Physica B-condensed Matter最新文献

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Magnetic structure and colossal dielectric properties in Ga3+ substituted Zn2Y hexaferrites by chemical co-precipitation method 化学共沉淀法制备的 Ga3+ 取代 Zn2Y 六铁氧体的磁结构和巨大介电性能
IF 2.8 3区 物理与天体物理
Physica B-condensed Matter Pub Date : 2024-10-16 DOI: 10.1016/j.physb.2024.416635
{"title":"Magnetic structure and colossal dielectric properties in Ga3+ substituted Zn2Y hexaferrites by chemical co-precipitation method","authors":"","doi":"10.1016/j.physb.2024.416635","DOIUrl":"10.1016/j.physb.2024.416635","url":null,"abstract":"<div><div>Y-type Ba<sub>0.5</sub>Sr<sub>1.5</sub>Zn<sub>2</sub>Fe<sub>12-<em>x</em></sub>Ga<sub><em>x</em></sub>O<sub>22</sub> (<em>x</em> = 0.0, 0.2, 0.4, 0.6, 0.8 and 1.0) hexaferrites are prepared through modified chemical co-precipitation method. X-ray diffraction (XRD) results reveal that these samples are single-phase and the space group is <span><math><mrow><mi>R</mi><mover><mn>3</mn><mo>‾</mo></mover><mi>m</mi></mrow></math></span>. The field-emission scanning electronic microscope (FE-SEM) measurements indicate that the grains are hexagonal-plate with a diameter of 2–5 μm. In the <em>M-T</em> diagrams, various magnetic structures are modulated, including proper-screw, longitudinal conical (LC), mixed conical (MC), and collinear ferrimagnetic (collinear FIM). In this series of samples, the values of dielectric constant (<span><math><mrow><msup><mi>ε</mi><mo>′</mo></msup></mrow></math></span>) achieve an order increase from 10<sup>2</sup> to 10<sup>4</sup>. For the best <em>x</em> = 0.8 sample, the <span><math><mrow><msup><mi>ε</mi><mo>′</mo></msup></mrow></math></span> is as high as 1804.76 at 1 MHz and 300 K. In conclusion, Ba<sub>0.5</sub>Sr<sub>1.5</sub>Zn<sub>2</sub>Fe<sub>12-<em>x</em></sub>Ga<sub><em>x</em></sub>O<sub>22</sub> with controllable magnetic structures and colossal dielectric constant are potential materials for miniaturization of modern electronic devices.</div></div>","PeriodicalId":20116,"journal":{"name":"Physica B-condensed Matter","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2024-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142446596","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of magneto-optoelectronics properties of Mg1-xMnxS alloys for optoelectronics and spintronic applications 用于光电子学和自旋电子学应用的 Mg1-xMnxS 合金的磁光特性研究
IF 2.8 3区 物理与天体物理
Physica B-condensed Matter Pub Date : 2024-10-15 DOI: 10.1016/j.physb.2024.416629
{"title":"Investigation of magneto-optoelectronics properties of Mg1-xMnxS alloys for optoelectronics and spintronic applications","authors":"","doi":"10.1016/j.physb.2024.416629","DOIUrl":"10.1016/j.physb.2024.416629","url":null,"abstract":"<div><div>Herein, the optical, electronic and magnetic properties of Mg<sub>1-x</sub>Mn<sub>x</sub>S alloys are computed by employing density functional theory. The full-potential linearized augmented plane wave (FP-LAPW) method was used within the frame work of Wein2k to explore spin polarized band structure along with total and partial density of states. The results of spin polarized band structure calculations exhibited semiconducting character in both spin states. The net magnetic moment (μ<sub>B</sub>) is primarily credited to presence of partially filled 3d state of Mn atom. μ<sub>B</sub> gives evidence of <em>p-d</em> hybridization between orbitals of Mn and parent lattice ions. Optical characteristics of Mg<sub>1-x</sub>Mn<sub>x</sub>S including dielectric constants along with relevant features have been reported at 0–10 eV energy range. High value of absorption coefficient and smaller reflectance in ultraviolet energy span suggests potentiality of doped alloy for optoelectronic applications. Moreover, ferromagnetic character makes it suitable for spintronic storage devices.</div></div>","PeriodicalId":20116,"journal":{"name":"Physica B-condensed Matter","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2024-10-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142446595","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Persistence luminescence and thermoluminescence of 260 nm UVC irradiated mixed-phase (BaAl2O4 - BaAl12O19) barium aluminate 经 260 纳米紫外线照射的混相(BaAl2O4 - BaAl12O19)铝酸钡的持久发光和热致发光
