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Ultrahigh pressure phase transition in ice
IF 41.2 1区 材料科学
Nature Materials Pub Date : 2026-09-07 DOI: 10.1038/s41563-026-02732-1
Israel Osmond, Mikhail A. Kuzovnikov, David A. Lewis, Hannah A. Shuttleworth, Tomás Marqueño, Milo J. Dixon, Cerian E. A. Robertson, Vitan Cherepnalkoski, Bihan Wang, Andreas Hermann, Miriam Peña-Alvarez, Ross T. Howie
{"title":"Ultrahigh pressure phase transition in ice","authors":"Israel Osmond, Mikhail A. Kuzovnikov, David A. Lewis, Hannah A. Shuttleworth, Tomás Marqueño, Milo J. Dixon, Cerian E. A. Robertson, Vitan Cherepnalkoski, Bihan Wang, Andreas Hermann, Miriam Peña-Alvarez, Ross T. Howie","doi":"10.1038/s41563-026-02732-1","DOIUrl":"https://doi.org/10.1038/s41563-026-02732-1","url":null,"abstract":"One of the most enduring problems in dense H2O ice has been the experimental realization of the pressure-induced symmetry breaking of cubic ice X to an orthorhombic crystal structure. Here, through diamond anvil cell experiments combined with synchrotron X-ray diffraction and Raman spectroscopy techniques, we demonstrate that post-symmetrization, the crystal structure of ice X continuously distorts with pressure. Subjecting ice to pressures in excess of 308(5) GPa, we observe a first-order phase transition to ice XXII, consistent with the long-predicted phase possessing an orthorhombic crystal structure with Pbcm symmetry. We find that ice XXII is stable to pressures of at least 340(5) GPa.","PeriodicalId":19058,"journal":{"name":"Nature Materials","volume":"29 1","pages":""},"PeriodicalIF":41.2,"publicationDate":"2026-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148899604","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electric-field switching of g-wave phonon chirality in ferroelectric BaTiO3
IF 41.2 1区 材料科学
Nature Materials Pub Date : 2026-09-07 DOI: 10.1038/s41563-026-02737-w
Michael Grimes, Hiroki Ueda, Clifford J. Allington, Carl P. Romao, Kurt Kummer, Puneet Kaur, Li-Shu Wang, Yao-Wen Chang, Jan-Chi Yang, Shih-Wen Huang, Urs Staub
{"title":"Electric-field switching of g-wave phonon chirality in ferroelectric BaTiO3","authors":"Michael Grimes, Hiroki Ueda, Clifford J. Allington, Carl P. Romao, Kurt Kummer, Puneet Kaur, Li-Shu Wang, Yao-Wen Chang, Jan-Chi Yang, Shih-Wen Huang, Urs Staub","doi":"10.1038/s41563-026-02737-w","DOIUrl":"https://doi.org/10.1038/s41563-026-02737-w","url":null,"abstract":"Lattice vibrations carrying angular momentum, known as chiral phonons, offer a route to couple lattice, electronic and magnetic degrees of freedom, but their deterministic control has remained elusive. Here we demonstrate reversible electric-field switching of phonon angular momentum in the technologically relevant ferroelectric BaTiO3. Using circularly dichroic resonant inelastic X-ray scattering, we directly resolve phonon chirality via angular momentum transfer between circularly polarized X-rays and the lattice. We observe a momentum-dependent dichroic response that switches with ferroelectric polarization, establishing a robust and non-volatile gyroelectric effect. The measured dichroism is in quantitative agreement with first-principles calculations. These results establish phonon angular momentum as an electrically controllable degree of freedom and provide a pathway towards phonon-based information and energy technologies.","PeriodicalId":19058,"journal":{"name":"Nature Materials","volume":"2 1","pages":""},"PeriodicalIF":41.2,"publicationDate":"2026-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148899606","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrically programmable polariton symmetry breaking via non-Hermitian dissipation engineering
IF 41.2 1区 材料科学
Nature Materials Pub Date : 2026-09-07 DOI: 10.1038/s41563-026-02734-z
