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Damping materials based on plasticized polybutyl methacrylate, polymethyl methacrylate and polyvinyl acetate 基于塑化聚甲基丙烯酸丁酯、聚甲基丙烯酸甲酯和聚醋酸乙烯酯的阻尼材料
Plasticheskie massy Pub Date : 2024-01-11 DOI: 10.35164/0554-2901-2023-11-12-26-30
A. Syatkovskiy, I. D. Simonov-Emelyanov
{"title":"Damping materials based on plasticized polybutyl methacrylate, polymethyl methacrylate and polyvinyl acetate","authors":"A. Syatkovskiy, I. D. Simonov-Emelyanov","doi":"10.35164/0554-2901-2023-11-12-26-30","DOIUrl":"https://doi.org/10.35164/0554-2901-2023-11-12-26-30","url":null,"abstract":"The purpose of the presented work is to investigate by DMA method the influence of the composition of filled and unfilled plasticized compositions based on polyvinyl acetate (PVA), polybutyl methacrylate (PBMA) and polymethyl methacrylate (PMMA) on their damping characteristics. It was found that when plasticizer is introduced into the polymer, the value of the mechanical loss coefficient first increases, reaches its maximum, and begins to decrease with further increase in the plasticizer content. The maximum effect is observed at a plasticizer/polymer volume ratio of 0.2-0.4. Two other dissipative characteristics, the temperature interval of effective damping and the integral coefficient of mechanical losses, are changing similarly. It is established that the additives of chlorinated paraffins in compositions based on PVA and PBMA can significantly improve their vibration absorbing characteristics. Introduction of mica filler into the composition of plasticized compositions based on PVA and PBMA does not lead to the appearаnсe of additional relaxation mechanisms. With increasing of the content of mica, the elastic modulus of compositions increases in the entire temperature range (especially significantly for compositions with a high content of plasticizer), the coefficient of mechanical losses slightly decreases, and the temperature practically does not change at which the maximum damping is observed.","PeriodicalId":20254,"journal":{"name":"Plasticheskie massy","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-01-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139627181","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Development of novel composite polydecylmethylsiloxane hollow fiber membranes on highly permeable polysulfone support for С2+/С1 separation 在高渗透性聚砜载体上开发用于С2+/С1分离的新型复合聚癸基甲基硅氧烷中空纤维膜
Plasticheskie massy Pub Date : 2023-11-21 DOI: 10.35164/0554-2901-2023-9-10-33-35
D. Matveev, E. Grushevenko, Yu. I. Matveeva, V. Vasilevsky, I. Borisov
{"title":"Development of novel composite polydecylmethylsiloxane hollow fiber membranes on highly permeable polysulfone support for С2+/С1 separation","authors":"D. Matveev, E. Grushevenko, Yu. I. Matveeva, V. Vasilevsky, I. Borisov","doi":"10.35164/0554-2901-2023-9-10-33-35","DOIUrl":"https://doi.org/10.35164/0554-2901-2023-9-10-33-35","url":null,"abstract":"A novel composite hollow fiber membrane has been developed for the separation of C2+ hydrocarbons from their mixture with methane. A high-performance porous polysulfone hollow fiber support was fabricated. Polydecylmethylsiloxane (PDecMS) and polydimethylsiloxane (PDMS) were used as a thin selective layer. Comparison of the results of separation of binary mixture of CH4 and C4H10 using PDecMS/PSF and PDMS/PSF membranes showed that for the PDecMS/PSF module the specific retentate flux and n-butane concentration in the permeate are 1.7 times higher and energy consumption is 9 times lower.","PeriodicalId":20254,"journal":{"name":"Plasticheskie massy","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139251469","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of mercury impurities in ethylene feed stream on ethylene gas-phase polymerisation processes 乙烯料流中的汞杂质对乙烯气相聚合过程的影响
Plasticheskie massy Pub Date : 2023-11-21 DOI: 10.35164/0554-2901-2023-9-10-39-42
T. V. Komarova, V. V. Shashkov, N. E. Kalaytanova
{"title":"Effect of mercury impurities in ethylene feed stream on ethylene gas-phase polymerisation processes","authors":"T. V. Komarova, V. V. Shashkov, N. E. Kalaytanova","doi":"10.35164/0554-2901-2023-9-10-39-42","DOIUrl":"https://doi.org/10.35164/0554-2901-2023-9-10-39-42","url":null,"abstract":"The effect of mercury impurities on the process of gas-phase polymerization of ethylene has been studied. The effect of the MERCURY catalytic poison on the ethylene polymerization process is twofold: the poisons interact with the active centers of the catalyst, thereby suppressing their activity, and also react with the molecule of the resulting polymer, breaking the growing chain. This results in a decrease in the activity of the catalyst due to poisoning of the active centers and a decrease in the molecular weight of the resulting polymer due to premature chain termination. At the same time, the flow index increases and the size of the obtained polymer particles decreases, the density increases, since the comonomer does not react.","PeriodicalId":20254,"journal":{"name":"Plasticheskie massy","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139252289","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Sinterm foam materials for thermocompression molding of PCM products 用于 PCM 产品热压成型的 Sinterm 泡沫材料
