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The improvement in properties of polyester resin-based composites using a new type of silane coupling agent 新型硅烷偶联剂对聚酯树脂基复合材料性能的改善
IF 1.6 4区 工程技术
Polimery Pub Date : 2023-07-13 DOI: 10.14314/polimery.2023.4.4
W. Urbaniak, W. Bednarek, D. Paukszta, M. Szostak, J. Szymańska
{"title":"The improvement in properties of polyester resin-based composites using a new type of silane coupling agent","authors":"W. Urbaniak, W. Bednarek, D. Paukszta, M. Szostak, J. Szymańska","doi":"10.14314/polimery.2023.4.4","DOIUrl":"https://doi.org/10.14314/polimery.2023.4.4","url":null,"abstract":"Adhesion between the polymer matrix and fillers is an important factor influencing the properties of the obtained composites. One way to improve interactions at the interface is to modify the filler with coupling agents, e.g., silanes. The article presents the effect of modifying the surface of the mineral filler with a new type of silane [triethoxy(ketoimino)silane] on the mechanical properties of polyester resin based composites. Composites with triethoxy(ketoimino)silane-modified filler had similar mechanical properties to composites obtained with commercial silanes, with slightly lower water absorption.","PeriodicalId":20319,"journal":{"name":"Polimery","volume":null,"pages":null},"PeriodicalIF":1.6,"publicationDate":"2023-07-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45949243","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effectiveness of polyethylene glycol-coated silica on ions adsorption in industrial wastewater 聚乙二醇包覆二氧化硅对工业废水中离子吸附的影响
IF 1.6 4区 工程技术
Polimery Pub Date : 2023-07-13 DOI: 10.14314/polimery.2023.5.2
M. Maryudi, A. Rahayu, D. C. Hakika
{"title":"Effectiveness of polyethylene glycol-coated silica on ions adsorption in industrial wastewater","authors":"M. Maryudi, A. Rahayu, D. C. Hakika","doi":"10.14314/polimery.2023.5.2","DOIUrl":"https://doi.org/10.14314/polimery.2023.5.2","url":null,"abstract":"The effect of coating silica with polyethylene glycol on the adsorption of iron and phosphate ions in industrial wastewater was investigated. Variable factors were temperature and time of coating, PEG concentration, and PEG to silica ratio. Infrared spectroscopy and scanning electron microscopy were used to evaluate the chemical structure and morphology of PEG-coated silica. Optimum iron and phosphate ions removal efficiency was obtained using a coating temperature of 50°C, a coating time of 15 min, a PEG concentration of 20%, and a PEG to silica ratio of 1:3.","PeriodicalId":20319,"journal":{"name":"Polimery","volume":null,"pages":null},"PeriodicalIF":1.6,"publicationDate":"2023-07-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"45976730","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
4-methyl-4-[2-(naphthalene)-2-oxoethyl] morpholin-4-ium iodide as a water soluble photoinitiator 4-甲基-4-[2-(萘)-2-氧乙基]morpholin-4-碘化铵的水溶性光引发剂
IF 1.6 4区 工程技术
Polimery Pub Date : 2023-06-27 DOI: 10.14314/polimery.2023.4.3
Fatma Ozcan, Z. Dogruyol, Sevnur Keskin Dogruyol
{"title":"4-methyl-4-[2-(naphthalene)-2-oxoethyl] morpholin-4-ium iodide as a water soluble photoinitiator","authors":"Fatma Ozcan, Z. Dogruyol, Sevnur Keskin Dogruyol","doi":"10.14314/polimery.2023.4.3","DOIUrl":"https://doi.org/10.14314/polimery.2023.4.3","url":null,"abstract":"Quaternary ammonium salt namely 4-methyl-4-[2-(naphthalen-2-yl)-2-oxoethyl] morpholin-4-ium iodide (WSMPM) was synthesized and characterized. High molar absorptivity at 347 nm (1910 L･mol-1･cm-1) and good solubility in distilled water (10-2 M) allows WSMPM to be used as an effective photoinitiator also in water-soluble systems. Photopolymerization of acrylamide monomer with WSMPM (10-3 M) and a tertiary amine (N-methyldiethanolamine), resulted in 84.4% monomer to polymer conversion. Based on laser photolysis and electron spin resonance, a photoinitiator mechanism was proposed.","PeriodicalId":20319,"journal":{"name":"Polimery","volume":null,"pages":null},"PeriodicalIF":1.6,"publicationDate":"2023-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43355023","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Functionalization methods of carbon fibers – an overview 碳纤维功能化方法综述
4区 工程技术
Polimery Pub Date : 2023-06-27 DOI: 10.14314/polimery.2023.6.1
Sylwia Magdziarz, Justyna Frączyk, Maciej Boguń