IF 2.8 3区 物理与天体物理
Physica B-condensed Matter Pub Date : 2024-10-13 DOI: 10.1016/j.physb.2024.416628
{"title":"Persistence luminescence and thermoluminescence of 260 nm UVC irradiated mixed-phase (BaAl2O4 - BaAl12O19) barium aluminate","authors":"","doi":"10.1016/j.physb.2024.416628","DOIUrl":"10.1016/j.physb.2024.416628","url":null,"abstract":"<div><div>Persistence luminescence (PerL) and thermoluminescence (TL) of BaAl<sub>2</sub>O<sub>4</sub> - BaAl<sub>12</sub>O<sub>19</sub> mixedphase compound under 260 nm UVC irradiation are studied. The sample shows PerL for more than 1 h post irradiation. TL glow curves of the sample recorded at 1 <sup>o</sup>C/s following irradiation to UVC radiation shows a composite glow peak between 30 and 230 °C. The TL intensity is found to be affected by thermal quenching. The activation energy for thermal quenching is estimated to be <em>W</em> = 0.85 ± 0.12 eV. A <em>T</em><sub>m</sub>-<em>T</em><sub>stop</sub> analysis reveals that the TL glow peak is composed of multiple first order components. The activation energy associated with the electron traps are found to vary from 0.66 to 1.70 eV. The density of the traps is high between 0.60 and 1.20 eV. Due to presence of continuous distribution of electron traps, there is an excellent scope of developing colour tuneable persistence luminescence phosphor using mixed phase barium aluminate.</div></div>","PeriodicalId":20116,"journal":{"name":"Physica B-condensed Matter","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2024-10-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142433779","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis, characterization, electrochemical impedance spectroscopy performance and photodegradation of methylene blue: Mesoporous PEG/TiO2 by sol-gel electrospinning 亚甲基蓝的合成、表征、电化学阻抗谱性能和光降解:溶胶-凝胶电纺丝法制备介孔 PEG/TiO2
IF 2.8 3区 物理与天体物理
Physica B-condensed Matter Pub Date : 2024-10-13 DOI: 10.1016/j.physb.2024.416627
{"title":"Synthesis, characterization, electrochemical impedance spectroscopy performance and photodegradation of methylene blue: Mesoporous PEG/TiO2 by sol-gel electrospinning","authors":"","doi":"10.1016/j.physb.2024.416627","DOIUrl":"10.1016/j.physb.2024.416627","url":null,"abstract":"<div><div>Sol-gel and electrospinning methods successfully prepared porous TiO<sub>2</sub> fibers. The samples were calcined at temperatures of 450 °C and 550 °C and characterized using different techniques. XRD analysis also revealed crystalline anatase and rutile phases of mp-TiO<sub>2</sub> observed at calcining temperatures of 450 °C and 550 °C, whereas as-prepared showed an amorphous-like structure. Relatively higher surface area and photocatalytic efficiency were increased with a decrease in crystallite size. All samples absorb UV region. The Rs value of TiO<sub>2</sub> calcined at 550 °C was 16.6 Ω, which is much lower than those of the 450 °C calcined TiO<sub>2</sub> powder electrode (52.7 Ω) and as-prepared TiO<sub>2</sub> electrode (95.3 Ω). In addition, the Rp resistance of TiO<sub>2</sub> calcined at 550 °C electrode (5.85 kΩ) was also lower than those of 450 °C calcined TiO<sub>2</sub> powder (39.0 kΩ) and as-prepared TiO<sub>2</sub> electrode (68.9 kΩ), revealing better electronic and ionic conduction of TiO<sub>2</sub> calcined at 550 °C electrode.</div></div>","PeriodicalId":20116,"journal":{"name":"Physica B-condensed Matter","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2024-10-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142433780","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structural, morphological and optical properties of the La2W2O9/Fe2O3 composite for UV-shielding applications 用于紫外线屏蔽应用的 La2W2O9/Fe2O3 复合材料的结构、形态和光学特性
IF 2.8 3区 物理与天体物理
