Materials SciencePub Date : 2023-12-28DOI: 10.1007/s11003-023-00736-9
I. M. Pohrelyuk, S. M. Lavrys, V. S. Trush, A. G. Lukyanenko, T. M. Kravchyshyn
{"title":"Effectiveness of Gas Nitriding of Two-Phase Titanium Alloys","authors":"I. M. Pohrelyuk, S. M. Lavrys, V. S. Trush, A. G. Lukyanenko, T. M. Kravchyshyn","doi":"10.1007/s11003-023-00736-9","DOIUrl":"https://doi.org/10.1007/s11003-023-00736-9","url":null,"abstract":"<p>Assessment of the efficiency of two-phase titanium alloys gas nitriding was carried out using metallographic, XRD and durometric analyses. It was ascertained that the higher the β-stabilization factor, the lower the intensity of nitride formation and gas saturation during nitriding. The lowest nitriding efficiency corresponded to VT22 high-alloyed titanium alloy with the highest β-stabilization factor. The main technological (thermocycling) and structural (preliminary deformation or laser treatment) approaches to improve the nitriding efficiency were analyzed.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"100 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2023-12-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139069278","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2023-12-28DOI: 10.1007/s11003-023-00742-x
{"title":"Electrochemical Properties of Plasma-Electrolytically Oxidized Aluminum Coatings Sprayed on MA5 Magnesium Alloy","authors":"","doi":"10.1007/s11003-023-00742-x","DOIUrl":"https://doi.org/10.1007/s11003-023-00742-x","url":null,"abstract":"<p>The aluminum-based coating was sprayed onto a substrate made of MA5 magnesium alloy by detonation and thermal vacuum methods. Potentiodynamic polarization studies were carried out to evaluate corrosion resistance of the modified surfaces. Thermal vacuum coating is non-porous, but thin (approx. 50 μm). The plasma-electrolytic oxidation (PEO) layer of the aluminum coating almost does not interact with the magnesium base during the process of synthesizing the oxide ceramic coating. The corrosion resistance of the detonation coating was twice as high as that of the MA5 magnesium alloy, but the layer synthesized on the PEO coating neutralized this effect. This is related with the growth of the PEO layer through the sprayed coating (thickness approx. 200 μm) to the base and the presence of through pores in it, which over time causes the spalling of such a combined coating. The opposite electrochemical picture is observed on the surface of the thermal vacuum sprayed coating without and with the presence of the PEO layer on it. Here the corrosion currents are lower in 25 times and by 2 orders of magnitude, respectively. Such a significant difference in the corrosion resistance of aluminum coatings is caused by their porosity and structural defects due to the peculiarities of the technological process.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"20 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2023-12-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139069575","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2023-12-27DOI: 10.1007/s11003-023-00752-9
O. P. Kozachok
{"title":"Local Frictional Wear of an Elastic Half-Space with a Regular System of Protrusions","authors":"O. P. Kozachok","doi":"10.1007/s11003-023-00752-9","DOIUrl":"https://doi.org/10.1007/s11003-023-00752-9","url":null,"abstract":"<p>Wear-contact of two elastic half-planes (plain deformation), the surface of one has periodic sloping protrusions of cylindrical shape under local wear on the basis of the frictional-fatigue fracture model is investigated. The formulated contact problem is reduced to a singular integro-differential equation with a Hilbert nucleus with respect to the thickness of the worn material and equations for determining the unknown areas of wear. The shape of the protrusions and contact pressure at the beginning and after wear are analyzed.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"70 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139055129","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2023-12-27DOI: 10.1007/s11003-023-00748-5
N. R. Demchenko, S. V. Trachenko, O. S. Bondar
{"title":"Inhibition of Steel Microbial Corrosion by Quaternary Salts of Imidazoquinolinium","authors":"N. R. Demchenko, S. V. Trachenko, O. S. Bondar","doi":"10.1007/s11003-023-00748-5","DOIUrl":"https://doi.org/10.1007/s11003-023-00748-5","url":null,"abstract":"<p>The 2.3-diaryl-4.5-dihydro-imidazo[1.2-a]quinolinium-3 bromides were tested as biocides and inhibitors of microbial corrosion of low-carbon steel induced by bacteria of <i>Desulfovibrio</i> sp. M-4.1 strain. The degree of metal protection against corrosion induced by sulfate-reducing <i>Desulfovibrio</i> sp. M-4.1 bacteria was 84.6–92.4%. 