Materials SciencePub Date : 2024-03-16DOI: 10.1007/s11003-024-00787-6
V. YA. Suprun, V. I. Marukha, V. P. Sylovanyuk
{"title":"Use of Polyols of Petroleum Chemical Processing as Raw Materials for the Synthesis of Polyurethanes","authors":"V. YA. Suprun, V. I. Marukha, V. P. Sylovanyuk","doi":"10.1007/s11003-024-00787-6","DOIUrl":"https://doi.org/10.1007/s11003-024-00787-6","url":null,"abstract":"<p>Polyurethanes (PU) are unique heteropolymers with a wide range of physicomechanical properties, fields of use and high development potential. PU is obtained by condensation of diisocyanate and various polyol compounds. The peculiarities of the structure and synthesis of commercial polyols based on the products of secondary oil processing, namely oligomeric glycols, oxides and dicarboxylic acids are presented.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":null,"pages":null},"PeriodicalIF":0.9,"publicationDate":"2024-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140155582","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-03-16DOI: 10.1007/s11003-024-00782-x
{"title":"Strength of the Welded Joint of the Connecting Pipe and the Collector of the Boiler Primary Steam Superheater","authors":"","doi":"10.1007/s11003-024-00782-x","DOIUrl":"https://doi.org/10.1007/s11003-024-00782-x","url":null,"abstract":"<p>The strength of the welded joint of the connecting pipe and the collector made of 12Kh1MF steel is investigated within the framework of the model of elastic solid, taking into account their real geometry and the dependence of the material characteristics on temperature. Zones of the maximum operating stresses in the joint for different types of welding are identified. Design and technological solutions aimed at significant reduction of the maximum operational stresses are proposed.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":null,"pages":null},"PeriodicalIF":0.9,"publicationDate":"2024-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140155586","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-03-16DOI: 10.1007/s11003-024-00785-8
{"title":"The Influence of the Initial Clearance on the Fracture of Bolted Joints of Composite Materials","authors":"","doi":"10.1007/s11003-024-00785-8","DOIUrl":"https://doi.org/10.1007/s11003-024-00785-8","url":null,"abstract":"<p>The results of experiments studying the dependence of contact angles for different initial clearances in a bolted joint on loading are presented. Considering the change of the interacting surface area of the composite plates with a pin, the bearing capacity of the hole is determined. The modified correlation algorithm for digital image processing is used to obtain the experimental results.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":null,"pages":null},"PeriodicalIF":0.9,"publicationDate":"2024-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140156941","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-03-16DOI: 10.1007/s11003-024-00781-y
S. A. Luzan, V. A. Bantkovskiy
{"title":"Structure and Tribotechnical Properties of Deposited Composite Layers Based on PG 10N-01 Alloy Containing AL2O3","authors":"S. A. Luzan, V. A. Bantkovskiy","doi":"10.1007/s11003-024-00781-y","DOIUrl":"https://doi.org/10.1007/s11003-024-00781-y","url":null,"abstract":"<p>The microstructure of deposited layers with a composite material (CM) based on the self-fluxing PG-10N-01 alloy, modified with a mechanoactivated CM obtained using the self-propagating hightemperature synthesis, was studied. The X-ray phase analysis revealed in the deposited layer structure the inclusions of nickel borides NiB , Ni<sub>2</sub>B , Ni<sub>3</sub>B , chromium borides CrB , Cr<sub>2</sub>B , chromium carbides Cr<sub>3</sub>C<sub>2</sub> , Cr<sub>7</sub>C<sub>3</sub> , distributed in the nickel matrix. The modifying CM during arc welding contributed to the grinding of structure and reduction of the friction coefficient, increase of the microhardness of the deposited coatings, and decrease of the wear intensity in various friction conditions.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":null,"pages":null},"PeriodicalIF":0.9,"publicationDate":"2024-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140155549","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-03-16DOI: 10.1007/s11003-024-00777-8
A. M. Syrotyuk, R. L. Leshchak, M. V. Hrynenko, N. T. Hembara
{"title":"Evaluation of Hydrogen Embrittlement Risk of Long-Term Operated Gas Pipelines Made of 10G2BT Steel","authors":"A. M. Syrotyuk, R. L. Leshchak, M. V. Hrynenko, N. T. Hembara","doi":"10.1007/s11003-024-00777-8","DOIUrl":"https://doi.org/10.1007/s11003-024-00777-8","url":null,"abstract":"<p>It was established that the metal of long-term operated gas pipelines made of 10G2BT steel contains relatively little hydrogen, which does not create prerequisites for the pipes hydrogen embrittlement. However, for the considered cases, it was established that the microstructure of steel is characterized by increased defectiveness, which increases with the extension of the pipeline operation time. Such a defective microstructure has an increased ability of absorbing hydrogen, and therefore there is a risk of hydrogen embrittlement of the material. It was concluded that the use of long-term operated pipelines for transportation mixtures of natural gas and hydrogen without additional verification is problematic.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":null,"pages":null},"PeriodicalIF":0.9,"publicationDate":"2024-03-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140155585","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Thi Hong Thu Nguyen, Sohyeon Sung, Q. Tran, Young-Sang Cho
