Nature MaterialsPub Date : 2025-04-04DOI: 10.1038/s41563-025-02200-2
Jiajie Qi, Kaihui Liu
{"title":"Boron nitride in AA stacking","authors":"Jiajie Qi, Kaihui Liu","doi":"10.1038/s41563-025-02200-2","DOIUrl":"https://doi.org/10.1038/s41563-025-02200-2","url":null,"abstract":"Controlled growth of suspended boron nitride layers with metastable AA stacking has been realized on gallium nitride wafers, with surface steps aligning the layer orientation and electron doping stabilizing the stacking configuration.","PeriodicalId":19058,"journal":{"name":"Nature Materials","volume":"37 1","pages":""},"PeriodicalIF":41.2,"publicationDate":"2025-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143775407","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Biorhythm-mimicking growth hormone patch","authors":"Jinpeng Han, Zhaoyuan Wu, Shumin Zhan, Tao Sheng, Jiahuan You, Jicheng Yu, Junfen Fu, Yuqi Zhang, Zhen Gu","doi":"10.1038/s41563-025-02188-9","DOIUrl":"https://doi.org/10.1038/s41563-025-02188-9","url":null,"abstract":"<p>Timing dosing throughout the day impacts the therapeutic efficacy and side effects of medications. Thus, optimizing release profiles to synchronize drug concentrations with natural rhythms is critical for optimal therapeutic benefits. However, existing delivery systems are still inefficient in delivering drugs in a biorhythm-mimicking fashion. Here we describe a biorhythm-inspired growth hormone transdermal microneedle patch with multistage drug release that mimics the natural rhythm of human growth hormone secretion at night. Programmed drug release is achieved by combining a ‘burst-release’ module with several ‘delayed-release’ modules. Compared with the subcutaneous daily injections currently used in clinics, the patch exhibits enhanced efficacy in terms of longitudinal bone growth and bone quality, leading to bone length increases of ~10 mm and ~5 mm in healthy rats and growth hormone gene knockout mice, respectively. Our findings reveal that the biorhythm-mimicking release pattern significantly enhances growth hormone bioavailability and effectively regulates the growth-related biological process, thus boosting the secretion of insulin-like growth factor-1 and ultimately promoting bone growth.</p>","PeriodicalId":19058,"journal":{"name":"Nature Materials","volume":"536 1","pages":""},"PeriodicalIF":41.2,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143766997","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nature MaterialsPub Date : 2025-04-03DOI: 10.1038/s41563-025-02197-8
Dimas G. de Oteyza, Bruno de la Torre
{"title":"Spinons in nanographene spin chains","authors":"Dimas G. de Oteyza, Bruno de la Torre","doi":"10.1038/s41563-025-02197-8","DOIUrl":"https://doi.org/10.1038/s41563-025-02197-8","url":null,"abstract":"The excitation spectra of spin-1/2 Heisenberg chains on carbon nanostructures, obtained by on-surface synthesis, are reported.","PeriodicalId":19058,"journal":{"name":"Nature Materials","volume":"73 1","pages":""},"PeriodicalIF":41.2,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143766995","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nature MaterialsPub Date : 2025-04-03DOI: 10.1038/s41563-025-02198-7
Congcheng Wang, Yuhgene Liu, Won Joon Jeong, Timothy Chen, Mu Lu, Douglas Lars Nelson, Elif Pınar Alsaç, Sun Geun Yoon, Kelsey Anne Cavallaro, Sazol Das, Diptarka Majumdar, Rajesh Gopalaswamy, Shuman Xia, Matthew T. McDowell