2-(<i>para</i>-tolyl)-3-(41-methoxyphenyl)-4.5-dihydro-imidazo[1.2-a]quinolinium bromide demonstrated the best protective effect. It was established that sulphate-reducing bacteria of <i>Desulfovibrio</i> sp. M-4.1 strain were sensitive to 2.3-diaryl-4.5-dihydro-imidazo[1.2-a]quinolinium-3 bromides. Under the influence of imidazoquinolinium quaternary salts, the inhibition zones of bacterial growth have the diameters of 24.7–45.5 mm. Quaternary salts of imidazoquinolinium completely suppress the growth of sulfate-reducing <i>Desulfovibrio</i> sp. M-4.1 bacteria in plankton and significantly influence the formation of biofilm (the number of cells decreases by 6–8 orders compared to the control sample) under conditions of microbial corrosion. Suppression of the sulfate-reducing activity of <i>Desulfovibrio</i> sp. M-4.1 bacteria by quaternary salts of imidazoquinolinium (by 88.8–91.6%) was proven. The effectiveness of the quaternary salts was discussed with the account of molecular descriptors.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"7 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139057868","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2023-12-27DOI: 10.1007/s11003-023-00744-9
L. G. Shcherbakova, N. P. Korzhova, T. M. Legka, A. V. Sameluk, I. V. Voskoboinik, V. Kh. Melnyk
{"title":"Corrosion Resistance of Eutectic Al–Mg–Ge Alloys","authors":"L. G. Shcherbakova, N. P. Korzhova, T. M. Legka, A. V. Sameluk, I. V. Voskoboinik, V. Kh. Melnyk","doi":"10.1007/s11003-023-00744-9","DOIUrl":"https://doi.org/10.1007/s11003-023-00744-9","url":null,"abstract":"<p>The influence of alloying on the mechanical and corrosion properties of casting eutectic (α-Al + Mg<sub>2</sub>Ge) aluminum alloys based on the Al–Mg–Ge ternary system was studied. Corrosion dissolution of aluminum alloys in a 3% NaCl solution was studied by electrochemical (voltammetric, chronopotentiometric) and gravimetric methods. It was shown that according to the scale of corrosion resistance these alloys are stable or very stable, and by the combination of corrosion and strength properties can compete with industrial casting aluminum alloys.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"17 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139055258","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2023-12-27DOI: 10.1007/s11003-023-00749-4
{"title":"Corrosion Resistance of Dysprosium Titanate Powders and Pellets in the Model Environment of the WWER-1000 Coolant","authors":"","doi":"10.1007/s11003-023-00749-4","DOIUrl":"https://doi.org/10.1007/s11003-023-00749-4","url":null,"abstract":"<p>The results of autoclave tests of corrosion resistance of dysprosium titanate powders and pellets in the model environment and the parameters of the primary coolant of the WWER-1000 reactor are presented. During exposure in autoclave for up to 500 h, powders are characterized by the decrease in weight, which does not exceed 0.5%, and weight increase depends on powder density. Pellets with the highest density (7.1–7.2 g/cm<sup>3</sup>) are most corrosion resistant and with the density of 5.74–5.79 g/cm<sup>3</sup> powders corrode with the monotonous weight growth under increasing exposure in the autoclave. After 2300 h of autoclaving, the average increase was approx. 156 mg/dm<sup>2</sup> (0.3%). The change in the powders and pellets phase composition of dysprosium titanate after corrosion tests was not detected. Studies of the conditions of defective models of absorbing elements after autoclave tests retain their integrity without changing the linear dimensions. After cutting the absorber elements models, the powders were freely removed from the cladding. The change in the powders’ phase composition also was not revealed.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"148 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139055218","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2023-12-27DOI: 10.1007/s11003-023-00745-8
G. S. Vasyliev, Yu. S. Herasymenko
{"title":"Use of Corrosion Control Device to Control Reagent Water Treatment of Heating Networks","authors":"G. S. Vasyliev, Yu. S. Herasymenko","doi":"10.1007/s11003-023-00745-8","DOIUrl":"https://doi.org/10.1007/s11003-023-00745-8","url":null,"abstract":"<p>Testing of the reagent method of water treatment with the use of corrosion control devices was performed at the district boiler house of Kyiv city. Corrosion rate probes were installed on the straight and return pipelines of the heating network, and on the feed line. The anti-scale efficiency of the reagent was determined by measuring the change in the hardness of water before and after the heating equipment. Corrosion monitoring showed that the corrosion rate in the heating network is maintained at 0.1 mm/year. The corrosion rate on the feed line due to reagent water treatment was reduced to 0.03 mm/year in non-deaerated water. The calculation of economic efficiency has shown that the reagent method of water treatment for heating networks is by 13% cheaper than traditional approach and can serve as an alternative to the traditional one, especially regarding energy conservation.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"8 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139055210","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2023-12-27DOI: 10.1007/s11003-023-00741-y
O. M. Shevchenko, L. D. Kulak, M. M. Kuzmenko, O. Yu. Koval, A. V. Kotko, I. F. Kravchenko, S. O. Firstov