{"title":"Functionalization methods of carbon fibers – an overview","authors":"Sylwia Magdziarz, Justyna Frączyk, Maciej Boguń","doi":"10.14314/polimery.2023.6.1","DOIUrl":"https://doi.org/10.14314/polimery.2023.6.1","url":null,"abstract":"This article is a literature review related to the methods of functionalization of carbon fibers for tissue engineering applications. Through physical modification, it is possible to obtain a layer of a chemical compound on the carbon fibers surface and to impart additional properties. On the other hand, chemical modification may lead to the incorporation of appropriate functional groups into the carbon fiber structure, capable of attaching, among others, biologically active compounds. The paper presents the advantages and disadvantages of the carbon fibers modifying methods, with particular emphasis on the use of such modified fibers in medicine.","PeriodicalId":20319,"journal":{"name":"Polimery","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135503897","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Wpływ dodatków uniepalniających na bazie Sb2O3 na palność PVC Sb2O3阻燃剂对PVC阻燃性能的影响
IF 1.6 4区 工程技术
Polimery Pub Date : 2023-06-16 DOI: 10.14314/polimery.2023.4.5
Sergiy Kurta, Olga Shevchenko А., Olga Khatsevich, Sofia Fedorchenko, Volodymyr Riy, Solomia Givel
{"title":"Wpływ dodatków uniepalniających na bazie Sb2O3 na palność PVC","authors":"Sergiy Kurta, Olga Shevchenko А., Olga Khatsevich, Sofia Fedorchenko, Volodymyr Riy, Solomia Givel","doi":"10.14314/polimery.2023.4.5","DOIUrl":"https://doi.org/10.14314/polimery.2023.4.5","url":null,"abstract":"Zbadano handlowe dodatki uniepalniające na bazie Sb2O3. Wykazują one działanie akceptorowe, termostabilizujące i uniepalniające na linoleum z PVC. Na podstawie spektroskopii IR, analizy DTA, dyfrakcji oraz analizy fluorescencji rentgenowskiej stwierdzono, że jedna z próbek zawiera 100% Sb2O3, natomiast pozostałe zawierają mikrokrystaliczny CaCO3 (50-95%) oraz inne związki np. chloroorganiczne i węglowodory. Mechanizm uniepalniania linoleum z PVC polega na synergicznym działaniu Sb2O3 i CaСО3 poprzez wiązanie gazowego chlorowodoru powstającego podczas spalania i rozkładu termicznego PVC.\u0000 ","PeriodicalId":20319,"journal":{"name":"Polimery","volume":null,"pages":null},"PeriodicalIF":1.6,"publicationDate":"2023-06-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44470154","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Pickering emulsion polymerization of styrene towards alfa-functionalized polystyrene latex: parameters and process conditions 苯乙烯酸洗乳液聚合制备α功能化聚苯乙烯乳液:参数和工艺条件
IF 1.6 4区 工程技术
Polimery Pub Date : 2023-06-15 DOI: 10.14314/polimery.2023.4.2
Dariusz Tercki, Beata Orlińska, D. Słotwińska, M. Sajdak
{"title":"Pickering emulsion polymerization of styrene towards alfa-functionalized polystyrene latex: parameters and process conditions","authors":"Dariusz Tercki, Beata Orlińska, D. Słotwińska, M. Sajdak","doi":"10.14314/polimery.2023.4.2","DOIUrl":"https://doi.org/10.14314/polimery.2023.4.2","url":null,"abstract":"Polymerization conditions in the Pickering emulsion of colloidal silica-stabilized polystyrene latex were optimized. The influence of process conditions on various parameters, including particle size and distribution was investigated. Monomodal particles distribution was obtained by conducting the process at a temperature of 80°C in a slightly acidic environment (pH = 5), while maintaining fast monomer conversion. It has been shown that the amount of stabilizer used in the polymerization process affects the rate of polymerization, therefore the temperature of the process should be adjusted to the amount of colloidal silica used in the process.","PeriodicalId":20319,"journal":{"name":"Polimery","volume":null,"pages":null},"PeriodicalIF":1.6,"publicationDate":"2023-06-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41717082","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effects of poly(vinyl alcohol) matrix on the release of substances from the fragrance composition 聚乙烯醇基质对香料组合物中物质释放的影响
IF 1.6 4区 工程技术
Polimery Pub Date : 2023-05-30 DOI: 10.14314/polimery.2023.3.5
Ł. Szajnecki, A. Nowak
{"title":"Effects of poly(vinyl alcohol) matrix on the release of substances from the fragrance composition","authors":"Ł. Szajnecki, A. Nowak","doi":"10.14314/polimery.2023.3.5","DOIUrl":"https://doi.org/10.14314/polimery.2023.3.5","url":null,"abstract":"The chemical composition of two commercially available lavender fragrance oils was determined and compared. The process of concentration by partial evaporation was carried out and its influence on changes in the content of individual components in the analysed mixtures was examined. The effect of poly(vinyl alcohol)-based polymer matrix on the release of volatile substances from oils was tested as well. The presence and chemical composition of the polymer matrix affects the relative content of volatile substances released from the liquid phase containing the tested fragrance composition.","PeriodicalId":20319,"journal":{"name":"Polimery","volume":null,"pages":null},"PeriodicalIF":1.6,"publicationDate":"2023-05-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"42922381","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The use of chitosan as an effective carrier of theophylline - an anti-asthmatic drug 利用壳聚糖作为抗哮喘药物茶碱的有效载体