{"title":"The influence of pressure on lithium dealloying in solid-state and liquid electrolyte batteries","authors":"Congcheng Wang, Yuhgene Liu, Won Joon Jeong, Timothy Chen, Mu Lu, Douglas Lars Nelson, Elif Pınar Alsaç, Sun Geun Yoon, Kelsey Anne Cavallaro, Sazol Das, Diptarka Majumdar, Rajesh Gopalaswamy, Shuman Xia, Matthew T. McDowell","doi":"10.1038/s41563-025-02198-7","DOIUrl":"https://doi.org/10.1038/s41563-025-02198-7","url":null,"abstract":"<p>Dealloying reactions underpin the operation of next-generation battery electrodes and are also a synthesis route for porous metals, but the influence of mechanical stress on these processes is not well understood. Here we investigate how the applied stack pressure affects structural evolution and electrochemical reversibility during the alloying/dealloying of Li alloy materials (Li–Al, Li–Sn, Li–In and Li–Si) using solid-state and liquid electrolytes. The extent of porosity formation during the dealloying of metals is found to be universally governed by stack pressure, with pressures of at least 20% of the yield strength required to achieve ~80% relative density. This concept is correlated to the cycling of alloy electrodes in solid-state batteries, with a yield-strength-dependent threshold pressure needed for reversible high Li-storage capacity due to densification. With this understanding, we design Al and Si anodes with a densified interfacial layer enabling stable cycling at low stack pressures (2 MPa), providing guidance towards practical high-energy solid-state batteries.</p>","PeriodicalId":19058,"journal":{"name":"Nature Materials","volume":"41 1","pages":""},"PeriodicalIF":41.2,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143766998","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Precise synthesis of advanced polyarylamines for efficient perovskite solar cells","authors":"Ziqiu Shen, Yanchun Huang, Yuan Dong, Kangrong Yan, Hongzhen Chen, Chang-Zhi Li","doi":"10.1038/s41563-025-02199-6","DOIUrl":"https://doi.org/10.1038/s41563-025-02199-6","url":null,"abstract":"<p>Although being highly demanded in organic electronics, functional conjugated polymers face challenges on scalable synthesis with batch uniformities. Here a reactivity-regulated sequent cross-coupling carbon–nitrogen polycondensation method is developed to enable the precise synthesis of functional polyarylamines with excellent batch-to-batch uniformity. It is revealed that the stepwise regulation of intermediate reactivities is key to accomplish controllable polycondensation via two sequent palladium-promoted carbon–nitrogen coupling cycles, which is distinct to the unicyclic carbon–carbon coupling. A variety of polyarylamines are prepared to improve the material functionalities, where a ternary polymer consisting of polar substituents is shown to optimize the interfacial and bulk properties of perovskite layers fabricated on top. The corresponding inverted perovskite solar cells achieved remarkable power conversion efficiencies of 25.2% (active area, 5.97 mm<sup>2</sup>) and 23.2% (active area, 128 mm<sup>2</sup>), along with decent operational stabilities. Overall, this work provides an effective polymerization method for advanced conjugated polymers to enable high-performance optoelectronics.</p>","PeriodicalId":19058,"journal":{"name":"Nature Materials","volume":"71 1","pages":""},"PeriodicalIF":41.2,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143766996","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nature MaterialsPub Date : 2025-04-02DOI: 10.1038/s41563-025-02196-9
Yi Jiang, He Lin, Jin-Qiang Pan, Jia-Ling Zhang, Hoi Lam Tam, King Fai Li, Qi Wei, Sheung Mei Ng, Chee Leung Mak, Yong Jie Huang, Yang Wang, Zhan-Bo Jia, Xiang-Chun Li, Luying Yi, Ifor D. W. Samuel, Kok Wai Cheah, Xiaogang Liu, Wei Huang, Wen-Yong Lai
{"title":"Giant nonlinear Raman responses from organic semiconductors","authors":"Yi Jiang, He Lin, Jin-Qiang Pan, Jia-Ling Zhang, Hoi Lam Tam, King Fai Li, Qi Wei, Sheung Mei Ng, Chee Leung Mak, Yong Jie Huang, Yang Wang, Zhan-Bo Jia, Xiang-Chun Li, Luying Yi, Ifor D. W. Samuel, Kok Wai Cheah, Xiaogang Liu, Wei Huang, Wen-Yong Lai","doi":"10.1038/s41563-025-02196-9","DOIUrl":"https://doi.org/10.1038/s41563-025-02196-9","url":null,"abstract":"<p>Organic semiconductors exhibit unique semiconducting behaviour due to <i>π-</i>electron delocalization along their molecular chains, making them attractive for various optoelectronic applications. However, their