and the mechanism of pore formation were provided. The linear sweep voltammetry (LSV) cure and cyclic voltammetry (CV) cure of MAX were tested using an electrochemical workstation. It can be calculated that MAX exhibits good hydrogen evolution reaction (HER) performance under alkaline conditions due to its high electrochemical active surface area (ECSA) of 373.2 and small Tafel slope of 41.7 ​mV·dec<sup>−1</sup>.</div></div>","PeriodicalId":20742,"journal":{"name":"Progress in Natural Science: Materials International","volume":"34 5","pages":"Pages 1100-1107"},"PeriodicalIF":4.8,"publicationDate":"2024-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142571243","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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