IF 1.6 4区 工程技术
Polimery Pub Date : 2023-05-17 DOI: 10.14314/polimery.2023.3.4
Noor Firas Aziz, S. Hussein-Al-Ali, M. M. Ghareeb, N. A. Nashwan
{"title":"The use of chitosan as an effective carrier of theophylline - an anti-asthmatic drug","authors":"Noor Firas Aziz, S. Hussein-Al-Ali, M. M. Ghareeb, N. A. Nashwan","doi":"10.14314/polimery.2023.3.4","DOIUrl":"https://doi.org/10.14314/polimery.2023.3.4","url":null,"abstract":"In order to solve the problem of frequent drug dosing and increase its effectiveness, theophylline (THP) was deposited on chitosan nanoparticles (CSNPs). THP-CSNPs nanocomposites with the composition of 50, 75, 100 or 150 mg of chitosan (CS) and 25, 50, 75, 100 or 200 mg of tripolyphosphate (TPP) at pH 4.0, 5.0, 6.0 and 6.5 were prepared, and a constant weight of THP of 100 mg. The nanocomposites were characterized by X-ray diffraction (PXRD), field emission scanning electron microscopy (FE-SEM), and Fourier transform infrared spectroscopy (FTIR). The rate of drug release was also tested. The Minitab 18 program was used to analyze the results. The independent variables were the CS, TPP, and pH, while loading efficiency, zeta potential, and particle size were the dependent variables. The nanocomposites successfully transported and protected the drug, providing its sustained release.","PeriodicalId":20319,"journal":{"name":"Polimery","volume":null,"pages":null},"PeriodicalIF":1.6,"publicationDate":"2023-05-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"43959617","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of acidic saliva on monomer leaching and surface roughness of 3D-printed and milled denture-base materials 酸性唾液对3D打印和研磨义齿基托材料单体浸出和表面粗糙度的影响
IF 1.6 4区 工程技术
Polimery Pub Date : 2023-05-16 DOI: 10.14314/polimery.2023.3.3
H. Al-Otaibi, Rafal Basaqer, S. Almania, A. Alfouzan, S. A. Al Taweel, H. Alshehri, N. Labban
{"title":"Effect of acidic saliva on monomer leaching and surface roughness of 3D-printed and milled denture-base materials","authors":"H. Al-Otaibi, Rafal Basaqer, S. Almania, A. Alfouzan, S. A. Al Taweel, H. Alshehri, N. Labban","doi":"10.14314/polimery.2023.3.3","DOIUrl":"https://doi.org/10.14314/polimery.2023.3.3","url":null,"abstract":"The study evaluated the effect of different acidic salivary pH values on monomer leaching and surface roughness of conventional and CAD/CAM processed (milled and 3D-printed) denture base materials. High-performance liquid chromatography was used to determine the quantity of residual methyl methacrylate monomer leaching after 30 days of immersion in acidic saliva. The surface roughness (Ra) before and after incubation was recorded using a non-contact optical profilometer. The monomer leaching and the surface roughness of the tested materials depended on the pH value of the saliva. The conventional denture framework material exhibited the highest and lowest leaching rates at pH=4.5 and pH=3.5, respectively, regardless of the treatment method. Among the CAD/CAM processed materials, the 3D-printed material showed the highest and lowest leaching at pH=5.5 and pH=3.5, respectively. Regardless of the pH, roughness after incubation was the lowest for conventional materials, and the highest for 3D printing.","PeriodicalId":20319,"journal":{"name":"Polimery","volume":null,"pages":null},"PeriodicalIF":1.6,"publicationDate":"2023-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47425166","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis of hydrogel nanocomposites and their application in removing dyes and impurities 水凝胶纳米复合材料的合成及其在去除染料和杂质中的应用
4区 工程技术
Polimery Pub Date : 2023-05-09 DOI: 10.14314/polimery.2023.5.5
Rajabali Ebrahimi, Mahboubeh Taherkhani
{"title":"Synthesis of hydrogel nanocomposites and their application in removing dyes and impurities","authors":"Rajabali Ebrahimi, Mahboubeh Taherkhani","doi":"10.14314/polimery.2023.5.5","DOIUrl":"https://doi.org/10.14314/polimery.2023.5.5","url":null,"abstract":"Polyacrylate hydrogels containing starch, ZeSe and Fe3O4 nanoparticles were obtained. The polymerization process was carried out in an ultrasonic field. The structure (SEM, FTIR), swelling properties and the ability of hydrogels to adsorb dyes (methylene blue, methyl orange, methyl red and Eriochrome black T) and heavy metals (Cu2+) from wastewater were investigated. Hydrogels containing AgCl nanoparticles were also obtained.","PeriodicalId":20319,"journal":{"name":"Polimery","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135806604","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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