Na Chen, Hanchao Teng, Yifu Sun, Yang Yang, Zhuoxin Xue, Oubo You, Ke Chen, Chengyu Jiang, Junlin Wang, Shenghan Zhou, Xiang Liu, Chong Wang, Zhen-Ze Li, Sheng Meng, Maguang Zhu, Hai Hu, Qing Dai
{"title":"Electrically programmable polariton symmetry breaking via non-Hermitian dissipation engineering","authors":"Na Chen, Hanchao Teng, Yifu Sun, Yang Yang, Zhuoxin Xue, Oubo You, Ke Chen, Chengyu Jiang, Junlin Wang, Shenghan Zhou, Xiang Liu, Chong Wang, Zhen-Ze Li, Sheng Meng, Maguang Zhu, Hai Hu, Qing Dai","doi":"10.1038/s41563-026-02734-z","DOIUrl":"https://doi.org/10.1038/s41563-026-02734-z","url":null,"abstract":"The optical response of natural materials is constrained by crystal symmetry, limiting the design of reconfigurable nanophotonic devices. Here we demonstrate the electrically programmable symmetry breaking of phonon polaritons via non-Hermitian dissipation engineering. In a heterostructure composed of α-MoO3 and aligned carbon nanotubes (A-CNTs), we identify the A-CNT layer as an anisotropic dissipative medium. Driven by overdamped carrier dynamics, the nanotubes preclude polariton hybridization, exerting a proximity-induced resistive coupling instead. Thus, the A-CNT layer operates as a tunable momentum-space loss filter that selectively attenuates propagation along specific crystallographic directions. By electrostatically gating the A-CNTs to regulate their Drude loss, we achieve the continuous and reversible tuning of the polariton topology with transitions from symmetric hyperbolas to asymmetric shear wavefronts. Unlike refractive-index engineering that requires strict wavevector matching, this dissipative filtering mechanism allows for topology shaping without coherent hybridization, establishing dissipation as a programmable degree of freedom in topological nanophotonics and non-Hermitian device physics.","PeriodicalId":19058,"journal":{"name":"Nature Materials","volume":"12 1","pages":""},"PeriodicalIF":41.2,"publicationDate":"2026-09-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148899605","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Octahedral connectivity reconfigures interfacial carrier-selective properties for efficient perovskite solar cells. 八面体连通性重新配置了高效钙钛矿太阳能电池的界面载流子选择特性。
IF 38 1区 材料科学
Nature Materials Pub Date : 2026-09-03 DOI: 10.1038/s41563-026-02722-3
Yalan Zhang, Zheng Liang, Seong Chan Cho, Seong-Ho Cho, Guiming Fu, Xin Chen, Boyuan Liu, Sang-Uk Lee, Jae Hun Seol, Sanwan Liu, Hui Zhang, Kui Zhao, Sang Uck Lee, Xu Pan, Nam-Gyu Park
{"title":"Octahedral connectivity reconfigures interfacial carrier-selective properties for efficient perovskite solar cells.","authors":"Yalan Zhang, Zheng Liang, Seong Chan Cho, Seong-Ho Cho, Guiming Fu, Xin Chen, Boyuan Liu, Sang-Uk Lee, Jae Hun Seol, Sanwan Liu, Hui Zhang, Kui Zhao, Sang Uck Lee, Xu Pan, Nam-Gyu Park","doi":"10.1038/s41563-026-02722-3","DOIUrl":"https://doi.org/10.1038/s41563-026-02722-3","url":null,"abstract":"<p><p>Regulation of electron- or hole-selective interfacial properties has traditionally relied on extrinsic chemical doping. Here we report a structurally driven strategy for modulating carrier-selective electronic characteristics through the organic-cation-induced reconfiguration of lead iodide octahedral connectivity. Two closely related imidazoline-based cations, which differ by only a single heteroatom, drive the formation of one-dimensional organic lead triiodide phases with distinct octahedral-sharing patterns. Single-crystal analysis combined with theoretical calculations reveals that the variation in connectivity reshapes orbital coupling, leading to pronounced changes in the work function and absolute band-edge positions that give rise to distinct carrier-selective interfacial behaviour without the introduction of extrinsic dopants. Leveraging this structural reconfiguration-induced electronic modulation, we realize complementary charge-selective contacts in perovskite solar cells, achieving a power conversion efficiency of 27.61% (certified steady-state 27.19%), together with excellent operational stability and scalability, including 22.26% efficiency in 655-cm<sup>2</sup> modules.