Plasticheskie massy Pub Date : 2023-11-21 DOI: 10.35164/0554-2901-2023-9-10-26-28
M. M. Platonov, A. N. Babin, M. A. Evtekhov, I. A. Sharova, A. A. Shimkin
{"title":"Sinterm foam materials for thermocompression molding of PCM products","authors":"M. M. Platonov, A. N. Babin, M. A. Evtekhov, I. A. Sharova, A. A. Shimkin","doi":"10.35164/0554-2901-2023-9-10-26-28","DOIUrl":"https://doi.org/10.35164/0554-2901-2023-9-10-26-28","url":null,"abstract":"A new technology for molding polymer composite materials (PCMs) from prepregs has been developed. It is based on on the use of a special “active” core made of a closed-pored gas-filled material (foam), which expands at elevated temperatures and the creates pressure on the prepreg layers inside the closed forming equipment. The paper describes the new technology and the assortment of polymer compositions for the manufacture of the core.","PeriodicalId":20254,"journal":{"name":"Plasticheskie massy","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139252904","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evaluation of the effect of acid-base nature of inorganic filler on the performance properties of epoxypolymer composite materials 评估无机填料的酸碱性质对环氧聚合物复合材料性能的影响
Plasticheskie massy Pub Date : 2023-11-21 DOI: 10.35164/0554-2901-2023-9-10-15-17
T. А. Grigorieva, P. А. Sitnikov
{"title":"Evaluation of the effect of acid-base nature of inorganic filler on the performance properties of epoxypolymer composite materials","authors":"T. А. Grigorieva, P. А. Sitnikov","doi":"10.35164/0554-2901-2023-9-10-15-17","DOIUrl":"https://doi.org/10.35164/0554-2901-2023-9-10-15-17","url":null,"abstract":"The paper considers the possibility of controlling the interfacial interactions of molecules of polar oligomers and the substrate by forming modified supramolecular structures as a result of acid-base interaction of components of the polymer matrix with the surface of nanodispersed oxides. The effect of aluminum oxide on the properties of ED-20 epoxy resin in the presence of the iso-ITA hardener has been studied: microstructure of oxide samples and acid-base properties of the oxide have been studied; the free energy of the surface and the work of adhesion of the material have been determined from the contact angle.","PeriodicalId":20254,"journal":{"name":"Plasticheskie massy","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139250681","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The effect of intra- and interphase interactions on strength of polyamide-6-based composites 相内和相间相互作用对聚酰胺-6 基复合材料强度的影响
Plasticheskie massy Pub Date : 2023-11-21 DOI: 10.35164/0554-2901-2023-9-10-9-11
D. S. Tochiev, I. Dolbin, Khuseyn Kh. Sapaev
{"title":"The effect of intra- and interphase interactions on strength of polyamide-6-based composites","authors":"D. S. Tochiev, I. Dolbin, Khuseyn Kh. Sapaev","doi":"10.35164/0554-2901-2023-9-10-9-11","DOIUrl":"https://doi.org/10.35164/0554-2901-2023-9-10-9-11","url":null,"abstract":"The effect of filler-filler and filler-polymer matrix interactions on the strength of polyamide-6-based composites has been studied. It is shown that the strengthening of interactions of both mentioned types leads to an increase in the strength of the investigated composites. Fillers with a layered structure are preferred over dispersed ones.","PeriodicalId":20254,"journal":{"name":"Plasticheskie massy","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139253159","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Properties of polyimide foams obtained using water-soluble salts of polyamide acids 使用聚酰胺酸水溶盐获得的聚酰亚胺泡沫的性能
Plasticheskie massy Pub Date : 2023-11-21 DOI: 10.35164/0554-2901-2023-9-10-29-32
V. Svetlichnyi, K. S. Polotnyanshchikov, E. M. Ivan’kova, A. G. Ivanov, G. Vaganov, L. A. Myagkova, E. N. Popova, V. Yudin