Physica B-condensed Matter Pub Date : 2024-10-12 DOI: 10.1016/j.physb.2024.416618
{"title":"Structural, morphological and optical properties of the La2W2O9/Fe2O3 composite for UV-shielding applications","authors":"","doi":"10.1016/j.physb.2024.416618","DOIUrl":"10.1016/j.physb.2024.416618","url":null,"abstract":"<div><div>Currently, research has been conducted on the individual oxides La<sub>2</sub>W<sub>2</sub>O<sub>9</sub> and Fe<sub>2</sub>O<sub>3</sub> but not on its composite form. Using a solid-state reaction technique, a La<sub>2</sub>W<sub>2</sub>O<sub>9</sub>/Fe<sub>2</sub>O<sub>3</sub> composite was created. A particular calcination cycle was followed by mixing the raw precursors. Scanning electron microscopy (SEM) was used to investigate the morphological microstructure, and X-ray diffraction (XRD) was used to examine the structural characteristics. The thermal and gravimetric properties were examined via differential thermal analysis (DTA) and thermogravimetric analysis (TGA). The optical characteristics were investigated via UV–visible spectroscopy, which investigated included the transmittance, absorbance, absorption coefficient, band gap (E<sub>g</sub>), penetration depth (β), Urbach energy (E<sub>U</sub>), refractive index, optical conductivity, and dielectric function. These findings indicate that the optical properties improved after the addition of Fe<sub>2</sub>O<sub>3</sub> compared with those of pure La<sub>2</sub>W<sub>2</sub>O<sub>9</sub>. The La<sub>2</sub>W<sub>2</sub>O<sub>9</sub>/Fe<sub>2</sub>O<sub>3</sub> composite holds promise as a prospective material for use in the fields of sunscreen products, UV shielding or solar filtration.</div></div>","PeriodicalId":20116,"journal":{"name":"Physica B-condensed Matter","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2024-10-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142442319","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Photoluminescence properties of SnO2 nanoparticles doped with group VI elements (Cr, Mo, W) synthesized by pulsed laser ablation in liquid 在液体中通过脉冲激光烧蚀合成的掺杂 VI 族元素(铬、钼、钨)的 SnO2 纳米粒子的光致发光特性
IF 2.8 3区 物理与天体物理
Physica B-condensed Matter Pub Date : 2024-10-12 DOI: 10.1016/j.physb.2024.416625
{"title":"Photoluminescence properties of SnO2 nanoparticles doped with group VI elements (Cr, Mo, W) synthesized by pulsed laser ablation in liquid","authors":"","doi":"10.1016/j.physb.2024.416625","DOIUrl":"10.1016/j.physb.2024.416625","url":null,"abstract":"<div><div>Tin oxide nanoparticles (SnO<sub>2</sub> NPs), both pure and doped with Group VI (G6) metal ions (Cr<sup>+3</sup>, Mo<sup>+5</sup>, and W<sup>+6</sup>), were synthesized using pulsed laser ablation in liquid. This study aimed to investigate the effect of G6 doping on the electronic properties of SnO<sub>2</sub> NPs, with an emphasis on enhancing their photoluminescence for optoelectronic applications. Transmission electron microscopy revealed well-crystallized samples with diameters of 3–6 nm, indicating quantum-confinement effects. The optical band gap, determined by UV–Vis spectroscopy, was reduced from 5.1 <em>e</em>V (undoped) to 4.9 <em>e</em>V (Cr-doped) due to defect states, while increasing to 5.3 <em>e</em>V and 5.7 <em>e</em>V for Mo- and W-doped SnO<sub>2</sub>, respectively, due to the Moss-Burstein effect. The photoluminescence spectra exhibited a redshift, with strong red emission around 700 nm, which was up to 90 % more intense than that of the undoped SnO<sub>2</sub>. This enhancement was attributed to the <sup>2</sup>E→<sup>4</sup>A<sub>2</sub> transition and increased defect states.</div></div>","PeriodicalId":20116,"journal":{"name":"Physica B-condensed Matter","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2024-10-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142446536","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Gradient distribution of cations in rhabdophane La0.27Y0.73PO4·nH2O nanoparticles 阳离子在La0.27Y0.73PO4-nH2O纳米颗粒中的梯度分布
IF 2.8 3区 物理与天体物理
Physica B-condensed Matter Pub Date : 2024-10-12 DOI: 10.1016/j.physb.2024.416623
