Nanostructured MaterialsPub Date : 1999-11-01Epub Date: 2000-05-19DOI: 10.1016/S0965-9773(99)00403-1
J Guerrero-Paz , D Jaramillo-Vigueras
{"title":"Nanometric grain formation in ductile powders by low-energy ball milling","authors":"J Guerrero-Paz , D Jaramillo-Vigueras","doi":"10.1016/S0965-9773(99)00403-1","DOIUrl":"10.1016/S0965-9773(99)00403-1","url":null,"abstract":"<div><p>Based on microstructural observations by TEM<span><span> and in particle size distribution done by sedimentation-photometry, a new </span>grain size refinement mechanism for ductile powders in mechanical alloying is proposed. A 90–95% of the particle population was of submicrometric fragmented particles. These were detected from the beginning of the milling process up to 90 ks. It seems that the fragmentation of the original particles occurred under dynamic conditions to generate those submicrometric ones. Under these conditions the original grain size (100 nm to 350 nm) was preserved and a low level of dislocations was observed at these submicrometric particles. Once these submicrometric particles were deformed, grains smaller than 20 nm were observed. It seems from TEM results that the submicrometric fragmented particles were also deformed under dynamic conditions. This could be a new grain size refinement mechanism present in ductile metallic powder systems where the fragmentation is the dominant stage from the beginning of the milling up to some intermediate milling time.</span></p><p>In the Cu-20at%Ni, Cu and Ni systems where the particle coalescence process was the dominant stage during all the milling process, a derivation of the mechanism proposed by Hellstern [3] was identified. In our case, powders were mainly deformed by slip and not by shear.</p><p>It recognizes that the way to refine the grain size in milled powders is influenced at least by the metallic system used as well as by the equipment and the process conditions employed.</p></div>","PeriodicalId":18878,"journal":{"name":"Nanostructured Materials","volume":"11 8","pages":"Pages 1123-1132"},"PeriodicalIF":0.0,"publicationDate":"1999-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S0965-9773(99)00403-1","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86839814","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nanostructured MaterialsPub Date : 1999-11-01Epub Date: 2000-05-19DOI: 10.1016/S0965-9773(99)00405-5
A Krell , H Ma
{"title":"Nanocorundum—advanced synthesis and processing","authors":"A Krell , H Ma","doi":"10.1016/S0965-9773(99)00405-5","DOIUrl":"https://doi.org/10.1016/S0965-9773(99)00405-5","url":null,"abstract":"<div><p>Inorganic and organic approaches for the synthesis of nanocorundum powders and products are described on a scale of 50 g batches. The median particle size of the volume distribution of redispersed powders is about 50 nm after calcination<span> at T < 950 °C. A key issue of advanced processing is the preparation of dense sintered bodies at a sintering temperature<span> < 1300 °C with a submicrometer grain size; the bodies are large enough to enable the measurement of a Vickers macrohardness > 21 GPa at a testing load of 10 kg. Porous sintered corundum bodies with an average pore size between 15 and 60 nm and a porosity of about 40–55% have been produced within the framework of the described synthesis by both powder or sol/gel technologies for the use as chemically highly stable filtration membranes or as catalyst supports. Other applications are amorphous or crystalline nanoporous products with average pore sizes of about 1 nm.</span></span></p></div>","PeriodicalId":18878,"journal":{"name":"Nanostructured Materials","volume":"11 8","pages":"Pages 1141-1153"},"PeriodicalIF":0.0,"publicationDate":"1999-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S0965-9773(99)00405-5","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91746790","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
H. Frase, R. Shull, L. Hong, T. A. Stephens, Z. Gao, B. Fultz
{"title":"Soft magnetic properties of nanocrystalline Ni3Fe and Fe75Al12.5Ge12.5","authors":"H. Frase, R. Shull, L. Hong, T. A. Stephens, Z. Gao, B. Fultz","doi":"10.1016/S0965-9773(00)00430-X","DOIUrl":"https://doi.org/10.1016/S0965-9773(00)00430-X","url":null,"abstract":"","PeriodicalId":18878,"journal":{"name":"Nanostructured Materials","volume":"22 1","pages":"987-993"},"PeriodicalIF":0.0,"publicationDate":"1999-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"77970772","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nanostructured MaterialsPub Date : 1999-11-01Epub Date: 2000-05-19DOI: 10.1016/S0965-9773(99)00399-2
Joshy Jose , M.Abdul Khadar