{"title":"Properties of polyimide foams obtained using water-soluble salts of polyamide acids","authors":"V. Svetlichnyi, K. S. Polotnyanshchikov, E. M. Ivan’kova, A. G. Ivanov, G. Vaganov, L. A. Myagkova, E. N. Popova, V. Yudin","doi":"10.35164/0554-2901-2023-9-10-29-32","DOIUrl":"https://doi.org/10.35164/0554-2901-2023-9-10-29-32","url":null,"abstract":"The synthesis of polyimide foams obtained as a result of heat treatment of lyophilized water-soluble salts of polyamide acids based on dianhydrides of 3,3’,4,4’-diphenyloxide-, 3,3’,4,4’-benzophenonetetracarboxylic acids and 4,4’-diaminodiphenyl ether was carried out. A study of the structure and morphology of foam samples obtained was carried out. The results of evaluating the mechanical properties and thermal stability of the resulting polyimide foams are presented.","PeriodicalId":20254,"journal":{"name":"Plasticheskie massy","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139254260","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermoplastic film materials for damping in mechanical engineering 用于机械工程阻尼的热塑性薄膜材料
Plasticheskie massy Pub Date : 2023-11-21 DOI: 10.35164/0554-2901-2023-9-10-48-52
A. Syatkovskiy
{"title":"Thermoplastic film materials for damping in mechanical engineering","authors":"A. Syatkovskiy","doi":"10.35164/0554-2901-2023-9-10-48-52","DOIUrl":"https://doi.org/10.35164/0554-2901-2023-9-10-48-52","url":null,"abstract":"An effective way of damping engineering structures is to use elements formed by a combination of hard and soft alternating layers. The outer rigid layers, made of structural materials, take up force infl uences, while the soft layers of viscoelastic polymers provide energy dissipation of the layered structure. The paper summarizes the results of research on the development of thin thermoplastic fi lms of plasticized polyvinyl acetate, polybutylmethacrylate and polymethylmethacrylate which have ultra-high dissipative properties and are used as a vibration-absorbing component of composite structures. It is shown that high damping properties are realized in fi lms with thickness of 0.1 –0.05 mm, which makes it possible to obtain two- and three-layer vibration-absorbing films with an extended temperature interval of effective damping in the metal-polymer-metal structures.","PeriodicalId":20254,"journal":{"name":"Plasticheskie massy","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139252213","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of electrophysical impacts on the flexural strength of a cured monolayer reinforced with continuous carbon fiber 电物理冲击对连续碳纤维固化单层增强材料抗弯强度的影响
Plasticheskie massy Pub Date : 2023-11-21 DOI: 10.35164/0554-2901-2023-9-10-21-25
I. Zlobina, N. Bekrenev, A. S. Egorov, T. M. Alukaev
{"title":"Influence of electrophysical impacts on the flexural strength of a cured monolayer reinforced with continuous carbon fiber","authors":"I. Zlobina, N. Bekrenev, A. S. Egorov, T. M. Alukaev","doi":"10.35164/0554-2901-2023-9-10-21-25","DOIUrl":"https://doi.org/10.35164/0554-2901-2023-9-10-21-25","url":null,"abstract":"The effect of ultrasonic and microwave treatment of a monolayer formed by three-dimensional printing from prepregs reinforced with continuous carbon fiber on its three-point bending strength has been investigated. Empirical strain–stress relationships were obtained and the microstructure was investigated. The highest efficiency of electrophysical treatment (increase by 54–72 %) is observed for specimens exposed to microwave field in the deformation range of 0.5–1.3 mm.","PeriodicalId":20254,"journal":{"name":"Plasticheskie massy","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139253114","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Research of resistance to hydro-abrasive wear of thermoplastic polymers used to protect the inner surface of hydraulic transport systems 研究用于保护液压运输系统内表面的热塑性聚合物的耐水磨磨损性
Plasticheskie massy Pub Date : 2023-11-21 DOI: 10.35164/0554-2901-2023-9-10-43-47
V. I. Skrebnev, S. L. Serzhan, E. V. Kalugina
{"title":"Research of resistance to hydro-abrasive wear of thermoplastic polymers used to protect the inner surface of hydraulic transport systems","authors":"V. I. Skrebnev, S. L. Serzhan, E. V. Kalugina","doi":"10.35164/0554-2901-2023-9-10-43-47","DOIUrl":"https://doi.org/10.35164/0554-2901-2023-9-10-43-47","url":null,"abstract":"The results of tests of materials for hydro-abrasive wear resistance, as well as the erosion values of studied materials, are presented. It has been found that the use of thermoplastic vulcanizates (TPV) as a co-extruded coating of the inner surface of polymer pipe systems can significantly increase the lifetime of slurry pipelines when exposed to hydraulic mixtures, in particular iron ore tailings. In a model test simulating actual operating conditions of the pipeline, it was shown that TPV and thermoplastic polyurethane (TPU) coatings are signifi cantly superior in wear resistance to high-density polyethylene (HDPE) and steel.","PeriodicalId":20254,"journal":{"name":"Plasticheskie massy","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139250693","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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