{"title":"Gradient distribution of cations in rhabdophane La0.27Y0.73PO4·nH2O nanoparticles","authors":"","doi":"10.1016/j.physb.2024.416623","DOIUrl":"10.1016/j.physb.2024.416623","url":null,"abstract":"<div><div>The structure of gradient rhabdophane nanoparticles of variable composition (La,Y)PO<sub>4</sub>·<em>n</em>H<sub>2</sub>O obtained by precipitation is considered. According to the data of HAADF TEM and EDX mapping using the Abel inversion procedure, it was shown that there is an inhomogeneous distribution of yttrium and lanthanum atoms in the particles from the central part to the periphery. At the same time, the nominal composition of both individual nanoparticles and the entire sample meets the value specified during synthesis within the error of the method – La<sub>0.27</sub>Y<sub>0.73</sub>PO<sub>4</sub>·<em>n</em>H<sub>2</sub>O. According to SAXS data, it was determined that in the particles of (La,Y)PO<sub>4</sub>·<em>n</em>H<sub>2</sub>O, there is a redistribution of scattering densities, which is caused by an increase in the fraction of YPO<sub>4</sub> in the peripheral region of the particles. The observed effect of the distribution of cations over the particle made it possible to determine the size of the gradient layer, which reaches 50 % of the total particle size.</div></div>","PeriodicalId":20116,"journal":{"name":"Physica B-condensed Matter","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2024-10-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142441703","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigation of rare earth metal ions (Sm and Er) doped CoMoO4 polymorphs for photocatalytic dye degradation 掺杂稀土金属离子(Sm 和 Er)的 CoMoO4 多晶体光催化染料降解研究
IF 2.8 3区 物理与天体物理
Physica B-condensed Matter Pub Date : 2024-10-11 DOI: 10.1016/j.physb.2024.416616
{"title":"Investigation of rare earth metal ions (Sm and Er) doped CoMoO4 polymorphs for photocatalytic dye degradation","authors":"","doi":"10.1016/j.physb.2024.416616","DOIUrl":"10.1016/j.physb.2024.416616","url":null,"abstract":"<div><div>Cobalt molybdate (CoMoO<sub>4</sub>) and its rare earth doped variants have emerged as promising photocatalysts for degrading dye pollutants in wastewater. The photocatalysts were prepared using a modified sol-gel method, employing ammonium heptamolybdate tetrahydrate and cobalt (II) nitrate hexahydrate as precursors. The incorporation of samarium and erbium as a dopant was hypothesized to improve the photocatalytic activity of CoMoO<sub>4</sub> by altering its band structure and creating defect sites for improved dye adsorption and degradation. The structural and optical properties of the synthesized photocatalysts were characterized using various techniques. The photocatalytic performance of CoMoO<sub>4</sub>, Sm:CoMoO<sub>4</sub> and Er:CoMoO<sub>4</sub> was evaluated by monitoring the degradation of MB dye under light irradiation. The results reveal that Sm:CoMoO<sub>4</sub> and Er:CoMoO<sub>4</sub> catalysts achieve a degradation efficiencies of 99 % and 97 %, respectively, highlighting the potential of rare earth-doped CoMoO<sub>4</sub> as an efficient photocatalyst for the remediation of dye contaminated wastewater.</div></div>","PeriodicalId":20116,"journal":{"name":"Physica B-condensed Matter","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2024-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142425058","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Anisotropic magnetic entropy change and magnetic critical behavior in van der Waals Fe3GaTe2 范德华Fe3GaTe2中各向异性的磁熵变化和磁临界行为
IF 2.8 3区 物理与天体物理
Physica B-condensed Matter Pub Date : 2024-10-11 DOI: 10.1016/j.physb.2024.416615