low optical damage thresholds have limited their use in nonlinear optics, particularly in stimulated Raman scattering. Here we demonstrate a general method to significantly amplify molecular vibrations in organic semiconductors by utilizing spectrally tailored gain from stimulated emission, bypassing the necessity for traditional optical cavities. This method achieves Raman thresholds as low as ~10–50 μJ cm<sup>−</sup><sup>2</sup> or ~2–10 kW cm<sup>−</sup><sup>2</sup>, outperforming current Raman lasers by four orders of magnitude. The resulting nonlinear Raman response leads to cascaded Raman emission characterized by pump-dependent emission efficiency, a nonlinearity factor of 3.8, a signal-to-noise ratio of 30.9 dB and a bandwidth of 110 nm. Our study opens exciting prospects for the development of compact, efficient Raman amplifiers and lasers, leveraging the unique properties of organic semiconductors for advanced photonic applications, including high-sensitivity spectroscopy and versatile frequency conversion technologies.</p>","PeriodicalId":19058,"journal":{"name":"Nature Materials","volume":"73 1","pages":""},"PeriodicalIF":41.2,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143758562","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nature MaterialsPub Date : 2025-04-02DOI: 10.1038/s41563-025-02168-z
Anmin Nie, Zhisheng Zhao, Bo Xu, Yongjun Tian
{"title":"Microstructure engineering in diamond-based materials","authors":"Anmin Nie, Zhisheng Zhao, Bo Xu, Yongjun Tian","doi":"10.1038/s41563-025-02168-z","DOIUrl":"https://doi.org/10.1038/s41563-025-02168-z","url":null,"abstract":"<p>Diamond possesses a suite of extraordinary properties, including unparalleled hardness, excellent thermal conductivity, a wide bandgap and optical transparency. These features render it essential for a broad spectrum of scientific and industrial applications. However, the inherent brittleness and limited toughness of diamond have posed substantial barriers to broader technological integration. Recent advances have demonstrated that engineered structural configurations—including nanotwinned diamond architectures, hierarchically structured nanotwinned diamond composites, graphite–diamond hybrids, diamond–graphene composites and amorphous diamond phases—can overcome these conventional limitations, exhibiting superior mechanical and physical properties. This Review examines the latest developments in diamond and its derivative materials, focusing on microstructural design strategies, phase transition mechanisms, opportunities to enhance properties and emergent phenomena. We also outline promising research directions and potential applications for diamond-based materials, advancing the frontiers of diamond-based technologies.</p>","PeriodicalId":19058,"journal":{"name":"Nature Materials","volume":"58 1","pages":""},"PeriodicalIF":41.2,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143758563","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nature MaterialsPub Date : 2025-04-01DOI: 10.1038/s41563-025-02193-y
Xiaodong Zheng, Shizhe Feng, Chi Shing Tsang, Quoc Huy Thi, Wei Han, Lok Wing Wong, Haijun Liu, Chun-Sing Lee, Shu Ping Lau, Thuc Hue Ly, Zhiping Xu, Jiong Zhao
{"title":"Twist-assisted intrinsic toughening in two-dimensional transition metal dichalcogenides","authors":"Xiaodong Zheng, Shizhe Feng, Chi Shing Tsang, Quoc Huy Thi, Wei Han, Lok Wing Wong, Haijun Liu, Chun-Sing Lee, Shu Ping Lau, Thuc Hue Ly, Zhiping Xu, Jiong Zhao","doi":"10.1038/s41563-025-02193-y","DOIUrl":"https://doi.org/10.1038/s41563-025-02193-y","url":null,"abstract":"<p>Material fractures are typically irreversible, marking a one-time event leading to failure. Great efforts have been made to enhance both strength and fracture toughness of bulk materials for engineering applications, such as by introducing self-recovery and secondary breaking behaviours. In low-dimensional structures, two-dimensional materials