{"title":"Impedance spectroscopic analysis of AC response of nanophase ZnO and ZnO-Al2O3 nanocomposites","authors":"Joshy Jose , M.Abdul Khadar","doi":"10.1016/S0965-9773(99)00399-2","DOIUrl":"https://doi.org/10.1016/S0965-9773(99)00399-2","url":null,"abstract":"<div><p><span>Nanoparticles of ZnO and Al</span><sub>2</sub>O<sub>3</sub> were prepared by chemical arrested precipitation. The average particle size was determined from x-ray line broadening and TEM. The ac electrical response of the consolidated nanoparticles of ZnO and ZnO-Al<sub>2</sub>O<sub>3</sub><span> nanocomposites was studied using impedance spectroscopic technique. The equivalent circuit parameters were determined by computer simulation. The grain and grain boundary contributions to the conductivity were determined and the difference in the conductivity was attributed to the grain boundary properties of nanomaterials. The variation in conductivity of nanocomposites with weight percentage of Al</span><sub>2</sub>O<sub>3</sub><span> was attributed to the change in interfacial defect structure<span>, band structure modifications and compensation of oxygen vacancies.</span></span></p></div>","PeriodicalId":18878,"journal":{"name":"Nanostructured Materials","volume":"11 8","pages":"Pages 1091-1099"},"PeriodicalIF":0.0,"publicationDate":"1999-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S0965-9773(99)00399-2","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91746238","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nanostructured MaterialsPub Date : 1999-11-01Epub Date: 2000-05-19DOI: 10.1016/S0965-9773(99)00416-X
M Monagheddu , F Delogu , L Schiffini , R Frattini , S Enzo
{"title":"Local icosahedral symmetries in Al-Mo alloys prepared by ball milling","authors":"M Monagheddu , F Delogu , L Schiffini , R Frattini , S Enzo","doi":"10.1016/S0965-9773(99)00416-X","DOIUrl":"https://doi.org/10.1016/S0965-9773(99)00416-X","url":null,"abstract":"<div><p>Annealing products of mechanically treated Al<sub>75</sub>Mo<sub>25</sub><span> powders have been studied by X-ray powder diffraction with the Rietveld method. The differential scanning calorimetry<span> traces of as-milled powders showed transformation features whose temperature decreased as a function of mechanical treatment time. Different phases were identified across the calorimetric events, which were also reported in the high-temperature phase diagram of the Al-Mo system, such as Al</span></span><sub>12</sub>Mo, Al<sub>5</sub>Mo, Al<sub>4</sub>Mo, Al<sub>3</sub>Mo and Al<sub>22</sub>Mo<sub>5</sub><span>. Nevertheless, the solid state transformation processes activated in the calorimeter at ambient pressure are of different nature with respect to those observed by means of neutron diffraction during in situ annealing under vacuum. In the specimen mechanically alloyed for 32 hours the Al</span><sub>12</sub>Mo phase was observed after annealing with both processes. In the crystal geometry of Al<sub>12</sub>Mo, which is regarded as a first order approximation of the quasi-crystalline phase, the molybdenum atoms are arranged in a BCC fashion and are surrounded icosahedrally by twelve aluminum atoms.</p></div>","PeriodicalId":18878,"journal":{"name":"Nanostructured Materials","volume":"11 8","pages":"Pages 1253-1261"},"PeriodicalIF":0.0,"publicationDate":"1999-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S0965-9773(99)00416-X","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"91746579","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Surfaces of doped nanophase cerium oxide catalysts","authors":"A. Palmqvist, M. Wirde, U. Gelius, M. Muhammed","doi":"10.1016/S0965-9773(00)00431-1","DOIUrl":"https://doi.org/10.1016/S0965-9773(00)00431-1","url":null,"abstract":"","PeriodicalId":18878,"journal":{"name":"Nanostructured Materials","volume":"17 1","pages":"995-1007"},"PeriodicalIF":0.0,"publicationDate":"1999-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"88021105","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Structural relaxation of residual amorphous matrix and modulus oscillation in nanocrystalline FeSiNbCuB ribbons","authors":"C. Shek, X. Hu, G. M. Lin, J. Lin","doi":"10.1016/S0965-9773(99)00404-3","DOIUrl":"https://doi.org/10.1016/S0965-9773(99)00404-3","url":null,"abstract":"","PeriodicalId":18878,"journal":{"name":"Nanostructured Materials","volume":"18 1","pages":"1133-1140"},"PeriodicalIF":0.0,"publicationDate":"1999-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"86050562","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Mechanical alloying of the Ti-Al system in atmosphere of hydrogen and argon","authors":"A. Takasaki, Y. Furuya","doi":"10.1016/S0965-9773(99)00411-0","DOIUrl":"https://doi.org/10.1016/S0965-9773(99)00411-0","url":null,"abstract":"","PeriodicalId":18878,"journal":{"name":"Nanostructured Materials","volume":"137 1","pages":"1205-1217"},"PeriodicalIF":0.0,"publicationDate":"1999-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76739657","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Comparison of grain size distributions obtained by XRD and TEM in milled FCC powders","authors":"J. Guerrero-Paz, D. Jaramillo-Vigueras","doi":"10.1016/S0965-9773(99)00410-9","DOIUrl":"https://doi.org/10.1016/S0965-9773(99)00410-9","url":null,"abstract":"","PeriodicalId":18878,"journal":{"name":"Nanostructured Materials","volume":"42 1","pages":"1195-1204"},"PeriodicalIF":0.0,"publicationDate":"1999-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"74941990","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}