</p>","PeriodicalId":19058,"journal":{"name":"Nature Materials","volume":" ","pages":""},"PeriodicalIF":38.0,"publicationDate":"2026-09-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148888012","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A chlorinated organic cation enables stable 2D/3D tin iodide perovskite photovoltaics. 氯化有机阳离子可实现稳定的2D/3D碘化锡钙钛矿光伏发电。
IF 38 1区 材料科学
Nature Materials Pub Date : 2026-09-01 DOI: 10.1038/s41563-026-02726-z
Christopher T Triggs, Lei Chen, Jiahao Xie, Nicholas J Weadock, Zihan Zhang, Jiselle Y Ye, Ross A Kerner, Margherita Taddei, Fengjiu Yang, Bennett Addison, Xiaoming Wang, Tianran Liu, Steven P Harvey, Michael F Toney, Matthew C Beard, Yanfa Yan, Kai Zhu, Song Jin
{"title":"A chlorinated organic cation enables stable 2D/3D tin iodide perovskite photovoltaics.","authors":"Christopher T Triggs, Lei Chen, Jiahao Xie, Nicholas J Weadock, Zihan Zhang, Jiselle Y Ye, Ross A Kerner, Margherita Taddei, Fengjiu Yang, Bennett Addison, Xiaoming Wang, Tianran Liu, Steven P Harvey, Michael F Toney, Matthew C Beard, Yanfa Yan, Kai Zhu, Song Jin","doi":"10.1038/s41563-026-02726-z","DOIUrl":"https://doi.org/10.1038/s41563-026-02726-z","url":null,"abstract":"<p><p>Tin halide perovskites (THPs) offer narrower bandgaps and improved environmental safety compared with the widely studied lead-based perovskites, but their air sensitivity has hindered their progress and demands new material design to enable their practical applications. Here we report stable and efficient 2D/3D tin perovskite solar cells enabled by new ultrastable 2D and quasi-2D THPs based on the 4-chloro-phenethylammonium (4ClPEA) cation. The stronger π-stacking interactions and tighter interlayer packing in (4ClPEA)<sub>2</sub>SnI<sub>4</sub> among (4XPEA)<sub>2</sub>SnI<sub>4</sub> structures (X = H, F, Cl, Br) substantially impede oxygen and water diffusion, enabling superior air and moisture stability and bright photoluminescence lasting several months in ambient air. The addition of 4ClPEA markedly improves 2D/3D THP film crystallinity and orientation, leading to 16.2% efficient 2D/3D THP solar cells that show prolonged storage stability and operational stability at 55 °C surpassing 1,000 h. This study establishes a new strategy for designing stable and efficient THPs towards their practical applications.</p>","PeriodicalId":19058,"journal":{"name":"Nature Materials","volume":" ","pages":""},"PeriodicalIF":38.0,"publicationDate":"2026-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148874196","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The meta way of thinking. 元思维方式。
IF 38 1区 材料科学
Nature Materials Pub Date : 2026-08-31 DOI: 10.1038/s41563-026-02710-7
Alexandre Dmitriev, Magnus P Jonsson, Mark L Brongersma, Nader Engheta, Nicolò Maccaferri
{"title":"The meta way of thinking.","authors":"Alexandre Dmitriev, Magnus P Jonsson, Mark L Brongersma, Nader Engheta, Nicolò Maccaferri","doi":"10.1038/s41563-026-02710-7","DOIUrl":"https://doi.org/10.1038/s41563-026-02710-7","url":null,"abstract":"","PeriodicalId":19058,"journal":{"name":"Nature Materials","volume":" ","pages":""},"PeriodicalIF":38.0,"publicationDate":"2026-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148866174","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Tuning moiré twist angles enhances tensile plasticity in bulk van der Waals crystals. 调节莫尔扭角可提高块状范德华晶体的拉伸塑性。
IF 38 1区 材料科学
Nature Materials Pub Date : 2026-08-31 DOI: 10.1038/s41563-026-02731-2