often exhibit exceptional strength but accompanied by extreme brittleness. Here we discover that the toughness of two-dimensional materials can be enhanced without sacrificing strength—by simply twisting the layers. Through in situ scanning transmission electron microscopy, supported by nanoindentation and theoretical analysis, we reveal that twisted bilayer structures enable sequential fracture events: initial cracks heal to form stable grain boundaries, which then shield subsequent fracture tips from stress concentration. This process consumes additional energy compared with conventional fracture, with toughness enhancement tunable through twist angle adjustment. The intrinsic toughening mechanism via twisting, along with the emerging electronic properties of twistronics that are currently attracting substantial attention, presents an exciting opportunity for future devices.</p>","PeriodicalId":19058,"journal":{"name":"Nature Materials","volume":"96 1","pages":""},"PeriodicalIF":41.2,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143744807","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nature MaterialsPub Date : 2025-04-01DOI: 10.1038/s41563-025-02201-1
Taketo Handa, Chun-Ying Huang, Yiliu Li, Nicholas Olsen, Daniel G. Chica, David D. Xu, Felix Sturm, James W. McIver, Xavier Roy, Xiaoyang Zhu
{"title":"Terahertz emission from giant optical rectification in a van der Waals material","authors":"Taketo Handa, Chun-Ying Huang, Yiliu Li, Nicholas Olsen, Daniel G. Chica, David D. Xu, Felix Sturm, James W. McIver, Xavier Roy, Xiaoyang Zhu","doi":"10.1038/s41563-025-02201-1","DOIUrl":"https://doi.org/10.1038/s41563-025-02201-1","url":null,"abstract":"<p>The exfoliation and stacking of two-dimensional van der Waals crystals have created unprecedented opportunities in the discovery of quantum phases. A major obstacle to the advancement of this field is the limited spectroscopic access due to a mismatch in the sample sizes (10<sup>−6</sup>–10<sup>−5</sup> m) and the wavelengths (10<sup>−4</sup>–10<sup>−3</sup> m) of electromagnetic radiation relevant to their low-energy excitations. Here we introduce ferroelectric semiconductor NbOI<sub>2</sub> as a two-dimensional van der Waals material capable of operating as a van der Waals terahertz emitter. We demonstrate intense and broadband terahertz generation from NbOI<sub>2</sub> with an optical rectification efficiency that is more than one order of magnitude higher than that of ZnTe, the current standard terahertz emitter. Moreover, this NbOI<sub>2</sub> terahertz emitter can be integrated into van der Waals heterostructures to enable on-chip near-field terahertz spectroscopy of a target van der Waals material and device. Our approach provides a general spectroscopic tool for two-dimensional van der Waals materials and quantum matter.</p>","PeriodicalId":19058,"journal":{"name":"Nature Materials","volume":"58 1","pages":""},"PeriodicalIF":41.2,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143744810","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nature MaterialsPub Date : 2025-04-01DOI: 10.1038/s41563-025-02178-x
Dennis H. C. Lin, Cesar Javier Lockhart de la Rosa
{"title":"Searching for a two-dimensional silver bullet","authors":"Dennis H. C. Lin, Cesar Javier Lockhart de la Rosa","doi":"10.1038/s41563-025-02178-x","DOIUrl":"10.1038/s41563-025-02178-x","url":null,"abstract":"Two-dimensional-materials-based gate-all-around field-effect transistors are demonstrated at the wafer scale using the high-mobility two-dimensional semiconductor Bi2O2Se and its native oxide dielectric Bi2SeO5, enabling promising performance and energy efficiency for monolithic three-dimensional integrated circuits beyond silicon.","PeriodicalId":19058,"journal":{"name":"Nature Materials","volume":"24 4","pages":"474-475"},"PeriodicalIF":37.2,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143744724","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}