{"title":"The Influence of the Deformation and Heat Treatment on the Structure and Heat-Resistance of Ti–Al–Zr–Si Alloys","authors":"O. M. Shevchenko, L. D. Kulak, M. M. Kuzmenko, O. Yu. Koval, A. V. Kotko, I. F. Kravchenko, S. O. Firstov","doi":"10.1007/s11003-023-00741-y","DOIUrl":"https://doi.org/10.1007/s11003-023-00741-y","url":null,"abstract":"<p>The heat-resistant Ti–Al–Zr–Si alloys (base Ti–(6–7)Al–(2–3) Zr–(1–1.5)Si and additionally alloyed Ti–(6–7)Al–(3–5)Zr–(1–1.5)Si–(2–4)Sn), obtained by electron beam smelting were studied. Deformation was carried out in the β- or upper part of the (α+β)-area by means of forging and rolling into a strip. The base alloy was subjected to rolling in the upper part of the α+β-area, and the fine-grained uniform structure with a grain size of 10–20 μm was obtained. Internal stresses and defective substructure of the deformed alloy intensify the decomposition of the solid solution and promote the formation of evenly distributed dispersed silicides, which allows obtaining high strength and heat resistance characteristics. Tensile tests at 20; 650 and 700°C of the Ti–(6–7)Al–(2–3)Zr–(1–1.5)Si alloy samples after deformation and annealing also showed a rather high level of the tensile strength and yield strength. After 20 h exposure at the operating temperature of 700°C, the structure becomes more equilibrium, due to which the strength of the deformed alloy decreases, and the relative elongation increases. Additional alloying of the base alloy with zirconium and tin slightly increases plasticity and decreases heat-resistant properties.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"64 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139055138","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2023-12-27DOI: 10.1007/s11003-023-00739-6
V. V. Kolomiyets, R. V. Antoshchenko, V. M. Lykyanenko, R. V. Ridnyi, S. O. Kharchenko, I. A. Fabrychnikova, S. A. Bogdanovych, O. A. Svirhun
{"title":"Characteristics of the Quality of Deposited Parts Treatment","authors":"V. V. Kolomiyets, R. V. Antoshchenko, V. M. Lykyanenko, R. V. Ridnyi, S. O. Kharchenko, I. A. Fabrychnikova, S. A. Bogdanovych, O. A. Svirhun","doi":"10.1007/s11003-023-00739-6","DOIUrl":"https://doi.org/10.1007/s11003-023-00739-6","url":null,"abstract":"<p>The quality characteristics of the finishing treatment of deposited materials with cutters made of hard alloy and super hard material (hexanite-R) were investigated. During finishing treatment of the deposited parts, the low roughness of the treated surface was achieved when treated with hexanite-R cutters. The roughness of the treated surface depends on feed, cutting speed, shape of the cutter tip, its wear and hardness of deposited layer. The depth of the surface hardening of the layer treated with cutters is greater than turning the weld materials of low hardness. During turning with hexanite-R cutters compressive residual stresses are formed in the surface layer, which improve the operating characteristics of parts.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"71 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139055333","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Materials SciencePub Date : 2023-12-27DOI: 10.1007/s11003-023-00743-w
T. O. Dergach, G. D. Sukhomlin, L. M. Deyneko, Z.-H. Jiang, J. Tian
{"title":"The Influence of Surface-Active Elements on Grains Boundary Structure and Resistance Against Intergranular Corrosion of Austenitic Cr–Ni and Cr–Ni–Mo Steels","authors":"T. O. Dergach, G. D. Sukhomlin, L. M. Deyneko, Z.-H. Jiang, J. Tian","doi":"10.1007/s11003-023-00743-w","DOIUrl":"https://doi.org/10.1007/s11003-023-00743-w","url":null,"abstract":"<p>The maximum permissiblse content of surface-active elements of carbon, nitrogen and boron in low-carbon Cr–Ni and Cr–Ni–Mo steels, which provide high resistance against intergranular corrosion (IGC) when tested in strongly and weakly oxidizing environments, was established. To ensure high resistance against IGC when tested in boiling 65% HNO<sub>3</sub> (according to ISO 3651-1), the carbon content in 03Kh18N11 (304L) and 03Kh17N14M3 (316L) steels should not exceed 0.025% and 0.015%, respectively, and when tested in boiling H<sub>2</sub>SO<sub>4</sub> (ISO 3651-2, method B) should not exceed 0.03%. The nitrogen amount up to 0.2% does not influence negatively the IGC of the studied steels, and the simultaneous increase of nitrogen and carbon gives a negative synergistic effect. The negative influence of 0.003% and, to a greater extent, 0.03% boron on the grain boundary structure and resistance against IGC of steels hardened at temperatures >1100°C was shown. Technologies for increasing the resistance against IGC of pipes made of the studied steels were developed, taking into account the principle of grain boundary engineering of polycrystalline materials.</p>","PeriodicalId":18230,"journal":{"name":"Materials Science","volume":"13 1","pages":""},"PeriodicalIF":0.9,"publicationDate":"2023-12-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139055379","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}