Jiali Zhou, Jiawei Zou, Zhiqiang Gao, Jiawei Zhang, Linlin Zhang, Zhi Li, Zhengyang Zhou, Pengfei Qiu, Yang Yang, Qian Yu, Lidong Chen, Xun Shi
{"title":"Tuning moiré twist angles enhances tensile plasticity in bulk van der Waals crystals.","authors":"Jiali Zhou, Jiawei Zou, Zhiqiang Gao, Jiawei Zhang, Linlin Zhang, Zhi Li, Zhengyang Zhou, Pengfei Qiu, Yang Yang, Qian Yu, Lidong Chen, Xun Shi","doi":"10.1038/s41563-026-02731-2","DOIUrl":"https://doi.org/10.1038/s41563-026-02731-2","url":null,"abstract":"<p><p>Moiré twisting breaks the inherent symmetry of crystal structures, providing a promising method for tuning emergent quantum phenomena and physical properties in layered materials. Here we demonstrate that moiré twisting can also be harnessed to effectively enhance the tensile plasticity of bulk layered van der Waals crystals. We show that interlayer moiré twisting, spanning a broad range of twist angles commensurate with the crystal's translational symmetry, can be controllably introduced through simple off-axis compression in ternary bulk layered van der Waals crystals. It facilitates efficient stress relaxation under mechanical loading with a further increase in the moiré twist angles and enables a substantial increase by up to 360% in room-temperature macroscopic tensile ductility, reaching 30% tensile strain along the a-b plane. Moreover, moiré twisting occurs only between layers and, thus, negligibly affects the in-plane electronic properties. By establishing tunable moiré twisting as an effective mechanism for plastic deformation, this work provides a broadly applicable strategy for enhancing tensile ductility in bulk layered materials.</p>","PeriodicalId":19058,"journal":{"name":"Nature Materials","volume":" ","pages":""},"PeriodicalIF":38.0,"publicationDate":"2026-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148866218","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Semiconducting polymers assembled to perfection. 完美组装的半导体聚合物。
IF 38 1区 材料科学
Nature Materials Pub Date : 2026-08-31 DOI: 10.1038/s41563-026-02720-5
Ying Diao
{"title":"Semiconducting polymers assembled to perfection.","authors":"Ying Diao","doi":"10.1038/s41563-026-02720-5","DOIUrl":"https://doi.org/10.1038/s41563-026-02720-5","url":null,"abstract":"","PeriodicalId":19058,"journal":{"name":"Nature Materials","volume":" ","pages":""},"PeriodicalIF":38.0,"publicationDate":"2026-08-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148866179","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
From invention to industrialization of materials in Europe. 欧洲的材料从发明到工业化。
IF 38 1区 材料科学
Nature Materials Pub Date : 2026-08-28 DOI: 10.1038/s41563-026-02713-4
Paula Maria Vilarinho, Sean Kelly
{"title":"From invention to industrialization of materials in Europe.","authors":"Paula Maria Vilarinho, Sean Kelly","doi":"10.1038/s41563-026-02713-4","DOIUrl":"https://doi.org/10.1038/s41563-026-02713-4","url":null,"abstract":"","PeriodicalId":19058,"journal":{"name":"Nature Materials","volume":" ","pages":""},"PeriodicalIF":38.0,"publicationDate":"2026-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148851173","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Neural network finds twisted crystals that steer light at the nanoscale. 神经网络发现了扭曲的晶体,可以在纳米尺度上引导光线。
IF 38 1区 材料科学
Nature Materials Pub Date : 2026-08-28 DOI: 10.1038/s41563-026-02744-x
{"title":"Neural network finds twisted crystals that steer light at the nanoscale.","authors":"","doi":"10.1038/s41563-026-02744-x","DOIUrl":"https://doi.org/10.1038/s41563-026-02744-x","url":null,"abstract":"","PeriodicalId":19058,"journal":{"name":"Nature Materials","volume":" ","pages":""},"PeriodicalIF":38.0,"publicationDate":"2026-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148851111","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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