{"title":"Anisotropic magnetic entropy change and magnetic critical behavior in van der Waals Fe3GaTe2","authors":"","doi":"10.1016/j.physb.2024.416615","DOIUrl":"10.1016/j.physb.2024.416615","url":null,"abstract":"<div><div>Fe<sub>3</sub>GaTe<sub>2</sub>, with intrinsic magnetism at ambient temperature and high perpendicular magnetic anisotropy, is a promising van der Waals material for 2D-materials-based spintronic devices. Herein, we report the anisotropic magnetocaloric effects and magnetic critical phenomena in Fe<sub>3</sub>GaTe<sub>2</sub> single crystal. Owing to the large anisotropy, magnetic entropy change <span><math><mrow><mo>(</mo><mrow><mo>−</mo><mo>Δ</mo><msub><mi>S</mi><mi>M</mi></msub></mrow><mo>)</mo></mrow></math></span> shows anisotropic character with <span><math><mrow><mo>−</mo><mo>Δ</mo><msubsup><mi>S</mi><mi>M</mi><mi>max</mi></msubsup></mrow></math></span> of 1.67 J kg<sup>−1</sup> K<sup>−1</sup> along the <em>c</em> axis and 1.11 J kg<sup>−1</sup> K<sup>−1</sup> in the <em>ab</em> plane under field change of 5 T. The rotating <span><math><mrow><mo>Δ</mo><msub><mi>S</mi><mi>M</mi></msub></mrow></math></span> from the <em>ab</em> plane to the <em>c</em> axis reaches 0.67 J kg<sup>−1</sup> K<sup>−1</sup> at magnetic field of 5 T. By carefully fitting the <span><math><mrow><mo>−</mo><mo>Δ</mo><msubsup><mi>S</mi><mi>M</mi><mi>max</mi></msubsup></mrow></math></span> and relative cooling power (RCP), we determine their relationships to be <span><math><mrow><mo>−</mo><mo>Δ</mo><msubsup><mi>S</mi><mi>M</mi><mi>max</mi></msubsup><mo>∝</mo><msup><mi>H</mi><mi>n</mi></msup></mrow></math></span> (<em>n</em> = 0.694(1)) and <span><math><mrow><mi>R</mi><mi>C</mi><mi>P</mi><mo>∝</mo><msup><mi>H</mi><mi>m</mi></msup></mrow></math></span> (<em>m</em> = 1.301(3)) for the magnetic field along the <em>c</em>-axis. Further analysis of critical behavior near <em>T</em><sub><em>C</em></sub> reveals critical exponents <em>β</em> = 0.41(1) at <em>T</em><sub><em>C</em></sub> = 341.5(1) K, <em>γ</em> = 1.01(1) at <em>T</em><sub><em>C</em></sub> = 341.6(3) K, and <em>δ</em> = 3.67(15) at <em>T</em><sub><em>C</em></sub> = 340 K, indicating a three-dimensional complex magnetic exchange.</div></div>","PeriodicalId":20116,"journal":{"name":"Physica B-condensed Matter","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2024-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142442317","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
CBD-synthesized Mg-doped CdS thin films for hybrid solar cells and self-powered photodetectors 用于混合太阳能电池和自供电光电探测器的 CBD 合成掺镁 CdS 薄膜
IF 2.8 3区 物理与天体物理
Physica B-condensed Matter Pub Date : 2024-10-11 DOI: 10.1016/j.physb.2024.416622
{"title":"CBD-synthesized Mg-doped CdS thin films for hybrid solar cells and self-powered photodetectors","authors":"","doi":"10.1016/j.physb.2024.416622","DOIUrl":"10.1016/j.physb.2024.416622","url":null,"abstract":"<div><div>Mg-doped CdS samples were deposited via chemical bath deposition onto fluorine-doped tin oxide slides with varying levels of Mg-doping. Structural analysis revealed improved crystal quality in CdS films upon Mg incorporation. Morphological examinations indicated a reduction in grain size alongside appearance of smooth, void-free surfaces particularly evident at 3 % Mg-doping. Mg-doping also resulted in enhanced transparency of CdS films, notably at 3 % and 5 % within the visible spectrum. Efficient exciton dissociation was observed in hybrid solar cells based on 1 % and 3 % Mg-doped CdS, as evidenced by photoluminescence. Top-performing solar cell achieved an efficiency of 0.220 %, nearly seven times that of control device. 5 % Mg-doped CdS-based photodetectors exhibited favorable photosensing characteristics: a responsivity of 0.011 A/W, detectivity of 4.4 × 10<sup>8</sup> Jones, external quantum efficiency of 3.1 %, and rise/decay times of 26/25 ms at zero bias. These findings underscore beneficial effects of Mg-doping on both hybrid solar cell and self-driven photodetector performance.</div></div>","PeriodicalId":20116,"journal":{"name":"Physica B-condensed Matter","volume":null,"pages":null},"PeriodicalIF":2.8,"publicationDate":"2024-10-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142433778","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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