{"title":"Synthesis of Monodisperse Silica Nanospheres and Titania Beads from Rotating Cylinder System","authors":"Thi Hong Thu Nguyen, Sohyeon Sung, Q. Tran, Young-Sang Cho","doi":"10.5755/j02.ms.34423","DOIUrl":"https://doi.org/10.5755/j02.ms.34423","url":null,"abstract":"Economic raw materials such as low-grade ethanol and Tetraethyl Ortosilicate (TEOS) were adopted as reactants for the synthesis of monodisperse silica nanospheres using a Taylor Vortex flow reactor with a rotating cylinder system. Factors affecting the mean diameter and size distribution of the silica grains were investigated by changing the rotating speed of the inner cylinder and the composition of reactants. In the case of titania beads, grain diameter size was adjusted by changing the amount of precursor (titanium (IV) isopropoxide, TIP), hexadecylamine (HDA) or Potassium Chloride (KCl) and reaction temperature as well as the rotation speed of the cylinder. As a demonstrative application, titania beads could be used for the removal of organic dye as a model contaminant dissolved in an aqueous medium using a photocatalytic decomposition system.","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":null,"pages":null},"PeriodicalIF":0.9,"publicationDate":"2024-03-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140246612","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-03-11DOI: 10.1007/s11003-024-00775-w
A. V. Moltasov, A. V. Klymenko
{"title":"The Influence of Corrosion Dissolution of the Metal Surface Layer on the Stress Concentration Factor in Butt-Welded Joins","authors":"A. V. Moltasov, A. V. Klymenko","doi":"10.1007/s11003-024-00775-w","DOIUrl":"https://doi.org/10.1007/s11003-024-00775-w","url":null,"abstract":"<p>The dissolution of the metal surface layer of butt-welded joints samples made of 09G2S steel by the anodic-cathodic process in the electrolyte, as a result of which the geometric parameters of the welded joint changed, was studied. For example, after corrosion tests the radius of transition from the weld metal to the base metal on the facial side of the joint increased from 3.07 to 3.88 mm, and on its root, side increased from 2.16 to 3.09 mm. Changes in the geometrical parameters of a welded joint affect the value of the stress concentration factors (SCF), which determine fatigue life of the welded joints Therefore, analytical calculations of the SCF in the sample of the 09G2S steel butt-weld before and after dissolution of the metal surface layer were performed. In this case, the existing formula for SCF determination on the root side of the joint was modified for the case when the bases of facial and root reinforcements were close enough. It was found that after corrosion dissolution of the metal surface layer, the maximum value of the SCF in the specimen decreased from 1.87 to 1.67.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":null,"pages":null},"PeriodicalIF":0.9,"publicationDate":"2024-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140098121","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-03-11DOI: 10.1007/s11003-024-00771-0
L. I. Muravsky
{"title":"Determination of the Surface Displacement Field under Dynamic Loads by the Method of Phase-Shifting Correlation Speckle Pattern Interferometry","authors":"L. I. Muravsky","doi":"10.1007/s11003-024-00771-0","DOIUrl":"https://doi.org/10.1007/s11003-024-00771-0","url":null,"abstract":"<p>A brief review of known digital speckle pattern interferometry methods for retrieving the surface displacement and deformation fields under dynamic loads is presented. A new nondestructive test method of three-step phase-shifting correlation speckle pattern interferometry to study the dynamic loads of structural materials is proposed. In this method three speckle interferograms (SIs) of the specimen surface, differing only by arbitrary unknown phase shifts, are recorded before the loading and one SI is recorded under the dynamic load. The surface displacement field under dynamic loading is determined using the obtained SIs. Two algorithms for the implementation of the method are proposed. They use an integrating bucket technique to record SIs and make it possible to determine the phase maps of the surface displacement fields at any moment of applying the dynamic load. We can use this method to produce a temporal sequence of surface displacement fields during loading.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":null,"pages":null},"PeriodicalIF":0.9,"publicationDate":"2024-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140098119","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-03-11DOI: 10.1007/s11003-024-00774-x
{"title":"Aluminum Alloy Corrosion Inhibition with a Composition of Guar Gum and Potassium Sorbate","authors":"","doi":"10.1007/s11003-024-00774-x","DOIUrl":"https://doi.org/10.1007/s11003-024-00774-x","url":null,"abstract":"<p>High efficiency of corrosion inhibition of aluminum alloy in a 0.1% NaCl solution with a composition of guar gum and potassium sorbate was established. The formation of an organic adsorption film was found on the surface of the metal samples. The degree of metal protection against corrosion by this inhibitory composition was more than 90%. The results of the research can be used for the development of eco-friendly “green” corrosion inhibitors of aluminum alloys from renewable plant materials.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":null,"pages":null},"PeriodicalIF":0.9,"publicationDate":"2024-03-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140097856","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2024-03-08DOI: 10.1007/s11003-024-00772-z
S. I. Gubenko
{"title":"Specific Features of Stresses Relaxation and Recrystallization of Steel under Laser Heating","authors":"S. I. Gubenko","doi":"10.1007/s11003-024-00772-z","DOIUrl":"https://doi.org/10.1007/s11003-024-00772-z","url":null,"abstract":"<p>The features of plastic relaxation and recrystallization processes of steels of various types with different crystal lattices were studied. It was established that structural signs of collective or secondary recrystallization, as well as high-speed shear or rotational plastic deformation, were observed in the laser impact zone. The conditions of the course of these processes associated with the behavior of defects in the crystal structure under pulsed loading were discussed. The conditions of laser action ensured the dynamic processes of restoring the structure of steels.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":null,"pages":null},"PeriodicalIF":0.9,"publicationDate":"2024-03-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140075897","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}